EP0011980A1 - Couches photoconductrices contenant un mélange constitué par au moins deux photoconducteurs organiques différents et éléments électrophotographiques contenant ces couches - Google Patents
Couches photoconductrices contenant un mélange constitué par au moins deux photoconducteurs organiques différents et éléments électrophotographiques contenant ces couches Download PDFInfo
- Publication number
- EP0011980A1 EP0011980A1 EP79302648A EP79302648A EP0011980A1 EP 0011980 A1 EP0011980 A1 EP 0011980A1 EP 79302648 A EP79302648 A EP 79302648A EP 79302648 A EP79302648 A EP 79302648A EP 0011980 A1 EP0011980 A1 EP 0011980A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substituted
- alkyl
- alkoxy
- photoconductive
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06144—Amines arylamine diamine
Definitions
- This invention provides novel photoconductive layers containing mixtures of certain organic photoconductors and novel photoconductive elements containing such layers.
- photoconductive elements in electrophotographic processes is well known.
- Such elements generally comprise a conductive support bearing a photoconductive layer.
- the photoconductive layer generally comprises a photoconductive material dispersed in an electrically insulating binder.
- useful organic photoconductive materials are tri-substituted methanes such as disclosed in U.S. Patent 3,820,989 by Rule and triarylmethane leuco bases such as disclosed in U.S. Patent 3,542,547 by Wilson.
- Photoconductive layers comprising the organic photoconductive materials disclosed in the aforementioned 7patents are capable of producing high resolution images at suitable exposures.
- elements which contain a photoconductive layer having only one photoconductor often will not perform well.
- Such poor electrophotographic performance is apparently due to the tendency of the organic photoconductor to migrate to the surface of the layer and crystallize out in a snake-like pattern.
- Such crystallization has been called the "snake” defect or "snake” problem. It impairs the capability of the photoconductive layer for producing high resolution images.
- an electrophotographic layer comprising an electrically insulating binder and organic photoconductive material which contains a crystallization inhibiting mixture of at least two organic photoconductors of the formula: wherein
- the photoconductive elements of this invention contain one or more of such photoconductive layers on a conductive support.
- Formula I representing the class of organic photoconductors useful in the present invention, includes certain of the organic photoconductive materials disclosed in aforementioned U.S. Patent 3,542,547 and U.S. Patent 3,820,989.
- Photoconductive elements comprising photoconductive layers of the type just described, are much more resistant to the formation of "snakes” resulting from crystallization of the organic photoconductors than elements comprising photoconductive layers which contain a single photoconductor represented by Formula I.
- Organic photoconductors which are representative of those having the structure of Formula I, and from which a mixture of at least two photoconductors may be selected in accordance with this invention, are set. out in Table I.
- triphenylamine type photoconductors including substituted triphenylamines, are useful in increasing the speed of the photoconductive compositions of the present invention.
- Expecially useful organic photoconductors in this regard are triphenylamine, 4-diphenylaminochalcone, bis(4-di- phenylaminobenzal)acetone, 4-hydroxymethyltriphenylamine, tri-2-tolylamine, 4-carboxytriphenylamine, 4-(2-hydroxyethyl)triphenylamine, 4,4',4"-trimethoxytriphenylamine and tri-p-tolylamine.
- Other useful triphenylamine photoconductors are disclosed in, for example, U.S. Patent 3,180,730.
- the photoconductive compositions of the present invention are homogeneous or heterogeneous.
- Homogeneous photoconductive compositions are prepared in a conventional manner, for example by simply admixing the selected formula I photoconductors and the electrically insulating binder in a coating solvent. Electrophotographic-elements are formed from the homogeneous photoconductive compositions by simply coating the compositions on a support having a conductive layer, such as described hereinafter.
- the heterogeneous compositions include aggregate photoconductive compositions of the type disclosed in U.S. Patent 3,615,415 by Light.
- Aggregate photoconductive compositions may be prepared by several techniques, such as by fuming as disclosed by Light; or the so-called “dye first" technique described in Gramza et al, U.S. Patent 3,615,396; or the so-called “shearing” method described in Gramza, U.S. Patent'3,615,415; or the two-stage dilution technique described in Kryman et al U.S. Patent 3,679,408.
- Still another method of preparation involves preforming the finely-divided aggregate particles such as is described in Gramza et al, U.S. Patent 3,732,180 and simply storing these preformed aggregate particles until it is desired to prepare the charge-transport layer. At this time, the preformed aggregate particles may be dispersed in an appropriate coating vehicle together with the desired electrically insulating polymeric binder and coated as a layer on a suitable substrate to form a heterogeneous photoconductive element.
- the crystallization inhibiting mixture of at least two organic photoconductors is selected from compounds of the types bis(4-N,N-dialkylamino-2-alkylaryl)-4-alkylarylmethane; 1,1-bis(4-N,N-dialkylamino-2-alkylaryl)-2-alkylpropane and 4,4'-bis(dialkylamino)-2,2'-dialkyltriarylmethane.
- a photoconductive layer of the invention can be prepared as a self-supporting layer.
- the total amount of the organic photoconductors included in the layer may vary widely but preferably ranges from 5 to 40 weight percent based on the total dry weight of the layer.
- Each of the organic photoconductors selected may be included in the layer at a concentration up to its solubility limit-in the resulting layer.
- the solubility of each organic photoconductor in a particular film-forming binder can be found by determining by differential thermal- analysis at what concentration the organic photoconductor forms a separate phase. It is preferred to use equal weights of the organic photoconductors present.
- the photoconductive layers of the invention can also be spectrally and/or chemically sensitized by the addition of effective amounts of sensitizing compounds.
- Sensitizing compounds useful with the photoconductive compounds of the present invention can be selected from a wide variety of materials, including such materials as pyrylium dye salts including thiapyrylium dye salts and selenapyrylium dye salts disclosed in U.S. Patent 3,250,615; fluorenes; aggretate-type sensitizers of the type described in . U.S. Patent 3,615,414; aromatic nitro compounds of the kind described in U.S. Patent 2,610,120; anthrones like those disclosed in U.S. Patent 2,670,284; quinones like those in U.S.
- Patent 2,670,286 benzophenones like those in U.S. Patent 2,670,287; thiazoles like those in U.S. Patent 2,732,301; mineral acids; carboxylic acids such as maleic acid, di- and trichloroacetic acids, and salicylic acid; sulphonic and phosphoric acids; and various dyes, such as cyanine (including carbocyanine), merocyanine, di- arylmethane, thiazihe, azine, oxazine, xanthene, phthalein, acridine, azo and anthraquinone dyes and mixtures thereof.
- cyanine including carbocyanine
- merocyanine di- arylmethane
- thiazihe azine, oxazine, xanthene
- the sensitizers preferred for use with the compounds of this invention are selected from pyrylium salts, including selenapyrylium salts and thiapyrylium salts, and cyanine dyes including carbocyanine dyes such as disclosed in U.S. Patent 3,5-7.196.
- a suitable amount of the sensitizing compound may be mixed with the coating composition so that, after thorough mixing and coating, the sensitizing compound is uniformly distributed in the coated element.
- Other methods of incorporating the sensitizer may, however, be employed.
- the amount of sensitizer that can be added to the organic photoconductor layer to give-effective increases in speed can vary widely.
- the optimum concentration in any given case will vary with the specific photoconductor(s) and sensitizing compound used.
- substantial speed gains can be obtained where an appropriate sensitizer is added in a concentration range from about 0.0001 to about 30 percent by weight based on the total dry weight of the photoconductive layer.
- a sensitizer is added in an amount by weight of from 0.005 to 5.0 percent by weight.
- Preferred electrically insulating binders for use in preparing the present organic photoconductive layers are film-forming, hydrophobic polymeric binders having fairly high dielectric strength.
- Materials of this type comprise styrenebutadiene copolymers; silicone resins; styrene-alkyd resins; silicone-alkyd resins; soya-alkyd resins; poly(vinyl.chloride); poly(vinylidene chloride); vinylidene chlorideacrylonitrile copolymers; poly(vinyl acetate); vinyl acetate vinyl chloride copolymers; poly-(vinyl acetals), such as poly(vinyl butyral); polyacrylic and polymethacrylic esters, such as poly-(methyl methacrylate), poly(n-butyl methacrylate) and poly(isobutyl methacrylate); polystyrene; nitrated polystyrene; polymethylstyrene; isobuty
- styrene-alkyd resins can be prepared according to the method described in U.S. Patent 2,361,019 and 2,258,423.
- Suitable resins of the type contemplated for use in the photoconductive layers of the invention are sold under such tradenames as 'Vitel' PE-101, 'Cymac', 'Pic- copale' 100, 'Saran' F-220 and 'Lexan'.
- Other types of insulating binders which can be used in the photoconductive layers of the invention include such materials as mineral waxes
- solvents are useful for preparing solutions or dispersions from which the photoconductive layers of the present invention can be made.
- solvents for example, benzene; toluene; acetone; 2-butanone; chlorinated hydrocarbons such as methylene chloride; ethylene chloride; ethers, such as tetrahydrofuran, or mixtures of such solvents, can advantageously be employed in the practice of this invention.
- Coating thicknesses of such dispersions or solutions on supports can vary widely. Normally, a wet coating thickness in the range of 0.025 mm to 2.5 mm is useful in the practice of the invention. A preferred range of wet coating thickness is from 0.050 mm to 0.15 mm.
- Suitable supporting materials for the photoconductive layers of the present invention can include any electrically conducting supports.
- Examples include conducting papers, aluminium-paper laminates, metal foils such as aluminium and zinc foils; metal plates, such as aluminium, copper, zinc, brass and galvanized plates; vapour-deposited metal layers (silver, nickel,-aluminium) on conventional film supports such as cellulose acetate, poly(ethylene terephthalate) and polystyrene.
- An especially useful conductive support can be prepared by coating a transparent film-support such'as poly(ethylene terephthalate) with a layer containing a semiconductor dispersed in a resin.
- a suitable conductive layer can be prepared from the sodium salt of a carboxyester lactone of a maleic anhydride-vinyl acetate copolymer or cuprous iodide.
- the photoconductive layers of the present invention can be employed in photoconductive elements useful in an electrophotographic process.
- an electrophotographic-element held in the dark is given a blanket positive or negative electrostatic charge as desired, by placing it under a corona discharge to give a uniform charge to the surface of the photoconductive layer. This charge is retained by the layer owing to the substantial dark-insulating property of the layer.
- the electrostatic charge on the surface of the photoconductive layer is then selectively dissipated from the surface of the layer by imagewise exposure to light by means of a conventional exposure technique to leave a latent electrostatic image on the photoconductive layer.
- Suitable exposure techniques include contact-printing, lens-projection of an image, and reflex and bireflex techniques.
- the latent electrostatic image is then developed, possibly after transfer to another surface, by treatment with a developer comprising electrostatically responsive particles having optical density.
- the developer is in the form of a liquid dispersion, dust, or powder and generally comprises a pigmented thermoplastic resin called a toner.
- the developed image can be fixed by heating which causes the toner resin to melt or fuse into or on the image receiver element.
- a transfer of the toner image formed on the photoconductive layer can be made to a second support such as paper which then becomes the final print after fusing. Techniques of this type are well known in the art.
- the organic photoconductive layers of the present invention can be used in electrophotographic elements having many structural variations.
- the layers can be formed as single layers or as multiple layers on a suitable opaque or transparent conducting support.
- the layers can be contiguous or spaced having layers of insulating material or other photoconductive or sensitizing material therebetween. Configurations differing from those disclosed herein are also useful.
- a standard thermal crystallization or "snake” test consisted of heating the electrophotographic element for one minute at 90°C followed by. storage at room temperature with periodical examination under 200X magnification. The time, in days, weeks or months when the defect is first observed, is recorded. This test accelerates-the crystallization of the organic photoconductor present in the element. Under normal conditions the element would only be subjected to this high a temperature during a 5-10 second fixation step.
- the electrophotographic element comprised a conductive support bearing a photoconductive layer containing an electrically insulating polyester binder poly-[ethylene-co-isopropylidene-2,2-bis(ethylene oxyphenylene)-terephthalate], one or more organic photoconductors, 4-[N-butylamino]-2(p-methoxyphenyl) benzo-[b] pyrylium fluoroborate spectral sensitizer and a polysiloxane surfactant of the type described by Cawley in U.S. Patent 3,861,915.
- the organic photoconductor (OP) content of each element and the results of the thermal test are tabulated in Table II.
- Aggregate photoconductive elements were formed substantally as described in Example 1 of U.S. Patent 3,615,414.
- the elements comprised a conducting support and an aggregate photoconductive layer containing a binder combination of bis phenol A polycarbonate (92% by weight based on binder), a polyethylene- co-neopentyl terephthalate polyester resin (8% by weight based on total binder content of the layer) one or more organic photoconductors and aggregate forming pyrylium sensitizers.
- the organic photoconductor content of these aggregate photoconductive layers and the results of the thermal test are tabulated in Table III.
- the electrophotographic element comprised a conductive support bearing a photoconductive layer containing an electrically insulating polyester binder consisting of about 94% by weight of poly[ethylene- co-isopropylidene-2,2'-bis(ethylene oxyphenylene)-terephthalate] and about 6% by weight of poly[ethylene- co-isopropylidene-2,2'-bis(ethylene oxymethylene)-terephthalate] 6% by weight based on binder), one or more formula I organic photoconductors, tri-p-tolylamine, a pyrylium spectral sensitizer and a polysiloxane surfactant of the type described by Cawley in U.S. Patent 3,861,915.
- the organic photoconductor (OP) content of each element and the results of the thermal test are tabulated in Table IV.
- the sensitizer used in Examples 7 and 9. was 4-[N-butylamino]-2(p-methoxyphenyl) benzo[b]-pyrylium perchlorate.
- the sensitizer of Example 8 was 2,4-bis(4-ethyl phenyl)-6-(2,6-diphenyl-4H-pyran-4-ylidine) methyl pyrylium fluoroborate.
- the electrophotographic element comprised a conductive support bearing a photoconductive layer containing an electrically insulating polyester binder poly-[ethylene-co-isopropylidene-2,2-bis(ethylene oxyphenylene)-terephthalate] (94% by weight based on binder) and poly-[ethylene-co-isopropylidene-2,2- bis(ethylene oxymethylene)-terephthalate] (6% by weight based on binder), three or more organic photoconductors, 2,4-bis(4-ethyl-phenyl)-6-(2,6-diphenyl-4H-pyran-4-ylidene)methyl-pyrylium fluoroborate (Example 11) or 4-[N-butylamino]-2-( E -methoxyphenyl)benzo[b]pyrylium perchlorate (Example 12) spectral sensitizer and a polysiloxane surfactant of the type described by Cawley in U.S. Patent 3,861,
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US96243378A | 1978-11-20 | 1978-11-20 | |
US962433 | 1992-10-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0011980A1 true EP0011980A1 (fr) | 1980-06-11 |
EP0011980B1 EP0011980B1 (fr) | 1984-03-28 |
Family
ID=25505860
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP79302648A Expired EP0011980B1 (fr) | 1978-11-20 | 1979-11-20 | Couches photoconductrices contenant un mélange constitué par au moins deux photoconducteurs organiques différents et éléments électrophotographiques contenant ces couches |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0011980B1 (fr) |
JP (1) | JPS5577745A (fr) |
CA (1) | CA1129702A (fr) |
DE (1) | DE2966859D1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1983001618A1 (fr) * | 1981-11-10 | 1983-05-11 | James River Graphics Inc | Photoconducteurs organiques ayant des proprietes ameliorees d'efflorescence et de resistance a la fatigue a la preexposition |
EP0738934A2 (fr) * | 1995-04-18 | 1996-10-23 | Mita Industrial Co., Ltd. | Matériau électrophotosensible |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1383461A (fr) * | 1963-02-26 | 1964-12-24 | Kodak Pathe | Nouvelle couche photoconductrice et nouvelle planche pour la xérographie |
FR84976E (fr) * | 1960-02-19 | 1965-05-21 | Gevaert Photo Prod Nv | Matériel électrophotographique |
US3291600A (en) * | 1963-01-14 | 1966-12-13 | Rca Corp | Electrophotographic recording element and method of making |
CH435979A (de) * | 1961-02-16 | 1967-05-15 | Rca Corp | Lichtelektrisch leitende Schicht und Verwendung derselben |
FR2099782A5 (fr) * | 1970-06-25 | 1972-03-17 | Eastman Kodak Co | |
US3679406A (en) * | 1970-11-13 | 1972-07-25 | Eastman Kodak Co | Heterogeneous photoconductor composition formed by low-temperature conditioning |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE756375A (fr) * | 1969-09-30 | 1971-03-01 | Eastman Kodak Co | Nouvelle composition photoconductrice et produit la contenant utilisables en electrophotographie |
-
1979
- 1979-10-22 CA CA338,119A patent/CA1129702A/fr not_active Expired
- 1979-11-20 DE DE7979302648T patent/DE2966859D1/de not_active Expired
- 1979-11-20 JP JP15056279A patent/JPS5577745A/ja active Granted
- 1979-11-20 EP EP79302648A patent/EP0011980B1/fr not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR84976E (fr) * | 1960-02-19 | 1965-05-21 | Gevaert Photo Prod Nv | Matériel électrophotographique |
CH435979A (de) * | 1961-02-16 | 1967-05-15 | Rca Corp | Lichtelektrisch leitende Schicht und Verwendung derselben |
US3291600A (en) * | 1963-01-14 | 1966-12-13 | Rca Corp | Electrophotographic recording element and method of making |
FR1383461A (fr) * | 1963-02-26 | 1964-12-24 | Kodak Pathe | Nouvelle couche photoconductrice et nouvelle planche pour la xérographie |
FR2099782A5 (fr) * | 1970-06-25 | 1972-03-17 | Eastman Kodak Co | |
US3679406A (en) * | 1970-11-13 | 1972-07-25 | Eastman Kodak Co | Heterogeneous photoconductor composition formed by low-temperature conditioning |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1983001618A1 (fr) * | 1981-11-10 | 1983-05-11 | James River Graphics Inc | Photoconducteurs organiques ayant des proprietes ameliorees d'efflorescence et de resistance a la fatigue a la preexposition |
EP0738934A2 (fr) * | 1995-04-18 | 1996-10-23 | Mita Industrial Co., Ltd. | Matériau électrophotosensible |
EP0738934A3 (fr) * | 1995-04-18 | 1997-11-19 | Mita Industrial Co., Ltd. | Matériau électrophotosensible |
US5780194A (en) * | 1995-04-18 | 1998-07-14 | Mita Industrial Co., Ltd. | Electrophotosensitive material |
US6187493B1 (en) | 1995-04-18 | 2001-02-13 | Kyocera Mita Corporation | Electrophotosensitive material |
Also Published As
Publication number | Publication date |
---|---|
DE2966859D1 (en) | 1984-05-03 |
EP0011980B1 (fr) | 1984-03-28 |
CA1129702A (fr) | 1982-08-17 |
JPS5577745A (en) | 1980-06-11 |
JPS639213B2 (fr) | 1988-02-26 |
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