EP0068520B1 - Compositions détergentes à charges contenant des systèmes actifs ternaires - Google Patents

Compositions détergentes à charges contenant des systèmes actifs ternaires Download PDF

Info

Publication number
EP0068520B1
EP0068520B1 EP82200416A EP82200416A EP0068520B1 EP 0068520 B1 EP0068520 B1 EP 0068520B1 EP 82200416 A EP82200416 A EP 82200416A EP 82200416 A EP82200416 A EP 82200416A EP 0068520 B1 EP0068520 B1 EP 0068520B1
Authority
EP
European Patent Office
Prior art keywords
alkyl
weight
composition
water
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP82200416A
Other languages
German (de)
English (en)
Other versions
EP0068520A3 (en
EP0068520A2 (fr
Inventor
Ronald Lowell Jacobsen
Dean Charles Hanley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AT82200416T priority Critical patent/ATE24016T1/de
Publication of EP0068520A2 publication Critical patent/EP0068520A2/fr
Publication of EP0068520A3 publication Critical patent/EP0068520A3/en
Application granted granted Critical
Publication of EP0068520B1 publication Critical patent/EP0068520B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to stable liquid detergent compositions having superior detergent properties.
  • U.S. Patent 4,247,424 discloses liquid detergent compositions in the form of water-in-oil emulsions which contain ethoxylated alcohol and amine oxide surfactants.
  • U.S. Patent 4,284,532 discloses liquid detergent compositions in isotropic form which contain ethoxylated alcohol and amine oxide surfactants.
  • U.S. Patent 4,276,205 discloses detergent compositions containing ethoxylated alcohol and amine oxide surfactants plus a polyalkylene glycol detergency improver such as polyethylene glycol.
  • British Patent 1,538,174 discloses a composition containing, in conjunction with casein, an alkylether sulfate and a nonionic detergent component which is selected from amine oxide and ethoxylated alcohols.
  • British Patent 1,091,517 discloses a liquid detergent composition containing an alkyl-polyethoxy- sulfate, an amine oxide, a pyrophosphate and low levels of an alkyl monoethoxy-ether as a viscosity- controlling and foam-enhancing agent.
  • the present invention encompasses a stable liquid detergent composition comprising:
  • compositions of the invention are single phase isotropic liquids which exhibit improved stability in that they return, or substantially return, to a single isotropic phase after freezing and thawing.
  • compositions of the invention also avoid yellowing of fabrics which are regularly softened with conventional cationic fabric softeners.
  • liquid detergent compositions herein comprise five essential ingredients:
  • compositions containing more than 40% by weight of such components tend to separate into a surfactant-rich soap phase and a salt-rich lye phase after freezing and thawing.
  • Preferred compositions herein contain less than 34%, and most preferably less than 28%, by weight of such components, and exhibit even greater stability in that they return to single phase isotropic liquids after being slowly frozen (e.g., over a period of days) and thawed.
  • the compositions, particularly those with higher surfactant and builder levels within the above limits also preferably contain the optional hydrotropes herein which help to solubilize the surfactants and salts in the water phase under a wide variety of conditions.
  • compositions of the present invention contain from 3% to 20% by weight of an ethoxylated nonionic surfactant of the formula R(OC 2 H 4 ),,OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from 8 to 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from 8 to 12 carbon atoms, n is from 3 to 9, and said nonionic surfactant has an HLB value of from 10 to 13.
  • R ethoxylated nonionic surfactant of the formula R(OC 2 H 4 ),,OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from 8 to 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from 8 to 12 carbon atoms, n is from 3 to 9, and said nonionic surfactant has an HLB value of from 10 to 13.
  • Suitable ethoxylated nonionic surfactants are the condensation products of alkyl phenols having an alkyl group containing from 8 to 12 carbon atoms, in either a straight chain or branched chain configuration, with ethylene oxide, the ethylene oxide being present in amounts equal to from 3 to 9 moles of ethylene oxide per mole of alkyl phenol.
  • the alkyl substituent in such compounds can be derived, for example, from polymerized propylene or isobutylene, or from octene or nonene.
  • Examples of compounds of this type include nonyl phenol condensed with 8 moles of ethylene oxide per mole of nonyl phenol and dodecyl phenol condensed with 9 moles of ethylene oxide per mole of dodecyl phenol.
  • Commercially available nonionic surfactants of this type include Igepal® CO-530, CO-610, CO-630, CA-520, CA-620, and CA-630, marketed by the GAF Corporation.
  • Nonionic surfactants herein are condensation products of primary or secondary aliphatic alcohols with from 3 to 9 moles of ethylene oxide per mole of alcohol.
  • the alkyl chain of the aliphatic alcohol can either be straight or branched and contains from 8 to 15 carbon atoms.
  • ethoxylated alcohols examples include the condensation product of 5 moles of ethylene oxide with 1 mole of tridecanol, myristyl alcohol condensed with 8 moles of ethylene oxide per mole of myristyl alcohol, the condensation product of ethylene oxide with coconut fatty alcohol wherein the coconut alcohol is a mixture of fatty alcohols with alkyl chains varying from 10 to 14 carbon atoms and wherein the condensate contains 6 moles of ethylene oxide per mole of alcohol, and the condensation product of 9 moles of ethylene oxide with coconut alcohol.
  • nonionic surfactants of this type include Tergitol@ 15-S-7 marketed by the Union Carbide Corporation and Neodol@ 23-6.5 marketed by the Shell Chemical Company. Whether the alcohol is derived from natural fats or produced by one of several petrochemical processes, a mixture of a carbon chain lengths is typical. The stated degree of ethoxylation is an average, the distribution being dependent on process conditions.
  • Ethoxylated alcohols are preferred because of their superior biodegradability relative to ethoxylated alkyl phenols. Particularly preferred are ethoxylated alcohols having an average of from 10 to 15 carbon atoms in the alcohol and an average degree of ethoxylation of from 3 to 8 moles of ethylene oxide per mole of alcohol.
  • the cloud point of a 1% aqueous solution of the ethoxylated nonionic surfactant is preferably below 75°C. and most preferably below 55°C.
  • the ethoxylated nonionic surfactants will have HLB (hydrophile-lipophile balance) values of from 10 to 13 and limited water solubility.
  • HLB hydrophile-lipophile balance
  • the HLB value of surfactants and emulsifiers can be determined experimentally in a well-known fashion.
  • the HLB value of compounds or mixtures of compounds in which the hydrophilic portion of the molecule is principally ethylene oxide can be estimated by the weight ratio of ethylene oxide portion to the lipophilic portion (e.g., the hydrocarbyl radical).
  • a preferred level of ethoxylated nonionic surfactants in the compositions of the invention is from 5% to 10%.
  • Optional ethoxylated nonionic surfactants include: (1) the condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide and propylene glycol, and (2) the condensation products of'ethylene oxide with the product resulting from the reaction of propylene oxide and ethylenediamine. These surfactants are marketed by BASF Wyandotte under the tradenames Pluronic@ and Tetronic@ respectively.
  • compositions of the present invention also contain from 2% to 15% by weight of an amine oxide surfactant having the formula wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms, R 2 and R 3 are methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or together are a heterocyclic, e.g., morpholino, structure in which the nitrogen is part of the heterocyclic ring, and n is from 0 to 10.
  • R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms
  • amine oxide surfactants include: dimethyldodecylamine oxide, dimethyl- tetradecylamine oxide, ethylmethyltetradecylamine oxide, cetyldimethylamine oxide, dimethylstearyl- amine oxide, cetylethylpropylamine oxide, diethyldodecylamine oxide, diethyltetradecylamine oxide, dipropyldodecylamine oxide, bis - (2 - hydroxyethyl)dodecylamine oxide, bis(2 - hydroxyethyl) - 3 - dodecoxy - 2 - hydroxypropylamine oxide, (2 - hydroxypropyl)methyltetradecylamine oxide, dimethyl- oleylamine oxide, dimethyl - (2 - hydroxydodecyl)amine oxide, C S - 1s alkyl alpha-dimethylamine oxide carboxylates, and the corresponding decyl,
  • a preferred level of amine oxide surfactant in the compositions of the invention is from 3% to 10%.
  • Preferred weight ratios of ethoxylated nonionic surfactant to amine oxide surfactant are from 1:1 to 4:1, more preferably from 1.5:1 to 3:1.
  • compositions contain from 1% to 10%, preferably from 2% to 6%, by weight of an alcohol polyethoxylate sulfate surfactant and of the formula R 4 0(C 2 H 4 0) m S0 3 M, wherein R 4 is an alkyl (preferred) or hydroxyalkyl radical containing from 10 to 18 carbon atoms, m is from 2 to 10 and M is a compatible cation.
  • the alcohol polyethoxylate sulfate surfactant is essential to the overall performance and stability of the present compositions. It has been found that if only the nonionic and amine oxide surfactants are present, fabrics which are regularly softened with conventional cationic fabric softening ingredients such as di-tallowdimethylammonium chloride will gradually become objectionably yellow. The reason for this effect is unclear, but in any event it can be controlled by the addition of an anionic surfactant to the compositions. Surprisingly, of the anionic surfactants tested, only the alcohol polyethoxylate sulfates can be added to the compositions in sufficient quantity to provide the desired effect without forming a separating phase or requiring the use of uneconomical amounts of compatibilizing materials.
  • the specific alcohol polyethoxylate sulfate surfactants require at least about two ethoxy groups per molecule on the average to keep the composition single phase.
  • Preferably the degree of ethoxylation is from two to three.
  • Preferred alcohol polyethoxylate sulfate surfactants are C 12 - 15 alkyl polyethoxylate (2.2) sulfate (C 12-15 E 2.2 S); C 14-15 E 2.2 S; C 12-13 E 3 S; C 16-18 E 5 S; C 14-15 E 3 S; and mixtures thereof.
  • the sodium, potassium, and monoethanolammonium salts, and mixtures thereof, are preferred.
  • a desirable and preferred additional ingredient is a C 10-18 fatty acid soap having the same cation or cations as the other anionic materials due to ion exchange.
  • This ingredient at a level of from 0.2% to 5%, .preferably from 0.5% to 1 %, provides corrosion protection, suds controI, and additional cleaning potential.
  • Coconut and unsaturated C, 6 - 18 soaps such as oleyl are preferred for solubility reasons.
  • compositions herein also contain from 5% to 25%, preferably from 10% to 20%, by weight of a water-soluble nitrilotriacetate or citrate detergency builder capable of sequestering calcium or magnesium ions in water solution.
  • the essential detergency builders of the present invention have the ability to sequester calcium or magnesium ions in water solution, and also maintain or assist in maintaining an alkaline pH in a washing solution. Sequestration is the formation of coordination complexes with metallic ions to prevent or inhibit precipitation or other interfering reactions. The phenomenon is also called chelation if certain structural criteria are met by the coordination complex.
  • Examples of such builders are sodium and potassium nitrilotriacetate.
  • polycarboxylate builders include the water-soluble salts, especially the sodium and potassium salts of citric acid.
  • Preferred builders for use in the present invention are sodium and potassium nitrilotriacetate, sodium and potassium citrate, and mixtures thereof.
  • Sodium nitrilotriacetate is particularly preferred.
  • alkali metal, and particularly the sodium and potassium, salts of the foregoing detergency builder salts are preferred for use herein from economic and solubility standpoints, the ammonium, alkanolammonium,. e.g., triethanolammonium, diethanolammonium, and the like, water-soluble salts of the foregoing builder anions are also useful herein.
  • compositions of this invention contain up to 89% water, and preferably contain from 35% to about 65% water.
  • liquid detergent compositions of this invention are stable and isotropic. Those containing lower levels of water are not necessarily true solutions. Many of the compositions herein appear to be microemulsions of an oil phase in water, the oil phase comprising inter alia the bulk of the ethoxylated nonionic surfactant.
  • the hydrotropes of the present invention are water soluble and preferably have an HLB value above 14. Suitable hydrotropes have shorter alkyl chain lengths than the corresponding surfactants used as the principal surfactant in detergent compositions.
  • the soluble salts, particularly sodium and potassium salts, of toluene sulfonate, xylene sulfonate, and cumene sulfonate are preferred hydrophilic stabilizing agents in the practice of the invention; a C 11-15 alkylbenzene sulfonate typically used in household detergent compositions is not suitable.
  • the cations are the same as or compatible with the anionic surfactants.
  • Phosphate esters particularly those with a predominance of single alkyl groups and designated primary esters, can have the hydropholic characteristics necessary to assist in the formation of an isotropic liquid detergent composition.
  • Emphos@ PS-413 and PS-236 (Witco Chemical Company) and Gafac@ PE-510 (GAF Corporation) are commercially available phosphate materials suitable as the hydrotrope in the practice of the invention.
  • Preferred phosphate esters will contain a high proportion of monoalkyl phosphate esters and can be of the type consisting of the condensation product of the reaction of R(OC 2 H 4 ) x OH and a phosphoric or polyphosphoric acid, R being an alkyl or alkyl phenyl group, said alkyl containing from 4 to 18 carbon atoms and x being 0 to 20.
  • Ethoxylated nonionic surfactants with a relatively high degree of ethoxylation and a corresponding high HLB value can find use in the compositions of the present invention.
  • hydrotropes especially mixtures of lower alkylbenzene sulfonates, such as toluene sulfonate, and phosphate esters, can be used, but preferably no phosphorus is present.
  • hydrotropes needed to produce an isotropic liquid detergent composition will be dependent on the type and level of other components, particularly the ethoxylated nonionic surfactant and its extent of water solubility.
  • a preferred level of hydrotrope is from 5% to 16% by weight of the liquid detergent composition.
  • the detergent compositions can contain up to 10%, preferably to 5%, of a fatty acid amide surfactant, such as ammonia amides, monoethanol amides, diethanol amides, and ethoxylated amides.
  • a fatty acid amide surfactant such as ammonia amides, monoethanol amides, diethanol amides, and ethoxylated amides.
  • Preferred amides are C a - 20 monoethanol amides; C a - 20 diethanol amides, and amides having the formula wherein R is a C a - 20 alkyl group, and mixtures thereof.
  • Particularly preferred amides are those where the alkyl group contains from 10 to 16 carbon atoms, such as coconut alkyl monoethanol or diethanol amide.
  • Such compounds are commercially available under the tradenames Super-Amide@ L-9 and GR, from Onyx Chemical Co., Jersey City, NJ, Super-Amide@ F-3 from Ryco, Inc., Conshohocken, PA, and Gafamide@ CDD-518, available from GAF Corp., New York, NY.
  • These amide components can be added to act as suds modifiers. They tend to boost the sudsing in an active system which exhibits relatively low sudsing and can depress the sudsing in systems which exhibit high sudsing.
  • compositions of the present invention may also contain additional ingredients generally found in laundry detergent compositions, at their conventional art-established levels, as long as these ingredients are compatible with the components required herein.
  • the compositions can contain up to 15%, preferably no more than 5%, and most preferably from 0.001 to 2%, of one or more suds control components:
  • Typical suds control agents useful in the compositions of the present invention include, but are not limited to, those described below.
  • Silicone suds control additives are described in U.S. Patent 3,933,672.
  • the silicone material can be represented by alkylated polysiloxane materials such as silica aerogels and xerogels and hydrophobic silicas of various types.
  • the silicone material can be described as a siloxane having the formula: wherein x is from 20 to 2,000, and R and R' are each alkyl or aryl groups, especially methyl, ethyl, propyl, butyl, and phenyl.
  • Polydimethylsiloxanes (R and R' are methyl, having a molecular weight within the range of from 200 to 200,000, and higher, are all useful as suds controlling agents.
  • Additional suitable silicone materials wherein the side chain groups R and R' are alkyl, aryl, or mixed alkyl and aryl hydrocarbyl groups exhibit useful suds controlling properties.
  • examples of such ingredients include diethyl-, dipropyl-, dibutyl-, methyl-, ethyl-, phenylmethyl polysiloxanes and the like.
  • Additional useful silicone suds control agents can be represented by a mixture of an alkylated siloxane, as referred to hereinbefore, and solid silica. Such mixtures are prepared by affixing the silicone to the surface of the solid silica.
  • a preferred silicone suds control agent is represented by a hydrophobic silanated silica having a particle size in the range from 10 to 20 nm and a specific surface area above 50 m 2 /gm intimately admixed with dimethyl silicone fluid having a molecular weight in the range from 500 to 200,000 at a weight ratio of silicone to silanated silica of from 19:1 to 1:2.
  • the silicone suds suppressing agent is advantageously releasably incorporated in a water-soluble or water-dispersible, substantially nonsurface-active, detergent- impermeable carrier.
  • Particularly useful suds control agents are the self-emulsifying silicone suds control agents described in U.S. Patent 4,075,118.
  • An example of such a compound is DB-544@, commercially available from Dow Corning, which contains a siloxane/glycol copolymer together with solid silica and a siloxane resin.
  • Microcrystalline waxes having a melting point in the range from 35°C-115°C and a saponification value of less than 100 represent additional examples of preferred suds control components for use in the subject compositions, and are described in detail in U.S. Patent 4,056,481.
  • the microcrystalline waxes are substantially water-insoluble, but are water-dispersible in the presence of organic surfactants.
  • Preferred microcrystalline waxes have a melting point from 65°C to 100°C, a molecular weight in the range from 400-1,000; and a penetration value of at least 6, measured at 25°C by ASTM-D1321.
  • Suitable examples of the above waxes include: microcrystalline and oxidized microcrystalline petroleum waxes; Fischer-Tropsch and oxidized Fischer-Tropsch waxes; ozokerite; ceresin; montan wax; beeswax; candelilla; and carnauba wax.
  • Alkyl phosphate esters represent an additional preferred suds control agent for use herein. These preferred phosphate esters are predominantly monostearyl phosphate which, in addition thereto, can contain di- and tristearyl phosphates and monooleyl phosphates, which can contain di- and trioleyl phosphates.
  • alkyl phosphate esters frequently contain some trialkyl phosphate. Accordingly, a preferred phosphate ester can contain, in addition to the monoalkyl ester, e.g., monostearyl phosphate, up to 50 mole percent of dialkyl phosphate and up to 5 mole percent of trialkyl phosphate.
  • adjunct components which can be included in the compositions of the present invention include anionic, zwitterionic, ampholytic and cationic surfactants; bleaching agents; bleach activators; soil release agents (particularly copolymers of ethylene terephthalate and polyethylene oxide terephthalate, such as Milease T@ sold by ICI, United. States, as disclosed in U.S. Patent 4,132,680); soil suspending agents; corrosion inhibitors; dyes; fillers; optical brighteners; germicides; pH adjusting agents; alkalinity sources; enzymes; enzyme-stabilizing agents; perfumes, solvents such as ethyl alcohol; carriers; opacifiers; and the like.
  • the required solution pH of from about 8 to about 13 can be obtained by the use of suitable alkaline materials such as sodium hydroxide, sodium or potassium carbonate or bicarbonate, sodium or potassium silicates, and the alkanolamines. Particularly preferred is monoethanol amine.
  • the composition contains an optical brightening or whitening agent.
  • Suitable optical brightening agents include:
  • optical whitening agents are used in a level of from 0.03% to 0.8% and preferably at a level of 0.4% by weight.
  • compositions of the present invention were prepared by mixing the ingredients to form single phase isotropic liquids.
  • the compositions remained as single phase isotropic liquids during the static testing for one week at the indicated temperatures.
  • the compositions of the present invention i.e., Examples I, II and III
  • compositions containing a total of 27.6% by weight of the builder and surfactants herein exhibit even greater stability in that they also return to single phase isotropic liquids after being slowly frozen over a period of several days and thawed.
  • compositions of the present invention are obtained when the sodium nitriloacetate in Examples I, II and III is replaced with 15% of 20% of sodium or potassium citrate.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (5)

1. Composition détergente liquide stable comprenant:
(a) de 3% à 20% en poids d'un tensioactif non ionique de type alcool éthoxylé ou alkylphénol éthoxylé, de formule R(OC2H4)nOH, dans laquelle R est choisi dans le groupe constitué par les radicaux' hydrocarbonés aliphatiques contenant de 8 à 15 atomes de carbone et les radicaux alkylphényle dans lesquels le groupe alkyle contient de 8 à 12 atomes de carbone, et n est de 3 à 9, et le dit tensioactif non ionique a un rapport hydrophile-lipophile de 10 à 13;
(b) de 2% à 15% en poids d'un tensioactif de type oxyde d'amine de formule
Figure imgb0010
dans laquelle R1 est un radical alkyle, hydroxyalkyle, alcoxyhydroxypropyle, alcoxyhydroxyéthyle, alkylamido ou alkylcarboxylate où les parties alkyle et alcoxy contiennent de 8 à 18 atomes de carbone, R2 et R3 sont choisis dans le groupe constitué par les radicaux méthyle, éthyle, propyle, isopropyle, 2-hydroxyéthyle, 2-hydroxypropyle, 3-hydroxypropyle, ou les dits groupes reliés l'un à l'autre pour former une structure cyclique dans laquelle l'azote fait partie d'un noyau hétérocyclique, et n est de 0 à 10;
(c) de 1% à 10% en poids d'un tensioactif de type alcoolsulfate polyéthoxylé de formule
Figure imgb0011
dans laquelle R4 est un radical alkyle ou hydroxyalkyle contenant de 10 à 18 atomes de carbone, m est de 2 à 10 et M est un cation compatible;
(d) de 5% à 25% en poids d'un adjuvant de détergence hydrosoluble;
(e) de 0% à 25% en poids d'un hydrotrope;
(f) jusqu'à 89% en poids d'eau;

caractérisée en ce que
- l'adjuvant de détergence hydrosoluble est un nitrilotriacétate ou un citrate, capable de séquestrer les ions calcium et magnésium en solution aqueuse;
- les constituants (a), (b), (c) et (d) ensemble représentent moins de 40% du poids de la composition;

la dite composition détergente liquide est sous une forme isotrope et a un pH de 8 à 13 en solution à 0,2% dans l'eau à 20°C.
2. Composition selon la revendication 1, comprenant de 5% à 10% d'un tensioactif non ionique de type alcool éthoxylé de formule R(OC2H4)nOH dans laquelle R est un groupe alkyle en Clo-15 et n est de 3 à 8, de 3% à 10% d'un oxyde d'alkyl (en C12-16) diméthylamine et de 2% à 6% d'un tensioactif de type alcoolsulfate polyéthoxylé de formule R4O(C2H4O)mSO3M dans laquelle R4 est un groupe alkyle en C10-18' m est de 2 à 3 et M est le sodium ou le potassium.
3. Composition selon la revendication 2, dans laquelle l'adjuvant représente de 10% à 20% du poids de la composition.
4. Composition selon la revendication 3, dans laquelle les tensioactifs non ionique, de type oxyde d'amine et de type sulfate polyéthoxylé et l'adjuvant représentent ensemble moins de 28% du poids de la composition.
5. Composition selon la revendication 1 ou 4, comprenant de 5% à 16% d'un hydrotrope choisi dans le groupe constitué par le toluène-sulfonate, le xylène-sulfonate, le cumène-sulfonate de sodium et de potassium et leurs mélanges.
EP82200416A 1981-04-06 1982-04-02 Compositions détergentes à charges contenant des systèmes actifs ternaires Expired EP0068520B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82200416T ATE24016T1 (de) 1981-04-06 1982-04-02 Verstaerkte reinigungsmittelzusammensetzungen die ternaere, aktive systeme enthalten.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25165081A 1981-04-06 1981-04-06
US251650 1981-04-06

Publications (3)

Publication Number Publication Date
EP0068520A2 EP0068520A2 (fr) 1983-01-05
EP0068520A3 EP0068520A3 (en) 1983-09-21
EP0068520B1 true EP0068520B1 (fr) 1986-12-03

Family

ID=22952849

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82200416A Expired EP0068520B1 (fr) 1981-04-06 1982-04-02 Compositions détergentes à charges contenant des systèmes actifs ternaires

Country Status (5)

Country Link
EP (1) EP0068520B1 (fr)
AT (1) ATE24016T1 (fr)
DE (1) DE3274558D1 (fr)
GR (1) GR76044B (fr)
IE (1) IE52472B1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4438024A (en) * 1982-05-10 1984-03-20 The Procter & Gamble Company Stable liquid detergent compositions
GB2245000B (en) * 1987-09-17 1992-06-03 Colgate Palmolive Co Liquid detergent composition
US5952285A (en) * 1990-04-10 1999-09-14 Albright & Wilson Limited Concentrated aqueous surfactant compositions
DZ1495A1 (fr) * 1990-04-10 2004-09-13 Albright & Wilson Composition détergente liquide versable à concentration élevée en tensioactifs.
US5851976A (en) * 1997-12-08 1998-12-22 Colgate Palmolive Company Microemulsion all purpose liquid cleaning compositions
GB2375356A (en) * 2001-05-11 2002-11-13 Reckitt Benckiser Nv Cationic fabric softening compositions
US10947480B2 (en) 2016-05-17 2021-03-16 Conopeo, Inc. Liquid laundry detergent compositions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1185756B (fr) * 1959-04-22
US3808156A (en) * 1971-11-22 1974-04-30 Ethyl Corp Chemical composition
GB1538174A (en) * 1976-11-05 1979-01-10 Unilever Ltd Cleaning composition
DE3166233D1 (en) * 1980-02-05 1984-10-31 Procter & Gamble Liquid detergent composition
US4316824A (en) * 1980-06-26 1982-02-23 The Procter & Gamble Company Liquid detergent composition containing alkyl sulfate and alkyl ethoxylated sulfate

Also Published As

Publication number Publication date
IE52472B1 (en) 1987-11-11
GR76044B (fr) 1984-08-03
IE820813L (en) 1982-10-06
DE3274558D1 (en) 1987-01-15
ATE24016T1 (de) 1986-12-15
EP0068520A3 (en) 1983-09-21
EP0068520A2 (fr) 1983-01-05

Similar Documents

Publication Publication Date Title
EP0028038B1 (fr) Compositions détergentes liquides isotropiques contenant un système actif à plusieurs composants
US4247424A (en) Stable liquid detergent compositions
US4405483A (en) Stable liquid detergents containing aluminosilicate ion exchange material
AU625049B2 (en) Liquid detergent containing solid peroxygen bleach
US4259217A (en) Laundry detergent compositions having enhanced greasy and oily soil removal performance
US3914185A (en) Method of preparing liquid detergent compositions
AU662501B2 (en) Liquid detergent compositions containing a suspended peroxygen bleach
US5597790A (en) Liquid detergent compositions containing a suspended peroxygen bleach
US4436653A (en) Stable liquid detergent compositions
US4438024A (en) Stable liquid detergent compositions
WO1992007057A1 (fr) Compositions detersives liquides et stables contenant un agent de blanchiment
EP0091802B1 (fr) Compositions à mousse controlée comme additifs à des détergents et leur utilisation dans des compositions détergentes
US4714565A (en) Homogeneous concentrated liquid detergent compositions containing a monoester of a dicarboxylic acid
CA1122094A (fr) Detergent liquide composite
IE861179L (en) Concentrated liquid detergent compositions
US5250212A (en) Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol
EP0068520B1 (fr) Compositions détergentes à charges contenant des systèmes actifs ternaires
CA1198026A (fr) Detergents liquides stables
US3751370A (en) Low-foaming rinsing washing and cleaning compositions
US3708427A (en) Washing and cleansing compositions
CA1210299A (fr) Detergents liquides a forte reserve d'alcalinite
IE904243A1 (en) Suspending liquid detergent compositions
JPH10502969A (ja) αスルホン化脂肪酸メチルエステルの塩を含んでなる重質液体洗剤組成物および織物への汚れの再付着を抑制するαスルホン化脂肪酸塩の使用
US3691082A (en) Low-foaming rinsing,washing and cleaning compositions
CA1100381A (fr) Traduction non-disponible

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

17P Request for examination filed

Effective date: 19840309

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 24016

Country of ref document: AT

Date of ref document: 19861215

Kind code of ref document: T

ITF It: translation for a ep patent filed
ET Fr: translation filed
REF Corresponds to:

Ref document number: 3274558

Country of ref document: DE

Date of ref document: 19870115

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19870430

Year of fee payment: 6

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Effective date: 19880402

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19880403

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19880430

Ref country code: CH

Effective date: 19880430

BERE Be: lapsed

Owner name: THE PROCTER & GAMBLE CY

Effective date: 19880430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19881101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19881121

GBPC Gb: european patent ceased through non-payment of renewal fee
NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19881229

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19890103

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Effective date: 19890430

EUG Se: european patent has lapsed

Ref document number: 82200416.4

Effective date: 19890726