EP0004724A2 - Procédé et appareil de coalescence et produits purifiés ainsi obtenus - Google Patents

Procédé et appareil de coalescence et produits purifiés ainsi obtenus Download PDF

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Publication number
EP0004724A2
EP0004724A2 EP79300443A EP79300443A EP0004724A2 EP 0004724 A2 EP0004724 A2 EP 0004724A2 EP 79300443 A EP79300443 A EP 79300443A EP 79300443 A EP79300443 A EP 79300443A EP 0004724 A2 EP0004724 A2 EP 0004724A2
Authority
EP
European Patent Office
Prior art keywords
cartridge
fibres
oil
coalescer
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP79300443A
Other languages
German (de)
English (en)
Other versions
EP0004724B1 (fr
EP0004724A3 (en
Inventor
David Eric Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Publication of EP0004724A2 publication Critical patent/EP0004724A2/fr
Publication of EP0004724A3 publication Critical patent/EP0004724A3/xx
Application granted granted Critical
Publication of EP0004724B1 publication Critical patent/EP0004724B1/fr
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B01D17/04—Breaking emulsions
    • B01D17/045—Breaking emulsions with coalescers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
    • B01D35/10—Brush filters ; Rotary brush filters

Definitions

  • This invention relates to apparatus and a method for removing contaminants from a liquid.
  • the contaminants may be solid particles and/or a second liquid immiscible with but finely dispersed in the first liquid.
  • coalescing cartridges having rigid elements have, in general, proved to be the most popular. These, however, suffer from certain disadvantages.
  • the element frequently a glass fibre element, acts both as a coalescing medium and as a filter.
  • the filtration effect means that the cartridge eventually becomes blocked by the suspended solids removed from the stream under treatment. When this happens, the cartridge must be discarded. This is undesirable, partly because of the cost of cartridges, but even more so on offshore platforms because of the supply, storage and disposal problems entailed.
  • a coalescer cartridge for removing contaminants from a liquid which cartridge comprises a fixed first end support plate, a moveable second end support plate moveable relative to the first plate and fixed to an actuating rod, and a plurality of fibres or bundles of fibres, each fibre or bundle being secured at one end to the first end support plate and at its other end to the second end support plate.
  • the end plates are positioned close to one another by movement of the rod so that the fibres are compressed together to form a fine network.
  • Suitable fibre materials include natural and synthetic products such as wool, cotton, viscose, polyamides, polyesters, polyolefins and minerals.
  • fibre diameters are in the range 1 - 1,000 micron and the fibres are preferably made into bundles up to 30 mm in diameter.
  • the cartridge preferably has a length in the range 1 mm to 1 m in the compressed state and a length in the range 10 mm to 10 m in the stretched state.
  • the cartridge preferably has a length to diameter ratio in the range 1,000:1 to 1:1 in the compressed state.
  • length in the above context is meant the distance between the end plates.
  • the cartridge is conveniently utilised in equipment comprising a container having an inlet and an outlet, the cartridge being interposed between them.
  • a settling zone is provided downstream of the coalescer cartridge to allow the coalesced droplets of the previously dispersed phase to settle.
  • a method for coalescing one immiscible liquid finely dispersed in another which method comprises passing a feedstock mixture of the liquids through coalescing equipment as hereinbefore described wherein the coalescer cartridge is in the compressed state, and recovering separated liquids.
  • the method of the invention is particularly suitable for removing crude petroleum and petroleum products from tanker washings and refinery effluent. Normally these contain from 5 to 750 mg of crude petroleum or petroleum products per kg of water. In general, the amount of suspended solids is very variable, however, typical effluents contain 10 to 500 ppm of suspended solids.
  • the degree of filtration can be regulated.
  • the flow rate of the contaminated water should be related to the fibre diameter in the beds, the cross sectional area of the beds and the extent of compression of the fibres, so that some turbulence is created in the liquid as it flows through the cartridge but not sufficient turbulence to prevent the deposition of a film of oil on the fibres nor to strip a deposited film off. This favours the movement of oil droplets across the stream lines in the winding passages in the network of the cartridge so that they will collide with the oil film on the fibres and with each other.
  • Optimum flow rates can be chosen for given cartridge dimensions and fibre diameteres in the cartridge.
  • the hydraulic loading of liquid flowing through the equipment is in the range 15 - 1 50 m 3 /m 2 / h.
  • the cartridge In use, as stated previously, the cartridge is operated with the fibres compressed. After an extended period of operation the cartridge may become blocked with solids and/or liquid causing an unacceptably high pressure drop and reducing the efficiency of coalescence. The cartridge is then easily regenerated by causing relative motion between the end plates to stretch the fibres, and open up the network to a series of relatively wide channels. The contaminants are then removed by flushing with wash liquid to wash them off.
  • the drawing is a diagrammatic representation of a coalescer according to the present invention with the fibres of the cartridge in the stretched condition.
  • a chamber 1 is fitted with an inlet 2 and an outlet 3.
  • a cartridge coalescer comprises a threaded rod 4 to which is fixed a perforated end plate 5. At its other end the rod 4 passes freely through a second perforated end plate 6 fixed in position relative to the chamber 1. Fibres 7 are shown stretched between the end plates 5 and 6. A nut 8 is threaded on to the rod 4 and bears against the end plate 6.
  • the nut 8 is tightened to withdraw the rod and move the end plate 5 closer to the end plate 6 to compress the fibres 7 to the desired extent.
  • Water contaminated with finely dispersed oil enters the chamber 1 through inlet 2 and passes through the perforations in end plate 5 into the network of fibres 7 where coalescence takes place. Larger droplets of oil and water pass out of the chamber through the performations in end plate 6 and flow to a settling zone (not shown) where the oil and water form separate layers.
  • the bed used was the same as in Example 1. Before the run the bed was expanded and ca 5 litres of water passed through in the normal flow direction to flush out oil and solids collected in the bed. It was then compressed to a depth of 35 mm. The performance of the coalescer deteriorates somewhat at high hydraulic loadings.
  • the bed used was that in Example 2, expanded, washed through and recompressed to 25 mm depth.
  • Example 3 The bed for this run was that from Example 3, expanded, flushed through and compressed to 25 mm depth. The initial pressure drop was 0.8 bar. This indicates that washing in the expanded state serves to remove solids from the bed.
  • the test procedure was the same as in Example 3 except that oil was also added at the rate of 370 mg/litre. The filtrate was again clear, and the oil content of the effluent was only 2 mg/litre.
  • This run indicates that the unit can be operated as a combined filter and coalescer, and will coalesce oil in the presence of solids.
  • Coalescer B (larger version of Coalescer A)
  • the device was tested on a refinery effluent product in a kerosine washing plant.
  • the effluent was acidic with a pH of 2.
  • the unit operated for 20 hours at a hydraulic loading of 45 m 3 /m 2 /h in which time the pressure drop rose from 0.4 to 0.9 bar, as shown in the following Table.
  • Influent oil concentration varied between 220 and 2,180 mg/litre with an average at 1,330 mg/litre.
  • the water stream from the coalescer unit ranged from 9 to 23 mg/litre with an average of 15 mg/litre.
  • Coalescer B was again tested using oil contaminated with water from a separation rig.
  • the coalescer consistently produced a treated oil stream containing less than 1% water, in most cases less than 0 .5%, as can be seen from the results tabulated below.
  • Small doses of sludge and sand were injected into the coalescer inlet and had little obvious effect. On stripping down the unit at the end of the run it was obvious that the sand had not penetrated into the bed, and could easily have been removed by backflushing.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Removal Of Floating Material (AREA)
  • Water Treatment By Sorption (AREA)
  • Filtration Of Liquid (AREA)
  • Liquid Carbonaceous Fuels (AREA)
EP79300443A 1978-04-05 1979-03-21 Procédé et appareil de coalescence et produits purifiés ainsi obtenus Expired EP0004724B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1323178 1978-04-05
GB1323178 1978-04-05

Publications (3)

Publication Number Publication Date
EP0004724A2 true EP0004724A2 (fr) 1979-10-17
EP0004724A3 EP0004724A3 (en) 1979-10-31
EP0004724B1 EP0004724B1 (fr) 1981-10-28

Family

ID=10019230

Family Applications (1)

Application Number Title Priority Date Filing Date
EP79300443A Expired EP0004724B1 (fr) 1978-04-05 1979-03-21 Procédé et appareil de coalescence et produits purifiés ainsi obtenus

Country Status (5)

Country Link
EP (1) EP0004724B1 (fr)
JP (1) JPS54134872A (fr)
CA (1) CA1112583A (fr)
DE (1) DE2961096D1 (fr)
NO (1) NO154878C (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057995A2 (fr) * 1981-01-21 1982-08-18 The British Petroleum Company p.l.c. Appareillage de séparation
US4631068A (en) * 1985-07-18 1986-12-23 Stauffer Chemical Company Removal of sulfur from aqueous suspension using filtration
EP0207797A2 (fr) * 1985-07-05 1987-01-07 The British Petroleum Company p.l.c. Filtre à lit de fibres expansibles et appareil de coalescence
EP0366362A1 (fr) * 1988-10-26 1990-05-02 Kaldair International Limited Appareil de filtration et de coalescence de liquides
EP0389346A1 (fr) * 1989-03-24 1990-09-26 Total Raffinage Distribution S.A. Dispositif de séparation de deux liquides non miscibles et application de ce dispositif au dessalage d'une charge hydrocarbonée
US5174907A (en) * 1985-07-05 1992-12-29 Kalsen Limited Method of filtering using an expandable bed fiber and coalescer
US5984108A (en) * 1997-09-30 1999-11-16 Choi; Choong-Hyun Fluid filtering system with variable filter layer
EP1264626A1 (fr) * 2001-06-07 2002-12-11 CHOI, Choong Hyun Microfiltre à pores variables ayant une structure simple et compacte capable de filtration à courant lateral et à courant transversal
WO2008092261A1 (fr) * 2007-02-02 2008-08-07 Prosep Inc. Ensemble cartouche cylindrique avec des panneaux de paroi interverrouillables

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59187721A (ja) * 1983-04-08 1984-10-24 株式会社ユ−・エス・シ−・インタ−ナショナル・カンパニ− 作物の水耕栽培方法
US10934519B2 (en) 2011-07-29 2021-03-02 Global Life Sciences Solutions Usa Llc Systems, methods and control laws for cell harvesting
JP6969531B2 (ja) 2018-10-10 2021-11-24 オムロン株式会社 電子機器

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1833315A (en) * 1923-12-21 1931-11-24 Harry H Burhans Filtering medium
US2649964A (en) * 1949-06-27 1953-08-25 Charles S Taylor Liquid dispersion separating device
FR1083869A (fr) * 1952-08-20 1955-01-13 Faudi Feinbau Filtre à liquides, utilisable en particulier pour éliminer l'eau des carburants
FR1405867A (fr) * 1964-04-04 1965-07-16 Installation de filtrage et de tamisage
DE1905536A1 (de) * 1969-02-05 1970-09-03 Gerhard Adler Vorrichtung zum Trennen von OEl-Wasser-Gemischen oder Wasser-OEl-Gemischen mit elastischem Trenngitter
GB1280066A (en) * 1970-05-29 1972-07-05 Mitsui Shipbuilding Eng Oil-water separators
US3810832A (en) * 1972-06-01 1974-05-14 Oil Mop International Inc Oil/water separation acceleration media
GB1384172A (en) * 1971-02-16 1975-02-19 Oil Mop International Inc Oil and water separating device
FR2255935A1 (en) * 1973-12-27 1975-07-25 Huardeau Jacques Clarifier with floating filtering material - for rapid combined settlement and filtration of polluted liqs.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5824235Y2 (ja) * 1975-10-02 1983-05-24 リコ−トケイ カブシキガイシヤ ヨウヒヨウジツキドケイノヒヨウジコウゾウ

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1833315A (en) * 1923-12-21 1931-11-24 Harry H Burhans Filtering medium
US2649964A (en) * 1949-06-27 1953-08-25 Charles S Taylor Liquid dispersion separating device
FR1083869A (fr) * 1952-08-20 1955-01-13 Faudi Feinbau Filtre à liquides, utilisable en particulier pour éliminer l'eau des carburants
FR1405867A (fr) * 1964-04-04 1965-07-16 Installation de filtrage et de tamisage
DE1905536A1 (de) * 1969-02-05 1970-09-03 Gerhard Adler Vorrichtung zum Trennen von OEl-Wasser-Gemischen oder Wasser-OEl-Gemischen mit elastischem Trenngitter
GB1280066A (en) * 1970-05-29 1972-07-05 Mitsui Shipbuilding Eng Oil-water separators
GB1384172A (en) * 1971-02-16 1975-02-19 Oil Mop International Inc Oil and water separating device
US3810832A (en) * 1972-06-01 1974-05-14 Oil Mop International Inc Oil/water separation acceleration media
FR2255935A1 (en) * 1973-12-27 1975-07-25 Huardeau Jacques Clarifier with floating filtering material - for rapid combined settlement and filtration of polluted liqs.

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057995A2 (fr) * 1981-01-21 1982-08-18 The British Petroleum Company p.l.c. Appareillage de séparation
EP0057995A3 (en) * 1981-01-21 1983-02-02 The British Petroleum Company P.L.C. Separation equipment
EP0207797A2 (fr) * 1985-07-05 1987-01-07 The British Petroleum Company p.l.c. Filtre à lit de fibres expansibles et appareil de coalescence
EP0207797A3 (en) * 1985-07-05 1989-04-26 The British Petroleum Company P.L.C. Expandable bed fibre filter and coalescer
US5174907A (en) * 1985-07-05 1992-12-29 Kalsen Limited Method of filtering using an expandable bed fiber and coalescer
US4631068A (en) * 1985-07-18 1986-12-23 Stauffer Chemical Company Removal of sulfur from aqueous suspension using filtration
WO1990004443A1 (fr) * 1988-10-26 1990-05-03 Kaldair International Limited Appareil a filtre et liquides de coalescence
EP0366362A1 (fr) * 1988-10-26 1990-05-02 Kaldair International Limited Appareil de filtration et de coalescence de liquides
EP0389346A1 (fr) * 1989-03-24 1990-09-26 Total Raffinage Distribution S.A. Dispositif de séparation de deux liquides non miscibles et application de ce dispositif au dessalage d'une charge hydrocarbonée
FR2644708A1 (fr) * 1989-03-24 1990-09-28 Total France Dispositif de separation de deux liquides non miscibles et application de ce dispositif
US5017294A (en) * 1989-03-24 1991-05-21 Compagnie De Raffinage Et De Distribution Total France Apparatus for the separation of two immiscible liquids and use of said apparatus in the desalting of a hydrocarbon feedstock
US5984108A (en) * 1997-09-30 1999-11-16 Choi; Choong-Hyun Fluid filtering system with variable filter layer
EP1264626A1 (fr) * 2001-06-07 2002-12-11 CHOI, Choong Hyun Microfiltre à pores variables ayant une structure simple et compacte capable de filtration à courant lateral et à courant transversal
WO2008092261A1 (fr) * 2007-02-02 2008-08-07 Prosep Inc. Ensemble cartouche cylindrique avec des panneaux de paroi interverrouillables

Also Published As

Publication number Publication date
EP0004724B1 (fr) 1981-10-28
JPS6332484B2 (fr) 1988-06-30
CA1112583A (fr) 1981-11-17
NO154878C (no) 1987-01-07
EP0004724A3 (en) 1979-10-31
DE2961096D1 (en) 1982-01-07
NO154878B (no) 1986-09-29
NO791109L (no) 1979-10-08
JPS54134872A (en) 1979-10-19

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