EP0078328A1 - Brennstoff auf Methanolbasis für Fahrzeuge - Google Patents

Brennstoff auf Methanolbasis für Fahrzeuge Download PDF

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Publication number
EP0078328A1
EP0078328A1 EP81109236A EP81109236A EP0078328A1 EP 0078328 A1 EP0078328 A1 EP 0078328A1 EP 81109236 A EP81109236 A EP 81109236A EP 81109236 A EP81109236 A EP 81109236A EP 0078328 A1 EP0078328 A1 EP 0078328A1
Authority
EP
European Patent Office
Prior art keywords
fuel
methanol
set forth
gasoline
peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81109236A
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English (en)
French (fr)
Other versions
EP0078328B1 (de
Inventor
Roland D. Earle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Prime Manufacturing Co
Original Assignee
Prime Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Prime Manufacturing Co filed Critical Prime Manufacturing Co
Priority to DE8181109236T priority Critical patent/DE3174990D1/de
Priority to EP81109236A priority patent/EP0078328B1/de
Priority to AT81109236T priority patent/ATE20904T1/de
Publication of EP0078328A1 publication Critical patent/EP0078328A1/de
Application granted granted Critical
Publication of EP0078328B1 publication Critical patent/EP0078328B1/de
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B75/00—Other engines
    • F02B75/02—Engines characterised by their cycles, e.g. six-stroke
    • F02B2075/022—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle
    • F02B2075/027—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle four

Definitions

  • coal it would, of course, be highly desirable to utilize coal as a fuel for powering automobiles and other vehicles.
  • One method suggested for utilizing coal as a fuel for internal combustion engines involves converting the coal to methanol.
  • a suggested use for methanol is to add it to gasoline to make a fuel similar to gasohol.
  • methanol could fulfill a function similar to that of ethanol; but, adding methanol to gasoline presents problems. If even a small quantity of water gets into an automobile tank, a methanol-gasoline blend will separate. The methanol and water fall to the bottom of the tank, get into the engine and stall it.
  • an object of the present invention is to provide a methanol or ethanol (and other lower alcohols) based fuel which can be utilized as a substitute in whole or in part for gasoline as a fuel for an internal combustion engine.
  • the sole figure of the drawing is a graph showing increase in miles per gallon versus percent of DTBP by volume.
  • the present invention is described in its broadest overall aspects with a more detailed description following.
  • the present invention is a fuel composition for an internal combustion engine. It includes methanol or ethanol or other lower alcohols and an additive.
  • the fuel composition may be utilized directly as a fuel for a typical gasoline engine or it may be mixed with gasoline in any proportion for use in such engines.
  • the additive itself is an alkyl peroxide.
  • the preferred alkyl peroxide is a ditertiary alkyl peroxide of the general formula: where R 1 through R 6 are lower alkyl radicals.
  • the most preferred additive is di-t-butyl peroxide of the formula:
  • Tertiary alkyl hydroperoxides having the following formula may also be used: where R l to R 3 are lower alkyl radicals.
  • the preferred alkyl hydroperoxide is t-butyl hydroperoxide of the formula:
  • Tests with methanol also indicate that the peroxide additives will improve the performance of straight ethanol and gasohol.
  • the fuel composition of the present invention is a mixture of methanol and/or ethanol and a peroxide, but may contain additives to improve the overall characteristics and performance of the fuel.
  • the fuel composition preferably contains about 1.5-6% peroxide with the balance being substantially methanol.
  • methanol As used throughout this specification and claims, all percentages are by volume at room temperature unless otherwise specified. To this composition, other additives may be added. The composition may be used straight or mixed with gasoline in any proportion. Also, all or part of the methanol may be replaced by ethanol to yield an improved fuel.
  • a di-tertiary alkyl peroxide (specifically di-tertiary butyl peroxide) and methanol was blended.
  • a mixture of 10% peroxide and 90% methanol was quite efficient but it was found that a 15%-85% mixture was a more optimum ratio.
  • the viscosity of this mixture being higher than gasoline, necessitated a change in the size of the Lincoln carburetor jets from 61 thousandths to 69 thousandths. With this size jet the peroxide mixture flows freely through the carburetor. This was the only modification made on the Lincoln for all experiments.
  • Experiment #5 Ran 4 3/4 oz. of #2 mixture and 1/4 oz. water. Speed 2,000 rpm, Brake 3 lbs., Time 18 3/4 minutes. (had to run leaner mixture with throttle adjustment)
  • Experiment #6 Ran 5 oz. methanol with throttle adjustment of #5. Speed 2,600 rpm, Brake 3 lbs., Time 10 3/4 minutes.
  • Experiment #13 Ran 5 oz. methanol, open throttle to almost maximum to obtain nearly same speed with greater brake pressure. Speed 3,000 rpm, Brake 7 1/2 lbs., Time 5 minutes.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)
EP81109236A 1981-10-29 1981-10-29 Brennstoff auf Methanolbasis für Fahrzeuge Expired EP0078328B1 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE8181109236T DE3174990D1 (en) 1981-10-29 1981-10-29 Methanol automotive fuel
EP81109236A EP0078328B1 (de) 1981-10-29 1981-10-29 Brennstoff auf Methanolbasis für Fahrzeuge
AT81109236T ATE20904T1 (de) 1981-10-29 1981-10-29 Brennstoff auf methanolbasis fuer fahrzeuge.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP81109236A EP0078328B1 (de) 1981-10-29 1981-10-29 Brennstoff auf Methanolbasis für Fahrzeuge

Publications (2)

Publication Number Publication Date
EP0078328A1 true EP0078328A1 (de) 1983-05-11
EP0078328B1 EP0078328B1 (de) 1986-07-23

Family

ID=8187981

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81109236A Expired EP0078328B1 (de) 1981-10-29 1981-10-29 Brennstoff auf Methanolbasis für Fahrzeuge

Country Status (3)

Country Link
EP (1) EP0078328B1 (de)
AT (1) ATE20904T1 (de)
DE (1) DE3174990D1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0303862A1 (de) * 1987-08-21 1989-02-22 Wynn Oil Company Zusammensetzung eines Zusatzes
WO2011026742A1 (de) * 2009-09-03 2011-03-10 Bundesanstalt für Materialforschung und -Prüfung (BAM) Ein effizienter und sauberer brennstoff für die prozessindustrie
CN114032124A (zh) * 2021-07-30 2022-02-11 三亚星油藤科技服务有限公司 一种甲醇车用m100甲醇燃料母液添加剂及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR775851A (fr) * 1933-09-25 1935-01-11 Carburant
US4045188A (en) * 1975-12-29 1977-08-30 Hirschey Kenneth A Fuel additives for internal combustion engines
US4294999A (en) * 1979-06-04 1981-10-13 Atlantic Richfield Company Preparing oxygen-containing fuel wherein tertiary butyl alcohol is the major product of the process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR775851A (fr) * 1933-09-25 1935-01-11 Carburant
US4045188A (en) * 1975-12-29 1977-08-30 Hirschey Kenneth A Fuel additives for internal combustion engines
US4294999A (en) * 1979-06-04 1981-10-13 Atlantic Richfield Company Preparing oxygen-containing fuel wherein tertiary butyl alcohol is the major product of the process

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0303862A1 (de) * 1987-08-21 1989-02-22 Wynn Oil Company Zusammensetzung eines Zusatzes
US4857073A (en) * 1987-08-27 1989-08-15 Wynn Oil Company Diesel fuel additive
WO2011026742A1 (de) * 2009-09-03 2011-03-10 Bundesanstalt für Materialforschung und -Prüfung (BAM) Ein effizienter und sauberer brennstoff für die prozessindustrie
CN114032124A (zh) * 2021-07-30 2022-02-11 三亚星油藤科技服务有限公司 一种甲醇车用m100甲醇燃料母液添加剂及其制备方法
CN114032124B (zh) * 2021-07-30 2022-08-30 三亚星油藤科技服务有限公司 一种甲醇车用m100甲醇燃料母液添加剂及其制备方法

Also Published As

Publication number Publication date
ATE20904T1 (de) 1986-08-15
EP0078328B1 (de) 1986-07-23
DE3174990D1 (en) 1986-08-28

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