EP0098902A2

EP0098902A2 - Cascade flotation process and apparatus for carrying out the process

Info

Publication number: EP0098902A2
Application number: EP82303547A
Authority: EP
Inventors: Hjalmar Andreas Kaare Hitland
Original assignee: Individual
Current assignee: Individual
Priority date: 1982-07-06
Filing date: 1982-07-06
Publication date: 1984-01-25
Also published as: EP0098902A3

Abstract

Minerals and metals are separated from a crushed ore mixture of crushed ore, aqueous solution, and flotation agent by allowing the mixture to fall freely from one or more outlets (11) into a container (1), so entrapping air during the free fall and encouraging the development of a large quantity of froth. Air entrainment is enhanced by passing the mixture to the outlets (11) via a header (9) in which air is drawn in through an air inlet pipe (39).

Description

The flotation principle as applied to the recovery of minerals or metals from ore has been known for the last century, an example of a known froth flotation apparatus being shown in Canadian Patent Specification No. 167,476 issued on February 8th 1916 to Minerals Separation American Syndicate (1913) Limited. This specification relates to the concentration of sulphide ores by froth flotation separation in which the ores are subjected to aeration in an aqueous separating medium in the presence of a frothing agent. The aeration is obtained by passing crushed ore, froth and water through a series of pipes between vertically spaced containers, each pipe having an intermediate open topped container so that air can be entrapped in the mixture by exposure at the open top of the container. The mixture with air therein then passes into the next container through a submerged outlet. This system does provide a certain amount of aeration to the mixture, however it has since been determined that if more air can be entrapped in the mixture then more frothing will occur and a more efficient separation of the mixture will be possible.
Other methods of forming froth have been by aerating an ore mixture in an aqueous medium by vigorous agitation by means of stirrers, impellers, or beaters or by means of injection of compressed air generated by compressors and/or by means of utilizing high capacity centrifugal pumps. Such apparatus consume large amounts of power and are therefore expensive to operate.
According to the invention, a process of separating minerals or metals from a crushed ore mixture of crushed ore, aqueous solution, and a flotation agent comprises causing the mixture to fall freely into a container while entrapping air during the fall and thereby encouraging the development of froth at the top of the mixture in the container, and separating the froth and lighter component from the rest of the mixture in the container.
The mixture may be caused to enter and to fall freely our of a header which is provided with an air inlet whereby the mixture entrains air as it passes through the header. The mixture will then draw in air by the venturi principle and cascade through air into the container, so entrapping additional air during the cascading. The mixture may be held at a substantially constant level in the container by regulating flow from the bottom of the container, e.g. by a level sensing device which operates a valve near the base of the container. The frothing may be promoted further if the mixture falls onto a baffle situated adjacent to the surface of the mixture in the container.
The invention also includes apparatus for carrying out the process, the apparatus comprising a container, a mixture outlet situated above the container so that, in use, an air space exists between the mixture outlet and the surface of the mixture in the container, means for collecting froth from the top of the mixture in the container, and means for maintaining a substantially constant level of mixture in the container.
In one construction, the apparatus further comprises a header distribution box having an inlet for the mixture and a number of mixture outlet ducts, each of the outlet ducts being associated with an air inlet pipe whereby mixture passing through the distribution box from the inlet to the outlet ducts will entrain air drawn in through the air inlet pipes.
The means for collecting the froth may comprise a collecting launder to which:. e.g. the froth may be moved across the top of the mixture.
The invention will now be described with reference to the accompanying drawing, in which:-

Figure 1 is a diagrammatic plan view of one embodiment of apparatus for carrying out the invention;
Figure 2 is a diagrammatic side elevation of the Figure 1 embodiment;
Figure 3 is a diagrammatic plan view of a second embodiment of apparatus for carrying out the invention;
Figure 4 is a diagrammatic side elevation of the Figure 3 embodiment; and,
Figure 5 is a diagrammatic front elevation of the Figure 3 embodiment.

Referring to Figures 1 and 2, a container 1 has a froth retainer 3 and a froth collecting launder 5. Inlet pipe 7 is coupled to a distribution header box 9 which has three vertically oriented outlet pipes 11 extending from the bottom thereof. Three pipes 11 are shown in this embodiment, however the apparatus will function with a lesser or greater number of outlet pipes, less pipes producing slightly less aeration and more pipes producing slightly more aeration of the mixture. Outlet pipes 11 are each fitted with an air intake venturi pipe 39 extending from above the header box 9 down into the pipe. A shield 13, adjustably held by rods 15 which pass through slots 17 in brackets 19, is positioned immediately below the outlet pipes 11 and above the level 21 of mixture in the container l.A perforate baffle 23 is situated inside the container below the shield 13 and is secured to the side of the container by a suitable bracket 25. The baffle 23 is shown as being flat and in a horizontally disposed position below the surface of the mixture, however it could be on the surface of the mixture, curved, or of any other form or inclined to the horizontal, the position, form and attitude of the baffle being selected, and preferably variable, possibly even during operation, to suit the mixture being processed, so as to achieve maximum dispersion of froth and flotation of fine and coarse materials.
A mixture level controlling valve 27 is situated near the base of the container and in the simple form shown consists of a U-shaped hollow body 29 having a stopper 31 which fits in a sealing manner in the top aperture of the body 29. The stopper 31 is secured to a rod 33 which is reciprocally moved by an actuator 35 which is operated through a sensor (not shown) which senses the level 21 of the mixture in the container. An outlet pipe 37 leads off the froth from the collecting launder 5.
The arrows in Figure 2 show the flow of the mixture entering through pipe 7, and after being aerated, falling through pipes 11 to be further aerated, being diverted against baffle 23 and being dumped through valve 27 to retain a constant level of mixture in the container. Arrows also show the removal of froth through outlet 370
In carrying out the process of this invention, crushed ore is mixed with water and flotation agents which are selected to suit the ore being treated. Such flotation agents are well known in the industry and form no part of this invention. The mixture is then passed through pipe 7 into distribution header box 9, wherein it is aerated by venturi pipes 39, and out through pipes 11. The mixture falls freely through the air into the container 1 through the shield 13 which merely reduces the amount of splashing caused when the aerated mixture hits the surface 21 of the mixture in the container. More aeration is achieved by the free fall of the mixture and by the splashing caused at the surface 21. The flow of the mixture is partly controlled in the container by baffle 23 which tends to cause the froth being formed to move towards the collecting launder 5 from which it is retrieved from outlet 37 for further processing. The level of the surface 21 of the mixture in the container is held constant by controlling valve 27, the mixture being dumped through valve 27 either being reprocessed through additional flotation apparatus, passed on to further mill processes or discarded,
By using this process, a very large amount of aeration of the mixture is achieved through the venturi injection of air and the cascading of the mixture from pipes 11 to the surface 21 of the mixture in container 1, and, as the separation efficiency rises through an increase in the aeration in the mixture, the efficiency of this process has been found to be at least as high as any presently known commercial process.
There is also a great reduction in power requirements over known froth flotation processes requiring agitators, stirrers compressed air injection and the like to provide aeration, as this process can be carried out mainly under the influence of gravity if it is arranged that the apparatus is situated below the ore crushing and mixture preparation apparatus.
Multiple cascading can also be arranged by positioning single units one above the other. An embodiment having two stacked units is shown in Figures 3, 4, and 5 and the same reference numerals are used for like parts to those in Figures 1 and 2. The level of mixture in a unit is held constant in this embodiment by permitting the mixture left, after froth collection from launder 5, to pass through pipe 41 and flow into a trough 43 so passing through outlet pipes 11 to the next unit. The level of mixture can be controlled at a desired height by use of interfitting collars 45 which are well known for mixture height control in this field. The baffle 23 is also shown in a horizontal attitude in this embodiment but it is preferable that the baffle be adjustable in height and/or inclination, preferably during operation, to suit the type of mixture being processed. If additional banks of units are required the residual mixture can be returned to a convenient height by pumping.
Single units can also be usefully employed at the discharge end of a mill to reclaim minerals which would be otherwise lost in the mill tailings flow. A single unit in such a location can recover up to 50 to 75% of the mineral presently being lost without additional expenditure of power or energy with or without additional frothing agents. Some milling processes lose as much or more than 2000 lbs. of mineral in a 24 hour period and therefore recovery of 50% of this amount can produce, with negligible cost, an additional recovery of 1000 lbs. of mineral in a 24 hour period which would otherwise be lost.
The ability of the unit to float much coarser materials and heavier minerals also leads to increased recoveries of heavier precious metals such as gold and silver and faster recoveries of base metals still in a coarse state. For instance iron is always present as an unwanted mineral in copper and/or zinc recovery and can be removed more easily with the unit of this invention. The iron and sulphide containing materials can, after removal, be then used as backfill in mining operations instead of being disposed of in tailings disposal areas where they create environment problems.
The ability of the unit to separate coarse material also reduces the necessity for excessively fine grinding of ores to attain maximum mineral recovery.
On screen tests the cascade unit shows remarkable ability to recover coarse materials. A standard recovery at an existing mill has shown that a very fine grind is necessary to obtain a large recovery of copper and that almost 3/4 of the recovery is attained at the excessively fine grind of -325 mesh with standard known Denver or Wemco (Trade Marks) units in use, and then only after passing the material through many consecutive standard units. A single cascade unit however, produced over 50% of its concentrate from coarse material, with less then 50% in the fine range. Several successive cascades can recover the same concentrate without the successively fine grinding now used.
The results obtained in the above test are as follows:
The cascade unit therefore produced 51.64% of coarse minerals whereas the standard Denver and Wemco units is multiple banks produced only 26.73% of coarse minerals.
A test has also been conducted with the cascade unit as a scavenger cell at the tailings end of a mill where it handled the full flow of the mill circuit which was between 1500 and 1800 tons every 24 hours. The recovered concentrate was assayed and produced recoveries of zin in concentrate of 21.5 to 26% with high iron recoveries of 29 to 33%.
The cascade unit was then placed in a primary copper recovery circuit in the same mill and in a two hour forty minutes test period produced the following results:
Finally, the cascade unit was placed on stream and in a test period of three and one half days produced a high grade concentrate at least equivalent to a unit tank cell which was 27 times larger in volume than the cascade unit.

Claims

1. A process of separating minerals or metals from a crushed ore mixture of crushed ore, aqueous solution, and a flotation agent by causing the mixture to fall freely into a container (1) while entrapping air during the fall and thereby encouraging the development of froth at the top of the mixture in the container, and separating the froth and lighter component from the rest of the mixture in the container.

2. A process according to claim 1, wherein the mixture is caused to enter and to fall freely out of'a header (9) which is provided with an air inlet whereby the mixture entrains air as it passes through the header.

3. A process according to claim 1 or claim 2, wherein the surface level of the mixture in the container (1) is regulated by dumping excess mixture from the base of the container.

4. A process according to any one of the preceding claims, wherein the mixture falls onto a baffle (23) situated adjacent to the surface of the mixture in the container.

5. Apparatus for carrying out the process according to any one of the preceding claims, the apparatus comprising a container (1), a mixture outlet (11) situated above the container so that, in use, an air space exists betweem the mixture outlet and the surface of the mixture in the container, means (5) for collecting froth from the top of the mixture in the container, and means (27,31,35) for maintaining a substantially constant level of mixture in the container.

6. Apparatus according to claim 5, wherein a perforate baffle (23) is situated in the top of the container in the free fall path from the mixture outlet.

7. Apparatus according to claim 5 or claim 6, further comprising a header distribution box (9) having an inlet (7) for the mixture and a number of mixture outlet ducts (11), each of the outlet ducts being associated with an air inlet pipe (39) whereby mixture passing through the distribution box from the inlet to the outlet ducts will entrain air drawn in through the air inlet pipes.

8. Apparatus according to any one of claims 5 to 7, wherein a tubular shield (13) extends upwards from the top of the container towards the mixture outlet, for the mixture to fall through into the container.

9. Apparatus according to any one of claim 5 to 8, wherein the means for maintaining a substantially constant level of mixture in the container comprises a sensor for sensing the surface level of mixture in the container and a valve (27) situated adjacent of the bottom of the container and responsive to the sensor for dumping mixture from the bottom of the container.

10. Apparatus according to any one of claims 5 to 9, in which the means for collecting the froth comprises a collecting launder (5)0