EP0105368A4 - Method of hot-forming metals prone to crack during rolling. - Google Patents

Method of hot-forming metals prone to crack during rolling.

Info

Publication number
EP0105368A4
EP0105368A4 EP19830902518 EP83902518A EP0105368A4 EP 0105368 A4 EP0105368 A4 EP 0105368A4 EP 19830902518 EP19830902518 EP 19830902518 EP 83902518 A EP83902518 A EP 83902518A EP 0105368 A4 EP0105368 A4 EP 0105368A4
Authority
EP
European Patent Office
Prior art keywords
metal
bar
hot
steel alloy
cross
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19830902518
Other languages
German (de)
French (fr)
Other versions
EP0105368A1 (en
EP0105368B1 (en
Inventor
Henry E Chia
Ronald D Adams
Niles N Engel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Southwire Co LLC
Original Assignee
Southwire Co LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Southwire Co LLC filed Critical Southwire Co LLC
Publication of EP0105368A1 publication Critical patent/EP0105368A1/en
Publication of EP0105368A4 publication Critical patent/EP0105368A4/en
Application granted granted Critical
Publication of EP0105368B1 publication Critical patent/EP0105368B1/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/463Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/1206Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/13Modifying the physical properties of iron or steel by deformation by hot working
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/003Rolling non-ferrous metals immediately subsequent to continuous casting, i.e. in-line rolling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)
  • Forging (AREA)

Description

'METHOD OF HOT-FORMING METALS PRONE TO CRACK DURING ROLLING
TECHNICAL FIELD The present invention relates to the hot forming of metals, and more particularly relates to the continuous casting and hot forming of the as-cast bars of certain impure or alloyed steels which may be prone to crack during hot-rolling.
BACKGROUND ART It is well known that metals, such as copper and aluminum, may be continuously cast, either in stationary vertical molds or in a rotating casting wheel, to obtain a cast bar which is then immediately hot formed, while in a substantially as-cast condition, by passing the cast bar exiting the mold to and through the roll stands of a rolling mill while the cast bar is still at a hot-forming temperature. It is also well known that the as-cast structure of the metal bar is such that cracking of the cast bar during hot forming may be a problem if the cast bar is required to be directly hot formed into a semi-finished product, such as redraw rod, during which the initially large cross-sectional area of the cast bar is substantially reduced by a plurality of deformations along different axes to provide a much small-er cross-sectional area in the product.
While this problem could be avoided by casting a cast bar having an initially small cross-sectional area which need not be substantially reduced to provide the desired cross-sectional area of the final product, this approach is not commercially practical for ferrous alloys since high casting outputs, and therefore low costs, can be readily achieved only with cast bars having large cross-sectional areas which are rapidly reduced to the smaller cross- sectional areas of the products, such as 3/8" diameter rod for drawing into wire, by a minimum number of severe
OMPI deformations. Thus, the problem of a cast bar cracking during hot forming must be solved within the commercial context of cast bars having initially large cross-sectional areas which are then hot formed into products having small cross-sectional areas by a series of reductions which often are substantial enough to cause cracking of the cast bar under certain conditions.
This problem has been overcome in the prior art for relatively pure electrolytically-refined copper having low impurity levels such as 3-10 ppm lead, 1 ppm bismuth, and 1 ppm antimony. For example, U.S. Patent No. 3,317,994, and U.S. Patent No. 3,672,430 disclose that this cracking problem can be overcome by conditioning such relatively pure copper cast bar by initial large reductions of the cross- sectional area in the initial roll stands sufficient to substantially destroy the as-cast structure of the cast bar. The additional reductions along different axes of deformation, which would cause cracking of the cast bar but for the initial destruction of the as-cast structure of the cast bar, may then safely be performed. This conditioning of the cast bar not only prevents cracking of the cast bar during hot forming but also has the advantage of accomplishing a large reduction in the cross-sectional area of the cast bar while its hot-forming temperature is such as to minimize the power required for the reduction.
The prior art has not, however, provided a solution to the cracking problem described above for metals, such as steel, containing a relatively high percentage of alloying elements. This is because the large amounts of alloying elements, often in the grain boundaries of the as-cast structure, cause the cast bar to crack when an attempt is made to substantially destroy the as-cast structure with the same large initial reduction of the cross-sectional area of the cast bar that is known to be effective with relatively pure non-ferrous metal. Moreover, the greater the percentage of alloying elements in the cast bar, the more likely it is that cracks will occur during hot forming. DISCLOSURE OF INVENTION The present invention solves the above-described cracking problem of the prior art by providing a method of continuously casting and hot forming both low and high alloy steels without substantial cracking of the cast bar occurring during the hot rolling process. Generally described, the invention provides, in a method of continuously casting molten metal to obtain a cast bar with a relatively large cross-sectional area, and hot forming the cast bar at a hot-forming temperature into a product having a relatively small cross-sectional area by a substantial reduction of the cross-sectional area of the cast bar which would be such that the as-cast structure of the cast bar would be expected to cause the cast bar to crack, the additional step of first forming a substantially uniform subgrain structure at least in the surface layers of the cast bar prior to later substantial reduction of the cross- sectional area of the cast bar, said substantially uniform subgrain structure being formed by relatively light deformations of the cast bar while at a hot-forming temperature.
The light deformations are of magnitude (preferably 5 to 25%) which will not cause the cast bar to crack, but which in combination with the hot-forming temperature of the cast bar will cause the cast bar to have a substantially uniform subgrain or cell structure of a thickness sufficient (about 10% of total area) to produce a bar of increased ductility when compared to a bar produced by the prior art process, which substantially inhibits the initiation of micro and macro cracking that normally begin at the as-cast grain boundaries, thus preventing cracking of the cast bar (even when having relatively high percentage alloying elements) during the subsequent substantial deformations. The substantially uniform subgrain structure of the surface provided by this invention allows substantial reduction of the cross-sectional area of the bar in a subsequent pass, even in excess of 30%, without cracking occurring a.nd even though the cast bar has a relatively high amount of impurities or alloying elements.
For example, the present invention allows a steel alloy cast bar having a cross-sectional area of 5 square inches, or more, and containing alloying elements, to be continuously hot formed into wrought rod having a cross- section area of 1/2 square inch, or less, without cracking.
Furthermore, the invention has wide general utility since it can also be used with certain other relatively impure or alloyed metals as an alternative to the solution to the problem of cracking described in U.S. Patent No. 3,317,994, and U.S. Patent No. 3,672,430.
Thus, it is an object of the present invention to provide an improved method of continuously casting a molten ferrous alloy to obtain a cast bar and continuously hot forming the cast bar into a product having a cross-sectional area substantially less than that of the cast bar without cracking of the cast bar occurring during hot forming.
It is a further object of the present invention to provide a method of continuously casting and hot-forming steel containing a relatively high percentage of alloying elements without using specially shaped reduction rolls in the hot-rolling mill or other complex rolling procedures.
It is a further object of the present invention to provide a method whereby a cast steel bar may be efficiently hot-formed using fewer roll stands following conditioning of the cast metal by first forming a substantially uniform fine grained, equiaxed or cell structure at the surface of the cast metal, then hot rolling the modified structure ' by successive heavy deformations.
Further objects, features and advantages of the present invention will become apparent upon reading the following specification when taken in conjunction with the accompanying drawing. BRIEF DESCRIPTION OF THE DRAWING
Fig. 1 is a schematic representation of casting and forming apparatus for practicing the method of the present invention.
Fig. 2 is a representation cross-section of a cast bar in substantially an as-cast condition (in this case columnar) .
Fig. 2A is a representation cross-section of a cast bar in substantially an as-cast condition (in this case equiaxed) .
Fig. 3 is a representation cross-section of the cast bar shown in Fig. 2 following one light reduction of the cross- section.
Fig. 3A is a representation of a magnification of 2000x of the subgrain (cell or recrystallized) structure, a portion of which is shown in Fig. 3.)
Fig. 4 is a representation cross-section of the cast bar shown in Fig. 2 following two perpendicular light compressions to form a complete shell of fine or equiaxed grains near the surface of the bar.
Fig. 5 is a representation cross-section of the cast bar shown in Fig. 2 following two light compressions and one severe hot-forming compression.
BEST MODE FOR CARRYING OUT THE INVENTION Referring now to the drawing, in which like numerals refer to like parts throughout the several views. Fig. 1 schematically depicts an apparatus for practicing the method of the present invention. The continuous casting and hot- forming system (10) includes a casting machine (12) which includes a casting wheel (14) having a peripheral groove therein, a flexible band (16) carried by a plurality of guide wheels (17) which bias the flexible band (16) against the casting wheel (14) for a portion of the circumference of the casting wheel (14) to cover the peripheral groove and
OMPI form a mold between the band (16) and the casting wheel (14). As molten metal is poured into the mold through the pouring spout (19) , the casting wheel (14) is rotated and the band (16) moves with the casting wheel (14) to form a moving mold. A cooling system (not shown) within the casting machine (12) causes the molten metal to solidify in the mold and to exit the casting wheel (14) as a solid cast bar (20).
From the casting machine (12), the cast bar (20) passes through a conditioning means (21) , which includes roll stands (22) and (23). The conditioning roll stands (22) and (23) lightly compress the bar to form a shell of substantially uniform fine or equiaxed grain structure at the surface of the bar (20). After conditioning, the bar (20) is passed through a conventional rolling mill (24), which includes roll stands (25), (26), (27) and (28). The roll stands of the rolling mill (24) provide the primary hot forming of the cast bar by compressing the conditioned bar sequentially until the bar is reduced to a desired cross- sectional size and shape.
The grain structure of the cast bar (20) as it exits from the casting machine (12) is shown in Fig. 2. The molten metal solidifies in the casting machine in a fashion that can be columnar, or equiaxed, or both, depending on the super heat and cooling rate. This as-cast structure can be characterized by grains (30) extending radially from the surfaces of the bar (if columnar) and separated from each other by grain boundaries (31). Most of the alloying elements present in the cast bar are located along the grain and dendrite boundaries (31). If the molten steel alloy poured through the spout (19) into the casting wheel (14) were cooled and the cast bar (20) was passed immediately to the rolling mill (24) without passing through the conditioning means (21), the impurities along the boundaries (31) of the cast bar (20) would usually cause the cast bar to crack at the boundaries upon deformation by the roll stands of the rolling mill (24). The conditioning means (21) prevents such cracking by providing a sequence of preliminary light compressions as shown in Fig. 3 and Fig. 4, wherein the result of a compression is shown and the previous shape of the cast bar is shown in broken lines. Fig. 3 shows the result of a 7% reduction provided by the roll stand (22) along a horizontal axis of compression (33). The columnar and/or equiaxed as- cast grain structure of the cast metal has been formed into a layer of substantially uniform fine grained, equiaxed or cell structure (35) covering a portion of the surface of the cast bar (20). The interior of the bar may still have an as-cast structure.
In Fig. 4 the bar (20) has been subjected to a second 7% reduction by the roll stand (23) along a vertical axis of compresion (33) perpendicular to the axis of compression, of roll stand (22). The volume of substantially uniform fine grained, equiaxed or cell structure (35) now forms a shell (36) around the entire surface of the bar (20), although the interior of the bar retains some as-cast structure.
It will be understood that the formation of the shell may be accomplished by a conditioning means comprising any number of roll stands, preferably at least two, or any other type of forming tools, such as extrusion dies, multiple forging hammers, etc., .so long as the preliminary light deformation of the metal results in a substantially uniform fine grained, equiaxed or cell structure covering substan¬ tially the entire surface of the bar, or at least the areas subject to cracking.
The individual light deformations should be between 5-25% reduction so as not to crack the bar during conditioning. The total deformation provided by the conditioning means (21) must provide a shell (36) of sufficient depth (at least about 10%) to prevent cracking of the bar during subsequent deformation of the bar when passing through the roll stands (25-28) of the rolling mill (24). When the shape of the bar in its as-cast condition includes prominent corners such as those of the bar shown in Fig. 2, the shape of the compressing surfaces in the roll stands (22) and (23) may be designed to avoid excessive compression of the corner areas as compared to the other surfaces of the cast bar, so that cracking will not result at the corners.
Fig. 5 shows a cross-section (20) following a substantial reduction of the cross-sectional area by the first roll stand (25) of the rolling mill (24). The remaining as-cast structure in the interior of the bar (20) has been transformed into a uniform fine grained, equiaxed or cell structure (35).
When a shell of improved structure (36) has been generated on the surface of the bar (20), a high reduction may be taken at the first roll stand (25) of the rolling mill (24). It has been found that such initial hot-forming compression may be in excess of 30% following conditioning according to the present invention. The ability to use very high reductions during subsequent hot-forming means that the desired final cross-sectional size and shape may be reached using a rolling mill having a few roll stands. Thus, even though a conditioning means according to the present invention requires one or more roll stands, the total amount and therefore cost of ..the conditioning and hot-forming apparatus may be reduced.
The method of the present invention allows continuous casting and rolling of relatively high percentage alloy steel, such as molybdum and tungsten containing steels and austeuitic steel alloys without cracking the bar. Furthermore, cracking is. prevented throughout the hot- forming temperature range of the metal. Thus, the same casting and hot-forming apparatus may be used to produce steel alloys of varying purities and alloying elements depending on the standards which must be met for a particular product.
Λ wip "- If it is desired to reduce even further the possibility of cracking, elliptically shaped rolling channels may be provided for all of the roll stands (22), (23), and (25-28) in order to provide optimal tangential velocities of the rolls in the roll stands with respect to the cast metal, as disclosed in U.S. Patent No. 3,317,994. However, such, measures are usually not needed to avoid cracking if the present invention is practiced as described herein on metals having alloy levels as described above.
It will be understood by those skilled in the art that the roll stands of the conditioning means (21) may be either a separate component of the system or may be constructed as an integral part of a rolling mill.
While this invention has been described in detail with particular reference to preferred embodiments thereof, it will be understood that variations and modifications can be effected within the spirit and scope of the invention as described herein before and as defined in the appended claims.
OMPI

Claims

WHAT IS CLAIMED IS:
1. In a method of continuously casting molten steel and hot forming said cast metal in substantially its as-cast condition at a hot-forming temperature by a plurality of substantial compressions, the improvement comprising the steps ofs following casting of said metal and prior to said substantial compression of said metal, forming a substantially uniform fine grained or equiaxed structure at least at the surface of said metal by at least one preliminary light compression of said metal.
2. The method of Claim 1 wherein said preliminary light compression reduces the cross-section of said metal by between 5 and 25%.
3. The method of Claim 1, wherein said substantial compressions following the forming of said substantially uniform fine grained or equiaxed structure includes an initial compression providing at least 30% reduction of the cross-section of said metal.
4. The method of Claim 1 wherein said light compressions comprise a first 7% .reduction of the cross-section of said metal followed by a second 7% reduction along an axis of compression 90° removed from the axis of compression of said first 7% reduction.
5. The method of Claim 1, wherein said light compressions comprise a first 7% reduction of the cross-section of said metal followed by at least one additional 7% reduction along an axis of compression 60° removed from the axis of said immediately prior 7% reduction. 6. The method of Claim 1 wherein the total of said light compressions res lts in less than a 30% reduction of the cross-section of said metal. i
7. The method of Claim 1 wherein said metal is a low carbon 1015 (SAE) steel alloy.
8. The method of Claim 1 wherein said metal is a medium carbon 1045 (SAE) steel alloy.
9. The method of Claim 1 wherein said metal is a high carbon 1095 (SAE) steel alloy.
10. The method of Claim 1 wherein said metal is a free cutting carbon 1151 (SAE) steel alloy.
11. The method of Claim 1 wherein said metal is a corrosion and creep resistant A 200 (ASTM) steel alloy.
12. The method of Claim 1 wherein said metal is a silicon spring 9259 (SAE) steel alloy.
13. The method of Claim 1 wherein said metal is a ball bearing 52100 steel alloy.
14. The method of Claim 1 wherein said metal is a martensitic stainless tool 440 C steel alloy.
15. The method of Claim 1 wherein said metal is a austenitic stainless 304 steel alloy.
16. The method of Claim 1 wherein said metal is a austenitic stainless 310 steel alloy.
17. The method of Claim 1 wherein said metal is a weldable stainless 348 steel alloy.
OM 18. The method of Claim 1 wherein said metal is a ferritic freecutting 430F (SE) steel alloy.
19. The method of Claim 1 wherein said metal is an engine valve 14Cr-14Ni-2W steel alloy.
20. The method of Claim 1 wherein said metal is a precipitation hardening 17-7 PH steel alloy.
21. The method of Claim 1 wherein said metal is a tool steel 07 alloy.
22. The method of Claim 1 wherein said metal is a tool steel D5 alloy.
23. A method of hot forming a continuously cast steel bar without cracking said bar comprising the steps of: passing said bar in substantially its as-cast condition and at a hot-forming temperature from a continuous casting machine to a hot-forming means; conditioning said bar for subsequent hot forming by forming a substantially uniform fine grained or equiaxed structure at least at the surface of said bar by a plurality of preliminary light sequential compressions of said bar each reducing the cross-section of said bar by from 5 to 25% each and a total reduction of less than 30%; hot forming said bar by a single compression of said bar to reduce its cross-sectional area by at least 40%; and hot forming said bar by a plurality of sequential compressions in each of which the cross-section of said bar is changed to the extent necessary to provide a hot- formed product having a predetermined cross-section.
OMPI 24. The method of Claim 23 wherein said conditioning of said bar includes passing said bar between rolls in a plurality of sequential roll stands.
25. The method of Claim 24 wherein said hot forming of said bar includes passing said bar through sequential roll stands of a rolling mill.
EP83902518A 1982-02-04 1983-02-04 Method of hot-forming metals prone to crack during rolling Expired EP0105368B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34588582A 1982-02-04 1982-02-04
US345885 1999-07-01

Publications (3)

Publication Number Publication Date
EP0105368A1 EP0105368A1 (en) 1984-04-18
EP0105368A4 true EP0105368A4 (en) 1984-07-03
EP0105368B1 EP0105368B1 (en) 1988-06-01

Family

ID=23356930

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83902518A Expired EP0105368B1 (en) 1982-02-04 1983-02-04 Method of hot-forming metals prone to crack during rolling

Country Status (3)

Country Link
EP (1) EP0105368B1 (en)
GB (1) GB2124939B (en)
WO (1) WO1983002783A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9014437D0 (en) * 1990-06-28 1990-08-22 Holton Machinery Ltd Continuous casting and extruding
TW297788B (en) * 1994-12-15 1997-02-11 Sumitomo Metal Ind
DE19915624A1 (en) * 1999-04-03 2000-10-05 Sms Demag Ag Process and arrangement for the continuous production of finished profiles from metal

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2019700A1 (en) * 1969-05-09 1970-11-19 Voest Ag Process for the production of heavy plates
FR2223114A1 (en) * 1973-03-26 1974-10-25 Nippon Kokan Kk
GB2014071A (en) * 1978-02-13 1979-08-22 Nippon Kokan Kk Continuous casting of steel
FR2461010A1 (en) * 1979-07-12 1981-01-30 Doryokuro Kakunenryo PROCESS FOR IMPROVING RESISTANCE TO DECARBURIZATION OF CHROME-MOLYBDENE STEEL
GB1596395A (en) * 1977-12-14 1981-08-26 Jernkontoret Forskningsavdelni Method of continuous casting of steels or metal alloys with segregation tendancy and apparatus for carrying out the method

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1816849C3 (en) * 1968-12-24 1973-12-13 Demag Ag, 4100 Duisburg Process for continuous casting and subsequent rolling from the casting heat of steel
DE2441795C2 (en) * 1974-08-31 1982-12-09 Kabel- und Metallwerke Gutehoffnungshütte AG, 3000 Hannover Endless metallic casting belt for the casting groove of a casting wheel for continuous casting
US4352697A (en) * 1979-10-01 1982-10-05 Southwire Company Method of hot-forming metals prone to crack during rolling
US4354880A (en) * 1979-10-01 1982-10-19 Southwire Company Method of forge-conditioning non-ferrous metals prior to rolling

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2019700A1 (en) * 1969-05-09 1970-11-19 Voest Ag Process for the production of heavy plates
FR2223114A1 (en) * 1973-03-26 1974-10-25 Nippon Kokan Kk
GB1596395A (en) * 1977-12-14 1981-08-26 Jernkontoret Forskningsavdelni Method of continuous casting of steels or metal alloys with segregation tendancy and apparatus for carrying out the method
GB2014071A (en) * 1978-02-13 1979-08-22 Nippon Kokan Kk Continuous casting of steel
FR2461010A1 (en) * 1979-07-12 1981-01-30 Doryokuro Kakunenryo PROCESS FOR IMPROVING RESISTANCE TO DECARBURIZATION OF CHROME-MOLYBDENE STEEL

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO8302783A1 *

Also Published As

Publication number Publication date
GB8326523D0 (en) 1983-11-02
EP0105368A1 (en) 1984-04-18
EP0105368B1 (en) 1988-06-01
WO1983002783A1 (en) 1983-08-18
GB2124939A (en) 1984-02-29
GB2124939B (en) 1986-02-05

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