EP0119958B1 - Desensitizing ink for wet offset printing - Google Patents
Desensitizing ink for wet offset printing Download PDFInfo
- Publication number
- EP0119958B1 EP0119958B1 EP84810115A EP84810115A EP0119958B1 EP 0119958 B1 EP0119958 B1 EP 0119958B1 EP 84810115 A EP84810115 A EP 84810115A EP 84810115 A EP84810115 A EP 84810115A EP 0119958 B1 EP0119958 B1 EP 0119958B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ink
- desensitising
- nucleophilic
- alkoxylated compound
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007645 offset printing Methods 0.000 title claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 12
- 230000000269 nucleophilic effect Effects 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 239000010685 fatty oil Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims 5
- 229920002635 polyurethane Polymers 0.000 claims 5
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 238000009736 wetting Methods 0.000 claims 1
- 239000000976 ink Substances 0.000 description 31
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 238000007639 printing Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 238000000518 rheometry Methods 0.000 description 5
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 238000007647 flexography Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/128—Desensitisers; Compositions for fault correction, detection or identification of the layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Definitions
- the subject of the invention is a desensitizing ink for wet offset printing on an acceptor surface of a carbonless chemical assembly, comprising at least two superimposed sheets, the facing faces of which have, one an electrophilic acceptor coating, and the another a nucleophilic coating capable of producing a chromogenic reaction with said accepting electrophilic coating.
- the owner of the present invention has produced a desensitizing ink, based on polyalkylene glycol or other high molecular weight alkanoxylated nucleophilic compounds, making it possible to print the surface acceptor of '' a carbonless chemical assembly by wet offset printing, following an alkanoxylation to a degree such that their hydrophilic-lipophilic balance (HLB) is between 2 and 9 in order to allow, on the one hand, a continuous transfer of the ink of the ink rollers on the hydrophobic zones of the printing plate moistened with an offset press, and, on the other hand, to neutralize corresponding zones of the acceptor surface of the carbonless carbon assembly.
- HLB hydrophilic-lipophilic balance
- the alkanoxylated nucleophilic compound is bridged by an aliphatic or aromatic polyisocyanate derivative which also makes it possible to improve the transfer of the ink onto the inking train of the wet offset press.
- This also results in an ink flow of constant thickness by the rollers of the inking train.
- This ink film is particularly resistant to the shock resulting from the emulsion of fountain water in the ink before being transferred successively to the offset printing plate, then to the blanket and finally in the form of a layer of desensitizing ink, at a rate of 1.5 to 5 gr / m 2 , on a paper support.
- a desensitizing ink according to the invention for wet offset printing of the acceptor surface of a carbonless carbon assembly, can be formulated as follows.
- 70 parts of a varnish obtained by reaction of 63 parts of polypropylene glycol (PM 2550) with 5 parts of hexamethylene triisocyanate and addition of 32 parts of acid modified phenolic resin, with 13 parts, are mixed on a three-cylinder grinder. parts of titanium dioxide, 1 part of silicon oxide and 6 parts of calcium carbonate.
- 60 parts of a varnish obtained by reacting 58 parts of polypropylene glycol (PM 2500) with 8 parts of ricinoleic acid and 10 parts of trimethylolpropane isocyanated with 3 moles of toluylene diisocyanate are mixed on a three-cylinder mill and adding 24 parts of neutral esterified rosin resin, with 20 parts of titanium dioxide, 2 parts of silicon oxide and 6 parts of calcium carbonate.
- This ink has a rheology suitable for printing in wet offset.
- This ink has a rheology suitable for printing in wet offset.
- This ink has a rheology suitable for printing in wet offset.
- part or all of the water required to ensure saturation of these areas can be emulsified in the ink mass.
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Color Printing (AREA)
Description
L'invention a pour objet une encre désensibilisante pour impression en offset humide sur une surface acceptrice d'un ensemble autocopiant chimique, comprenant au-moins deux feuilles superposées dont les faces en regard présentent, l'une un enduit électrophile accepteur, et l'autre un enduit nucléophile susceptible de produire une réaction chromogène avec ledit enduit électrophile accepteur.The subject of the invention is a desensitizing ink for wet offset printing on an acceptor surface of a carbonless chemical assembly, comprising at least two superimposed sheets, the facing faces of which have, one an electrophilic acceptor coating, and the another a nucleophilic coating capable of producing a chromogenic reaction with said accepting electrophilic coating.
Par le brevet anglais N° 1 433 469, on connaît déjà des encres désensibilisantes contenant du polypropylène glycol de poids moléculaire compris entre 400 et 5000 permettant d'imprimer en typographie, flexographie ou héliographie la surface acceptrice d'une ensemble autocopiant et d'empêcher ainsi toute formation colorée dans les zones ainsi imprimées, lors d'une écriture ou frappe subséquente sur l'ensemble autocopiant.By English patent No. 1,433,469, desensitizing inks are already known containing polypropylene glycol of molecular weight between 400 and 5000 enabling printing in typography, flexography or heliography the accepting surface of a carbonless assembly and preventing thus any colored formation in the areas thus printed, during a subsequent writing or typing on the carbonless assembly.
Comme indiqué dans le brevet anglais W 1 525269, la titulaire du brevet anglais N° 1 433 469 n'avait toutefois pas réussi à formuler une encre à base de polyalkylène glycol permettant d'imprimer en offset humide la surface acceptrice d'un ensemble autocopiant chimique.As indicated in the English patent W 1 525 269, the owner of the English patent N ° 1 433 469 had however not succeeded in formulating an ink based on polyalkylene glycol making it possible to print in wet offset the acceptor surface of a carbonless assembly chemical.
Comme décrit dans le brevet suisse N° 628 288, la titulaire de la présente invention a réalisé une encre désensibilisante, à base de polyalkylène glycol ou d'autre composés nucléophiles alca- noxylés de poids moléculaire élevé, permettant d'imprimer la surface acceptrice d'une ensemble autocopiant chimique par impression en offset humide, à la suite d'une alcanoxylation à un degré tel que leur équilibre hydrophile-lipophile (HLB) soit compris entre 2 et 9 afin de permettre, d'une part, un transfert continu de l'encre des rouleaux encreurs sur les zones hydrophobes de la plaque d'impression humidifiée d'une presse offset, et, d'autre part, de neutraliser des zones correspondantes de la surface acceptrice de l'ensemble autocopiant chimique.As described in Swiss Patent No. 628,288, the owner of the present invention has produced a desensitizing ink, based on polyalkylene glycol or other high molecular weight alkanoxylated nucleophilic compounds, making it possible to print the surface acceptor of '' a carbonless chemical assembly by wet offset printing, following an alkanoxylation to a degree such that their hydrophilic-lipophilic balance (HLB) is between 2 and 9 in order to allow, on the one hand, a continuous transfer of the ink of the ink rollers on the hydrophobic zones of the printing plate moistened with an offset press, and, on the other hand, to neutralize corresponding zones of the acceptor surface of the carbonless carbon assembly.
Afin d'augmenter le poids moléculaire du composant désensibilisant l'encre selon l'invention, est caractérisée en ce que le composé nucléophile alcanoxylé est ponté par un dérivé polyisocyanate aliphatique ou aromatique qui permet en plus d'améliorer le transfert de l'encre sur le train d'encrage de la presse offset humide. Il en résulte encore un débit d'encre d'épaisseur constante par les rouleaux du train d'encrage. Ce film d'encre résiste particulièrement bien au choc résultant de l'émulsion de l'eau de mouillage dans l'encre avant d'être transféré successivement sur la plaque d'impression offset, puis sur le blanchet et finalement sous forme d'une couche d'encre désensibilisante, à raison de 1,5 à 5 gr/m2, sur un support de papier.In order to increase the molecular weight of the ink desensitizing component according to the invention, is characterized in that the alkanoxylated nucleophilic compound is bridged by an aliphatic or aromatic polyisocyanate derivative which also makes it possible to improve the transfer of the ink onto the inking train of the wet offset press. This also results in an ink flow of constant thickness by the rollers of the inking train. This ink film is particularly resistant to the shock resulting from the emulsion of fountain water in the ink before being transferred successively to the offset printing plate, then to the blanket and finally in the form of a layer of desensitizing ink, at a rate of 1.5 to 5 gr / m 2 , on a paper support.
Une encre désensibilisante selon l'invention, pour impression en offset humide de la surface acceptrice d'un ensemble autocopiant chimique, peut être formulée de la façon suivante.A desensitizing ink according to the invention, for wet offset printing of the acceptor surface of a carbonless carbon assembly, can be formulated as follows.
On mélange sur une broyeuse à trois cylindres, 70 parties d'un vernis obtenu par réaction de 63 parties de polypropylène-glycol (P. M. 2550) avec 5 parties de triisocyanate d'hexaméthylène et adjonction de 32 parties de résine phénolique modifiée acide, avec 13 parties de dioxyde de titane, 1 partie d'oxyde de silicium et 6 parties de carbonate de calcium.70 parts of a varnish obtained by reaction of 63 parts of polypropylene glycol (PM 2550) with 5 parts of hexamethylene triisocyanate and addition of 32 parts of acid modified phenolic resin, with 13 parts, are mixed on a three-cylinder grinder. parts of titanium dioxide, 1 part of silicon oxide and 6 parts of calcium carbonate.
A cette encre broyée on ajoute 12 parties du dérivé alcanoxylé. La valeur HLB de l'encre s'élève à3(±1). Cette encre possède une rhéologie adéquate pour l'impression en offset humide.To this ground ink 12 parts of the alkanoxylated derivative are added. The HLB value of the ink is 3 (± 1). This ink has a rheology suitable for printing in wet offset.
On mélange sur une broyeuse à trois cylindres, 68 parties d'un vernis obtenu par réaction de 66 parties de diéthylène triamine propoxylé (P. M. 2500) avec 9 parties de triméthylolpropane isocyanuré par 3 parties de di-isocyanate de toluylène et adjonction de 25 parties de résine phénolique modifié acide, avec 12 parties de dioxyde de titane, 2 parties d'oxyde de silicium et 6 parties de carbonate de calcium.68 parts of a varnish obtained by reaction of 66 parts of propoxylated diethylene triamine (PM 2500) with 9 parts of trimethylolpropane isocyanurized with 3 parts of toluylene diisocyanate and addition of 25 parts of a three-cylinder mill is mixed on a three-cylinder mill acid modified phenolic resin, with 12 parts of titanium dioxide, 2 parts of silicon oxide and 6 parts of calcium carbonate.
A cette encre broyée on ajoute 12 parties du dérivé alcanoxylé. La valeur HLB de l'encre s'élève à 4 (± 1). Cette encre possède une rhéologie adéquate pour l'impression en offset humide.To this ground ink 12 parts of the alkanoxylated derivative are added. The HLB value of the ink is 4 (± 1). This ink has a rheology suitable for printing in wet offset.
On mélange sur une broyeuse à trois cylindres, 60 parties d'un vernis obtenu par réaction de 58 parties de polypropylène glycol (P. M. 2500) avec 8 parties d'acide ricinoléique et 10 parties de triméthylolpropane isocyanuré par 3 moles de di-isocyanate de toluylène et adjonction de 24 parties de résine de collophane esterifiée neutre, avec 20 parties de dioxyde de titane, 2 parties d'oxyde de silicium et 6 parties de carbonate de calcium.60 parts of a varnish obtained by reacting 58 parts of polypropylene glycol (PM 2500) with 8 parts of ricinoleic acid and 10 parts of trimethylolpropane isocyanated with 3 moles of toluylene diisocyanate are mixed on a three-cylinder mill and adding 24 parts of neutral esterified rosin resin, with 20 parts of titanium dioxide, 2 parts of silicon oxide and 6 parts of calcium carbonate.
A cette encre broyée, on ajoute 12 parties du dérivé alcanoxylé. La valeur HLB de l'encre s'élève à 3 (±1). Cette encre possède une rhéologie adéquate pour l'impression en offset humide.To this ground ink, 12 parts of the alkanoxylated derivative are added. The HLB value of the ink is 3 (± 1). This ink has a rheology suitable for printing in wet offset.
On mélange sur une broyeuse à trois cylindres 60 parties d'un vernis obtenu par réaction de 72 parties de diéthylène triamine propoxylé (P. M. 2500) avec 5 parties d'huile de ricin et 5 parties de tri-isocyanate d'hexaméthyléne et adjonction de 18 parties de résine de collophane esterifiée neutre, avec 20 parties de dioxyde de titane, 2 parties d'oxyde de silicium et 6 parties de carbonate de calcium.60 parts of a varnish obtained by reaction of 72 parts of propoxylated diethylene triamine (PM 2500) with 5 parts of castor oil and 5 parts of hexamethylene triisocyanate and addition of 18 are mixed on a three-cylinder mill parts of neutral esterified rosin resin, with 20 parts of titanium dioxide, 2 parts of silicon oxide and 6 parts of calcium carbonate.
A cette encre broyée, on ajoute 12 parties du dérivé alcanoxylé. La valeur HLB de l'encre s'élève à 4 (±1). Cette encre possède une rhéologie adéquate pour l'impression en offset humide.To this ground ink, 12 parts of the alkanoxylated derivative are added. The HLB value of the ink is 4 (± 1). This ink has a rheology suitable for printing in wet offset.
On mélange sur une broyeuse à trois cylindres 68 parties d'un vernis obtenu par réaction de 75 parties de polypropylène glycol (P. M. 2500) avec 5 parties d'alkyle longue en huile portant un groupe hydroxyle et 5 parties de tri-isocyanate d'hexaméthyléne et adjonction de 15 parties de résine phénolique modifiée acide, avec 12 parties de dioxyde de titane, 2 parties d'oxyde de silicium et 6 parties de carbonate de calcium.68 parts of a varnish obtained by reacting 75 parts of polypropylene glycol (PM 2500) with 5 parts of long alkyl in oil carrying a hydroxyl group and 5 parts of hexamethylene triisocyanate are mixed on a three-cylinder mill and addition of 15 parts of acid modified phenolic resin, with 12 parts of titanium dioxide, 2 parts of silicon oxide and 6 parts of calcium carbonate.
A cette encre broyée, on ajoute 12 parties du dérivé alcanoxylé. La valeur HLB de l'encre s'élève à 3 (±1). Cette encre possède une rhéologie adéquate pour l'impression en offset humide.To this ground ink, 12 parts of the alkanoxylated derivative are added. The HLB value of the ink is 3 (± 1). This ink has a rheology suitable for printing in wet offset.
Dans l'encre désensibilisante telle que formulée aux exemples 3, 4 et 5, on a substitué soit un acide gras porteur de groupes hydroxyles (exemple 3), soit une huile grasse (exemple 4), soit un alkyde long en huile (exemple 5) à une partie du composé nucléophile alcanoxylé, ce qui permet d'augmenter la viscosité de l'encre.In the desensitizing ink as formulated in Examples 3, 4 and 5, either a fatty acid bearing hydroxyl groups (Example 3) or a fatty oil (Example 4) or a long oil alkyd (Example 5) has been substituted. ) to a part of the alkanoxylated nucleophilic compound, which makes it possible to increase the viscosity of the ink.
Afin de rendre l'humidification des zones hydrophiles de la plaque d'impression en offset humide plus aisée, on peut émulsionner dans la masse d'encre une partie ou la totalité de l'eau requise pour assurer la saturation de ces zones.In order to make it easier to moisten the hydrophilic areas of the wet offset printing plate, part or all of the water required to ensure saturation of these areas can be emulsified in the ink mass.
Claims (9)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1443/83A CH653049A5 (en) | 1983-03-16 | 1983-03-16 | DESENSITIZING INK FOR WET OFFSET PRINTING. |
| CH1443/83 | 1983-03-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0119958A1 EP0119958A1 (en) | 1984-09-26 |
| EP0119958B1 true EP0119958B1 (en) | 1989-05-24 |
Family
ID=4210579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84810115A Expired EP0119958B1 (en) | 1983-03-16 | 1984-03-07 | Desensitizing ink for wet offset printing |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4599111A (en) |
| EP (1) | EP0119958B1 (en) |
| JP (1) | JPS60500759A (en) |
| AU (1) | AU568854B2 (en) |
| CA (1) | CA1216388A (en) |
| CH (1) | CH653049A5 (en) |
| DE (1) | DE3478293D1 (en) |
| PH (1) | PH20466A (en) |
| WO (1) | WO1984003663A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH676118A5 (en) * | 1988-02-16 | 1990-12-14 | Sicpa Holding Sa | |
| US4988563A (en) * | 1988-05-10 | 1991-01-29 | Wehr Mary A | Thermal transfer ribbon with protective layer |
| DE4105767C1 (en) * | 1991-02-23 | 1992-05-27 | Drescher Geschaeftsdrucke Gmbh, 7255 Rutesheim, De | |
| EP1669213A1 (en) | 2004-12-09 | 2006-06-14 | Sicpa Holding S.A. | Security element having a viewing-angle dependent aspect |
| CN104364225A (en) * | 2012-06-06 | 2015-02-18 | 格雷斯公司 | Polyurethane-based waterproofing composition for the water-proofing of concrete structures |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS551919B2 (en) * | 1973-08-08 | 1980-01-17 | ||
| JPS5163710A (en) * | 1974-11-26 | 1976-06-02 | Fuji Photo Film Co Ltd | |
| GB2032932B (en) * | 1978-09-30 | 1983-03-30 | Mitsubishi Paper Mills Ltd | Carbonless pressure sensitive copying paper and a desensitizing ink composition therefor |
-
1983
- 1983-03-16 CH CH1443/83A patent/CH653049A5/en not_active IP Right Cessation
-
1984
- 1984-03-07 EP EP84810115A patent/EP0119958B1/en not_active Expired
- 1984-03-07 DE DE8484810115T patent/DE3478293D1/en not_active Expired
- 1984-03-07 CA CA000449033A patent/CA1216388A/en not_active Expired
- 1984-03-12 US US06/668,379 patent/US4599111A/en not_active Expired - Lifetime
- 1984-03-12 JP JP59501826A patent/JPS60500759A/en active Pending
- 1984-03-12 WO PCT/EP1984/000122 patent/WO1984003663A1/en unknown
- 1984-03-12 AU AU28635/84A patent/AU568854B2/en not_active Expired
- 1984-03-15 PH PH30402A patent/PH20466A/en unknown
Non-Patent Citations (2)
| Title |
|---|
| PATENTS ABSTRACTS OF JAPAN, vol. 6, no. 65 (M-124)[943], 24 avril 1982; & JP - A - 57 4793 (TOYO INK SEIZO K.K.) 11-01-1982 * |
| PATENTS ABSTRACTS OF JAPAN, vol. 6, no. 89 (M-132)[967], 27 mai 1982; & JP - A - 57 25 991 (TOYO INK SEIZO K.K.) 10-02-1982 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CH653049A5 (en) | 1985-12-13 |
| AU568854B2 (en) | 1988-01-14 |
| US4599111A (en) | 1986-07-08 |
| DE3478293D1 (en) | 1989-06-29 |
| AU2863584A (en) | 1984-10-09 |
| EP0119958A1 (en) | 1984-09-26 |
| PH20466A (en) | 1987-01-14 |
| JPS60500759A (en) | 1985-05-23 |
| CA1216388A (en) | 1987-01-06 |
| WO1984003663A1 (en) | 1984-09-27 |
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