EP0100125A3 - Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them - Google Patents

Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them Download PDF

Info

Publication number
EP0100125A3
EP0100125A3 EP83201070A EP83201070A EP0100125A3 EP 0100125 A3 EP0100125 A3 EP 0100125A3 EP 83201070 A EP83201070 A EP 83201070A EP 83201070 A EP83201070 A EP 83201070A EP 0100125 A3 EP0100125 A3 EP 0100125A3
Authority
EP
European Patent Office
Prior art keywords
alkylcellulose
carboxymethylcellulose
liquid detergent
detergent compositions
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83201070A
Other versions
EP0100125B1 (en
EP0100125A2 (en
Inventor
Jean Wevers
Barry Stoddart
Christian Barrat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AT83201070T priority Critical patent/ATE39126T1/en
Publication of EP0100125A2 publication Critical patent/EP0100125A2/en
Publication of EP0100125A3 publication Critical patent/EP0100125A3/en
Application granted granted Critical
Publication of EP0100125B1 publication Critical patent/EP0100125B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618—Protease or amylase in liquid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Aqueous homogeneous liquid detergent compositions containing additive levels of alkylcellulose and carboxymethylcellulose and a mixture of anionic and nonionic surface-active agents are disclosed. The compositions have a pH in the neutral to mildly alkaline range. The alkylcellulose/carboxymethylcellulose is present as a coacervate capable of forming, in combination with the surfactants, a network of loosely associated droplets. This network is tridimensional and provides means for stably and homogeneously suspending detergent components/additives which otherwise could not be incorporated, particularly ingredients which are substantially insoluble in the liquid compositions.
EP83201070A 1982-07-27 1983-07-20 Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them Expired EP0100125B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83201070T ATE39126T1 (en) 1982-07-27 1983-07-20 LIQUID DETERGENTS COMPOSITIONS CONTAINING A KOACERVAE MIXTURE OF ALKYLCELLULOSE AND CARBOXYMETHYLCELLULOSE AND PROCESS FOR THE PREPARATION THEREOF.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8221726 1982-07-27
GB8221726 1982-07-27

Publications (3)

Publication Number Publication Date
EP0100125A2 EP0100125A2 (en) 1984-02-08
EP0100125A3 true EP0100125A3 (en) 1986-09-10
EP0100125B1 EP0100125B1 (en) 1988-12-07

Family

ID=10531944

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83201070A Expired EP0100125B1 (en) 1982-07-27 1983-07-20 Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them

Country Status (7)

Country Link
EP (1) EP0100125B1 (en)
JP (1) JPH0713237B2 (en)
AT (1) ATE39126T1 (en)
CA (1) CA1217107A (en)
DE (1) DE3378637D1 (en)
GR (1) GR78636B (en)
IE (1) IE55461B1 (en)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3329400A1 (en) * 1983-08-13 1985-02-28 Henkel KGaA, 4000 Düsseldorf GRAY PREVENTIVE ADDITIVE FOR PHOSPHATE-FREE AND LOW-PHOSPHASE DETERGENTS
NL8304144A (en) * 1983-12-02 1985-07-01 Shell Int Research DETERGENT CONCENTRATES.
GB2160888B (en) * 1984-06-28 1987-12-23 Procter & Gamble Liquid cleansing compositions
GB8519046D0 (en) * 1985-07-29 1985-09-04 Unilever Plc Detergent compositions
GB8519047D0 (en) * 1985-07-29 1985-09-04 Unilever Plc Detergent composition
US5009800A (en) * 1987-12-01 1991-04-23 Lever Brothers Company, Division Of Conopco Inc. Fabric softening additive for detergent compositions: cellulose ether and organic fabric softener
GB8927729D0 (en) * 1989-12-07 1990-02-07 Unilever Plc Liquid detergents
GB8928067D0 (en) * 1989-12-12 1990-02-14 Unilever Plc Detergent compositions
GB8928022D0 (en) * 1989-12-12 1990-02-14 Unilever Plc Enzymatic liquid detergent compositions and their use
GB2245262A (en) * 1990-06-22 1992-01-02 Unilever Plc Aluminosilicate slurries l
DE4027832A1 (en) * 1990-09-01 1992-03-05 Henkel Kgaa LIQUID STAINLESS DETERGENT
ES2079138T3 (en) * 1991-06-14 1996-01-01 Procter & Gamble SELF-THICKENING CLEANING COMPOSITIONS.
EP0598335A3 (en) * 1992-11-13 1996-01-10 Albright & Wilson Novel cleaning compositions.
US6025311A (en) * 1993-12-17 2000-02-15 Aqualon Company Fluid suspension of polysaccharides for personal care and household applications
BR9508160A (en) * 1994-06-30 1997-08-12 Procter & Gamble Detergent compositions
GB2297978A (en) * 1995-02-15 1996-08-21 Procter & Gamble Detergent compositions containing amylase
US5990066A (en) * 1995-12-29 1999-11-23 The Procter & Gamble Company Liquid hard surface cleaning compositions based on carboxylate-containing polymer and divalent counterion, and processes of using same
US6384011B1 (en) 1997-09-15 2002-05-07 The Procter & Gamble Company Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith
EP1015543B1 (en) * 1997-09-15 2004-11-03 The Procter & Gamble Company Laundry detergent compositions with cyclic amine based polymers to provide appearance and integrity benefits to fabrics laundered therewith
CA2303560C (en) * 1997-09-15 2005-10-18 The Procter & Gamble Company Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6362156B1 (en) * 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6258771B1 (en) 1998-12-16 2001-07-10 Unilever Home & Personal Care, Usa Division Of Conopco Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
DE69937841T2 (en) 1999-01-13 2008-12-11 The Procter & Gamble Company, Cincinnati CELLULOSEPOLYMER-CONTAINING DETERGENT
MXPA03003739A (en) † 2000-10-27 2003-07-28 Procter & Gamble Stabilized liquid compositions.
DE10351321A1 (en) * 2003-02-10 2004-08-26 Henkel Kgaa Enhancing the cleaning performance of detergents through a combination of cellulose derivatives
DE102004053970A1 (en) * 2004-11-09 2005-09-15 Clariant Gmbh Liquid detergent and cleansing agent showing anti-creasing and anti-wear effects on textiles contains a combination of anionic and cationic surfactants
DE102004053969A1 (en) * 2004-11-09 2005-09-15 Clariant Gmbh Liquid laundry and other detergents, used for washing textiles and giving crease-resistant finish and protection from mechanical wear, contain secondary alkanesulfonate, soap and nonionic and cationic surfactants
DE102006039873B4 (en) * 2006-08-25 2013-10-31 Henkel Ag & Co. Kgaa Reinforcement of the cleaning performance of detergents by cotton-active soil release cellulose derivative
DE102007021793A1 (en) * 2007-05-07 2008-11-13 Henkel Ag & Co. Kgaa Washing or cleaning agent with polysaccharide
US8512480B2 (en) 2008-01-22 2013-08-20 The Procter & Gamble Company Liquid detergent composition comprising a hydrophobically modified cellulosic polymer
EP2083066A1 (en) * 2008-01-22 2009-07-29 The Procter and Gamble Company Liquid detergent composition
GB0808293D0 (en) * 2008-05-08 2008-06-11 Unilever Plc Laundry detergent composition
DE102012212726A1 (en) * 2012-07-19 2014-01-23 Henkel Ag & Co. Kgaa Stable, liquid detergent with graying-inhibiting performance
CN106795455B (en) * 2014-10-22 2020-08-07 罗门哈斯公司 Laundry detergents with amine additives
BR112017007537A2 (en) * 2014-10-22 2018-01-30 Rohm And Haas Company liquid laundry detergent containing amine additives
EP3101107B1 (en) * 2015-06-05 2019-04-24 The Procter and Gamble Company Compacted liquid laundry detergent composition
EP3101102B2 (en) * 2015-06-05 2023-12-13 The Procter & Gamble Company Compacted liquid laundry detergent composition
DE102016210744A1 (en) * 2016-06-16 2017-12-21 Henkel Ag & Co. Kgaa Concentrated liquid detergents with constant pH
DE17784205T1 (en) * 2016-09-28 2019-11-28 Cp Kelco Oy DETERGENT COMPOSITIONS WITH POLYSACCHARIDES WITH EXTREMELY LOW MOLECULAR WEIGHT

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB783585A (en) * 1954-11-18 1957-09-25 Armour & Co Improvements in or relating to liquid detergent compositions
US2886533A (en) * 1956-07-17 1959-05-12 Wyandotte Chemicals Corp Promoted detergent compositions
FR1192968A (en) * 1956-11-02 1959-10-29 Unilever Nv Improvements to liquid detergent compositions
US2994665A (en) * 1959-04-15 1961-08-01 Lever Brothers Ltd Heavy duty liquid detergent compositions containing a pair of cellulosic soil suspending agents
US3523088A (en) * 1966-12-13 1970-08-04 Procter & Gamble Novel antiredeposition agent and built detergent compositions containing said antiredeposition agent
DE1467704B1 (en) * 1965-12-09 1971-01-21 Witco Chemical Corp Process for the production of aqueous high-performance detergents and cleaning agents

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3163112D1 (en) * 1980-12-17 1984-05-17 Unilever Nv Detergent composition with reduced soil-redeposition effect

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB783585A (en) * 1954-11-18 1957-09-25 Armour & Co Improvements in or relating to liquid detergent compositions
US2886533A (en) * 1956-07-17 1959-05-12 Wyandotte Chemicals Corp Promoted detergent compositions
FR1192968A (en) * 1956-11-02 1959-10-29 Unilever Nv Improvements to liquid detergent compositions
US2994665A (en) * 1959-04-15 1961-08-01 Lever Brothers Ltd Heavy duty liquid detergent compositions containing a pair of cellulosic soil suspending agents
DE1467704B1 (en) * 1965-12-09 1971-01-21 Witco Chemical Corp Process for the production of aqueous high-performance detergents and cleaning agents
US3523088A (en) * 1966-12-13 1970-08-04 Procter & Gamble Novel antiredeposition agent and built detergent compositions containing said antiredeposition agent

Also Published As

Publication number Publication date
JPH0713237B2 (en) 1995-02-15
EP0100125B1 (en) 1988-12-07
DE3378637D1 (en) 1989-01-12
JPS5985000A (en) 1984-05-16
EP0100125A2 (en) 1984-02-08
IE55461B1 (en) 1990-09-26
IE831758L (en) 1984-01-27
CA1217107A (en) 1987-01-27
ATE39126T1 (en) 1988-12-15
GR78636B (en) 1984-09-27

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Free format text: AUTHORSHIP EACH 1/3 DR. HEYN, DR, SEIFERT, DR, STELZER; CHANGED FROM 1/2 DR. SEIFERT, 1/2 DR. STELZER

Inventor name: DR ARMIN HEYN