EP0000812B1 - Procédé d'isomérisation de xylènes - Google Patents

Procédé d'isomérisation de xylènes Download PDF

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Publication number
EP0000812B1
EP0000812B1 EP78300170A EP78300170A EP0000812B1 EP 0000812 B1 EP0000812 B1 EP 0000812B1 EP 78300170 A EP78300170 A EP 78300170A EP 78300170 A EP78300170 A EP 78300170A EP 0000812 B1 EP0000812 B1 EP 0000812B1
Authority
EP
European Patent Office
Prior art keywords
zeolite
xylene
silica
zsm
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP78300170A
Other languages
German (de)
English (en)
Other versions
EP0000812A1 (fr
Inventor
Samuel Allen Tabak
Roger Allan Morrison
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of EP0000812A1 publication Critical patent/EP0000812A1/fr
Application granted granted Critical
Publication of EP0000812B1 publication Critical patent/EP0000812B1/fr
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (6)

1. Procédé pour l'isomérisation de xylènes mélangés à de l'éthylbenzène par mise en contact, dans des conditions de transformation en présence d'hydrogène, avec un catalyseur comprenant une zéolite ayant un indice de contrainte de 1 à 12, caractérisé en ce que la zéolite possède un rapport silice/alumine d'au moins 500 et en ce que la température de transformation est supérieure à 426°C.
2. Procédé selon la revendication 1, caractérisé en ce que ladite zéolite présente la structure de ZSM-5.
3. Procédé selon la revendication 2, caractérisé en ce que ladite zéolite ZSM-5 a été synthétisée à partir d'une solution de formation dans laquelle se trouve du platine et que ladite zéolite ZSM-5 contient 0,2 à 0,8% en poids de platine.
4. Procédé selon l'une quelconque des revendications 1 à 3, caractérisé en ce que ladite zéolite constitue 1 à 99, de préférence 5 à 80% en poids d'un composite avec un liant.
5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce qu'il est mis en oeuvre à une température de 426 à 538°C.
6. Procédé selon l'une quelconque des revendications 1 à 5, caractérisé en ce que ladite zéolite possède un rapport molaire silice/alumine de 500 à 3000.
EP78300170A 1977-07-22 1978-07-20 Procédé d'isomérisation de xylènes Expired EP0000812B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US81817177A 1977-07-22 1977-07-22
US818171 1997-03-14

Publications (2)

Publication Number Publication Date
EP0000812A1 EP0000812A1 (fr) 1979-02-21
EP0000812B1 true EP0000812B1 (fr) 1981-09-02

Family

ID=25224859

Family Applications (1)

Application Number Title Priority Date Filing Date
EP78300170A Expired EP0000812B1 (fr) 1977-07-22 1978-07-20 Procédé d'isomérisation de xylènes

Country Status (9)

Country Link
US (1) US4163028A (fr)
EP (1) EP0000812B1 (fr)
JP (1) JPS6024772B2 (fr)
CA (1) CA1096890A (fr)
DE (1) DE2861001D1 (fr)
ES (1) ES471957A1 (fr)
IN (1) IN149484B (fr)
IT (1) IT1099583B (fr)
ZA (1) ZA784167B (fr)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4218573A (en) * 1978-06-12 1980-08-19 Mobil Oil Corporation Xylene isomerization
US4371721A (en) * 1978-12-14 1983-02-01 Mobil Oil Corporation Selective cracking of disubstituted benzenes having polar substituents
JPS55129232A (en) * 1979-03-29 1980-10-06 Teijin Yuka Kk Isomerization of xylenes
US4224141A (en) * 1979-05-21 1980-09-23 Mobil Oil Corporation Manufacture of aromatic compounds
US4231955A (en) * 1979-07-13 1980-11-04 Mobil Oil Corporation Synthesis of alkyl and alkylaminonitriles
AU540104B2 (en) * 1980-01-10 1984-11-01 Mobil Oil Corp. Calytic reforming
US4312790A (en) * 1980-04-14 1982-01-26 Mobil Oil Corporation Aromatics processing catalysts
JPS5732735A (en) * 1980-08-04 1982-02-22 Teijin Yuka Kk Regenerating method for catalyst
ATE14869T1 (de) * 1980-12-12 1985-08-15 Exxon Research Engineering Co Xylol-isomerisierung.
ATE15613T1 (de) * 1980-12-12 1985-10-15 Exxon Research Engineering Co Zeolithzusammensetzung.
JPS62228031A (ja) * 1981-06-03 1987-10-06 Toray Ind Inc 芳香族炭化水素の変換方法
JPS5877828A (ja) * 1981-11-02 1983-05-11 Toray Ind Inc エチルベンゼンを含むキシレン類の変換方法
US4482773A (en) * 1982-02-25 1984-11-13 Mobil Oil Corporation Catalyst for xylene isomerization
US4469909A (en) * 1982-06-18 1984-09-04 Mobil Oil Corporation Heavy aromatics process
US4563435A (en) * 1982-06-23 1986-01-07 Mobil Oil Corporation Catalytic composition from reaction of high silica zeolites with binder
FR2529100B1 (fr) * 1982-06-23 1986-10-03 Inst Francais Du Petrole Nouveau catalyseur a base de mordenite fortement desaluminee
US4665265A (en) * 1984-06-13 1987-05-12 Mobil Oil Corporation Conversion of olefins and paraffins over novel catalyst composition
US4665269A (en) * 1984-06-13 1987-05-12 Mobil Oil Corporation Conversion of oxygenates over novel catalyst composition
US4665253A (en) * 1984-06-13 1987-05-12 Mobil Oil Corporation Conversion of aromatics over novel catalyst composition
US4681747A (en) * 1984-11-16 1987-07-21 The Standard Oil Company Process for the preparation of metallosilicates of tetravalent lanthanide and actinide series metals using heterpoly metallates
US4899011A (en) * 1986-01-15 1990-02-06 Mobil Oil Corporation Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics
US4723050A (en) * 1986-09-03 1988-02-02 Cosden Technology, Inc. Xylene isomerization process
US4700012A (en) * 1986-12-30 1987-10-13 Teijin Petrochemical Industries, Ltd. Process for isomerizing xylene
US4873387A (en) * 1987-10-13 1989-10-10 Uop Process for the isomerization of aromatics
US5043512A (en) * 1988-10-06 1991-08-27 Mobil Oil Corp. Alkylaromatic isomerization process
US5030787A (en) * 1990-01-24 1991-07-09 Mobil Oil Corp. Catalytic disproportionation/transalkylation utilizing a C9+ aromatics feed
US5082984A (en) * 1990-01-29 1992-01-21 Mobil Oil Corp. Dual function catalyst and isomerization therewith
US5028573A (en) * 1990-01-29 1991-07-02 Mobil Oil Corp. Dual function catalyst and isomerization therewith
US5001296A (en) * 1990-03-07 1991-03-19 Mobil Oil Corp. Catalytic hydrodealkylation of aromatics
US5043513A (en) * 1990-03-07 1991-08-27 Mobil Oil Corp. Catalytic hydrodealkylation of aromatics
US5705726A (en) * 1994-11-18 1998-01-06 Mobil Oil Corporation Xylene isomerization on separate reactors
US5689027A (en) * 1994-11-18 1997-11-18 Mobil Oil Corporation Selective ethylbenzene conversion
US5516956A (en) * 1994-11-18 1996-05-14 Mobil Oil Corporation Dual bed xylene isomerization
US6342649B1 (en) * 1995-05-10 2002-01-29 Denim Engineering, Inc Method for removing ethylbenzene from a para-xylene feed stream
US5958217A (en) * 1995-11-15 1999-09-28 Chevron Chemical Company Llc Two-stage reforming process that enhances para-xylene yield and minimizes ethylbenzene production
EP0880487B1 (fr) * 1996-01-25 2001-09-05 ExxonMobil Research and Engineering Company Procede de separation utilisant une membrane
US6051744A (en) * 1998-12-17 2000-04-18 Chevron Chemical Company Llc Low pressure hydrodealkylation of ethylbenzene and xylene isomerization
US6398947B2 (en) 1999-09-27 2002-06-04 Exxon Mobil Oil Corporation Reformate upgrading using zeolite catalyst
TWI240716B (en) 2000-07-10 2005-10-01 Bp Corp North America Inc Pressure swing adsorption process for separating paraxylene and ethylbenzene from mixed C8 aromatics
TWI263630B (en) * 2003-07-08 2006-10-11 Toray Industries Conversion catalyst for ethylbenzene containing xylenes and process for converting ethylbenzene containing xylenes by using catalyst
US7247762B2 (en) * 2003-09-12 2007-07-24 Exxonmobil Chemical Patents Inc. Process for xylene isomerization and ethylbenzene conversion
US7439204B2 (en) * 2004-03-15 2008-10-21 Exxonmobil Chemical Patents Inc. Process for producing catalysts with reduced hydrogenation activity and use thereof
US7271118B2 (en) * 2004-07-29 2007-09-18 Exxonmobil Chemical Patents Inc. Xylenes isomerization catalyst system and use thereof
DK2364761T3 (da) 2010-02-26 2014-02-03 Fischer Georg Jrg Ag Filterindretning, der kan tilbageskylles
CA2905937A1 (fr) * 2013-03-15 2014-09-25 Bp Corporation North America Inc. Tamis moleculaires de boroaluminosilicate et leurs procedes d'utilisation pour l'isomerisation de xylene
US10799852B2 (en) * 2015-10-28 2020-10-13 Bp Corporation North America Inc. Catalyst for ethylbenzene conversion in a xylene isomerization process
CN112023978B (zh) * 2019-06-04 2023-06-09 中国石油化工股份有限公司 一种二甲苯异构化催化剂及其制备方法与应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856873A (en) * 1973-09-13 1974-12-24 Mobil Oil Corp Xylene isomerization
US3856872A (en) * 1973-09-13 1974-12-24 Mobil Oil Corp Xylene isomerization
JPS5341658B2 (fr) * 1973-09-13 1978-11-06
US3856871A (en) * 1973-09-13 1974-12-24 Mobil Oil Corp Xylene isomerization

Also Published As

Publication number Publication date
ZA784167B (en) 1980-02-27
US4163028A (en) 1979-07-31
IT7826000A0 (it) 1978-07-21
CA1096890A (fr) 1981-03-03
JPS5424834A (en) 1979-02-24
IN149484B (fr) 1981-12-26
EP0000812A1 (fr) 1979-02-21
JPS6024772B2 (ja) 1985-06-14
ES471957A1 (es) 1979-02-01
IT1099583B (it) 1985-09-18
DE2861001D1 (en) 1981-11-26

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