Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/83—Mixtures of non-ionic with anionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/72—Ethers of polyoxyalkylene glycols
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
  • C11D1/146—Sulfuric acid esters
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/29—Sulfates of polyoxyalkylene ethers
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/38—Cationic compounds
  • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
  • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group

Definitions

• This invention relates to aqueous liquid detergent compositions and particularly to dishwashing compositions incorporating a mixture of anionic and ethoxylated nonionic surfactants.
• Liquid detergent compositions intended for use as dishwashing products conventionally take the form of clear aqueous solutions containing a mixture of one or more sulphate and sulphonate anionic surfactants together with a suds stabilising agent.
• sulphonate surfactants may be of the olefin sulphonate, paraffin sulphonate or most usually alkyl benzene sulphonate type whilst alkyl sulphates and alkyl ether sulphates form the sulphate species commonly employed.
• magnesium cations for at least part of the anionic surfactants present and the disclosures of British Patent Specifications Nos.
• Ethoxylated nonionic surfactants constitute a class of materials capable of solubilising other components in aqueous media but this capability is strongly dependent on their average degree of ethoxylation (E av ).
• Highly ethoxylated nonionic surfactants, (i.e. E av >20) are very hydrophilic in nature and thus tend to reduce the oily soil removal capability of liquid dishwashing detergent formulations, which is undesirable where oil and grease removal is an important criterion of consumer acceptance.
• Highly ethoxylated nonionics having hydrocarbon chain lengths less than C 12 are not readily available commercially, but longer chain length materials having high levels of ethoxylation which are available in bulk (e.g.
• nonionic surfactants having low levels of ethoxylation i. e . E av ⁇ 2
• ethoxylation i. e . E av ⁇ 2
• a feature shared by all ethoxylated nonionic surfactants is the presence of a level of unethoxylated material, the magnitude of which depends on the degree of ethoxylation, but which can constitute up to 20% by weight of the nonionic surfactant.
• Unethoxylated C 6 -C 13 aliphatic primary alcohols are odorous materials having a low water solubility, and these characteristics are discernible in the ethoxylated alcohols to an extent which depends on the level of ethoxylation, the effect diminishing as E av increases.
• ethoxylated alcohol surfactants in particulate laundry detergent formulations makes the odour characteristics of the ethoxylated alcohol of relatively minor importance in such products, particularly granular products for use in automatic washing machines.
• consumers tend to be very aware of the physical characteristics of liquid detergent compositions, particularly those used for dishwashing, because of the manual nature of the task and the greater degree of exposure of the consumer to the hot wash liquor.
• Dishwashing liquid detergent formulations are commercially available containing paraffin sulphonate as the principal anionic species together with ethoxylated nonionic surfactants having E av in the range 2-6 so that such formulations have a measure of aesthetic acceptance by consumers.
• the adverse influence of unethoxylated components in the nonionic surfactant on the phase stability characteristics of liquid dishwashing detergents has been judged to be unacceptable.
• liquid dishwashing detergent compositions containing alkyl sulphates and/or alkyl benzene sulphonates have been found to be subject to odour and storage stability problems when formulated with ethoxylated nonionic surfactants containing the normal spread of ethoxylated species, and this effect is more pronounced when the composition also contains magnesium ions.
• the ethoxylated aliphatic alcohol has an HLB in the range from 8.0 to 17.0 more preferably from 11.0 to 17.0, and most preferably from 11.0 to 15.0.
• the ethoxylated aliphatic alcohol is a C 9 -C 11 primary alcohol condensed with an average of from 6 to 10 moles of ethylene oxide per mole of alcohol.
• the ethoxylated alcohol contains less than 0.7%, most preferably less than 0.5% of unethoxylated material, and in highly preferred compositions the level of mono-ethoxylated C 9 -C 11 alcohol is no more than 5% by weight of the nonionic surfactant.
• Preferred liquid detergent compositions incorporate an alkyl sulphate surfactant and magnesium ions in a molar amount corresponding to at least half of the molar amount of the alkyl sulphate present and contain from 1% to 5% by weight of the ethoxylated alcohol.
• compositions incorporates a three component anionic surfactant system, comprising 8-12% by weight of the composition of C 10 -C 16 primary alkyl sulphate, 9-11% of a C 10 -C 16 primary alkyl ethoxysulphate containing an average of from 1.5 to 3 ethoxy groups per alkyl group, and 13-17% of a C 10 -C 16 alkyl benzene sulphonate.
• the cations in this system are a mixture of ammonium and magnesium ions, the level of magnesium corresponding to approximately one half of the molar amount of alkyl sulphate present.
• compositions employs a two component anionic surfactant system comprising from 4-8% C 10 -C 16 primary alkyl sulphate and from 20-2 5% C 10 -C 16 alkyl ethoxy sulphate containing from 0.5 to 2.0 ethoxy groups per alkyl group.
• compositions in accordance with the invention also contain 2%-8%, most preferably 3%-4% by weight of a suds booster selected from C 10 -C 16 mono and di C 2 - C 3 alkanolamides, and C 8 -C 18 alkyl di C l -C 3 alkyl amine oxides.
• a suds booster selected from C 10 -C 16 mono and di C 2 - C 3 alkanolamides, and C 8 -C 18 alkyl di C l -C 3 alkyl amine oxides.
• Detergent compositions in accordance with the present invention comprise a mixture of anionic surfactants of defined constitution, an amount of from 20% to 50% by weight of the composition, together with an ethoxylated nonionic surfactant having a low content of unethoxylated material.
• compositions in accordance with the invention incorporate an alkyl sulphate and/or an alkyl benzene sulphonate component in combination with an alkyl ethoxy sulphate.
• the alkyl sulphate component is a primary alkyl sulphate in which the alkyl group contains 10-16 carbon atoms, more preferably an average of 12-14 carbon atoms.
• the alkyl group may be linear or branched in configuration.
• Examples of synthetically derived materials include Dobanol 23 (RIM) sold by Shell Chemicals (UK) Ltd, Ethyl 24 sold by the Ethyl Corporation, a blend of C 13 -C 15 alcohols in the ratio 67% C 13 , 33% C 15 sold under the trade name Lutensol by BASF CmbH and Synperonic (RIM) by ICI Ltd, and Lial 125 sold by Liquichimica Italiana.
• Examples of naturally occurring materials from which the alcohols can be derived are coconut oil and palm kernel oil and the corresponding fatty acids.
• the level of the alkyl sulphate component lies in the range of from 4% to 20% by weight of the composition, more generally from 4% to 16% by weight.
• the usage level lies in the range from 8% to 12% by weight, most preferably in the range from 8% to 11% by weight.
• the alkyl sulphate level lies in the range from 12% to 20%, more preferably from 14% to 18% by weight.
• any alkali metal, alkali earth metal, ammonium or substituted ammonium cation can be used in association with the alkyl sulphate.
• the alkyl sulphate is associated with a source of magnesium ions which, as will be described hereinafter, can either be introduced as the oxide or hydroxide to neutralise the acid, or can be added to the composition as a water soluble salt.
• the addition of appreciable levels of magnesium salts to the dishwashing compositions of the invention raises the temperature at which inorganic salt crystals form in the compositions on cooling and is therefore less preferable.
• the molar amount of magnesium ion in the compositions is controlled to correspond to 0.20-0.70X, preferably 0.45-0.55X where X is the number of moles of CIO-C16 alkyl sulphate present.
• the magnesium ion content is adjusted to provide the stoichiometric equivalent of the alkyl sulphate present.
• the magnesium ion will be present at a level of from about 0.15% to about 0.70% by weight, preferably from 0.25% to 0.55% by weight of the composition.
• compositions containing only alkyl sulphate and alkyl ether sulphate as the anionic surfactants will preferably contain up to about 0.90% by weight of the composition of magnesium ion, and part of the alkyl ether sulphate will also be neutralised by magnesium ion.
• Alkyl benzene sulphonates useful in compositions of the present invention are those in which the alkyl group, which is substantially linear, contains 10-16 carbon atoms, preferably 11-13 carbon atoms, a material with an average carbon chain length of 11.8 being most preferred.
• the phenyl isomer distribution i.e. the point of attachment of the alkyl chain to the benzene nucleus, is not critical but alkyl benzenes having a high 2-phenyl isomer content are preferred.
• an alkylbenzene sulphonate content of from 10% to 28% by weight of the composition is required generally from 12% to 26% by weight.
• an alkylbenzene sulphonate content of from 13% to 17% by weight is used and highly preferred compositions in accordance with this aspect of the invention have from 14% to 17% of C 11 . 8 alkyl benzene sulphonate.
• the alkyl ethoxy sulphate surfactant ccmponent comprises a primary alkyl ethoxy sulphate derived from the condensation product of a C 10 -C 16 alcohol with an average of up to 6 ethylene oxide groups.
• the C 10 -C 16 alcohol itself can be obtained from any of the sources previously described for the alkyl sulphate component. It has, however, been found preferable to use alkyl sulphate and alkyl ether sulphate in which the carbon chain length distributions are the same.
• C 12 -C 13 alkyl ether sulphates are preferred and the level of alkyl ethoxy sulphate in the composition lies between 8% and 25% by weight of the compositions, generally in the range from 10% to 25% by weight.
• the level lies in the range from 9% to 15% by weight, most preferably in the range from 9% to 11% by weight.
• Blends can be made of material having different degrees of ethoxylation and/or different ethoxylate distributions arising from the specific ethoxylation techniques employed and subsequent processing steps such as distillation. For example, it has been found that equivalent sudsing and grease removal performance to that given by a blend of alkyl sulphate and alkyl triethoxy ether sulphate can be obtained by reducing the level of alkyl sulphate and using an alkyl ether sulphate with an average of approximately two ethoxy groups per mole of alcohol.
• the average degree of ethoxylation is from 0.5 to 4, more preferably from 0.8 to 2.0.
• the counter ion for the alkyl ethoxy sulphate can be any one of sodium, potassium, ammonium or alkanol-ammonium or a mixture thereof. However, for the purposes of obtaining the lowest possible chill point temperature, (the temperature at which inorganic salt crystals separate), it is desirable that at least 30% of the counter ions for the alkyl ethoxy sulphate should be ammonium. In compositions containing an alkyl benzene sulphonate component it is highly preferred that the alkyl ethoxy sulphate is completely neutralized by ammonium ions.
• the counter ions in association with the alkyl benzene sulphonate are independently selected in the same manner as those for the alkyl ethoxy sulphate, there being preferably at least 50% of ammonium icns.
• at least 70% of the neutralising cations for the anionic surfactants should be ammonium ions and most preferably ammonium constitutes the only cation present other than magnesium.
• the ethoxylated nonionic surfactant component of the invention is a C6-C13 aliphatic alcohol ethoxylate containing an average of from 1.5 to 25, more preferably from 2 to 15 and most preferably from 6 to 10 moles of ethylene oxide per mole of alcohol.
• the aliphatic alcohol ethoxylate contains not more than 1% by weight of unethoxylated alcohol where the ethoxylated alcohol contains an average of less than 9 moles of ethylene oxide and not more than 2% by weight of unethoxylated alcohol where the ethoxylated alcohol contains an average of from 9 to 25 moles of ethylene oxide per mole of alcohol.
• the starting alcohol may be a primary or secondary alcohol but is preferably a primary alcohol which may be derived fran natural or synthetic sources.
• natural fats or oils, or products of Ziegler olefin build up reactions or OXO synthesis may all be used as the source of the hydrocarbon chain, the structure of which may be linear or branched in type.
• the preferred alcohol chain length range is from C 9 -C 11 as it has been found that performance, viz. sudsing volume and mileage, are optimum for ethoxylates made from such alcohols.
• the average degree of ethoxylation (E ) lies in the range from 1.5 to 25 moles per mole of alcohol, but is preferably in the range from 2-15 and most preferably in the range from 6 to 10 moles per mole of alcohol. It is also desirable for performance reasons that the hydrophilic-lipophilic balance (HLB) of the ethoxylated alcohol is in the range from 8.0 to 17.0, more preferably from 11.0 to 17.0 and most preferably from 11.0 to 15.0.
• HLB hydrophilic-lipophilic balance
• a normal (base catalysed) ethoxylation process results in a wide distribution of ethoxylate species.
• this range extends from 1 to at least 15 moles of ethylene oxide per mole of alcohol and for an average in the range of from 20 to 25 moles per mole of alcohol the range may extend up to 50 moles/mole of alcohol.
• Increases in E av cause the ethoxylate distribution to become less peaked about the average value and also lead to a reduction in the level of unethoxylated material.
• Condensation products having an E av in the range from 3 to 9 moles per mole of alcohol contain 3-20% unethoxylated material while products having an E av in the range from 10 to 20 moles per mole of alcohol will still contain up to 2% of unethoxylated material.
• levels of unethoxylated material in the ethoxylated nonionic surfactant of greater than 2% by weight will give rise to phase stability/chill point problems and/or will result in a product having a fatty alcohol odour which is unacceptable to consumers and which is difficult to mask with conventional detergent perfumes.
• the maximum level of unethoxylated alcohol that can be tolerated in the ethoxylated alcohol component is 1% by weight of the alcohol ethoxylate where the level of ethoxylation is less than 9 moles per mole of alcohol and 2% by weight where the level of ethoxylation is from 9 to 25 moles per mole of alcohol. More preferably the unethoxylated alcohol level is not more than 0.7% and most preferably is less than 0.5% by weight of the ethoxylated alcohol component.
• Distillation under vacuum is employed to remove the undesired material and this also removes a portion of the monoethoxylate fraction, thereby increasing the E av of the remaining material.
• the ethoxylated alcohol is a C 9 -C 11 primary alcohol ethoxylate the level of monoethoxylate is not more than 5% by weight of the ethoxylated alcohol.
• the level of usage of the ethoxylated alcohol component in compositions of the invention is from 1 to 10% by weight, more preferably from 1 to 5% and most preferably from 2% to 4% by weight.
• a highly preferred ingredient of the composition according to the invention is a suds-promoting agent present at a level of from 2% to 8% by weight of the composition, preferably from 3% to 6% and most preferably 3%-4%.
• the suds-promoting agent can be any of C 10 -C 16 mono-and di-C 2 -C 3 alkanolamide, and tertiary amine oxides containing a C 8 -C 18 alkyl group.
• alkanolamides examples include coconut alkyl monoethanolamide, coconut alkyl diethanolamides and palm kernel and coconut alkyl mono and di isopropanol amides.
• the palm kernel or coconut alkyl residue may either be 'whole cut', including the C 10 and C 16 fractions or may be the so-called 'narrow-cut' C 12 -C 14 fraction. Synthetic sources of the C 10 -C 16 alkyl group can also be used.
• Amine oxides useful in the present invention have one alkyl or hydroxyalkyl moiety of 8 to 18 carbon atoms, preferably 8 to 16 carbon atoms and two moieties selected from alkyl groups and hydroxyalkyl groups containing 1 to 3 carbon atoms.
• Examples of such materials include dimethyloctylamine oxide, diethyldecylamine oxide, bis-(2-hydroxyethyl) dodecylamine oxide, methylethylhexa- decylamine oxide, and dimethyl-2-hydroxyoctadecylamine oxide.
• tertiary amine oxide is a C 12 - C 14 alkyl dimethyl amine oxide in which the C 12 -C 14 alkyl group is derived from coconut oil.
• the balance of the formula comprises a hydrotrcpe-water system in which the hydrotrope may be urea, a C l -C 3 aliphatic alcohol, or a lower alkyl benzene sulphonate or mixtures of any of these.
• the hydrotrope may be urea, a C l -C 3 aliphatic alcohol, or a lower alkyl benzene sulphonate or mixtures of any of these.
• a single hydrotrope will be adequate to provide the required phase stability, but compositions in accordance with the present invention preferably employ a mixture such as urea-alcohol-water or alcohol-lower alkyl benzene sulphonate-water in order to achieve the desired viscosity, and to remain stable and easily pourable.
• the preferred alcoholic hydrotrope is ethanol which is employed at from 3% to 10% by weight of the conposition, preferably at from 4% to 8%, usually in admixture with urea.
• Mixtures of hydrotropes can, of course, be employed for cost effectiveness reasons irrespective of any stability/viscosity considerations.
• Optional ingredients of the liquid detergent compositions of the invention include opacifiers such as ethylene glycol distearate, antibacterial agents such as glutaraldehyde and Bronopol (RIM), antitarnish agents such as benzoxytriazole, heavy metal chelating agents such as ETDK or ETDMP, perfumes and dyes.
• opacifiers such as ethylene glycol distearate
• antibacterial agents such as glutaraldehyde and Bronopol (RIM)
• antitarnish agents such as benzoxytriazole
• heavy metal chelating agents such as ETDK or ETDMP
• compositions of the invention can be made in a number of ways but it is preferred that the ethoxylated nonionic surfactant is incorporated towards the end of the making process if not actually forming the last ingredient to be added. This is particularly important where the ethoxylated nonionic surfactant has an HLB 9.5 which is normally taken to be the value below which such materials are basically water insoluble.
• individual anionic surfactants can be made as aqueous solutions of alkali metal.or ammonium salts which are then mixed together with the suds booster and with the hydrotrope, following which any magnesium ion can be introduced as a water soluble salt such as the chloride or sulphate.
• the ethoxylated nonionic surfactant and any optional minor ingredients are then added at the same time as the pH and viscosity are adjusted.
• This method has the advantage of utilising conventional techniques and equipment but does result in the introduction of additional chloride or sulphate ions which can increase the chill point temperature (the temperature at which inorganic salts precipitate as crystals in the liquid).
• An alternative and preferred method is to mix an alcohol and alcohol ethoxylate together and carry out a single sulphation and neutralisation.
• the alcohol and alcohol ethoxylate should be mixed in a weight ratio lying in the range 4:3 to 1:6.
• Sulphation can take place by means of any of the conventional sulphating agents such as e.g. sulphur trioxide or chlorosulphonic acid.
• Neutralisation of the alkyl ether sulphuric acid and the alkyl sulphuric acid is carried out with the appropriate alkali or with a magnesium oxide or hydroxide slurry which avoids the addition of chloride or sulphate ions.
• magnesium hydroxide slurry in which magnesium hydroxide slurry is emplayed, it is convenient to use a mixture of these acids, as the magnesium salt of the alkyl ether sulphuric acid has relatively greater aqueous solubility than the alkyl sulphuric acid component.
• the suds booster is then dissolved in this heel of alkyl sulphate and alkyl ether sulphate actives.
• the separately neutralised alkyl benzene sulphonate salt, and the neutralised alkyl and alkyl ether sulphate salts containing the suds booster and hydrotrcpe are then added to the final mixing tank and the ethoxylated nonionic surfactant and any optional ingredients added before the pH is adjusted as above.
• compositions in accordance with the invention are clear single phase liquids, but the invention also embraces opaque products containing dispersed phases provided that such products are physically stable (i.e., do not separate) on storage.
• compositions were prepared:
• Composition A In the preparation of Composition A, a mixture of alcohol and alcohol ethoxylate was sulphated using SO 3 -air sulphation, and was then neutralised in an alcoholic ammonium hydroxide solution to which magnesium hydroxide had been added in an amount corresponding to half the molar quantity of alkyl sulphate present. A separate sulphonation of the alkyl benzene was employed to produce alkyl benzene sulphonic acid which was added to the alkaline solution of the other actives and neutralised with the excess ammonia to pH 7. The monoethanolamide was then added before final pH trimming to pH 6.8. The chill point of Composition A was -5°C. Compositions B-E were prepared in a similar manner except that the ethoxylated nonionic surfactant was added during the final pH trimming operation.
• the Cake Mix is McDougall's Sponge Mix
• the free fatty acids comprise 2 parts oleic acid 2 parts linoleic acid 1 part stearic acid 2.5 parts palmitic acid 367 parts corn oil
• the method uses 4 cylinders of length 30 cm and diameter 10 cm fixed side by side, and rotatable at a speed of 24 rpm about a central axis. Each cylinder is charged with 500 mls of product solution at a concentration of 0.12% and a temperature of 45°C. The outer two cylinders are used for one of the products being compared and the inner two for the other product.
• the cylinders are rotated for 2 minutes, stopped, the initial suds are measured and a soil load is then added.
• the grease soil comprises a mixture of fatty acids in a cooking oil base and 1 ml of this mixture (MFFA) is added to each cylinder. All of the particulate soil is also added at this stage. After 1 minute the cylinders are restarted and allowed to rotate for 1 minute. The suds height is noted and 1 ml of the 2% MFFA is added to each cylinder. After 1 minute the cylinders are restarted. This process continues until the suds height in the cylinder is lower than 0.5 cms.
• Product A is designated as the control and suds mileage figures are calculated for the other product versus the 'control' product on the following basis.
• Composition B showed the combination of a consistent mileage advantage in both hard and soft water, an acceptable chill point and an acceptable odour.
• compositions are in accordance with the present invention.
• compositions were made up in accordance with Example 1 except that the type, level * and HLB of ethoxylated primary alcohol surfactant was as follows
• compositions H-0 inclusive show advantages over the Comparison Composition A which does not contain an ethoxylated nonionic component. It can also be seen that Compositions H & I which represent preferred emodiments of the invention provide superior performance to other, less preferred, embodiments such as Compositions L & M.

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Cited By (25)

Citations (5)

• 1983
  • 1983-05-14 GB GB838313348A patent/GB8313348D0/en active Pending
• 1984
  • 1984-05-04 EP EP84303044A patent/EP0125854B1/fr not_active Expired
  • 1984-05-04 DE DE8484303044T patent/DE3480717D1/de not_active Expired - Fee Related
  • 1984-05-04 AT AT84303044T patent/ATE48634T1/de not_active IP Right Cessation
  • 1984-05-10 GR GR74666A patent/GR81944B/el unknown
  • 1984-05-11 CA CA000454126A patent/CA1228521A/fr not_active Expired
  • 1984-05-11 ES ES532449A patent/ES532449A0/es active Granted
  • 1984-05-11 FI FI841907A patent/FI75597C/fi not_active IP Right Cessation
  • 1984-05-11 IE IE1178/84A patent/IE57396B1/en not_active IP Right Cessation
  • 1984-05-11 DK DK236084A patent/DK162608C/da not_active IP Right Cessation

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