EP0094958A1 - Procede de production de pentose et d'hexose a partir d'un materiau cellulosique contenant des pentosanes au moyen d'une hydrolyse acide - Google Patents
Procede de production de pentose et d'hexose a partir d'un materiau cellulosique contenant des pentosanes au moyen d'une hydrolyse acideInfo
- Publication number
- EP0094958A1 EP0094958A1 EP19820903578 EP82903578A EP0094958A1 EP 0094958 A1 EP0094958 A1 EP 0094958A1 EP 19820903578 EP19820903578 EP 19820903578 EP 82903578 A EP82903578 A EP 82903578A EP 0094958 A1 EP0094958 A1 EP 0094958A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pentose
- xylose
- hexose
- acid
- hydrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class
- C13K13/002—Xylose
Definitions
- This invention relates to a process for the production of pentose and hexose from a cellulosic material containing pentosans by -> 5 acid hydrolysis, said process comprising the step of heating the cel ⁇ lulosic material to an elevated temperature in the presence of a ? strong acid .
- glucose can be prepared from various cellulosic materials, such as straw, sawdust, wood waste and sugar 10 cane bagasse, by heating the cellulosic material to an elevated tempe ⁇ rature in the presence of sulphuric acid .
- Methods of this type have lately attracted considerable interest, partly because ' cellulosic raw materials are available in very large amounts and partly because there is a growing need for providing cheap glucose for use as a 15 starting material in the production of ethanol by fermentation .
- hydrolysis of the pentosans to form xylose should also be carefully controlled in order to avoid that the hydrolysate, viz. xylose, is further converted into furfural .
- the hydrolysis is effected at a tempe ⁇ rature of between 210 and 250°C for a period of between 5 and 90 seconds and in the presence of an acid having a concentration of from 0.2 to 2.0 % by weight.
- the invention is based on the discovery that when using for example straw as starting material and by performing the hydro ⁇ lysis under the above mentioned operational conditions, it is possible to obtain a yield of xylose of about 50% (based on the amount of pentosans present in the starting material) together with a yield of glucose of above 50% (based on the amount of cellulose in the starting material).
- the highest yields of xylose and glucose are obtained by effecting the hydrolysis at a temperature of from 225 to 235°C for a period of 30-60 seconds.
- the reaction temperature and the reaction time should be carefully controlled and in a preferred embodiment of the method of the invention the acid hydrolysis is effected under pressure, e.g. at a pressure of 2-5 MPa in a tubular reactor and by heating the start ⁇ ing material by steam injection .
- the reaction mixture can be rapidly heated and a corresponding rapid cooling can be effected by pressure relief, e. g . to atmospheric pressure.
- the pressure- relieved product Is preferably further cooled or is neutral- ized by addition of base, such as Ca(OH) , in order to raise the pH value to 3 or above so as to stop the decomposition of glucose and xylose.
- the neutralized product may then be filtered so as to form a filtrate containing xylose and glucose and a filter cake which option ⁇ ally after being dried is suitable as a solid fuel.
- a filter cake which option ⁇ ally after being dried is suitable as a solid fuel.
- the use of the filter cake as a solid fuel decreases the energy consumption of the process.
- the filtrate may be separated into a xylose fraction and a glucose fraction but it is preferred to subject the filtrate to a fer ⁇ mentation before xylose is separated.
- xylose is subse- quently separated, optionally in connection with part of the fermen ⁇ tation medium which is also suitable as animal feed together with the xylose.
- the straw When using straw as starting material the straw is prefer ⁇ ably cut into pieces having a length of about 1-10 cm. When using other naturally occurring cellulosic materials containing pentosans, these should preferably be comminuted before the acid hydrolysis is started.
- Examples of other suitable starting materials are sawdust, paper waste, bagasse, oat shells, corncobs and beet pulp.
- the acid used is preferably a strong mineral acid, such as sulphuric acid, but also other mineral acids, such as hydrochloric acid are suitable.
- Example 1 Barley straw was cut into lengths of about 1 cm and slurr ⁇ ed in a sulphuric acid solution .
- the slurry thus obtained was pumped into a tubular reactor under a pressure of 3.2-4 MPa.
- the temperature was raised to 230°C by direct injection of steam. After the injection of steam the acid concentration was 0.75%.
- the tempera ⁇ ture was maintained for 30 seconds and then the pressure was sud ⁇ denly relieved to atmospheric pressure. As a result of said pressure relief a steam phase and an aqueous phase having a temperature of 100 C were formed .
- the aqueous phase containing xylose and glucose was cooled to below 70°C.
- Xylose was separated from the cooled aqueous phase in a yield of 63% (based on the weight of the pentosans present in the straw) and glucose was separated in a yield of 35% (based on the weight of the cellulose present in the straw) .
- Example 3 The same procedure as described in Example 1 was used except that the reaction time was 41 seconds. The yield of xylose was 53% and the yield of glucose 41%.
- Example 4 The same procedure as described in Example 1 was used, except that the concentration of the sulphuric acid solution was 0.63% and the reaction time was 45 seconds. The yield of xylose was 55% and the yield of glucose 48%.
- Example 5 Barley straw was cut into lengths of about 3 cm and was pumped into a reactor under a pressure of 3.2-4 MPa. To the straw was added a sulfurlc acid solution of a temperature of 180 C and the mixture thus obtained was immediately heated to a temperature of 230 C by direct injection of steam . After the injection of steam the acid concentration was 0.8%. The temperature was maintained for 59 seconds and then the pressure was suddenly relieved to atmospheric pressure. As a result of said pressure relief a steam phase and an aqueous phase having a temperature of 100 C were formed . The aqueous phase containing xylose and glucose was cooled to below 70°C .
- Xylose was recovered from the cooled aqueous phase in a yield of 18% (based on the weight of the pentosans present in the straw) and glucose was recovered in a yield of 53% (based on the weight of the cellulose present in the straw) .
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procédé de production de pentose et d'hexose à partir d'un matériau cellulosique contenant des pentosanes au moyen d'une hydrolyse acide, dans lequel le matériau de base est chauffé à une température comprise entre 210 et 250oC pendant une durée variable entre 5 et 90 secondes en présence d'un acide fort possédant une concentration comprise entre 0,2 et 2 % en poids. Un rendement élevé de production du pentose aussi bien que de l'hexose est obtenu par ce procédé à phase unique.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK5228/81 | 1981-11-25 | ||
DK522881A DK522881A (da) | 1981-11-25 | 1981-11-25 | Fremgangsmaade til omdannelse af et pentosanholdigt cellulosemateriale til xylose og glukose ved syrehydrolyse |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0094958A1 true EP0094958A1 (fr) | 1983-11-30 |
Family
ID=8140623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19820903578 Withdrawn EP0094958A1 (fr) | 1981-11-25 | 1982-11-24 | Procede de production de pentose et d'hexose a partir d'un materiau cellulosique contenant des pentosanes au moyen d'une hydrolyse acide |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0094958A1 (fr) |
DK (1) | DK522881A (fr) |
WO (1) | WO1983001958A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2580669B1 (fr) * | 1985-04-18 | 1987-09-18 | Inst Francais Du Petrole | Procede de conversion de substrats lignocellulosiques en pentoses |
CN112159869B (zh) | 2010-01-19 | 2024-04-19 | 瑞恩麦特克斯股份有限公司 | 使用超临界流体从生物质产生可发酵的糖和木质素 |
MY171010A (en) | 2011-05-04 | 2019-09-23 | Renmatix Inc | Lignin production from lignocellulosic biomass |
WO2012151521A2 (fr) | 2011-05-04 | 2012-11-08 | Renmatix, Inc. | Hydrolyse de cellulose en plusieurs étapes, et trempe avec ou sans acide |
WO2012151536A2 (fr) | 2011-05-04 | 2012-11-08 | Renmatix, Inc. | Hydrolyse de cellulose avec ajustement du ph |
US8759498B2 (en) | 2011-12-30 | 2014-06-24 | Renmatix, Inc. | Compositions comprising lignin |
CN107074981A (zh) | 2014-09-26 | 2017-08-18 | 瑞恩麦特克斯股份有限公司 | 含纤维素的组合物以及其制造方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3212933A (en) * | 1963-04-12 | 1965-10-19 | Georgia Pacific Corp | Hydrolysis of lignocellulose materials with solvent extraction of the hydrolysate |
AT358491B (de) * | 1979-03-01 | 1980-09-10 | Ruthner Othmar | Aufbereitung von muell- und klaerschlamm |
-
1981
- 1981-11-25 DK DK522881A patent/DK522881A/da not_active Application Discontinuation
-
1982
- 1982-11-24 WO PCT/DK1982/000104 patent/WO1983001958A1/fr not_active Application Discontinuation
- 1982-11-24 EP EP19820903578 patent/EP0094958A1/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO8301958A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1983001958A1 (fr) | 1983-06-09 |
DK522881A (da) | 1983-05-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19831202 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Withdrawal date: 19841228 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: NIELSEN, WERNER KOFOD Inventor name: BUUS, LASSE |