EP0090645A1 - Detergent bar processing - Google Patents
Detergent bar processing Download PDFInfo
- Publication number
- EP0090645A1 EP0090645A1 EP83301763A EP83301763A EP0090645A1 EP 0090645 A1 EP0090645 A1 EP 0090645A1 EP 83301763 A EP83301763 A EP 83301763A EP 83301763 A EP83301763 A EP 83301763A EP 0090645 A1 EP0090645 A1 EP 0090645A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cavities
- rotor
- stator
- soap
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/10—Mixing; Kneading
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/14—Shaping
Definitions
- This invention relates to the processing of soap-containing feedstocks to harden the soap bar product.
- Soap bars are required to have a hardness which allows them to maintain their physical integrity during manufacture, packing and use.
- a bar having a hardness below the satisfactory level may deform and may be marked by handling after manufacture.
- Examples of bars which are liable to softness include those having a high proportion of unsaturated feedstocks eg, tallow, soya and palm, and those containing a relatively high level of water (ca 13% and higher).
- the high level of water may be present to provide optimum properties relating to another component.
- the present invention achieves hardening of the soap material by subjecting it to considerable working within a specific temperature range in an efficient manner; the temperature range being sensitive to composition.
- the present invention uses a device of the cavity transfer mixer class to work the soap base.
- These devices comprise two closely spaced mutually displaceable surfaces each having a pattern of cavities which overlap during movement of surfaces so that material moved between the surfaces traces a path through cavities alternately in each surface so that the bulk of the material passes through the shear zone in the material generated by displacement of the surfaces.
- Cavity transfer mixers are normally prepared with a cylindrical geometry and in the preferred devices for this process the cavities are arranged to give constantly available but changing pathways through the device during mutual movement of the two surfaces.
- the devices having a cylindrical geometry will comprise a stator within which is journalled a rotor; the opposing faces of the stator and rotor carry the cavities through which the material passes during its passage through the device.
- the device may also have a planar geometry in which opposed plane surfaces having patterns of cavities would be moved mutually, for example by rotation of one plane, so that material introduced between the surfaces at the point of rotation would move outwards and travel alternately between cavities on each surface.
- auxilliary equipment As the rotor is turned.
- auxilliary equipment are screw extruders and piston rams.
- the auxiliary equipment is preferably operated separately from the mixer so that the throughput and work performed on it can be separately varied.
- the separate operation may be achieved by arranging the auxiliary equipment to provide material for processing at an angle to the centre line of the shear-producing device. This arrangement allows rotational energy to be supplied to the device producing shear around its centre line. An in-line arrangement is more easily achieved when the external member of the device is the rotor. Separate operation of the device and auxiliary equipment assists in providing control of the processing.
- cavity shapes In general a variety of cavity shapes can be used, for example Metal Box (UK 930 339) disclose longitudinal slots in the two surfaces.
- the stator and rotor may carry slots, for example six to twelve, spaced around their periphery and extending along their whole length.
- one or both surfaces are subjected to thermal control.
- the process allows efficient heating/ cooling of the material to be achieved.
- the temperature of the material during processing is in the range from about 30°C to about 55°C, preferably up to 50°C.
- the soap feedstock may contain non-soap detergents in amounts which would not interfere with the desired effect.
- these actives are alkane sulphonates, alcohol sulphates, alkyl benzene sulphonates, alkyl sulphates, acyl isethionates, olefin sulphonates and ethoxylated alcohols.
- the processed feedstock was made into bar form using standard stamping machinery.
- Other product forms eg extruded particles (noodles) and beads can be prepared from the feedstock.
- a cavity transfer mixer is shown in Figure 1 in longitudinal section. This comprises a hollow cylindrical stator member 1, a cylindrical rotor member 2 journalled for rotation within the stator with a sliding fit, the facing cylindrical surfaces of the rotor and stator carrying respective pluralities of parallel, circumferentially extending rows of cavities which are disposed with:
- the pattern of cavities carried on the stator 3 and rotor 4 are illustrated on Figure 3.
- the cavities 3 on the stator are shown hatched.
- the overlap between patterns of cavities 3, 4 is also shown in Figure 2. .
- a liquid jacket 1A is provided for the application of temperature control by the passage of heating or cooling water.
- a temperature control conduit 2A is provided in the rotor.
- the material passing through the device moves through the cavities alternately on the opposing faces of the stator and rotor.
- the cavities immediately behind those shown in section are indicated by dotted profiles on Figure 1 to allow the repeating pattern to be seen.
- the material flow is divided between pairs of adjacent cavities on the same rotor or stator face because of the overlapping position of the cavity on the opposite stator or rotor face.
- the whole or bulk of the material flow is subjected to considerable working during its passage through the shear zone generated by the mutual displacement of the stator and rotor surfaces.
- the material is entrained for a short period in each cavity during passage and thus one of its velocity components is altered.
- the mixer had a rotor radius of 2.54 cm with 36 hemispherical cavities (radius 0.9 cm) arranged in six rows of six cavities.
- the internal surface of the stator carried seven rows of six cavities to provide cavity overlap at the entry and exit.
- the material to be worked was injected into the device through channel 5, which communicates with the annular space between the rotor and stator, during operation by a screw extruder. The material left the device through nozzle 6.
- Figure 4 shows elongate cavities arranged in a square pattern; these cavities have the sectional profile of Figure 2. These cavities are aligned with their longitudinal axis parallel to the longitudinal axis of the device and the direction of movement of material through the device; the latter is indicated by the arrow.
- Figure 5 shows a pattern of cavities having the dimensions and profile of those shown in Figures 1, 2 and 3.
- the cavities of Figure 5 are arranged in a square pattern with each cavity being closely spaced from flow adjacent cavities on the same surface. This pattern does not provide as high a degree of overlap as given by the pattern of Figure 3.
- the latter has each cavity closely spaced to six cavities on the same surface, ie a hexagonal pattern.
- Figure 6 is a section of a cavity transfer mixer having a rotor 7 rotatably positioned within the hollow stator 8 having an effective length of 10.7 cm and a diameter of 2.54 cm.
- the rotor carried five parallel grooves 9 of semi-circular cross section (diameter 5 mm) equally spaced around the periphery and extending parallel to the longitudinal axis along the length of the rotor.
- the inner cylindrical surface of the stator 8 carried eight grooves 10 of similar dimensions extending along its length and parallel to the longitudinal axis. This embodiment, utilised cavities extending along the length of the stator and rotor without interruption. Temperature control jacket and conduit were present.
- Figure 7 shows a pattern of cavities wherein the cavities on the rotor, shown hatched, and stator have a larger dimension normal to the material flow; the latter is indicated by an arrow.
- the cavities are thus elongate.
- This embodiment provides a lower pressure drop over its length compared with devices of similar geometry but not having cavities positioned with a longer dimension normal, i.e. perpendicular to the material flow. To obtain a reduction in pressure drop at least one of the surfaces must carry elongate cavities having their longer dimension normal to the material flow.
- the cavity transfer mixer of Figure 8 had the external cylinder 11 journalled for rotation about central shaft 12. Temperature control jacket 13 and conduit were present but the latter is now shown because the cavities on the central shaft are shown in plan view while the rotor is sectioned.
- the central stator (diameter 52 mm) had three rows 14 of three cavities with partial, i.e. half cavities at the entry and exit points. On the rotor there were four rows 15 of three cavities.
- TIle cavities on the stator and rotor were elongate with a total arc dimension of 5.1 cm normal to the material flow with hemispherical section ends of 1.2 cm radius joined by a semicircular sectioned panel of the same radius.
- the cavities were arranged in the pattern of Figure 7, i.e. with their long dimension normal to material flow.
- the rotor was driven by a chain drive to external toothed wheel 16.
- the mixer had a rotor radius of 2.54cm with 36 hemispherical cavities (radius 0.9cm) arranged in six rows of six cavities.
- the internal surface of the stator carried seven rows of six cavities to provide cavity overlap at the entry and exit.
- the temperatures used for processing the feedtocks to provide the designed hardening will be dependant on the composition used.
- Tallow fat was saponified, washed, fitted and vacuum dried to 20% moisture. The chips were then extruded through the device with the aid of a soap plodder. The hardness was measured with a SUR (Berlin) penetrometer using a 9° conical needle under a total force of 200g for 10 seconds. Cooling water was applied to the stator and rotor. The results are given in the Table I.
- a soap feedstock comprising tallow 76% coconut 12% and soya bean oil 12% was prepared at a moisture content of 16.5%.
- the feedstock was processed as in Example I and the hardness measured.
- a feedstock of tallow/coconut 80/20 was prepared and the moisture increased to 18% by cold milling additional waterin.
- the feedstock was processed as in Example I and the hardness measured.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Compounds Of Unknown Constitution (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
- This invention relates to the processing of soap-containing feedstocks to harden the soap bar product.
- Soap bars are required to have a hardness which allows them to maintain their physical integrity during manufacture, packing and use. A bar having a hardness below the satisfactory level may deform and may be marked by handling after manufacture.
- Examples of bars which are liable to softness include those having a high proportion of unsaturated feedstocks eg, tallow, soya and palm, and those containing a relatively high level of water (ca 13% and higher). The high level of water may be present to provide optimum properties relating to another component. The present invention achieves hardening of the soap material by subjecting it to considerable working within a specific temperature range in an efficient manner; the temperature range being sensitive to composition.
- The present invention uses a device of the cavity transfer mixer class to work the soap base. These devices comprise two closely spaced mutually displaceable surfaces each having a pattern of cavities which overlap during movement of surfaces so that material moved between the surfaces traces a path through cavities alternately in each surface so that the bulk of the material passes through the shear zone in the material generated by displacement of the surfaces.
- Cavity transfer mixers are normally prepared with a cylindrical geometry and in the preferred devices for this process the cavities are arranged to give constantly available but changing pathways through the device during mutual movement of the two surfaces. The devices having a cylindrical geometry will comprise a stator within which is journalled a rotor; the opposing faces of the stator and rotor carry the cavities through which the material passes during its passage through the device.
- The device may also have a planar geometry in which opposed plane surfaces having patterns of cavities would be moved mutually, for example by rotation of one plane, so that material introduced between the surfaces at the point of rotation would move outwards and travel alternately between cavities on each surface.
- Another form of cylindrical geometry maintains the inner cylinder stationary while rotating the outer cylinder. The central stator is more easily cooled, or heated if required, because the fluid connections can be made in a simple manner; the external rotor can also be cooled or heated in a simple manner. It is also mechanically simpler to apply rotational energy to the external body rather than the internal cylinder. Thus this configuration has advantages in construction and use.
- Material is forced through the mixer using auxilliary equipment as the rotor is turned. Examples of the auxilliary equipment are screw extruders and piston rams. The auxiliary equipment is preferably operated separately from the mixer so that the throughput and work performed on it can be separately varied. The separate operation may be achieved by arranging the auxiliary equipment to provide material for processing at an angle to the centre line of the shear-producing device. This arrangement allows rotational energy to be supplied to the device producing shear around its centre line. An in-line arrangement is more easily achieved when the external member of the device is the rotor. Separate operation of the device and auxiliary equipment assists in providing control of the processing.
- In general a variety of cavity shapes can be used, for example Metal Box (UK 930 339) disclose longitudinal slots in the two surfaces. The stator and rotor may carry slots, for example six to twelve, spaced around their periphery and extending along their whole length.
- Preferably one or both surfaces are subjected to thermal control. The process allows efficient heating/ cooling of the material to be achieved.
- Preferably the temperature of the material during processing is in the range from about 30°C to about 55°C, preferably up to 50°C.
- The soap feedstock may contain non-soap detergents in amounts which would not interfere with the desired effect. Examples of these actives are alkane sulphonates, alcohol sulphates, alkyl benzene sulphonates, alkyl sulphates, acyl isethionates, olefin sulphonates and ethoxylated alcohols.
- The processed feedstock was made into bar form using standard stamping machinery. Other product forms, eg extruded particles (noodles) and beads can be prepared from the feedstock.
- Drawings:
- The invention will be described with reference to the accompanying diagrammatic drawings in which:
- Figure 1 is a longitudinal section of a cavity transfer mixer with cylindrical geometry;
- Figure 2 is a transverse section along the line II-II on Figure 1;
- Figure 3 illustrates the pattern of cavities in the device of Figure 1;
- Figures 4, 5 and 7 illustrate other patterns of cavities;
- Figure 6 is a transverse section through a mixer having grooves in the opposed surfaces of the device;
- Figure 8 is a longitudinal section of a cavity transfer mixer in which the external cylinder forms the rotor.
- Embodiments of the devices will now be described.
- A cavity transfer mixer is shown in Figure 1 in longitudinal section. This comprises a hollow cylindrical stator member 1, a
cylindrical rotor member 2 journalled for rotation within the stator with a sliding fit, the facing cylindrical surfaces of the rotor and stator carrying respective pluralities of parallel, circumferentially extending rows of cavities which are disposed with: - a) the cavities in adjacent rows on the stator circumferentially offset;
- b) the cavities in adjacent rows on the rotor circumferentially offset; and
- c) the rows of cavities on the stator and rotor axially offset.
- The pattern of cavities carried on the
stator 3 and rotor 4 are illustrated on Figure 3. Thecavities 3 on the stator are shown hatched. The overlap between patterns ofcavities 3, 4 is also shown in Figure 2.. A liquid jacket 1A is provided for the application of temperature control by the passage of heating or cooling water. Atemperature control conduit 2A is provided in the rotor. - The material passing through the device moves through the cavities alternately on the opposing faces of the stator and rotor. The cavities immediately behind those shown in section are indicated by dotted profiles on Figure 1 to allow the repeating pattern to be seen.
- The material flow is divided between pairs of adjacent cavities on the same rotor or stator face because of the overlapping position of the cavity on the opposite stator or rotor face.
- The whole or bulk of the material flow is subjected to considerable working during its passage through the shear zone generated by the mutual displacement of the stator and rotor surfaces. The material is entrained for a short period in each cavity during passage and thus one of its velocity components is altered.
- The mixer had a rotor radius of 2.54 cm with 36 hemispherical cavities (radius 0.9 cm) arranged in six rows of six cavities. The internal surface of the stator carried seven rows of six cavities to provide cavity overlap at the entry and exit. The material to be worked was injected into the device through
channel 5, which communicates with the annular space between the rotor and stator, during operation by a screw extruder. The material left the device through nozzle 6. - Figure 4 shows elongate cavities arranged in a square pattern; these cavities have the sectional profile of Figure 2. These cavities are aligned with their longitudinal axis parallel to the longitudinal axis of the device and the direction of movement of material through the device; the latter is indicated by the arrow.
- Figure 5 shows a pattern of cavities having the dimensions and profile of those shown in Figures 1, 2 and 3. The cavities of Figure 5 are arranged in a square pattern with each cavity being closely spaced from flow adjacent cavities on the same surface. This pattern does not provide as high a degree of overlap as given by the pattern of Figure 3. The latter has each cavity closely spaced to six cavities on the same surface, ie a hexagonal pattern.
- Figure 6 is a section of a cavity transfer mixer having a rotor 7 rotatably positioned within the
hollow stator 8 having an effective length of 10.7 cm and a diameter of 2.54 cm. The rotor carried fiveparallel grooves 9 of semi-circular cross section (diameter 5 mm) equally spaced around the periphery and extending parallel to the longitudinal axis along the length of the rotor. The inner cylindrical surface of thestator 8 carried eight grooves 10 of similar dimensions extending along its length and parallel to the longitudinal axis. This embodiment, utilised cavities extending along the length of the stator and rotor without interruption. Temperature control jacket and conduit were present. - Figure 7 shows a pattern of cavities wherein the cavities on the rotor, shown hatched, and stator have a larger dimension normal to the material flow; the latter is indicated by an arrow. The cavities are thus elongate. This embodiment provides a lower pressure drop over its length compared with devices of similar geometry but not having cavities positioned with a longer dimension normal, i.e. perpendicular to the material flow. To obtain a reduction in pressure drop at least one of the surfaces must carry elongate cavities having their longer dimension normal to the material flow.
- The cavity transfer mixer of Figure 8 had the
external cylinder 11 journalled for rotation aboutcentral shaft 12.Temperature control jacket 13 and conduit were present but the latter is now shown because the cavities on the central shaft are shown in plan view while the rotor is sectioned. The central stator (diameter 52 mm) had threerows 14 of three cavities with partial, i.e. half cavities at the entry and exit points. On the rotor there were fourrows 15 of three cavities. TIle cavities on the stator and rotor were elongate with a total arc dimension of 5.1 cm normal to the material flow with hemispherical section ends of 1.2 cm radius joined by a semicircular sectioned panel of the same radius. The cavities were arranged in the pattern of Figure 7, i.e. with their long dimension normal to material flow. The rotor was driven by a chain drive to external toothed wheel 16. - Examples of the process of the invention will now be given. The cavity transfer mixer illustrated in Figure 1 was used.
- The mixer had a rotor radius of 2.54cm with 36 hemispherical cavities (radius 0.9cm) arranged in six rows of six cavities. The internal surface of the stator carried seven rows of six cavities to provide cavity overlap at the entry and exit.
- The temperatures used for processing the feedtocks to provide the designed hardening will be dependant on the composition used.
- Tallow fat was saponified, washed, fitted and vacuum dried to 20% moisture. The chips were then extruded through the device with the aid of a soap plodder. The hardness was measured with a SUR (Berlin) penetrometer using a 9° conical needle under a total force of 200g for 10 seconds. Cooling water was applied to the stator and rotor. The results are given in the Table I.
- A soap feedstock comprising tallow 76
% coconut 12% andsoya bean oil 12% was prepared at a moisture content of 16.5%. The feedstock was processed as in Example I and the hardness measured. -
- The treatment of these feedstocks thus produced a hardening of the bars.
- These examples utilised a cavity transfer mixing device with cavities of diameter 2.4 cm arranged circumferentially.
- Eight cavities on the stator and seven cavities plus half cavities at each end on the rotor were present on the components shown in Figure I. Water cooling was applied to the stator and rotor. The formulations, which had a relatively high water content and which contained feedstocks providing physically soft bars, are given in Table II. The results are quoted in Table III. The feedstock oils and fats are quoted as percentages of the fat charge.
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT83301763T ATE22463T1 (en) | 1982-03-29 | 1983-03-29 | PROCESS FOR DETERGENT BAR MANUFACTURE. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8209150 | 1982-03-29 | ||
GB8209150 | 1982-03-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0090645A1 true EP0090645A1 (en) | 1983-10-05 |
EP0090645B1 EP0090645B1 (en) | 1986-09-24 |
Family
ID=10529358
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83301763A Expired EP0090645B1 (en) | 1982-03-29 | 1983-03-29 | Detergent bar processing |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0090645B1 (en) |
JP (1) | JPS58208396A (en) |
AT (1) | ATE22463T1 (en) |
AU (1) | AU552314B2 (en) |
BR (1) | BR8301597A (en) |
CA (1) | CA1209434A (en) |
DE (1) | DE3366383D1 (en) |
ES (1) | ES521069A0 (en) |
GB (1) | GB2118055B (en) |
GR (1) | GR78501B (en) |
IN (1) | IN157134B (en) |
MY (1) | MY8700907A (en) |
PH (1) | PH22057A (en) |
PT (1) | PT76464B (en) |
ZA (1) | ZA832187B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0287300A2 (en) * | 1987-04-13 | 1988-10-19 | Unilever Plc | Cleaning compositions |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB930339A (en) * | 1961-05-01 | 1963-07-03 | Metal Box Co Ltd | Improvements in or relating to the extrusion of molten thermoplastic material |
US3779521A (en) * | 1971-05-11 | 1973-12-18 | Creusot Loire | Extrusion assembly |
GB2034742A (en) * | 1978-11-02 | 1980-06-11 | Zucker Friedrich Josef | Process for the continuous production of soap |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2970116A (en) * | 1957-07-16 | 1961-01-31 | Lever Brothers Ltd | Soapmaking process |
GB843849A (en) * | 1957-11-22 | 1960-08-10 | Ici Ltd | Mixing apparatus |
DD124023A1 (en) * | 1974-10-09 | 1977-02-02 | ||
US4419014A (en) * | 1980-09-23 | 1983-12-06 | Rubber And Plastics Research Association Of Great Britain | Extruder mixer |
-
1983
- 1983-03-25 IN IN99/BOM/83A patent/IN157134B/en unknown
- 1983-03-25 PH PH28702A patent/PH22057A/en unknown
- 1983-03-25 AU AU12863/83A patent/AU552314B2/en not_active Ceased
- 1983-03-28 PT PT76464A patent/PT76464B/en unknown
- 1983-03-28 CA CA000424683A patent/CA1209434A/en not_active Expired
- 1983-03-28 BR BR8301597A patent/BR8301597A/en not_active IP Right Cessation
- 1983-03-28 GR GR70895A patent/GR78501B/el unknown
- 1983-03-28 ES ES521069A patent/ES521069A0/en active Granted
- 1983-03-28 ZA ZA832187A patent/ZA832187B/en unknown
- 1983-03-29 GB GB08308630A patent/GB2118055B/en not_active Expired
- 1983-03-29 EP EP83301763A patent/EP0090645B1/en not_active Expired
- 1983-03-29 JP JP58053427A patent/JPS58208396A/en active Granted
- 1983-03-29 DE DE8383301763T patent/DE3366383D1/en not_active Expired
- 1983-03-29 AT AT83301763T patent/ATE22463T1/en not_active IP Right Cessation
-
1987
- 1987-12-30 MY MY907/87A patent/MY8700907A/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB930339A (en) * | 1961-05-01 | 1963-07-03 | Metal Box Co Ltd | Improvements in or relating to the extrusion of molten thermoplastic material |
US3779521A (en) * | 1971-05-11 | 1973-12-18 | Creusot Loire | Extrusion assembly |
GB2034742A (en) * | 1978-11-02 | 1980-06-11 | Zucker Friedrich Josef | Process for the continuous production of soap |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0287300A2 (en) * | 1987-04-13 | 1988-10-19 | Unilever Plc | Cleaning compositions |
EP0287300A3 (en) * | 1987-04-13 | 1990-12-27 | Unilever Plc | Cleaning compositions |
Also Published As
Publication number | Publication date |
---|---|
JPS6131756B2 (en) | 1986-07-22 |
PT76464A (en) | 1983-04-01 |
GR78501B (en) | 1984-09-27 |
JPS58208396A (en) | 1983-12-05 |
AU552314B2 (en) | 1986-05-29 |
ZA832187B (en) | 1984-11-28 |
AU1286383A (en) | 1983-10-06 |
ES8405066A1 (en) | 1984-05-16 |
IN157134B (en) | 1986-01-25 |
EP0090645B1 (en) | 1986-09-24 |
GB8308630D0 (en) | 1983-05-05 |
PT76464B (en) | 1986-02-27 |
CA1209434A (en) | 1986-08-12 |
ES521069A0 (en) | 1984-05-16 |
DE3366383D1 (en) | 1986-10-30 |
MY8700907A (en) | 1987-12-31 |
GB2118055B (en) | 1986-07-16 |
ATE22463T1 (en) | 1986-10-15 |
BR8301597A (en) | 1983-12-06 |
PH22057A (en) | 1988-05-13 |
GB2118055A (en) | 1983-10-26 |
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