EP0047246B1 - Process and device for suppressing magnetic disturbances in electrolytic cells - Google Patents

Process and device for suppressing magnetic disturbances in electrolytic cells Download PDF

Info

Publication number
EP0047246B1
EP0047246B1 EP80902175A EP80902175A EP0047246B1 EP 0047246 B1 EP0047246 B1 EP 0047246B1 EP 80902175 A EP80902175 A EP 80902175A EP 80902175 A EP80902175 A EP 80902175A EP 0047246 B1 EP0047246 B1 EP 0047246B1
Authority
EP
European Patent Office
Prior art keywords
series
cathodic
tank
current
conductors
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP80902175A
Other languages
German (de)
French (fr)
Other versions
EP0047246A1 (en
Inventor
Pierre Homsi
Maurice Keinborg
Bernard Langon
Paul Morel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rio Tinto France SAS
Original Assignee
Aluminium Pechiney SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aluminium Pechiney SA filed Critical Aluminium Pechiney SA
Publication of EP0047246A1 publication Critical patent/EP0047246A1/en
Application granted granted Critical
Publication of EP0047246B1 publication Critical patent/EP0047246B1/en
Expired legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/16Electric current supply devices, e.g. bus bars

Definitions

  • the present invention relates to a new device and a new method for eliminating magnetic disturbances harmful to the proper functioning of very high intensity electrolysis cells placed across.
  • These tanks are intended for the production of aluminum by electrolysis of the alumina dissolved in the aluminum and sodium fluoride baths.
  • the invention applies to the reduction of the magnetic forces applied to the liquid metal contained in these tanks. These forces are due to the combined action of the horizontal currents appearing in the metal and the magnetic field created by the conductors of a tank and its neighbors in the same line, as well as by the conductors of the tanks of adjacent lines.
  • the tanks are, in fact, arranged in series according to a certain number of adjacent rows, so as to ensure the return of the current to its source.
  • the invention only applies to the balancing of the magnetic field created by the conductors of the tank and of its neighbors in the same line.
  • the influence of one or more adjacent lines, when these are at a distance relatively close to the line in question, is the subject of separate patents: French patent 2,333,060 and its certificate of addition 2,343,826 and French patent application filed on May 11, 1978 and published under number 2425482.
  • the sides of the tank are called “short sides” and “long sides”, the latter being, in the case of series of tanks across, perpendicular to the axis of the series; the expression “head” is used to designate the ends, on the short sides, of both the tank and the anode system.
  • the direction of the current will go from the bottom to the top of each drawing and will be indicated by an arrow.
  • the object of the invention is a device for the suppression of magnetic disturbances in the series of igneous electrolysis cells intended for the production of aluminum, from alumina dissolved in the molten cryolite, operating at a very high intensity. , being able to reach from 200,000 to 300,000 amperes, said tanks comprising a parallelepipedic box supporting cathode blocks in which the cathode current outputs, called “cathode outputs", are sealed, and an anode system (which may be of the self-cooking Soderberg type, or of the prebaked multiple anode type) - suspended from a spider, the tanks being electrically connected in series by connecting conductors and arranged transversely with respect to the axis Ox of the series, so that the short side of the box and of the anode system are parallel to the axis of the series, the cathode outputs being constituted by a plurality conductive elements sealed in the cathode blocks and emerging vertically from the bottom of the box, device in which
  • Another object of the invention is a method for the suppression of magnetic disturbances in the series of igneous electrolysis cells intended for the production of aluminum from alumina dissolved in the molten cryolite, operating at an intensity of up to 200 000 to 300,000 amperes, said tanks comprising a parallelepipedic box supporting cathode carbon blocks in which the cathode current outputs are sealed, and an anode system suspended from a cross, the tanks being electrically connected in series by conductors connecting the outputs cathodics of a tank at the cross of the next tank, and being arranged transversely with respect to the axis Ox of the series, so that the short side of the box and of the anode system are parallel to the axis of the series , the cathode current being extracted by a plurality of conductive elements sealed in the cathode blocks and exiting vertically through the bottom of the caisso n, method according to which a fraction of the total current of between 30 and 54%, flowing in the connecting conductors
  • the current is extracted from the carbon cathode by vertical outlets (2) which we will designate hereinafter by the term of bottom outlets.
  • vertical outlets (2) which we will designate hereinafter by the term of bottom outlets.
  • This process makes it possible to considerably reduce the horizontal currents in the metal while obtaining a gain of the order of 0.1 V on the. cathodic fall.
  • This improvement in cathodic drop results in a reduction of 300 kMh / t in the specific energy consumed by the tank.
  • bottom exits has been described in several old patents; three of them only use bottom outlets, excluding any description of the connecting conductors: FR 953 374, IT 451 183 and FR 1,125,949.
  • the first relates only to tanks with relatively low intensity, close to 100,000 A.
  • the paths of the connecting conductors are long, leading to a significant investment in conductors and drops high line voltage.
  • the invention makes it possible to eliminate magnetic disturbances on these tanks by eliminating horizontal currents and by balancing the magnetic field.
  • the components Bx and Bz are, by construction, asymmetrical with respect to the plane x o z.
  • the invention consists, for tanks across an intensity between 200,000 A and 300,000 A, in a combination of the outputs from the bottom and a bypass of part of the current in conductors arranged outside the two vertical planes passing through the ends of the anode system.
  • the branch conductors are therefore placed in the hatched area ABCDEF of FIG. 4.
  • This area is delimited on the box side, by the vertical walls AB on the short side of the box, and, below the box, by the bottom up to 'plumb with the end of the anode system (BC).
  • BC anode system
  • the conductor will be slightly moved away from the wall of the box, at a distance compatible with the requirements of electrical safety.
  • On the side opposite to the wall of the box there is no theoretical limit of the area.
  • we will not deviate beyond an EF plane located about one meter from the wall of the box.
  • the height of the zone is theoretically unlimited, but, for reasons of economy of journey and so that the bypass conductor does not interfere with operations on the tank, the height of the zone will be delimited, in its upper part, by the top of the box (FA) and, in its lower part, by a border ED located about one meter below the bottom of the box.
  • Figures 5, 6 and 7 provide a better definition of the term "branch conductor”.
  • the cathodic current collected under the tank considered circulates in the conductor (10) and is derived by the heads of the tank considered (outside the vertical plane passing through the end of the anode system (4) by the bypass conductor (11) which bypasses the two upstream and downstream angles of the end (12) of the anode plane).
  • the bypass conductor (11) passes under the box (3) of the tank in question and is connected to the crosspiece of the next tank by the rise (13).
  • the cathodic current collected under the tank in question circulates in the conductor (14) and is derived by the heads of the next tank by the bypass conductor (15) which bypasses the two angles upstream and downstream of the end (12) of the anodic plane of the next tank (outside the vertical plane passing through the end of said anodic system).
  • the bypass conductor (15) runs along its side of the next tank on its short side.
  • part of the cathode current collected under the tank in question circulates in the conductor (16) and is derived by the heads of the tank considered by the bypass conductor (17) which bypasses the two angles upstream and downstream of the end (12) of the anode plane of the tank considered.
  • the bypass conductor (17) runs along the box (3) of the tank considered on its short side.
  • Another part of the cathode current, collected under the tank in question circulates in the conductor (18) and is derived by the heads of the next tank by the same conductor.
  • bypass (19) which bypasses the two upstream and downstream angles of the end (12) of the anode plane of the next tank.
  • the bypass conductor (19) runs along the box (3) of the next tank on its short side.
  • the number of positive rises will generally be greater than or equal to four. However, in the case where the invention is applied to tanks with an intensity of less than 200,000 A, it will be possible to settle for less than four positive rises.
  • This circuit although having the advantage of the shortest electrical path, does not allow the magnetic field of a tank with outlets from the bottom to be balanced.
  • FIGS. 9 and 13 we only very schematically represent the conductors connecting the cathode outputs (2) of the tank in question to the spider (9) supplying the anodes of the next tank.
  • the connecting conductors pass below the level of the work surface, and then join the cross braces by vertical or slightly oblique climbs.
  • each cathode block arranged parallel to the axis Ox has three vertical outlets. But, well heard, the actual number of outputs can be different without departing from the scope of the invention.
  • the current drawn at the two ends of the cathode is derived by the heads of the next tank to feed its cross-bar downstream by two positive rises located at 1/4 and 3/4.
  • the fraction of current flowing through each of the two branch conductors is 3/16, or 18.75%, of the total current.
  • the rest of the current feeds the spider of the next tank upstream, in three positive ascents, one located along the axis Ox of the tank and the other two at the heads of the spider.
  • the latter climbs can be placed either on the large or on the small side of the tank.
  • the maximum horizontal field Bx is 60.1 0 - 4.
  • the current drawn at the two ends of the cathode is collected on either side of the tank considered in the inter-tank space. Part of this current is derived from the heads of the tank in question.
  • the bypass conductor then goes along the heads of the next tank and feeds its spider, downstream at 1/4 and 3/4 of the long side. Each of the bypass conductors by the heads of the next tank is crossed by 1/5 of the total current.
  • the rest of the cathode current feeds upstream the cross of the next tank by four positive ascents located at 1/8, 3/8, 5/8 and 7/8.
  • the maximum horizontal field Bx is 25.10- 4 T.
  • the current drawn at 1/4 and 3/4 of the cathode joins along the large upstream side of the tank considered the bypass conductor circulating on the heads of the tank considered before supplying upstream the heads of the spider of the next tank by a positive rise on both sides of the tank.
  • the climbs can be indifferently placed on the long side or on the short side of the tank.
  • Each of the bypass conductors through the heads of the tank in question is traversed by 3/16, or 18.75%, of the total intensity.
  • the rest of the cathode current feeds directly upstream, as shown in Figure 11, the cross of the next tank by three positive rises located 1/4, 1/2 and 3/4 of the large. side.
  • the average vertical field per quadrant of this tank at 250,000 A, and taking into account the effect of the ferromagnetic parts is:
  • the maximum horizontal field Bx is 40.10- 4 T.
  • the current drawn at the two ends of the cathode joins along the large upstream side of the tank considered the bypass conductor circulating on the heads of the tank considered before supplying the upstream end of the crosspiece of the next tank by a positive rise on either side of the tank.
  • the climbs can be placed either on the long side or on the short side.
  • Each of the bypass conductors by the heads of the tank in question is traversed by 1/4 of the total intensity.
  • the rest of the cathode current feeds directly upstream the cross of the next tank by three positive rises located at 1/4, 1/2 and 3/4 of the long side.
  • the maximum horizontal field Bx is 48.10- 4 T.
  • This collector supplies the bypass conductor through the heads of the tank in question.
  • the bypass current then feeds the upstream crosspiece of the next tank by two positive ascents located 1/8 and 7/8 of the long side.
  • Each of the bypass conductors by the heads of the tank in question is traversed by 1/4 of the total intensity.
  • the rest of the cathode current feeds upstream the cross of the next tank by two positive ascents located 3/8 and 5/8 of the long side.
  • the maximum horizontal field Bx is 22.10- 4 T.
  • Figure 14 schematically gives the arrangement of all the connecting conductors between the tank considered and the next tank.
  • Figure 15 is a cross section along an axis parallel to Ox of the tank considered and the next tank. The numbering of the elements is common to the two figures.
  • the alumina supply device, the superstructure, the anodes and their suspension system have either been omitted, or shown very schematically for clarity of the drawing. They are, in reality, in accordance with the prior art.
  • the cathodic outputs through the bottoms (20) are connected to several negative collectors (21).
  • the current collected at the two ends of the cathode is connected by the conductors (22) to the bypass conductors (8) by the heads of the next tank and then feeds the crosspiece (9) of this tank by the risers (23) located ' on the downstream side at 1/4 and 3/4.
  • Each of the bypass conductors through the heads is crossed by 3/16, or 18.75%, of the total intensity.
  • the Oz dimension of these conductors is determined so as to ensure the balance of the magnetic field.
  • the location area of these conductors was previously defined ( Figure 4).
  • the current collected at the center of the cathode is connected by the conductors (24) to three vertical risers, connected to the heads and in the middle of the spider, on the upstream side.
  • Each of the conductors supplying the heads of the cross is crossed by 1/4 of the total intensity and the conductor feeding the center of the cross is crossed by 1/8 of the total intensity.
  • the tanks of the series built according to the invention have the following characteristics: inner dimension 13.68x4.15 (in meters) of the box
  • the corresponding specific energy consumption is 12,690 kMh / tonne AI, which is a record value with tanks operating at such a high intensity. This gain was obtained inter alia by a lowering of the cathodic drop which was on average at 0.25 V.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Process and device for the suppression of magnetic disturbances in series of igneous electrolysis cells, for the production of aluminum, arranged transversally with respect to the axis of the series, operating with currents ranging from 200000 to 300000 amperes. It comprises the removal of the cathode current by a plurality of conductor elements (20) sealed in the cathode block and coming out vertically through the bottom of the vat, and the tapping off from 30 to 54% of the total cathode current in the connection conductor (8) arranged, at least on one portion of their path, outside the two vertical planes passing by the extremities of the anode system.

Description

La présente invention concerne un nouveau dispositif et un nouveau procédé pour la suppression des perturbations magnétiques néfastes au bon fonctionnement des cuves d'électrolyse à très haute intensité placées en travers. Ces cuves sont destinées à la production d'aluminium par électrolyse de l'alumine dissoute dans les bains de fluorures d'aluminium et de sodium. L'invention s'applique à la réduction des forces magnétiques appliquées au métal liquide contenu dans ces cuves. Ces forces sont dues à l'action conjuguée des courants horizontaux apparaissant dans le métal et du champ magnétique créé par les conducteurs d'une cuve et de ses voisines d'une même file, ainsi que par les conducteurs des cuves des files adjacentes. Les cuves sont, en effet, disposées en série selon un certain nombre de files adjacentes, de façon à assurer le retour du courant à sa source.The present invention relates to a new device and a new method for eliminating magnetic disturbances harmful to the proper functioning of very high intensity electrolysis cells placed across. These tanks are intended for the production of aluminum by electrolysis of the alumina dissolved in the aluminum and sodium fluoride baths. The invention applies to the reduction of the magnetic forces applied to the liquid metal contained in these tanks. These forces are due to the combined action of the horizontal currents appearing in the metal and the magnetic field created by the conductors of a tank and its neighbors in the same line, as well as by the conductors of the tanks of adjacent lines. The tanks are, in fact, arranged in series according to a certain number of adjacent rows, so as to ensure the return of the current to its source.

L'invention ne s'applique qu'à l'équilibrage du champ magnétique créé par les conducteurs de la cuve et de ses voisines de la même file. L'influence d'une ou plusieurs files adjacentes, lorsque celles-ci se trouvent à une distance relativement proche de la file considérée, fait l'objet de brevets séparés: brevet français 2 333 060 et son certificat d'addition 2 343 826 et demande de brevet français déposée le 11 Mai 1978 et publiée sous le numéro 2425482.The invention only applies to the balancing of the magnetic field created by the conductors of the tank and of its neighbors in the same line. The influence of one or more adjacent lines, when these are at a distance relatively close to the line in question, is the subject of separate patents: French patent 2,333,060 and its certificate of addition 2,343,826 and French patent application filed on May 11, 1978 and published under number 2425482.

Expose du problemeExpose the problem

On sait que pour réduire les investissements et diminuer les coûts d'exploitation, la tendance est d'augmenter la taille des unités de production, ce qui entraîne un accroissement de l'intensité traversant chaque cuve. La gamme d'intensité des nouvelles cuves, qui se situait récemment en-dessous de 200 000 A, est actuellement comprise dans la fourchette 200.000 à 300.000 A.We know that to reduce investment and reduce operating costs, the trend is to increase the size of production units, which leads to an increase in the intensity passing through each tank. The intensity range of the new tanks, which was recently below 200,000 A, is currently in the range 200,000 to 300,000 A.

A ces intensités, les effets magnétiques prennent une telle amplitude que, si l'on ne prenait pas de dispositions particulières pour en atténuer les effets, le rendement des cellules d'électrolyse s'en trouverait fortement diminué et, à la limite, tout fonctionnement normal pourrait devenir impossible.At these intensities, the magnetic effects take on such an amplitude that, if no special measures were taken to attenuate their effects, the efficiency of the electrolysis cells would be greatly reduced and, ultimately, all functioning normal might become impossible.

Ces perturbations se manifestent par plusieurs effets:

  • - déformation permanente de la nappe de métal avec, d'une part, une dénivellation globale, pente pouvant atteindre, dans certains cas, une valeur supérieure à la distance anode-métal et, d'autre part, une déformation en dôme symétrique;
  • - existence de mouvements permanents du bain et du métal dont la configuration peut être plus ou moins favorable au bon déroulement de l'électrolyse;
  • - existence de mouvements périodiques de l'interface bain/métal, néfastes au rendement de l'électrolyse (instabilités), et pouvant aller, dans certains cas, jusqu'à l'expulsion de métal liquide hors de la cuve.
These disturbances are manifested by several effects:
  • - permanent deformation of the metal sheet with, on the one hand, a global drop, slope which can reach, in certain cases, a value greater than the anode-metal distance and, on the other hand, a symmetrical dome deformation;
  • - Existence of permanent movements of the bath and of the metal, the configuration of which may be more or less favorable for the smooth running of the electrolysis;
  • - existence of periodic movements of the bath / metal interface, detrimental to the efficiency of electrolysis (instabilities), and which can go, in certain cases, until the expulsion of liquid metal out of the tank.

Pour supprimer les perturbations magnétiques, on peut soit agir sur les courants horizontaux, soit agir sur le champ magnétique, soit sur les deux; la présente invention est basée sur ce dernier cas.To suppress magnetic disturbances, one can either act on the horizontal currents, or act on the magnetic field, or both; the present invention is based on the latter case.

Expose de l'inventionExhibition of the invention

Par convention, dans tout ce qui suit, on désigne par Bx, By et Bz les composantes du champ magnétique selon les axes Ox, Oy et Oz, dans un trièdre direct dont l'origine 0 est le centre du plan cathodique de la cuve, Ox étant l'axe transversal de la cuve dirigé dans le sens de la circulation du courant dans la file des cuves, Oy l'axe longitudinal de la cuve et Oz l'axe vertical dirigé vers le haut.By convention, in all that follows, we denote by Bx, By and Bz the components of the magnetic field along the axes Ox, Oy and Oz, in a direct trihedron whose origin 0 is the center of the cathode plane of the tank, Ox being the transverse axis of the tank directed in the direction of current flow in the queue of tanks, Oy the longitudinal axis of the tank and Oz the vertical axis directed upwards.

Les côtés de la cuve sont appelés "petits côtés" et "grands côtés", ces derniers étant, dans le cas de séries de cuves en travers, perpendiculaires à l'axe de la série; l'expression "tête" est utilisée pour désigner les extrémités, sur les petits côtés, aussi bien de la cuve que du système anodique. De la façon habituelle, on parlera pour chaque cuve de côté amont et de côté aval par référence au sens conventionnel du courant dans la série. Sur les figures qui suivront, le sens du courant ira du bas vers le haut de chaque dessin et sera indiqué par une flèche.The sides of the tank are called "short sides" and "long sides", the latter being, in the case of series of tanks across, perpendicular to the axis of the series; the expression "head" is used to designate the ends, on the short sides, of both the tank and the anode system. In the usual way, we will speak for each tank upstream side and downstream side by reference to the conventional direction of the current in the series. In the following figures, the direction of the current will go from the bottom to the top of each drawing and will be indicated by an arrow.

Enfin, on conviendra d'appeler "cuve considérée" celle dont on extrait le courant par la cathode, "cuve précédente" celle qui alimente, à partir de ses sorties cathodiques, le système anodique de la cuve considérée, et "cuve suivante" celle dont le croisillon anodique est alimenté en courant à partir des sorties cathodiques de la cuve considérée.Finally, it will be appropriate to call "tank considered" that from which the current is extracted by the cathode, "previous tank" that which feeds, from its cathode outputs, the anode system of the tank considered, and "next tank" that whose anode spider is supplied with current from the cathode outputs of the tank in question.

Toutes les valeurs des champs magnétiques sont données en 'Tesla" (T) (1 T=104 Gauss).All the values of the magnetic fields are given in 'Tesla "(T) (1 T = 10 4 Gauss).

L'objet de l'invention est un dispositif pour la suppression des perturbations magnétiques dans les séries de cuves d'électrolyse ignée destinées à la production d'aluminium, à partir d'alumine dissoute dans la cryolithe fondue, fonctionnant sous une intensité très élevée, pouvant atteindre de 200000 à 300000 ampères, lesdites cuves comportant un caisson parallélépipédique supportant des blocs cathodiques dans lesquels sont scellées les sorties de courant cathodique, dites "sorties cathodiques", et un système anodique (qui peut être du type Sôderberg à autocuisson, ou du type à anodes multiples précuites) - suspendu à un croisillon, les cuves étant connectées électriquement en série par des conducteurs de liaison et disposées en travers par rapport à l'axe Ox de la série, de telle sorte que le petit côté du caisson et du système anodique soient parallèles à l'axe de la série, les sorties cathodiques étant constituées par une pluralité d'éléments conducteurs scellés dans les blocs cathodiques et sortant verticalement par le fond du caisson, dispositif dans lequel une partie des conducteurs de liaison reliant les sorties cathodiques d'une cuve au croisillon de la cuve suivante sont disposés, sur au moins une partie de leur trajet à l'extérieur des deux plans verticaux passant par les extrémités du système anodique sur le petit côté.The object of the invention is a device for the suppression of magnetic disturbances in the series of igneous electrolysis cells intended for the production of aluminum, from alumina dissolved in the molten cryolite, operating at a very high intensity. , being able to reach from 200,000 to 300,000 amperes, said tanks comprising a parallelepipedic box supporting cathode blocks in which the cathode current outputs, called "cathode outputs", are sealed, and an anode system (which may be of the self-cooking Soderberg type, or of the prebaked multiple anode type) - suspended from a spider, the tanks being electrically connected in series by connecting conductors and arranged transversely with respect to the axis Ox of the series, so that the short side of the box and of the anode system are parallel to the axis of the series, the cathode outputs being constituted by a plurality conductive elements sealed in the cathode blocks and emerging vertically from the bottom of the box, device in which part of the connecting conductors connecting the cathode outputs of a tank to the cross of the next tank are arranged, on at least part of their path outside the two vertical planes passing through the ends of the anode system on the short side.

Un autre objet de l'invention est un procédé pour la suppression des perturbations magnétiques dans les séries de cuves d'électrolyse ignée destinées à la production d'aluminium à partir d'alumine dissoute dans la cryolithe fondue, fonctionnant sous une intensité pouvant atteindre 200 000 à 300 000 ampères, lesdites cuves comportant un caisson parallélépipédique supportant des blocs cathodiques en carbone dans lesquels sont scellées les sorties du courant cathodique, et un système anodique suspendu à un croisillon, les cuves étant connectées électriquement en série par des conducteurs reliant les sorties cathodiques d'une cuve au croisillon de la cuve suivante, et étant disposées en travers par rapport à l'axe Ox de la série, de telle sorte que le petit côté du caisson et du système anodique soient parallèles à l'axe de la série, le courant cathodique étant extrait par une pluralité d'éléments conducteurs scellés dans les blocs cathodiques et sortant verticalement par le fond du caisson, procédé selon lequel une fraction du courant total comprise entre 30 et 54%, circulant dans les conducteurs de liaison entre les cuves, est dérivée dans des conducteurs disposés, sur au moins une partie de leur trajet, à l'extérieur des deux plans verticaux passant par les extrémités du système anodique sur le petit côté. La répartition de ce courant dérivé peut être symétrique par rapport à l'axe de la série, et se répartir également sur chaque côté des cuves, ou être dissymétrique, et se répartir inégalement sur chaque côté des cuves.Another object of the invention is a method for the suppression of magnetic disturbances in the series of igneous electrolysis cells intended for the production of aluminum from alumina dissolved in the molten cryolite, operating at an intensity of up to 200 000 to 300,000 amperes, said tanks comprising a parallelepipedic box supporting cathode carbon blocks in which the cathode current outputs are sealed, and an anode system suspended from a cross, the tanks being electrically connected in series by conductors connecting the outputs cathodics of a tank at the cross of the next tank, and being arranged transversely with respect to the axis Ox of the series, so that the short side of the box and of the anode system are parallel to the axis of the series , the cathode current being extracted by a plurality of conductive elements sealed in the cathode blocks and exiting vertically through the bottom of the caisso n, method according to which a fraction of the total current of between 30 and 54%, flowing in the connecting conductors between the tanks, is derived in conductors arranged, on at least part of their path, outside the two planes vertical passing through the ends of the anode system on the short side. The distribution of this derivative current may be symmetrical with respect to the axis of the series, and be equally distributed on each side of the tanks, or be asymmetrical, and distributed unevenly on each side of the tanks.

Le croisillon d'une cuve considérée est alimenté en courant à partir des sorties cathodiques de la cuve précédente par une pluralité de montées verticales qui peuvent se raccorder soit en totalité sur le côté amont dudit croisillon, soit à la fois sur le côté amont et sur le côté aval une partie du courant pouvant, en outre, être amenée à l'une et/ou à l'autre des têtes dudit croisillon.

  • La figure 1 représente les deux systèmes de sorties cathodiques dessinées, par simplification, sur la même cuve: sorties latérales et sorties par le fond.
  • La figure 2 représente schématiquement la coupe d'une cuve, sur laquelle apparaissent les trois axes de coordonnées utilisés pour définir la direction des composantes du champ magnétique.
  • La figure 3 représente la répartition de la moyenne de la composante verticale Bz du champ magnétique sur les quatre quadrants de la cuve.
  • La figure 4 schématise la position des conducteurs de liaison, selon l'invention, par rapport au plan vertical zz' passant par l'extrémité du système anodique.
  • Les figures 5, 6, 7 indiquent, de façon schématique, les diverses variantes des trajets que peuvent suivre les conducteurs de liaison, dans le cadre de l'invention.
  • La figure 8 indique comment seraient constituées les liaisons entre cuve, en mettant en oeuvre les connaissances de l'art antérieur.
  • Les figures 9 à 13 représentent la mise en oeuvre de l'invention sous cinq variantes différences, qui font chacune l'objet d'exemple de mise en oeuvre.
  • La figure 14 est le schéma d'une réalisation pratique et la figure 15, une coupe, dans le sens de l'axe de la série, de cette même réalisation, indiquant la position réelle des conducteurs.
The spider of a tank considered is supplied with current from the cathode outputs of the previous tank by a plurality of vertical risers which can be connected either entirely on the upstream side of said spider, or both on the upstream side and on the downstream side a part of the current which can, moreover, be brought to one and / or the other of the heads of said spider.
  • FIG. 1 shows the two cathode outlet systems drawn, for simplification, on the same tank: lateral outlets and outlets from the bottom.
  • Figure 2 shows schematically the section of a tank, on which appear the three coordinate axes used to define the direction of the components of the magnetic field.
  • FIG. 3 represents the distribution of the average of the vertical component Bz of the magnetic field over the four quadrants of the tank.
  • Figure 4 shows schematically the position of the connecting conductors, according to the invention, relative to the vertical plane zz 'passing through the end of the anode system.
  • Figures 5, 6, 7 indicate, schematically, the various variants of the paths that the connecting conductors can follow, within the framework of the invention.
  • FIG. 8 indicates how the connections between tanks would be made up, using the knowledge of the prior art.
  • Figures 9 to 13 show the implementation of the invention under five different variations, each of which is the subject of an example of implementation.
  • FIG. 14 is the diagram of a practical embodiment and FIG. 15, a section, in the direction of the axis of the series, of this same embodiment, indicating the actual position of the conductors.

Sur ces différentes figures, les mêmes éléments sont désignés par les mêmes repères numériques. (1) désigne les sorties cathodiques latérales selon l'art antérieur, (2) les sorties cathodiques par le fond du caisson, (3) le caisson, (4) le contour des blocs anodiques, (5) le système anodique, (6) le bain d'électrolyse, (7) la nappe d'aluminium liquide formée sur la cathode, (8) le conducteur (ou groupe de conducteurs) de dérivation, (9) le croisillon.In these different figures, the same elements are designated by the same reference numerals. (1) designates the lateral cathode outputs according to the prior art, (2) the cathode outputs through the bottom of the box, (3) the box, (4) the outline of the anode blocks, (5) the anode system, (6 ) the electrolysis bath, (7) the sheet of liquid aluminum formed on the cathode, (8) the bypass conductor (or group of conductors), (9) the spider.

Dans les cuves classiques, les courants horizontaux sont principalement générés par le mode de collecte du courant cathodique. Le courant est extrait par des barres cathodiques (1) latérales qui ont l'inconvénient de concentrer le courant sur les deux grands côtés de la cathode. Quand on augmente la taille de la cuve, on est amené à élargir la cathode, ce qui a pour effet d'accroître les courants horizontaux dans le métal liquide.In conventional tanks, horizontal currents are mainly generated by the cathode current collection mode. The current is extracted by lateral cathode bars (1) which have the disadvantage of concentrating the current on the two long sides of the cathode. When the size of the tank is increased, the cathode is enlarged, which has the effect of increasing the horizontal currents in the liquid metal.

Dans la présente invention, le courant est extrait de la cathode de carbone par des sorties verticales (2) que nous désignerons dans la suite de l'exposé par le terme de sorties par le fond. Ce procédé permet de réduire considérablement les courants horizontaux dans le métal tout en obtenant un gain de l'ordre de 0,1 V sur la. chute cathodique. Cette amélioration de la chute cathodique se traduit par une réduction de 300 kMh/t de l'énergie spécifique consommée par la cuve.In the present invention, the current is extracted from the carbon cathode by vertical outlets (2) which we will designate hereinafter by the term of bottom outlets. This process makes it possible to considerably reduce the horizontal currents in the metal while obtaining a gain of the order of 0.1 V on the. cathodic fall. This improvement in cathodic drop results in a reduction of 300 kMh / t in the specific energy consumed by the tank.

Du fait des sorties par le fond, nous ne distinguerons plus le courant cathodique extrait par l'amont de celui extrait par l'aval, comme il était d'usage de la faire dans le cas des cuves à sorties cathodiques latérales, puisque l'ensemble du courant sort par le dessous de la cuve. La définition du nombre, de la position et du dispositif d'ancrage dans la cathode de carbone des sorties verticales par le fond, sera considérée comme connue de l'homme de l'art.Because of the bottom outlets, we will no longer distinguish the cathode current extracted upstream from that extracted downstream, as it was customary to do in the case of tanks with lateral cathode outlets, since the all the current comes out from below the tank. The definition of the number, the position and the anchoring device in the carbon cathode of the vertical outlets from the bottom, will be considered to be known to those skilled in the art.

L'idée des sorties par le fond a été décrite dans plusieurs brevets anciens; trois d'entre eux ne font appel qu'aux sorties par le fond, à l'exclusion de toute description des conducteurs de liaison: FR 953 374, IT 451 183 et FR 1 125 949. Le premier ne concerne que les cuves à intensité relativement faible, voisine de 100.000 A. Deux autres brevets, ne s'appliquant également qu'aux cuves d'intensité voisine de 100.000 A, décrivent des. dispositions coûteuses des conducteurs conduisant à un équilibrage sommaire sur le plan du champ magnétique: NO 83 883 et FR 1 079 131 et son additif n° 65 320. Les trajets des conducteurs de liaison sont longs, entraînant un investissement important en conducteurs et des chutes de tension en ligne élevées. L'invention permet de supprimer les perturbations magnétiques sur ces cuves par la suppression des courants horizontaux et par l'équilibrage du champ magnétique.The idea of bottom exits has been described in several old patents; three of them only use bottom outlets, excluding any description of the connecting conductors: FR 953 374, IT 451 183 and FR 1,125,949. The first relates only to tanks with relatively low intensity, close to 100,000 A. Two other patents, also applying only to tanks with intensity close to 100,000 A, describe. costly arrangements of conductors leading to summary balancing in terms of the magnetic field: NO 83 883 and FR 1 079 131 and its additive no. 65 320. The paths of the connecting conductors are long, leading to a significant investment in conductors and drops high line voltage. The invention makes it possible to eliminate magnetic disturbances on these tanks by eliminating horizontal currents and by balancing the magnetic field.

En ce qui concerne le champ magnétique, on conviendra d'appeler "antisymétrique" par rapport à un plan donné, une composante, lorsqu'à tout couple de points symétriques par rapport à ce plan correspondent deux valeurs opposées de la composante.With regard to the magnetic field, it will be appropriate to call "antisymmetric" with respect to a given plane, a component, when any pair of points symmetrical with respect to this plane correspond to two opposite values of the component.

Dans les cuves en travers, en l'absence de l'effet de files voisines, les composantes Bx et Bz sont, par construction, antisymétriques par rapport au plan x o z.In the transverse tanks, in the absence of the effect of neighboring lines, the components Bx and Bz are, by construction, asymmetrical with respect to the plane x o z.

En ce qui concerne l'équilibrage du champ magnétique, qui préside au choix de la disposition des conducteurs de liaisons, nous avons adopté les deux critères suivants:

  • - Un critère principal appliqué à la composante verticale consistant en l'égalité des moyennes de Bz par quart de cuve. La numérotation des quadrants de cuve est définie sur la figure 3. Légalité des moyennes s'écrit:
    Figure imgb0001
    Cette égalité, compte tenu de l'antisymétrie, entraînera, en l'absence de files voisines:
    Figure imgb0002
    De plus, les valeurs ponctuelles de Bz devont être faibles. Le champ sera calculé en prenant en compte l'effet des pièces ferromagnétiques de la cuve et de son environnement.
  • - Un critère secondaire consistant en la réduction de la valeur maximale de la composante horizontale Bx. La valeur maximale sera généralement située à l'extrémité du plan anodique, sur les petits côté de la cuve.
With regard to the balancing of the magnetic field, which governs the choice of the arrangement of the conductors of links, we adopted the following two criteria:
  • - A main criterion applied to the vertical component consisting of the equality of the means of Bz per quarter of tank. The numbering of the tank quadrants is defined in Figure 3. Legality of the means is written:
    Figure imgb0001
    This equality, taking into account the asymmetry, will lead, in the absence of neighboring lines:
    Figure imgb0002
    In addition, the point values of Bz should be small. The field strength will be calculated taking into account the effect of the ferromagnetic parts of the tank and its environment.
  • - A secondary criterion consisting in the reduction of the maximum value of the horizontal component Bx. The maximum value will generally be located at the end of the anode plane, on the short sides of the tank.

L'invention consiste, pour les cuves en travers d'intensité comprise entre 200.000 A et 300.000 A, en une combinaison des sorties par le fond et d'une dérivation d'une partie du courant dans des conducteurs disposés à l'extérieur des deux plans verticaux passant par les extrémités du système anodique.The invention consists, for tanks across an intensity between 200,000 A and 300,000 A, in a combination of the outputs from the bottom and a bypass of part of the current in conductors arranged outside the two vertical planes passing through the ends of the anode system.

En réalité, cette définition de l'emplacement des conducteurs de dérivation doit être précisée, car elle englobe une partie du caisson, et il est évident que les conducteurs de liaison ne peuvent pas passer à l'intérieur du caisson.In reality, this definition of the location of the branch conductors must be clarified, because it includes part of the box, and it is obvious that the connecting conductors cannot pass inside the box.

En pratique, les conducteurs de dérivation sont donc placés dans la zone hachurée ABCDEF de la figure 4. Cette zone est délimitée côté caisson, par la parois verticale AB du petit côté du caisson, et, au-dessous du caisson, par le fond jusqu'à l'aplomb de l'extrémité du système anodique (BC). Néanmoins, le conducteur sera légèrement écarté de la paroi du caisson, à une distance compatible avec les exigences de la sécurité électrique. Côté opposé à la paroi du caisson, il n'y a pas de limite théorique de la zone. Cependant, afin de ne pas allonger inconsidérément le trajet des conducteurs, on ne s'écartera pas au-delà d'un plan EF situé à un mètre environ de la paroi du caisson. La hauteur de la zone est théoriquement illimitée, mais, pour des raisons d'économie de trajet et afin que le conducteur de dérivation ne gêne pas les opérations sur la cuve, la hauteur de la zone se ra délimitée, en sa partie supérieure, par le haut du caisson (FA) et, en sa partie inférieure, par une frontière ED située à un mètre environ en-dessous du fond du caisson.In practice, the branch conductors are therefore placed in the hatched area ABCDEF of FIG. 4. This area is delimited on the box side, by the vertical walls AB on the short side of the box, and, below the box, by the bottom up to 'plumb with the end of the anode system (BC). However, the conductor will be slightly moved away from the wall of the box, at a distance compatible with the requirements of electrical safety. On the side opposite to the wall of the box, there is no theoretical limit of the area. However, in order not to inconsiderately lengthen the path of the conductors, we will not deviate beyond an EF plane located about one meter from the wall of the box. The height of the zone is theoretically unlimited, but, for reasons of economy of journey and so that the bypass conductor does not interfere with operations on the tank, the height of the zone will be delimited, in its upper part, by the top of the box (FA) and, in its lower part, by a border ED located about one meter below the bottom of the box.

Les figures 5, 6 et 7 permettent de mieux préciser le terme de "conducteur de dérivation".Figures 5, 6 and 7 provide a better definition of the term "branch conductor".

Sur la figure 5, le courant cathodique collecté sous la cuve considérée, circule dans le conducteur (10) et est dérivé par les têtes de la cuve considérée (à l'extérieur du plan vertical passant par l'extrémité du système anodique (4) par le conducteur de dérivation (11) qui contourne les deux angles amont et aval de l'extrémité (12) du plan anodique). Le conducteur de dérivation (11) passe sous le caisson (3) de la cuve considérée et se raccorde au croisillon de la cuve suivante par la montée (13).In FIG. 5, the cathodic current collected under the tank considered, circulates in the conductor (10) and is derived by the heads of the tank considered (outside the vertical plane passing through the end of the anode system (4) by the bypass conductor (11) which bypasses the two upstream and downstream angles of the end (12) of the anode plane). The bypass conductor (11) passes under the box (3) of the tank in question and is connected to the crosspiece of the next tank by the rise (13).

Sur la figure 6, le courant cathodique collecté sous la cuve considérée circule dans le conducteur (14) et est dérivé par les têtes de la cuve suivante par le conducteur de dérivation (15) qui contourne les deux angles amont et aval de l'extrémité (12) du plan anodique de la cuve suivante (à l'extérieur du plan vertical passant par l'extrémité dudit système anodique). Le conducteur de dérivation (15) longe le caisson de la cuve suivante sur son petit côté.In FIG. 6, the cathodic current collected under the tank in question circulates in the conductor (14) and is derived by the heads of the next tank by the bypass conductor (15) which bypasses the two angles upstream and downstream of the end (12) of the anodic plane of the next tank (outside the vertical plane passing through the end of said anodic system). The bypass conductor (15) runs along its side of the next tank on its short side.

Sur la figure 7, une partie du courant cathodique collecté sous la cuve considérée, circule dans le conducteur (16) et est dérivée par les têtes de la cuve considérée par le conducteur de dérivation (17) qui contourne les deux angles amont et aval de l'extrémité (12) du plan anodique de la cuve considérée. Le conducteur de dérivation (17) longe le caisson (3) de la cuve considérée sur son petit côté. Une autre partie du courant cathodique, collecté sous la cuve considérée, circule dans le conducteur (18) et est dérivée par les têtes de la cuve suivante par le même conducteur de dérivation (19) qui contourne les deux angles amont et aval de l'extrémité (12) du plan anodique de la cuve suivante. Le conducteur de dérivation (19) longe le caisson (3) de la cuve suivante sur son petit côté.In FIG. 7, part of the cathode current collected under the tank in question, circulates in the conductor (16) and is derived by the heads of the tank considered by the bypass conductor (17) which bypasses the two angles upstream and downstream of the end (12) of the anode plane of the tank considered. The bypass conductor (17) runs along the box (3) of the tank considered on its short side. Another part of the cathode current, collected under the tank in question, circulates in the conductor (18) and is derived by the heads of the next tank by the same conductor. bypass (19) which bypasses the two upstream and downstream angles of the end (12) of the anode plane of the next tank. The bypass conductor (19) runs along the box (3) of the next tank on its short side.

La partie du courant qui est dérivée par chacune des têtes de la cuve est comprise entre 15% et 27% de la totalité du courant de la cuve. Plus précisément:

  • - dans le cas où le conducteur de dérivation alimente le croisillon de la cuve suivante par une montée positive située sur le grand côté amont de la cuve suivante, la fraction de courant dérivé par chacune des têtes de la cuve considérée sera comprise entre 15% et 27% de l'intensité totale;
  • - dans le cas où le conducteur de dérivation alimente le croisillon de la cuve suivante par une montée positive située sur le grand côté aval de la cuve suivante, la fraction de courant dérivé par chacune des têtes de la cuve suivante sera comprise entre 15% et 27% de l'intensité totale.
The part of the current which is derived by each of the heads of the tank is between 15% and 27% of the total current of the tank. More precisely:
  • - in the case where the bypass conductor feeds the spider of the next tank by a positive rise located on the large upstream side of the next tank, the fraction of current diverted by each of the heads of the tank considered will be between 15% and 27% of the total intensity;
  • - in the case where the bypass conductor feeds the spider of the next tank by a positive rise located on the large downstream side of the next tank, the fraction of current diverted by each of the heads of the next tank will be between 15% and 27% of the total intensity.

Dans ces fourchettes, on ne prend pas en compte la compensation de l'effet d'une ou plusieurs files voisines adjacentes à la file considérée.In these ranges, the compensation for the effect of one or more neighboring queues adjacent to the queue in question is not taken into account.

Pour les cuves à haute intensité, le nombre de montées positives sera généralement supérieur ou égal à quatre. Néanmoins, dans le cas où l'invention est appliquée à des cuves d'intensité inférieure à 200.000 A, on pourra se contenter de moins de quatre montées positives.For high intensity tanks, the number of positive rises will generally be greater than or equal to four. However, in the case where the invention is applied to tanks with an intensity of less than 200,000 A, it will be possible to settle for less than four positive rises.

Illustrons sur un exemple l'importance d'un choix judicieux des conducteurs de liaisons pour une cuve à sorties par le fond:

  • En reliant directement les sorties par le fond au plan anodique de la cuve suivante à l'aide de cinq montées positives d'égale intensité, réparties sur le grand côté d'une cuve 250.000 ampères (figure 8), comme on le ferait en appliquant les connaissances de l'art antérieur, on obtient un champ magnétique vertical croissant du centre de la cuve vers les têtes, avec des valeurs moyennes par quadrant, déduction faite de l'effet des pièces ferromagnétiques:
    Figure imgb0003
    la condition:
    Figure imgb0004
    n'est absolument pas vérifiée puisque l'on a au contraire:
    Figure imgb0005
Let us illustrate with an example the importance of a judicious choice of connection conductors for a tank with bottom outlets:
  • By directly connecting the outputs from the bottom to the anode plane of the next tank using five positive rises of equal intensity, distributed on the long side of a 250,000 amp tank (Figure 8), as we would do by applying knowledge of the prior art, a vertical magnetic field is obtained increasing from the center of the tank towards the heads, with average values per quadrant, minus the effect of the ferromagnetic parts:
    Figure imgb0003
    the condition:
    Figure imgb0004
    is absolutely not verified since on the contrary we have:
    Figure imgb0005

Ce circuit, bien que présentant l'avantage du trajet électrique le plus court, ne permet par l'équilibrage du champ magnétique d'une cuve à sorties par le fond.This circuit, although having the advantage of the shortest electrical path, does not allow the magnetic field of a tank with outlets from the bottom to be balanced.

Nous fournissons ci-après des exemples d'application de l'invention qui montrent l'amélioration obtenue sur l'équilibrage du champ magnétique. Sur les figures 9 et 13, par souci de clarté, nous ne représentons très schématiquement que les conducteurs reliant les sorties cathodiques (2) de la cuve considérée au croisillon (9) alimentant les anodes de la cuve suivante. En pratique, les conducteurs de liaison passent au-dessous du niveau du plan de travail, et rejoignent ensuite les croisillons par des montées verticales ou légèrement obliques.We provide below examples of application of the invention which show the improvement obtained on the balancing of the magnetic field. In FIGS. 9 and 13, for the sake of clarity, we only very schematically represent the conductors connecting the cathode outputs (2) of the tank in question to the spider (9) supplying the anodes of the next tank. In practice, the connecting conductors pass below the level of the work surface, and then join the cross braces by vertical or slightly oblique climbs.

Dans tous les exemples présentés, chaque bloc cathodique disposé parallèlement à l'axe Ox, présente trois sorties verticales. Mais, bein entendue, le nombre réel de sorties peut être différent sans sortir du cadre de l'invention.In all the examples presented, each cathode block arranged parallel to the axis Ox has three vertical outlets. But, well heard, the actual number of outputs can be different without departing from the scope of the invention.

Exemple 1Example 1 Cuves à sorties par le fond, à cinq montées positives, dont le courant dérivé par les têtes de la cuve suivante alimente cette dernière par le grand côté aval (figure 9)Tanks with bottom outlets, with five positive ascents, the current derived by the heads of the next tank feeds the latter through the large downstream side (Figure 9)

Le courant prélevé aux deux extrémités de la cathode est dérivé par les têtes de la cuve suivante pour aller alimenter son croisillon par l'aval par deux montées positives situées aux 1/4 et 3/4. La fraction de courant parcourant chacun des deux conducteurs de dérivation est égale aux 3/16, soit 18,75%, de l'intensité totale. Le reste du courant alimente le croisillon de la cuve suivante à l'amont, selon trois montées positives, l'une située selon l'axe Ox de la cuve et les deux autres aux têtes du croisillon. Ces dernières montées peuvent être indifféremment placées sur le grand ou sur le petit côté de la cuve.The current drawn at the two ends of the cathode is derived by the heads of the next tank to feed its cross-bar downstream by two positive rises located at 1/4 and 3/4. The fraction of current flowing through each of the two branch conductors is 3/16, or 18.75%, of the total current. The rest of the current feeds the spider of the next tank upstream, in three positive ascents, one located along the axis Ox of the tank and the other two at the heads of the spider. The latter climbs can be placed either on the large or on the small side of the tank.

Le champ vertical moyen par quadrant de cette cuve à 250.000 A, et compte tenu de l'effet des pièces ferromagnétiques, est:

Figure imgb0006
The average vertical field per quadrant of this tank at 250,000 A, and taking into account the effect of the ferromagnetic parts, is:
Figure imgb0006

Le champ horizontal Bx maximum est de 60.10-4. The maximum horizontal field Bx is 60.1 0 - 4.

Exemple 2Example 2 Cuves à sorties par le fond, à six montées positives, dont le courant dérivé par les têtes de la cuve suivante est collecté dans l'espace intercuve et est envoyé à l'aval du croisillon de la cuve suivante (figure 10)Tanks with outlet from the bottom, with six positive ascents, the current derived by the heads of the next tank is collected in the inter-tank space and is sent downstream of the spider of the next tank (Figure 10)

Le courant prélevé aux deux extrémités de la cathode est collecté de part et d'autre de la cuve considérée dans l'espace intercuve. Une partie de ce courant est dérivée sur les têtes de la cuve considérée. Le conducteur de dérivation longe ensuite les têtes de la cuve suivante et alimente son croisillon, par l'aval aux 1/4 et 3/4 du grand côté. Chacun des conducteurs de dérivation par les têtes de la cuve suivante est traversé par 1/5 du courant total. Le reste du courant cathodique alimente par l'amont le croisillon de la cuve suivante par quatre montées positives situées aux 1/8, 3/8, 5/8 et 7/8.The current drawn at the two ends of the cathode is collected on either side of the tank considered in the inter-tank space. Part of this current is derived from the heads of the tank in question. The bypass conductor then goes along the heads of the next tank and feeds its spider, downstream at 1/4 and 3/4 of the long side. Each of the bypass conductors by the heads of the next tank is crossed by 1/5 of the total current. The rest of the cathode current feeds upstream the cross of the next tank by four positive ascents located at 1/8, 3/8, 5/8 and 7/8.

Le champ vertical moyen par quadrant de cette cuve à 250.000 A, et compte tenu de l'effet des pièces ferromagnétiques, est:

Figure imgb0007
The average vertical field per quadrant of this tank at 250,000 A, and taking into account the effect of the ferromagnetic parts, is:
Figure imgb0007

Le champ horizontal Bx maximum est de 25.10-4 T.The maximum horizontal field Bx is 25.10- 4 T.

Exemple 3Example 3 Cuve à sorties par le fond, à cinq montées positives dont le courant dérivé par les têtes de la cuve considérée est prélevé aux 1/4 et 3/4 de la cathode (figure 11)Tank with outputs from the bottom, with five positive ascents, the current derived by the heads of the tank in question is taken at 1/4 and 3/4 of the cathode (Figure 11)

Le courant prélevé aux 1/4 et 3/4 de la cathode rejoint le long du grand côté amont de la cuve considérée le conducteur de dérivation circulant sur les têtes de la cuve considérée avant d'alimenter par l'amont les têtes du croisillon de la cuve suivante par une montée positive de part et d'autre de la cuve. Les montées peuvent être indifféremment placées sur le grand côté on sur le petit côté de la cuve.The current drawn at 1/4 and 3/4 of the cathode joins along the large upstream side of the tank considered the bypass conductor circulating on the heads of the tank considered before supplying upstream the heads of the spider of the next tank by a positive rise on both sides of the tank. The climbs can be indifferently placed on the long side or on the short side of the tank.

Chacun des conducteurs de dérivation par les têtes de la cuve considérée est parcouru par 3/16, soit 18,75%, de l'intensité totale. Le reste du courant cathodique alimente directement par l'amont, comme indiqué sur la figure 11, le croisillon de la cuve suivante par trois montées positives situées aux 1/4, 1/2 et 3/4 du grand. côté.Each of the bypass conductors through the heads of the tank in question is traversed by 3/16, or 18.75%, of the total intensity. The rest of the cathode current feeds directly upstream, as shown in Figure 11, the cross of the next tank by three positive rises located 1/4, 1/2 and 3/4 of the large. side.

Le champ vertical moyen par quadrant de cette cuve à 250.000 A, et compte tenu de l'effet des pièces ferromagnétiques est:

Figure imgb0008
Le champ horizontal Bx maximum est de 40.10-4 T.The average vertical field per quadrant of this tank at 250,000 A, and taking into account the effect of the ferromagnetic parts is:
Figure imgb0008
The maximum horizontal field Bx is 40.10- 4 T.

Exemple 4Example 4 Cuve à sorties par le fond, à cinq montées positives, dont le courant dérivé par les têtes de la cuve considérée est prélevé aux deux extrémités de la cathode (figure 12)Tank with outputs from the bottom, with five positive ascents, the current derived by the heads of the tank in question is taken at both ends of the cathode (Figure 12)

Le courant prélevé aux deux extrémités de la cathode rejoint le long du grand côté amont de la cuve considérée le conducteur de dérivation circulant sur les têtes de la cuve considérée avant d'alimenter l'extrémité amont du croisillon de la cuve suivante par une montée positive de part et d'autre de la cuve. Les montées peuvent être indifféremment placées sur le grand côté ou sur le petit côté. Chacun des conducteurs de dérivation par les têtes de la cuve considérée est parcouru par 1/4 de l'intensité totale. Le reste du courant cathodique alimente directement par l'amont le croisillon de la cuve suivante par trois montées positives situées aux 1/4, 1/2 et 3/4 du grand côté.The current drawn at the two ends of the cathode joins along the large upstream side of the tank considered the bypass conductor circulating on the heads of the tank considered before supplying the upstream end of the crosspiece of the next tank by a positive rise on either side of the tank. The climbs can be placed either on the long side or on the short side. Each of the bypass conductors by the heads of the tank in question is traversed by 1/4 of the total intensity. The rest of the cathode current feeds directly upstream the cross of the next tank by three positive rises located at 1/4, 1/2 and 3/4 of the long side.

Le champ vertical moyen par quadrant de cette cuve à 250.000 A et compte tenu de l'effet des pièces ferromagnétiques est:

Figure imgb0009
The average vertical field per quadrant of this tank at 250,000 A and taking into account the effect of the ferromagnetic parts is:
Figure imgb0009

Le champ horizontal Bx maximum est de 48.10-4 T.The maximum horizontal field Bx is 48.10- 4 T.

Exemple 5Example 5 Cuve à sorties par le fond, à quatre montées positives dont le courant dérivé par les têtes de la cuve considérée est collecté dans l'espace intercuve amont de la cuve considérée (figure 13)Tank with outlets from the bottom, with four positive ascents, the current derived by the heads of the tank considered is collected in the inter-tank space upstream of the tank considered (Figure 13)

Ce collecteur alimente le conducteur de dérivation par les têtes de la cuve considérée. Le courant dérivé alimente ensuite le croisillon amont de la cuve suivante par deux montées positives situées aux 1/8 et 7/8 du grand côté. Chacun des conducteurs de dérivation par les têtes de la cuve considérée est parcouru par 1/4 de l'intensité totale. Le reste du courant cathodique alimente par l'amont le croisillon de la cuve suivante par deux montées positives situées aux 3/8 et 5/8 du grand côté.This collector supplies the bypass conductor through the heads of the tank in question. The bypass current then feeds the upstream crosspiece of the next tank by two positive ascents located 1/8 and 7/8 of the long side. Each of the bypass conductors by the heads of the tank in question is traversed by 1/4 of the total intensity. The rest of the cathode current feeds upstream the cross of the next tank by two positive ascents located 3/8 and 5/8 of the long side.

Le champ vertical moyen par quadrant de cette cuve 250.000 A, et compte tenu de l'effet des pièces ferromagnétiques est:

Figure imgb0010
The average vertical field per quadrant of this 250,000 A tank, and taking into account the effect of the ferromagnetic parts is:
Figure imgb0010

Le champ horizontal Bx maximum est de 22.10-4 T.The maximum horizontal field Bx is 22.10- 4 T.

Mise en oeuvre de l'inventionImplementation of the invention

Nous avons réalisé une série de cuves suivant l'invention dont l'intensité de fonctionnement a été fixée à 250.000 A.We have produced a series of tanks according to the invention, the operating intensity of which has been set at 250,000 A.

La figure 14 donne schématiquement la disposition de l'ensemble des conducteurs de liaison entre la cuve considérée et la cuve suivante.Figure 14 schematically gives the arrangement of all the connecting conductors between the tank considered and the next tank.

La figure 15 est une coupe transversale selon un axe parallèle à Ox de la cuve considérée et de la cuve suivante. La numérotation des éléments est commune aux deux figures. Sur la figure 15, le dispositif d'alimentation en alumine, la superstructure, les anodes et leur système de suspension ont été soit supprimés, soit représentés très schématiquement pour la clarté du dessin. Ils sont, dans la réalité, conformes à l'art antérieur.Figure 15 is a cross section along an axis parallel to Ox of the tank considered and the next tank. The numbering of the elements is common to the two figures. In FIG. 15, the alumina supply device, the superstructure, the anodes and their suspension system have either been omitted, or shown very schematically for clarity of the drawing. They are, in reality, in accordance with the prior art.

Les sorties cathodiques par les fonds (20) sont reliées à plusieurs collecteurs négatifs (21 ). Le courant collecté aux deux extrémités de la cathode est raccordé par les conducteurs (22) aux conducteurs de dérivation (8) par les têtes de la cuve suivante et alimente ensuite le croisillon (9) de cette cuve par les montées (23) situées 'sur le côté aval au 1/4 et 3/4.The cathodic outputs through the bottoms (20) are connected to several negative collectors (21). The current collected at the two ends of the cathode is connected by the conductors (22) to the bypass conductors (8) by the heads of the next tank and then feeds the crosspiece (9) of this tank by the risers (23) located ' on the downstream side at 1/4 and 3/4.

Chacun des conducteurs de dérivation par les têtes est traversé par 3/16, soit 18,75%, de l'intensité totale. La cote selon Oz de ces conducteurs est déterminée de façon à assurer l'équilibrage du champ magnétique. La zone de localisation de ces conducteurs a été définie précédemment (figure 4).Each of the bypass conductors through the heads is crossed by 3/16, or 18.75%, of the total intensity. The Oz dimension of these conductors is determined so as to ensure the balance of the magnetic field. The location area of these conductors was previously defined (Figure 4).

Le courant collecté au centre de la cathode est raccordé par les conducteurs (24) à trois montées verticales, reliées aux têtes et au milieu du croisillon, du côté amont. Chacun des conducteurs alimentant les têtes du croisillon est traversé par 1/4 de l'intensité totale et le conducteur alimentant le centre du croisillon est traversé par 1/8 de l'intensité totale.The current collected at the center of the cathode is connected by the conductors (24) to three vertical risers, connected to the heads and in the middle of the spider, on the upstream side. Each of the conductors supplying the heads of the cross is crossed by 1/4 of the total intensity and the conductor feeding the center of the cross is crossed by 1/8 of the total intensity.

Les cuves de la série construite selon l'invention ont les caractéristiques suivantes:

Figure imgb0011
dimension intérieure 13,68x4,15 (en mêtres) du caissonThe tanks of the series built according to the invention have the following characteristics:
Figure imgb0011
inner dimension 13.68x4.15 (in meters) of the box

Au cours de leur fonctionnement, les résultats suivants ont été obtenus:

Figure imgb0012
During their operation, the following results were obtained:
Figure imgb0012

La consommation spécifique d'énergie correspondante est de 12.690 kMh/tonne AI, ce qui constitue une valeur record avec des cuves fonctionnant à une intensité aussi élevée. Ce gain a été obtenu entre autres par un abaissement de la chute cathodique qui s'est située en moyenne à 0,25 V.The corresponding specific energy consumption is 12,690 kMh / tonne AI, which is a record value with tanks operating at such a high intensity. This gain was obtained inter alia by a lowering of the cathodic drop which was on average at 0.25 V.

Claims (7)

1. A device for eliminating magnetic disturbances in series of igneous electrolysis cells intended for the production of aluminium from alumina dissolved in molten cryolite, operating at a very high intensity capable of reaching from 200,000 to 300,000 amperes, the said cells comprising a parallelepiped box which supports the cathodic blocks (4) in which there are sealed the cathodic current outlets (2) and an anodic system (5) suspended from a bus bar (9), the cells being connected electrically in series by linking conductors and arranged transversely to the Ox axis of the series in such a manner that the small side of the box and of the anodic system are parallel to the axis of the series, the cathodic outlets being formed by more than one conducting element sealed in the cathodic blocks and projecting vertically through the base of the box, characterised in that some of the linking conductors (8) connecting the cathodic outlets (2) of one cell to the bus-bar (5) of the following cell are arranged, over at least a section of the path thereof, outside the two vertical planes passing through the ends (12) of the anodic system (5) on the small side.
2. A process for eliminating magnetic disturbances in series of igneous electrolysis cells intended for the production of aluminium from alumina dissolved in molten cryolite, operating at an intensity capable of reaching from 200,000 to 300,000 amperes, the said cells comprising a parallelepiped box which supports the carbon cathodic blocks in which there are sealed the outlets of the cathodic current, and an anodic system suspended from a bus-bar, the cells being connected electrically in series by conductors connecting the cathodic outlets of one cell to the bus-bar of the following cell and being arranged transversely to the Ox axis of the series, such that the small side of the box and of the anodic system are parallel to the axis of the series, the cathodic current being extracted by several conducting elements sealed in the cathodic blocks and projecting vertically through the base of the box, characterised in that a fraction of the total current of from 30 and 54%, circulating in the linking conductors between the cells is shunted in conductors arranged over at least part of the path thereof, outside the two vertical planes passing through the ends of the anodic system on the small side.
3. A process for eliminating magnetic disturbances in series of igneous electrolysis cells according to claim 2, characterised in that the shunted current is distributed in the shunt conductors symmetrically to the axis of the series.
4. A process for eliminating magnetic disturbances in series of igneous electrolysis cells according to claim 2, characterised in that the shunted current is distributed in the shunt conductors asymmetrically to the axis of the series.
5. A process for eliminating magnetic disturbances in series of igneous electrolysis cells according to any one of claim 3 or 4, characterised in that the bus-bar of each cell is supplied with current from the cathodic outlets of the preceding cell by several vertical risers connected to the upstream side thereof.
6. A process for eliminating magnetic disturbances in series of igneous electrolysis cells according to any one of claims 3 or 4, characterised in that the bus-bar of each cell is supplied with current from the cathodic outlets of the preceding cell, partially by several vertical risers connected to the upstream side thereof, and partially by several vertical risers connected to the downstream side thereof.
7. A process for eliminating magnetic disturbances in series of igneous electrolysis cells according to any one of claims 3 or 4, characterised in that the bus-bar of each cell is partially supplied with current from the cathodic outlets of the preceding cell by vertical risers connected to either or to both of the two ends thereof on the small side of the anodic system.
EP80902175A 1979-11-07 1980-11-04 Process and device for suppressing magnetic disturbances in electrolytic cells Expired EP0047246B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7928132 1979-11-07
FR7928132A FR2469475A1 (en) 1979-11-07 1979-11-07 METHOD AND DEVICE FOR THE REMOVAL OF MAGNETIC DISTURBANCES IN VERY HIGH-INTENSITY ELECTROLYSING Cuvettes Placed Through Them

Publications (2)

Publication Number Publication Date
EP0047246A1 EP0047246A1 (en) 1982-03-17
EP0047246B1 true EP0047246B1 (en) 1985-01-23

Family

ID=9231687

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80902175A Expired EP0047246B1 (en) 1979-11-07 1980-11-04 Process and device for suppressing magnetic disturbances in electrolytic cells

Country Status (18)

Country Link
EP (1) EP0047246B1 (en)
JP (1) JPS56501247A (en)
KR (1) KR850001537B1 (en)
BR (1) BR8008907A (en)
CA (1) CA1143695A (en)
DE (1) DE3070034D1 (en)
ES (1) ES8200410A1 (en)
FR (1) FR2469475A1 (en)
GR (1) GR70348B (en)
HU (1) HU191178B (en)
IN (1) IN152568B (en)
MX (1) MX154537A (en)
NZ (1) NZ195424A (en)
OA (1) OA08223A (en)
PL (1) PL132150B1 (en)
RO (1) RO82538B (en)
WO (1) WO1981001299A1 (en)
YU (1) YU42988B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2008233392B2 (en) * 2007-04-02 2012-04-26 Norsk Hydro Asa Improvements relating to electrolysis cells connected in series and a method for operation of same
CN105452536A (en) * 2013-08-09 2016-03-30 力拓艾尔坎国际有限公司 Aluminium smelter comprising a compensating electric circuit

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH648605A5 (en) * 1980-06-23 1985-03-29 Alusuisse RAIL ARRANGEMENT OF AN ELECTROLYSIS CELL.
FR2505368B1 (en) * 1981-05-05 1985-09-27 Pechiney Aluminium DEVICE FOR THE PRODUCTION OF ALUMINUM BY HIGH-DENSITY IGNITED ELECTROLYSIS
FR2552782B1 (en) * 1983-10-04 1989-08-18 Pechiney Aluminium ELECTROLYSIS TANK WITH INTENSITY HIGHER THAN 250,000 AMPERES FOR THE PRODUCTION OF ALUMINUM BY THE HALL-HEROULT PROCESS
FR2583068B1 (en) * 1985-06-05 1987-09-11 Pechiney Aluminium ELECTRICAL CONNECTION CIRCUIT OF SERIES OF ELECTROLYSIS TANKS FOR THE PRODUCTION OF ALUMINUM AT VERY HIGH INTENSITY
AU713342B2 (en) * 1996-06-18 1999-12-02 Comalco Aluminium Limited Cathode construction
AUPO053496A0 (en) * 1996-06-18 1996-07-11 Comalco Aluminium Limited Cathode construction
CA2841847A1 (en) 2011-07-12 2013-01-17 Rio Tinto Alcan International Limited Aluminium smelter comprising electrical conductors made from a superconducting material
FR2977898A1 (en) * 2011-07-12 2013-01-18 Rio Tinto Alcan Int Ltd ALUMINERY COMPRISING CATHODIC EXIT TANKS THROUGH THE BOTTOM OF THE HOUSING AND TANK STABILIZATION MEANS
FR3032459B1 (en) 2015-02-09 2019-08-23 Rio Tinto Alcan International Limited ALUMINERY AND METHOD FOR COMPENSATING A MAGNETIC FIELD CREATED BY CIRCULATION OF THE ELECTROLYSIS CURRENT OF THIS ALUMINUM

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1187809B (en) * 1963-11-22 1965-02-25 Vaw Ver Aluminium Werke Ag Electrolysis cell for the production of aluminum by melt flow electrolysis
US3640800A (en) * 1970-07-14 1972-02-08 Arthur F Johnson Electrolytic cell
GB2008617B (en) * 1977-11-23 1982-03-31 Alcan Res & Dev Electrolytic reduction cells
US4194959A (en) * 1977-11-23 1980-03-25 Alcan Research And Development Limited Electrolytic reduction cells
SU863719A1 (en) * 1978-02-06 1981-09-15 Всесоюзный Научно-Исследовательский И Проектный Институт Алюминиевой,Магниевой И Электродной Промышленности Leads of aluminium electrolyzer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2008233392B2 (en) * 2007-04-02 2012-04-26 Norsk Hydro Asa Improvements relating to electrolysis cells connected in series and a method for operation of same
CN105452536A (en) * 2013-08-09 2016-03-30 力拓艾尔坎国际有限公司 Aluminium smelter comprising a compensating electric circuit
CN105452536B (en) * 2013-08-09 2017-09-19 力拓艾尔坎国际有限公司 Aluminium manufacturer including compensation circuit

Also Published As

Publication number Publication date
PL227652A1 (en) 1981-08-21
CA1143695A (en) 1983-03-29
DE3070034D1 (en) 1985-03-07
MX154537A (en) 1987-09-28
FR2469475A1 (en) 1981-05-22
PL132150B1 (en) 1985-02-28
IN152568B (en) 1984-02-11
ES496595A0 (en) 1981-10-16
OA08223A (en) 1987-10-30
FR2469475B1 (en) 1982-12-17
KR830004457A (en) 1983-07-13
ES8200410A1 (en) 1981-10-16
EP0047246A1 (en) 1982-03-17
BR8008907A (en) 1981-08-25
RO82538A (en) 1984-02-21
YU280380A (en) 1984-02-29
WO1981001299A1 (en) 1981-05-14
NZ195424A (en) 1984-12-14
GR70348B (en) 1982-09-23
RO82538B (en) 1984-02-28
YU42988B (en) 1989-02-28
KR850001537B1 (en) 1985-10-16
HU191178B (en) 1987-01-28
JPS56501247A (en) 1981-09-03

Similar Documents

Publication Publication Date Title
EP0047246B1 (en) Process and device for suppressing magnetic disturbances in electrolytic cells
EP0204647B1 (en) Connection device between very high intensity electrolytic pots for aluminium production, comprising a current supply circuit and an independent circuit for correcting the magnetic field
CA2561258C (en) Series of electrolysis cells for the production of aluminium comprising means for equilibration of the magnetic fields at the ends of the lines
EP2732074B1 (en) Aluminum smelter including cells having a cathode outlet through the base of the casing, and a means for stabilizing the cells
CA1061745A (en) Method and apparatus for supplying power to igneous electrolysis baths st crosswise____________________________________________________________
CA1100906A (en) Method for improving current feed to lengthwise aligned electrolysis baths
CH619006A5 (en)
FR2552782A1 (en) ELECTROLYSIS TANK WITH AN INTENSITY UP TO 250 000 AMPERES FOR THE PRODUCTION OF ALUMINUM BY THE HALL-HEROULT PROCESS
CA2919050C (en) Aluminium smelter comprising a compensating electric circuit
CA1125226A (en) Method for compensating the magnetic field induced by the neighbouring row in a series of high intensity electrolysis tanks
CA2975962C (en) Aluminium smelter and method to compensate for a magnetic field created by the circulation of the electrolysis current of said aluminium smelter
FR2583068A1 (en) ELECTROLYSIS SERIES ELECTRICAL CONNECTION CIRCUIT FOR ALUMINUM PRODUCTION UNDER VERY HIGH INTENSITY
EP2616571B1 (en) Electrical connection device, for connecting between two successive cells of a series of cells for the production of aluminium
EP3362590B1 (en) Series of electrolysis cells for the production of aluminium comprising means for balancing the magnetic fields at the end of the line
FR2522021A1 (en) ELECTROLYTIC CELLS FOR THE PRODUCTION OF ALUMINUM
RU2168564C2 (en) Compensation device
RU2169797C1 (en) Rus arrangement of aluminum electrolyzer
FR2610332A1 (en) Prebaked carbon elements forming the anodes of cells for the production of aluminium by igneous electrolysis
FR2505368A1 (en) Aluminium prodn. in Hall-Heroult cell - with high current intensity and reduced energy consumption
OA18402A (en) Aluminum smelter and process for compensating a magnetic field created by the circulation of electrolysis current from this smelter.
RU2092622C1 (en) Device for powering consecutively connected electrolyzer cells
OA16842A (en) Aluminum plant comprising tanks with cathodic outlet through the bottom of the box and means for stabilizing the tanks

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19810605

AK Designated contracting states

Designated state(s): CH DE GB NL SE

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): CH DE GB LI NL SE

REF Corresponds to:

Ref document number: 3070034

Country of ref document: DE

Date of ref document: 19850307

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19881130

Ref country code: CH

Effective date: 19881130

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19921012

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19921014

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19921015

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19921130

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19931104

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19931105

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19940601

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19931104

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19940802

EUG Se: european patent has lapsed

Ref document number: 80902175.1

Effective date: 19940610