EP0040713A1 - Use of mixed formals of alkylpolyglycol ethers as foam suppressing agents - Google Patents

Use of mixed formals of alkylpolyglycol ethers as foam suppressing agents Download PDF

Info

Publication number
EP0040713A1
EP0040713A1 EP81103326A EP81103326A EP0040713A1 EP 0040713 A1 EP0040713 A1 EP 0040713A1 EP 81103326 A EP81103326 A EP 81103326A EP 81103326 A EP81103326 A EP 81103326A EP 0040713 A1 EP0040713 A1 EP 0040713A1
Authority
EP
European Patent Office
Prior art keywords
carbon atoms
mixed formals
agents
formula
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81103326A
Other languages
German (de)
French (fr)
Other versions
EP0040713B1 (en
Inventor
geb. Hartlieb Margarete Grünert
Karl Dr. Schmid
Holger Dr. Tesmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT81103326T priority Critical patent/ATE5328T1/en
Publication of EP0040713A1 publication Critical patent/EP0040713A1/en
Application granted granted Critical
Publication of EP0040713B1 publication Critical patent/EP0040713B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions

Definitions

  • the invention relates to the use of certain alkyl polyglycol ether mixed formals as anti-foaming agents in strongly alkaline cleaning agents.
  • Industrial cleaning agents in particular those which are used in automatic systems for cleaning rigid surfaces such as metal, ceramic or glass and in particular for bottle cleaning, are said to have low foaming power with a strong cleaning power exhibit.
  • the industrial cleaning agents of the type mentioned are mostly products which contain strongly alkaline substances such as, in particular, alkali metal hydroxides or also alkali metal silicates or alkali metal orthophosphates, individually or in a mixture. In the case of such products, high demands are placed on the defoamers not only with regard to the anti-foam effect but also with regard to the storage stability in the corresponding solid products.
  • alkyl polyglycol ether mixed formals of the formula are used as anti-foaming agents in alkaline cleaning agents in which R 1 is a straight-chain or branched alkyl or alkylene radical having 8 to 22 carbon atoms, R 2 is a straight-chain or branched alkyl radical having 1 to 5 carbon atoms, m is a number from 2 to 30 and n is a number from 1 to 3.
  • R 1 is an alkyl radical having 12 to 18 carbon atoms
  • R 2 is an alkyl radical having 2 to 4 carbon atoms
  • m is an integer from 7 to 15
  • n is 1.
  • the alkyl polyglycol ether mixed formals of the formula given above which are used can be prepared, for example by reaction of fatty alcohol ethoxylate of the formula with a di-alkyl glycol formal of the formula in the presence of a strong acid, such as sulfuric acid, by heating to temperatures of about 150 ° C. for several hours.
  • R 1 and R 2 have the same meaning as given in formula I.
  • Suitable starting products for the fatty alcohol ethoxylates are straight-chain or branched aliphatic alcohols, such as hexadecyl, tetradecyl and octadecyl alcohols, and the corresponding branched iso alcohols.
  • Branched aliphatic alcohols which can be prepared by the so-called Guerbet reaction (dimerization of primary alcohols) can also be used.
  • synthetic fatty alcohols or mixtures thereof, such as those obtained in oxo synthesis can also be used.
  • the strongly alkaline cleaning agents (pH above 10) contain sodium or potassium hydroxide in particular.
  • other strongly alkaline substances such as alkali carbonate and alkali orthophosphates, are used alone or in a mixture with alkali hydroxides.
  • the alkaline cleaning agents can also contain the usual constituents, such as alkali silicates, alkali borates, polymeric alkali phosphates and / or complexing agents, such as phosphonic acids, in particular 1-hydroxy ethane-1,1-diphosphonic acid, aminotrimethylene phosphonic acid or 2-phosphonobutane-1,2,4-tricarboxylic acid.
  • the molar ratio of Na 2 O or K 2 0: P 2 O 5 can be 1: 1 to 2: 1.
  • sodium tripolyphosphate is used.
  • Fine-particle synthetically produced, water - insoluble, bound water-containing aluminosilicates of the general formula can also be used as substitutes for the polyphosphates in the cat a cation of valence n, preferably sodium, exchangeable for calcium, x a number from 0.7 to 1.5, preferably 0.9 to 1.3, and y a number from 0.8 to 6, preferably of 1 , 3 to 4, which have a calcium binding capacity of 50 to 200, preferably 100 to 200 mg CaO / g of the anhydrous aluminosilicate can be used.
  • aluminosilicates can be crystalline or X-ray amorphous.
  • the crystalline sodium aluminosilicates are preferred, in particular the zeolites A and X.
  • alkali stable anionic surfactants such as alkyl and / or aryl sulfonates, are also suitable as constituents.
  • the amount of anti-foaming agent added is about 0.1 to 1 g / l, based on the solution used. The amount added depends on the desired antifoam effect and the impurities or bath concentration of the cleaning agent.
  • the detergents are generally used with a bath concentration of 0.2 to 10% depending on the intended use.
  • the application temperature is generally between 40 and 90 ° C.
  • the cleaning agents prepared in this way were each stored in closed polypropylene containers at 45 ° C. and the defoamer tests were carried out at intervals of 2 weeks each.
  • the free fall cycle method consists of heating 500 ml of cleaning solution to 60 ° C in a jacketed 2-1 measuring cylinder.
  • this solution is put into constant circulation at a throughput capacity of 4 l / minute so that the solution is sucked from the bottom of the measuring cylinder with a glass tube and in the open via a second glass tube with the 2000 ml mark of the measuring cylinder Case traced. becomes.
  • a constant initial foam volume for example 2000 ml

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Alkylpolyglykolethermischformale der Formel R1 - O - (CH2CH2O)m - CH2 - (OCH2CH2)n - O - R2 in der R1 einen geradkettigen oder verzweigten Alkyl- oder Alkylenrest mit 8 bis 22 Kohlenstoffatomen, R2 einen geradkettigen oder verzweigten Alkylrest mit 1 bis 5 Kohlenstoffatomen, m eine Zahl von 2 bis 30 und n eine Zahl von 1 bis 3 bedeuten, werden als Antischaummittel in alkalischen Reinigungsmitteln verwendet. Die alkalistabilen Mischformale werden den alkalischen Reinigungsmitteln in einer Menge von 0,1 bis 1 g/l, bezogen auf die zur Anwendung kommende Lösung, zugesetzt. Die gut dispergierbaren Antischaummittel sind biologisch abbaubar.Alkyl polyglycol ether mixed formals of the formula R1 - O - (CH2CH2O) m - CH2 - (OCH2CH2) n - O - R2 in which R1 is a straight-chain or branched alkyl or alkylene radical having 8 to 22 carbon atoms, R2 is a straight-chain or branched alkyl radical having 1 to 5 carbon atoms , m is a number from 2 to 30 and n is a number from 1 to 3, are used as anti-foaming agents in alkaline cleaning agents. The alkali-stable mixed formals are added to the alkaline cleaning agents in an amount of 0.1 to 1 g / l, based on the solution used. The highly dispersible anti-foaming agents are biodegradable.

Description

Gegenstand der Erfindung ist die Verwendung bestimmter Alkylpolyglykolethermischformale als Antischaummittel in stark alkalischen Reinigungsmitteln.iIndustrielle Reinigungsmittel, insbesondere solche, die in automatischen Anlagen zur Reinigung von starren Oberflächen wie Metall, Keramik oder Glas sowie insbesondere zur Flaschenreinigung eingesetzt werden, sollen bei starker Reinigungskraft eine geringe Schaumentwicklung aufweisen. Bei den industriellen Reinigungsmitteln der genannten Art handelt es sich meist um Produkte, die stark alkalische Stoffe wie insbesondere Alkalihydroxide oder auch Alkalisilikate oder Alkaliorthophosphate einzeln oder im Gemisch enthalten. Bei derartigen Produkten werden an die Entschäumer nicht nur hinsichtlich der Antischaumwirkung sondern auch hinsichtlich der Lagerstabilität in den entsprechenden festen Produkten hohe Anforderungen gestellt.The invention relates to the use of certain alkyl polyglycol ether mixed formals as anti-foaming agents in strongly alkaline cleaning agents. Industrial cleaning agents, in particular those which are used in automatic systems for cleaning rigid surfaces such as metal, ceramic or glass and in particular for bottle cleaning, are said to have low foaming power with a strong cleaning power exhibit. The industrial cleaning agents of the type mentioned are mostly products which contain strongly alkaline substances such as, in particular, alkali metal hydroxides or also alkali metal silicates or alkali metal orthophosphates, individually or in a mixture. In the case of such products, high demands are placed on the defoamers not only with regard to the anti-foam effect but also with regard to the storage stability in the corresponding solid products.

Es ist bekannt, sowohl in festen als auch in flüssigen Produkten für die industrielle Reinigung, Anlagerungsprodukte von Ethylenoxid und Propylenoxid an Verbindungen wie Fettalkohole, Fettsäuren, Polyglycerin und Ethylendiamine als Entschäumer einzusetzen. Es hat sich jedoch gezeigt, daß bei der Konfektionierung beispielsweise in festen Reinigungsmitteln, die einen sehr hohen Alkaligehalt, insbesondere an über 50 % und mehr Ätzalkali enthalten die Lagerstabilität nicht immer hinreichend ist. Auch ist es erwünscht, daß die Antischaummittel eine gute biologische Abbaubarkeit besitzen, laugenstabil sind, indem sie während des Reinigungsprozesses unter andauernder Temperaturbelastung ihre Wirksamkeit nicht verlieren.It is known to use both in solid and in liquid products for industrial cleaning, adducts of ethylene oxide and propylene oxide with compounds such as fatty alcohols, fatty acids, polyglycerol and ethylenediamines as defoamers. However, it has been shown that the storage stability is not always sufficient in the case of packaging, for example in solid cleaning agents which contain a very high alkali content, in particular more than 50% and more caustic alkali. It is also desirable that the anti-foaming agents have good biodegradability, are alkali-stable, so that they do not lose their effectiveness during the cleaning process under constant exposure to temperature.

Es wurde nun gefunden, daß in besonderem Maße die Anforderungen an die Alkalistabilität und die Dispergierbarkeit und biologische Abbaubarkeit erfüllt werden, wenn man als Antischaummittel in alkalischen Reinigungsmitteln Alkylpolyglykolethermischformale der Formel

Figure imgb0001
in der R1 einen geradkettigen oder verzweigten Alkyl- oder Alkylenrest mit 8 bis 22 Kohlenstoffatomen, R2 einen geradkettigen oder verzweigten Alkylrest mit 1 bis 5 Kohlenstoffatomen, m eine Zahl von 2 bis 30 und n eine Zahl von 1 bis 3 bedeuten, verwendet.It has now been found that the requirements for alkali stability and dispersibility and biodegradability are met to a particular degree when alkyl polyglycol ether mixed formals of the formula are used as anti-foaming agents in alkaline cleaning agents
Figure imgb0001
 in which R 1 is a straight-chain or branched alkyl or alkylene radical having 8 to 22 carbon atoms, R 2 is a straight-chain or branched alkyl radical having 1 to 5 carbon atoms, m is a number from 2 to 30 and n is a number from 1 to 3.

Insbesondere hat sich die Verwendung der Verbindungen der Formel I als geeignet erwiesen, in der R1 einen Alkylrest mit 12 bis 18 Kohlenstoffatomen, R2 einen Alkylrest mit 2 bis 4 Kohlenstoffatomen, m eine ganze Zahl von 7 bis 15 und n gleich 1 ist. Die zur Anwendung gelangenden Alkylpolyglykolethermischformale der oben angegebenen Formel können hergestellt werden, beispielsweise durch Umsetzung von Fettalkoholethoxilat der Formel

Figure imgb0002
mit einem Di-alkylglykolformal der Formel
Figure imgb0003
in Gegenwart einer starken Säure,wie Schwefelsäure, durch mehrstündiges Erwärmen auf Temperaturen von etwa 150°C. R1 und R2 haben dabei die gleiche Bedeutung wie in der Formel I angegeben.In particular, the use of the compounds of the formula I has proven to be suitable in which R 1 is an alkyl radical having 12 to 18 carbon atoms, R 2 is an alkyl radical having 2 to 4 carbon atoms, m is an integer from 7 to 15 and n is 1. The alkyl polyglycol ether mixed formals of the formula given above which are used can be prepared, for example by reaction of fatty alcohol ethoxylate of the formula
Figure imgb0002
 with a di-alkyl glycol formal of the formula
Figure imgb0003
 in the presence of a strong acid, such as sulfuric acid, by heating to temperatures of about 150 ° C. for several hours. R 1 and R 2 have the same meaning as given in formula I.

Als Ausgangsprodukte für die Fettalkoholethoxilate kommen gradkettige oder auch verzweigte aliphatische Alkohole, wie Hexadecyl-, Tetradecyl- und Octadecylalkohole sowie die entsprechenden verzweigten Isoalkohole in Betracht. Auch können als verzweigte aliphatische Alkohole solche verwendet werden, die durch die sogenannte Guerbet-Reaktion (Dimerisierung von primären Alkoholen) herstellbar sind. Es können jedoch auch synthetische Fettalkohole oder Gemische davon, wie sie bei der Oxosynthese anfallen, Anwendung finden.Suitable starting products for the fatty alcohol ethoxylates are straight-chain or branched aliphatic alcohols, such as hexadecyl, tetradecyl and octadecyl alcohols, and the corresponding branched iso alcohols. Branched aliphatic alcohols which can be prepared by the so-called Guerbet reaction (dimerization of primary alcohols) can also be used. However, synthetic fatty alcohols or mixtures thereof, such as those obtained in oxo synthesis, can also be used.

Die stark alkalischen Reinigungsmittel (pH-Wert über 10) enthalten insbesondere Natrium- oder Kaliumhydroxid. Es werden jedoch auch andere stark alkalisch reagierende Stoffe, wie Alkalicarbonat und Alkaliorthophosphate, allein oder im Gemisch mit Alkalihydroxiden, verwendet. Die alkalischen Reinigungsmittel können jedoch darüber hinaus auch die üblichen Bestandteile, wei Alkalisilikate, Alkaliborate, polymere Alkaliphosphate und/oder Komplexbildner, wie Phosphonsäuren, insbesondere 1-Hydroxyethan-1,1-diphosphonsäure, Aminotrimethylenphosphonsäure oder 2-Phosphono-butan-1,2,4-tricarbonsäure, enthalten.The strongly alkaline cleaning agents (pH above 10) contain sodium or potassium hydroxide in particular. However, other strongly alkaline substances, such as alkali carbonate and alkali orthophosphates, are used alone or in a mixture with alkali hydroxides. However, the alkaline cleaning agents can also contain the usual constituents, such as alkali silicates, alkali borates, polymeric alkali phosphates and / or complexing agents, such as phosphonic acids, in particular 1-hydroxy ethane-1,1-diphosphonic acid, aminotrimethylene phosphonic acid or 2-phosphonobutane-1,2,4-tricarboxylic acid.

Bei den polymeren Phosphaten kann das Molverhältnis von Na2O oder K 2 0 : P2O5 1: 1 bis 2 : 1 betragen. Insbesondere wird Natriumtripolyphosphat verwendet.In the polymeric phosphates, the molar ratio of Na 2 O or K 2 0: P 2 O 5 can be 1: 1 to 2: 1. In particular, sodium tripolyphosphate is used.

Als Substitute für die Polyphosphate können auch feinteilige synthetisch hergestellte, wasserunlös- liche, gebundenes Wasser enthaltende Alumosilikate der allgemeinen Formel

Figure imgb0004
in der Kat ein gegen Calcium austauschbares Kation der Wertigkeit n, vorzugsweise Natrium, x eine Zahl von 0,7 bis 1,5, vorzugsweise 0,9 bis 1,3, und y eine Zahl von 0,8 bis 6, vorzugsweise von 1,3 bis 4, bedeuten, die ein Calciumbindevermögen von 50 bis 200, vorzugsweise 100 bis 200 mg CaO/g des wasserfreien Alumosilikats aufweisen, verwendet werden. Diese Alumosilikate können kristallin oder röntgenamorph sein. Bevorzugt sind die kristallinen Natriumalumosilikate, insbesondere die Zeolithe A und X.Fine-particle synthetically produced, water - insoluble, bound water-containing aluminosilicates of the general formula can also be used as substitutes for the polyphosphates
Figure imgb0004
 in the cat a cation of valence n, preferably sodium, exchangeable for calcium, x a number from 0.7 to 1.5, preferably 0.9 to 1.3, and y a number from 0.8 to 6, preferably of 1 , 3 to 4, which have a calcium binding capacity of 50 to 200, preferably 100 to 200 mg CaO / g of the anhydrous aluminosilicate can be used. These aluminosilicates can be crystalline or X-ray amorphous. The crystalline sodium aluminosilicates are preferred, in particular the zeolites A and X.

Ferner kommen in besonderen Fällen Alkali stabile anionische Tenside, wie Alkyl- und/oder Arylsulfonate, als Bestandteile in Betracht.In special cases, alkali stable anionic surfactants, such as alkyl and / or aryl sulfonates, are also suitable as constituents.

Die zugesetzte Menge an Antischaummittel beträgt etwa 0,1 bis 1 g/l, bezogen auf die zur Anwendung gelangende Lösung. Die Zusatzmenge richtet sich nach der gewünschten Antischaumwirkung und nach den Verunreinigungen beziehungsweise der Badkonzentration des Reinigungsmittels. Die Reinigungsmittel werden im allgemeinen mit einer Badkonzentration von 0,2 bis 10 % je nach dem Verwendungszweck eingesetzt. Die Anwendungstemperatur liegt im allgemeinen zwischen 40 und 90°C.The amount of anti-foaming agent added is about 0.1 to 1 g / l, based on the solution used. The amount added depends on the desired antifoam effect and the impurities or bath concentration of the cleaning agent. The detergents are generally used with a bath concentration of 0.2 to 10% depending on the intended use. The application temperature is generally between 40 and 90 ° C.

Beispiel 1example 1

Durch intensives Vermischen der Bestandteile wurden verschiedene Reinigungsmittel, wie sie insbesondere für die Flaschenreinigung üblich sind, hergestellt. Diese hatten die folgende Zusammensetzung:

  • a) 75 % technisches Natriumhydroxid in Schuppenform 6 % Natriumtripolyphosphat 15,5 % Natriummetasilikat . 5 Hydrat sowie jeweils 3,5 % des zu prüfenden Entschäumers
  • b) 15 % Natriumhydroxid 25 % Natriumtripolyphosphat 25 % Natriummetasilikat. 32 % Natriumcarbonat 3 % des zu prüfenden Entschäumers
By intensive mixing of the components, various cleaning agents, as are particularly common for bottle cleaning, were produced. These had the following composition:
  • a) 75% technical sodium hydroxide in the form of flakes 6% sodium tripolyphosphate 15.5% sodium metasilicate. 5 hydrate and 3.5% each of the defoamer to be tested
  • b) 15% sodium hydroxide 25% sodium tripolyphosphate 25% sodium metasilicate. 32% sodium carbonate 3% of the defoamer to be tested

Die so hergestellten Reinigungsmittel wurden jeweils bei 45°C in verschlossenen Behältern aus Polypropylen gelagert und die Entschäumerteste in Zeitabständen von je 2 Wochen durchgeführt.The cleaning agents prepared in this way were each stored in closed polypropylene containers at 45 ° C. and the defoamer tests were carried out at intervals of 2 weeks each.

Zur Prüfung wurden je 1,5 % der Reinigermischung in jeweils eine 0,025%ige Schmierseifen- beziehungsweise 0,025%ige Alkylbenzolsulfonat-Lösung eingeführt. Je 500 ml dieser Lösungen wurden anschließend nach der Freifallkreislaufmethode geprüft und die Schaumwerte bestimmt.For testing, 1.5% of the detergent mixture was introduced into a 0.025% lubricating soap and 0.025% alkylbenzenesulfonate solution. Each 500 ml of these solutions were then tested using the free-fall cycle method and the foam values were determined.

Die Freifallkreislaufmethode besteht darin, daß 500 ml Reinigerlösung in einem ummantelten 2-1-Meßzylinder auf 60°C erhitzt werden.The free fall cycle method consists of heating 500 ml of cleaning solution to 60 ° C in a jacketed 2-1 measuring cylinder.

Mit Hilfe einer Pumpe wird diese Lösung bei einer Durchlaufkapazität von 4 1/Minute so in einen ständigen Umlauf gebracht, daß die Lösung mit einem Glasrohr vom Boden des Meßzylinders angesaugt und über ein zweitesj mit der 2000-ml-Marke des Meßzylinders abschließendes Glasrohr im freien Fall zurückgeführt. wird. Nach kurzer Laufzeit stellt sich hierbei ein konstantes Ausgangsschaumvolumen (zum Beispiel 2000 ml) ein.With the help of a pump, this solution is put into constant circulation at a throughput capacity of 4 l / minute so that the solution is sucked from the bottom of the measuring cylinder with a glass tube and in the open via a second glass tube with the 2000 ml mark of the measuring cylinder Case traced. becomes. After a short running time, a constant initial foam volume (for example 2000 ml) is established.

Die sich ergebenden Gesamtvolumina, Schaum und Lösung, wurden in Abständen von 1, 3, 5, 10, 20 und 30 Minuten äbgelesen.The resulting total volumes, foam and solution, were read at 1, 3, 5, 10, 20 and 30 minute intervals.

Bei den Produkten, die nicht oder nur beschränkt nach einer mehrwöchigen Lagerzeit stabil sind, tritt entweder keine schaumdrückende Wirkung auf oder die Schaumdepression nimmt nach kurzer Zeit, zum Beispiel innerhalb 10 bis 30 Minuten, erheblich ab. Bei stabilen Produkten bleibt die Antischaumwirkung von Anfang an bis zum Ende der Prüfzeit (30 Minuten) praktisch konstant. Bei instabilen Produkten erreicht. der Schaum nach wenigen Minuten seine maximale Höhe, zum Beispiel 2000 ml.For products that are not stable or only stable to a limited extent after a storage period of several weeks, either there is no foam-suppressing effect or the foam depression decreases considerably after a short time, for example within 10 to 30 minutes. In the case of stable products, the anti-foam effect remains practically constant from the beginning to the end of the test period (30 minutes). Achieved for unstable products. the foam reaches its maximum height after a few minutes, for example 2000 ml.

Die nachstehende Tabelle gibt einen Überblick über die Stabilität und Entschäumerwirkung der erfindungsgemäßen Produkte im Vergleich mit ähnlichen Handelsprodukten.

Figure imgb0005
The table below gives an overview of the stability and defoaming action of the products according to the invention in comparison with similar commercial products.
Figure imgb0005

Beispiel 2Example 2

Ein Mittel zur Dampfstrahlreinigung von metallischen Oberflächen hatte folgende Zusammensetzung:

  • 51 % Wasser
  • 5 % gesättigte Fettsäure (C8/C10)
  • 8 % Mischformal von Fettalkohol C12/C18 + 9 EO mit Butylglycol
  • 26 % Kalilauge (38%ig).
  • 10 % Kaliumpyrophosphat
A composition for steam jet cleaning of metallic surfaces had the following composition:
  • 51% water
  • 5% saturated fatty acid (C 8 / C 10 )
  • 8% mixed formal of fatty alcohol C 12 / C 18 + 9 EO with butyl glycol
  • 26% potassium hydroxide solution (38%).
  • 10% potassium pyrophosphate

Man erhält ein klares Mischprodukt mit extrem schwachem Schaumverhalten, welches als 1%ige Lösung ingesetzt wird.A clear mixed product with extremely weak foaming behavior is obtained, which is used as a 1% solution.

Beispiel 3Example 3

Ein alkalisches Reinigungsgranulat zur Entfettung von Metalloberflächen bestehend aus folgender Zusammensetzung:

  • 75 % NaOH granuliert
  • 19 % Trinatriumphosphat
  • 3 % Natrium-tripolyphosphat
  • 2 % Natrium-dodecylbenzolsulfonat
  • 1 % Mischformal von Oxoalkohol C14/C15 + 11 EO mit Butylglycol
An alkaline cleaning granulate for degreasing metal surfaces consisting of the following composition:
  • 75% NaOH granulated
  • 19% trisodium phosphate
  • 3% sodium tripolyphosphate
  • 2% sodium dodecylbenzenesulfonate
  • 1% mixed formal of oxo alcohol C 14 / C 15 + 11 EO with butyl glycol

Eine 5%ige Lösung dieses Reinigers zeigt bei 60 bis 90°C ein extrem schwaches Schaumverhalten und sehr gute Entfettungswirkung.A 5% solution of this cleaner shows an extremely weak foaming behavior and very good degreasing effect at 60 to 90 ° C.

Claims (3)

1. Verwendung von Alkylpolyglykolethermischformalen der Formel
Figure imgb0006
in der R1 einen geradkettigen oder verzweigten Alkyl- oder Alkylenrest mit 8 bis 22 Kohlenstoffatomen, R2 einen geradkettigen oder verzweigten Alkylrest mit 1 bis 5 Kohlenstoffatomen, m eine Zahl von 2 bis 30 und n eine Zahl von 1 bis 3 bedeuten, als Antischaummittel in alkalischen Reinigungsmitteln.1. Use of alkyl polyglycol ether mixed formals of the formula
Figure imgb0006
 in which R 1 is a straight-chain or branched alkyl or alkylene radical having 8 to 22 carbon atoms, R 2 is a straight-chain or branched alkyl radical having 1 to 5 carbon atoms, m is a number from 2 to 30 and n is a number from 1 to 3, as anti-foaming agents in alkaline cleaning agents. 2. Verwendung nach Anspruch 1, dadurch gekennzeichnet, daß man Alkylpolyglykolethermischformale der Formel I einsetzt, in der R1 einen Alkylrest mit 12 bis 18 Kohlenstoffatomen, R2 einen Alkylrest mit 2 bis 4 Kohlenstoffatomen, m eine Zahl von 7 bis 15 und n gleich 1 ist.2. Use according to claim 1, characterized in that one uses alkylpolyglycol ether mixed formals of formula I in which R 1 is an alkyl radical with 12 to 18 carbon atoms, R 2 is an alkyl radical with 2 to 4 carbon atoms, m is a number from 7 to 15 and n is the same 1 is. 3. Verwendung nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, daß die Alkylpolyglykolethermisch- formale der Formel I den alkalischen Reinigungsmitteln in einer Menge von 0,1 bis 1 g/l, bezogen auf die zur Anwendung kommende Lösung, zugesetzt werden.3. Use according to claims 1 and 2, characterized in that the alkyl p olyglykolethermisch- formal of the formula I the alkaline cleaning agents are used in an amount of 0.1 to 1 g / l to the coming to the application solution is added.
EP81103326A 1980-05-12 1981-05-02 Use of mixed formals of alkylpolyglycol ethers as foam suppressing agents Expired EP0040713B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81103326T ATE5328T1 (en) 1980-05-12 1981-05-02 USE OF ALKYLPOLYGLYCOLE THERMAL FORMALS FOR ANTIFOAM.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3018149 1980-05-12
DE19803018149 DE3018149A1 (en) 1980-05-12 1980-05-12 USE OF ALKYLPOLYGLYKOLETHERMAL FORMAL FOR FOAM PREVENTION

Publications (2)

Publication Number Publication Date
EP0040713A1 true EP0040713A1 (en) 1981-12-02
EP0040713B1 EP0040713B1 (en) 1983-11-16

Family

ID=6102215

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81103326A Expired EP0040713B1 (en) 1980-05-12 1981-05-02 Use of mixed formals of alkylpolyglycol ethers as foam suppressing agents

Country Status (15)

Country Link
US (1) US4364777A (en)
EP (1) EP0040713B1 (en)
JP (1) JPS5715806A (en)
AR (1) AR223116A1 (en)
AT (1) ATE5328T1 (en)
BR (1) BR8102900A (en)
CA (1) CA1157736A (en)
DE (2) DE3018149A1 (en)
DK (1) DK166781A (en)
ES (1) ES502104A0 (en)
FI (1) FI66900C (en)
MX (1) MX7094E (en)
NO (1) NO151244C (en)
TR (1) TR21341A (en)
ZA (1) ZA813128B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054894A1 (en) * 1980-12-23 1982-06-30 Hoechst Aktiengesellschaft Surfactant-containing mixture for cleaning hard surfaces
EP0124815A2 (en) * 1983-05-02 1984-11-14 Henkel Kommanditgesellschaft auf Aktien Use of polyglycol ethers as foam-depressing additives in cleaning agents producing little foam
EP0564402A1 (en) * 1992-04-01 1993-10-06 Ciba-Geigy Ag Low foaming surfactant compounds
WO2015113860A1 (en) * 2014-01-30 2015-08-06 Basf Se Asymmetric formales and acetales as adjuvants for crop protection

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4394273A (en) * 1981-12-10 1983-07-19 Nl Industries, Inc. Defoamers for aqueous liquids containing soluble zinc salts
DE3338923C1 (en) * 1983-10-27 1985-02-21 Th. Goldschmidt Ag, 4300 Essen Use of copolymers of polyoxyalkylene ethers of allyl and / or methallyl alcohol and vinyl esters as demulsifiers for crude oil containing water
DE3345349A1 (en) * 1983-12-15 1985-06-27 Henkel KGaA, 4000 Düsseldorf USE OF POLYGLYCOLETHERS AS FOAM-PRESSING ADDITIVES IN LOW-FOAM CLEANERS
DE3418523A1 (en) * 1984-05-18 1985-11-21 Basf Ag, 6700 Ludwigshafen END-GROUP LOCKED FATTY ALCOHOL ALCOXYLATES FOR INDUSTRIAL CLEANING PROCESSES, ESPECIALLY FOR BOTTLE WASHING AND FOR METAL CLEANING
DE3641447A1 (en) * 1986-12-04 1988-06-09 Henkel Kgaa TENSIDE MIXTURES AS COLLECTORS FOR THE FLOTATION OF NON-SULFIDIC ORES
SE462599B (en) * 1987-04-06 1990-07-23 Berol Kemi Ab PRE-PACKING THAT PREVENTS FOAM PREPARATION, PREPARING SUCH PRE-PACKAGING AND ANTI-DUMPING AGENTS
KR960002629B1 (en) * 1987-06-25 1996-02-24 가오 가부시끼가이샤 Additive for alkaline detergent and the composition containing the same
GB8906820D0 (en) * 1989-03-23 1989-05-10 Ici Plc Novel chemical compounds and their use as low foam surfactants and antifoamingagents
US5068444A (en) * 1989-10-31 1991-11-26 Texaco Chemical Company Tetramines by amination of dialdehyde glycol adducts
US5399239A (en) * 1992-12-18 1995-03-21 Ceridian Corporation Method of fabricating conductive structures on substrates
CN109607648A (en) * 2018-12-19 2019-04-12 宁波瑞凌新能源科技有限公司 A kind of radiation refrigeration formula desalination plant

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1225800B (en) * 1964-01-11 1966-09-29 Henkel & Cie Gmbh Low-foaming detergents and cleaning agents
DE2523588A1 (en) * 1975-05-28 1976-12-16 Hoechst Ag POLYGLYCOL ETHERMAL FORMALS AND THEIR USE AS CORROSIVE WETTING, DETERGENT AND CLEANING AGENTS

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA656004A (en) * 1963-01-15 A. Bixler Dean Detergent composition
US2905719A (en) * 1959-09-22 Cxhzo
US2905718A (en) * 1957-09-24 1959-09-22 Rohm & Haas Surface-active acetals and formals
US2905720A (en) * 1957-09-24 1959-09-22 Rohm & Haas Surface-active acetals and formals
US3048548A (en) * 1959-05-26 1962-08-07 Economics Lab Defoaming detergent composition
NL285082A (en) * 1962-02-28
US4070298A (en) * 1976-07-26 1978-01-24 Olin Corporation Defoaming detergent additive
DE2812443C2 (en) 1978-03-22 1982-12-02 Hoechst Ag, 6000 Frankfurt Polyglycol ether thermal formals and their use as fiber finishes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1225800B (en) * 1964-01-11 1966-09-29 Henkel & Cie Gmbh Low-foaming detergents and cleaning agents
DE2523588A1 (en) * 1975-05-28 1976-12-16 Hoechst Ag POLYGLYCOL ETHERMAL FORMALS AND THEIR USE AS CORROSIVE WETTING, DETERGENT AND CLEANING AGENTS

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054894A1 (en) * 1980-12-23 1982-06-30 Hoechst Aktiengesellschaft Surfactant-containing mixture for cleaning hard surfaces
EP0124815A2 (en) * 1983-05-02 1984-11-14 Henkel Kommanditgesellschaft auf Aktien Use of polyglycol ethers as foam-depressing additives in cleaning agents producing little foam
EP0124815A3 (en) * 1983-05-02 1987-04-08 Henkel Kommanditgesellschaft Auf Aktien Use of polyglycol ethers as foam-depressing additives in cleaning agents producing little foam
EP0564402A1 (en) * 1992-04-01 1993-10-06 Ciba-Geigy Ag Low foaming surfactant compounds
CH684933A5 (en) * 1992-04-01 1995-02-15 Ciba Geigy Ag Low foaming surfactants.
WO2015113860A1 (en) * 2014-01-30 2015-08-06 Basf Se Asymmetric formales and acetales as adjuvants for crop protection
CN105939602A (en) * 2014-01-30 2016-09-14 巴斯夫欧洲公司 Asymmetric formales and acetales as adjuvants for crop protection
AU2015213032B2 (en) * 2014-01-30 2018-11-01 Basf Se Asymmetric formales and acetales as adjuvants for crop protection
CN105939602B (en) * 2014-01-30 2020-01-14 巴斯夫欧洲公司 Asymmetric formals and acetals as adjuvants in crop protection
US11051510B2 (en) 2014-01-30 2021-07-06 Basf Se Asymmetric formales and acetales as adjuvants for crop protection

Also Published As

Publication number Publication date
MX7094E (en) 1987-06-08
NO811284L (en) 1981-11-13
DK166781A (en) 1981-11-13
EP0040713B1 (en) 1983-11-16
ATE5328T1 (en) 1983-12-15
AR223116A1 (en) 1981-07-15
FI66900C (en) 1984-12-10
NO151244C (en) 1985-03-06
DE3018149A1 (en) 1981-11-19
CA1157736A (en) 1983-11-29
FI66900B (en) 1984-08-31
FI811131L (en) 1981-11-13
TR21341A (en) 1984-04-16
NO151244B (en) 1984-11-26
DE3161415D1 (en) 1983-12-22
ES8300018A1 (en) 1982-10-01
JPS5715806A (en) 1982-01-27
US4364777A (en) 1982-12-21
BR8102900A (en) 1982-02-02
ES502104A0 (en) 1982-10-01
ZA813128B (en) 1982-05-26

Similar Documents

Publication Publication Date Title
EP0040713B1 (en) Use of mixed formals of alkylpolyglycol ethers as foam suppressing agents
EP0254208B1 (en) Low foaming and/or foam inhibiting mixtures of tensides and their use
EP0054895B1 (en) Mixture of surfactants for the cleaning of hard surfaces
DE1617239B2 (en) Low-foaming detergent for automatic dishwashers
EP0161537A2 (en) End-capped fatty alcohol alcoxylates for industrial cleaning processes especially for bottle wasting and for the cleaning of metal
DE2029598A1 (en)
DE1467655A1 (en) Substituted methylenediphosphonic acid compounds and their use as detergents
EP0124851A2 (en) Composition and process for metal cleaning and passivation by spraying
EP0946697B1 (en) Mixtures of alkoxylates with antifoaming and disinfectant effect and use thereof in cleaning compositions
EP0054894A1 (en) Surfactant-containing mixture for cleaning hard surfaces
EP0024340A1 (en) Washing process
DE3018173C2 (en)
CH526629A (en) Foam-inhibited detergent contg fatty acid alkali soaps - and alkali silicone
DE1621592B2 (en) Use of alkaline cleaning agents as storage-stable, low-foaming metal cleaning agents
DE1273736B (en) Alkaline detergents
DE1135122B (en) Low-foaming detergents
DE1259345B (en) Process for the preparation of water-soluble polyglycerine ethers of alkylphenols
DE2657517A1 (en) DETERGENTS AND DETERGENTS
WO1989011524A1 (en) Anti-froth alkyl polyglycol ethers for detergents (ii)
DE2540873A1 (en) Foam inhibitors for detergents - which are compatible with cationic surfactants and comprise higher acetals
DE2113211C3 (en) Mixture of surfactants
EP0078918B1 (en) High alkaline pickling or cleaning agents as well as there use
AT295704B (en) Composition for a foam-bonded, biodegradable, liquid detergent product
AT259733B (en) Alkaline detergent
EP1092804B1 (en) Composition for the pretreatment of textiles

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL

17P Request for examination filed

Effective date: 19811028

ITF It: translation for a ep patent filed
GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

RBV Designated contracting states (corrected)

Designated state(s): AT BE CH DE FR GB IT LI NL

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL

REF Corresponds to:

Ref document number: 5328

Country of ref document: AT

Date of ref document: 19831215

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3161415

Country of ref document: DE

Date of ref document: 19831222

ET Fr: translation filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19840321

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19840413

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19840419

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19840630

Year of fee payment: 4

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19860425

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19870531

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19890502

Ref country code: AT

Effective date: 19890502

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19890531

Ref country code: CH

Effective date: 19890531

Ref country code: BE

Effective date: 19890531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19891201

GBPC Gb: european patent ceased through non-payment of renewal fee
NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19900131

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19900201

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST