EA201650034A1 - CATALYST AND METHOD FOR CONVERSION OF C-C ALIPHATIC HYDROCARBONS, C-ALCOHOLS, THEIR ETHERS OR THEIR MIXES FRIEND WITH A FRIEND INTO A HIGH-OCTANE COMPONENT OF AUTOMOBILE GASOLINE OR IN A DEVELOPMENT OF THE CAR-MOTOR BENZINE OR IN THE WORLD, IN A HIGH-ORGANIZE COMPONENT OF AUTOMOBILE GASOLINE OR IN A HIGH-ORANGE HIGH-OCTANE COMPONENT OF AUTOMOBILE GASOLINE OR IN THEIR HIGH-OCTANE COMPONENT - Google Patents
CATALYST AND METHOD FOR CONVERSION OF C-C ALIPHATIC HYDROCARBONS, C-ALCOHOLS, THEIR ETHERS OR THEIR MIXES FRIEND WITH A FRIEND INTO A HIGH-OCTANE COMPONENT OF AUTOMOBILE GASOLINE OR IN A DEVELOPMENT OF THE CAR-MOTOR BENZINE OR IN THE WORLD, IN A HIGH-ORGANIZE COMPONENT OF AUTOMOBILE GASOLINE OR IN A HIGH-ORANGE HIGH-OCTANE COMPONENT OF AUTOMOBILE GASOLINE OR IN THEIR HIGH-OCTANE COMPONENTInfo
- Publication number
- EA201650034A1 EA201650034A1 EA201650034A EA201650034A EA201650034A1 EA 201650034 A1 EA201650034 A1 EA 201650034A1 EA 201650034 A EA201650034 A EA 201650034A EA 201650034 A EA201650034 A EA 201650034A EA 201650034 A1 EA201650034 A1 EA 201650034A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- gasoline fractions
- component
- catalyst
- octane
- olefin
- Prior art date
Links
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Изобретение относится к области нефтепереработки, газопереработки и нефтехимии, а именно к составу цеолитсодержащего катализатора и способу превращения на нем алифатических углеводородов C-C, содержащихся в низкооктановых прямогонных нефтяных или газоконденсатных бензиновых фракциях, олефинсодержащих бензиновых фракциях вторичных процессов переработки нефти, широких фракциях легких углеводородов (ШФЛУ), попутных нефтяных или отходящих нефтезаводских парафин- или олефинсодержащих газах, спиртов C-C, их эфиров или их смесей друг с другом в высокооктановый компонент автомобильного бензина с октановым числом не менее 76 пунктов по моторному методу (м.м.) или в дизельную фракцию в стационарном или движущемся слое гранулированного или шарикового катализатора. Катализатор и способ с его использованием превращения алифатических углеводородов C-C,спиртов C-C, их эфиров или их смесей друг с другом в адиабатическом реакторе или изотермическом реакторе с тепловой трубой (трубами) или панелями при температуре 200-580°C, давлении 0,1-10,0 МПа, объемной скорости подачи сырья (по жидкости) 0,1-11,0 чв высокооктановый компонент автомобильного бензина или в дизельную фракцию, содержащий в своем составе цеолит группы пентасилов (ZSM-5 или ZSM-11) с мольным отношением SiO/AlO=20-80 и содержанием оксида натрия NaO не более 0,2 мас.%, содержащий оксид цинка и связующий компонент (гамма - AlO, и/или двуокись кремния, и/или синтетический алюмосиликат, и/или глина, и/или двуокись циркония и другие), отличающийся тем, что он дополнительно содержит оксид стронция, причем его содержание в составе катализатора составляет от 0,01 до 3,0 мас.%, содержание оксида цинка составляет от 0,1 до 6,0 мас.%, содержание цеолита составляет от 20,0 до 90,0 мас.%, содержание связующего - остальное до 100 мас.%. Катализатор также может содержать в своем составе оксид бора, и/или оксид железа(III), и/или оксид магния, и/или оксид кальция, и/или пентоксид фосфора, и/или фтор при общем содержании всех промотирующих элементов (оксидов) (B, Fe, Mg, Ca, P, F) не более 5,0 мас.%.The invention relates to the field of oil refining, gas processing and petrochemistry, in particular to the composition of a zeolite-containing catalyst and a method for converting on it aliphatic hydrocarbons CC contained in low-octane straight-run oil or gas condensate gasoline fractions, olefin-containing gasoline fractions of the secondary processing of petroleum, gasoline fractions, olefin-containing gasoline fractions, and petrochemical gasoline fractions, olefin-containing gasoline fractions, and petrochemical gasoline fractions, olefin-containing gasoline fractions, olefin-containing gasoline fractions, and petrochemical gasoline fractions; associated petroleum or waste refinery paraffin or olefin containing gases, alcohols CC, their esters or their mixtures with each other ohm into the high-octane component of motor gasoline with an octane rating of at least 76 points by the motor method (m. m) or into the diesel fraction in a stationary or moving bed of a granular or ball catalyst. Catalyst and method of using it to convert aliphatic hydrocarbons CC, alcohols CC, their esters or their mixtures with each other in an adiabatic reactor or an isothermal reactor with a heat pipe (s) or panels at a temperature of 200-580 ° C, pressure 0.1-10 , 0 MPa, the volumetric feed rate of the raw material (liquid) 0.1-11.0 chv high-octane component of motor gasoline or diesel fraction containing in its composition a zeolite of the pentasil group (ZSM-5 or ZSM-11) with a molar ratio of SiO / AlO = 20-80 and the content of sodium oxide NaO is not more than 0.2 wt.%, Soda Corrosive zinc oxide and a binder component (gamma - AlO, and / or silicon dioxide, and / or synthetic aluminosilicate, and / or clay, and / or zirconium dioxide, etc.), characterized in that it additionally contains strontium oxide, and its content in the composition of the catalyst is from 0.01 to 3.0 wt.%, the content of zinc oxide is from 0.1 to 6.0 wt.%, the content of zeolite is from 20.0 to 90.0 wt.%, the content of the binder is the rest is up to 100 wt.%. The catalyst may also contain boron oxide, and / or iron (III) oxide, and / or magnesium oxide, and / or calcium oxide, and / or phosphorus pentoxide, and / or fluorine with a total content of all promoting elements (oxides). (B, Fe, Mg, Ca, P, F) not more than 5.0 wt.%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EA201650034A EA033290B1 (en) | 2016-10-28 | 2016-10-28 | Catalyst and method to convert c-caliphatic hydrocarbons, c-calcohols, their esters or mixtures into high-octane gasoline component or diesel fraction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EA201650034A EA033290B1 (en) | 2016-10-28 | 2016-10-28 | Catalyst and method to convert c-caliphatic hydrocarbons, c-calcohols, their esters or mixtures into high-octane gasoline component or diesel fraction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201650034A1 true EA201650034A1 (en) | 2018-04-30 |
| EA033290B1 EA033290B1 (en) | 2019-09-30 |
Family
ID=62045895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201650034A EA033290B1 (en) | 2016-10-28 | 2016-10-28 | Catalyst and method to convert c-caliphatic hydrocarbons, c-calcohols, their esters or mixtures into high-octane gasoline component or diesel fraction |
Country Status (1)
| Country | Link |
|---|---|
| EA (1) | EA033290B1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2768115C1 (en) * | 2021-04-13 | 2022-03-23 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") | Catalyst and method for production thereof |
| RU2768118C1 (en) * | 2021-04-13 | 2022-03-23 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") | Method of producing catalyst |
| RU2766555C1 (en) * | 2021-05-21 | 2022-03-15 | Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" | Catalyst for selective oxidation of hydrogen sulfide and method of its use |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2100075C1 (en) * | 1996-02-16 | 1997-12-27 | Николай Николаевич Ростанин | Zeolite-containing catalyst and method of converting $$$-hydrocarbons into high-antiknock gasoline component or aromatic hydrocarbon concentrate |
| EA002139B1 (en) * | 2000-03-09 | 2001-12-24 | Генрих Семенович Фалькевич | Catalst and method for converting alyphatic hydrocarbons c2-c12 into high-octane gasoline or aromatic hydrocarbon concentrate |
| RU2183656C1 (en) * | 2000-12-25 | 2002-06-20 | Мельников Вячеслав Борисович | Method for production of motor fuels and catalyst for implementation thereof |
| RU2236289C1 (en) * | 2002-12-30 | 2004-09-20 | Общество с ограниченной ответственностью "Томскнефтехим" | Aliphatic c2-c12-hydrocarbon conversion catalyst, method of preparation thereof and a method for converting aliphatic c2-c12-hydrocarbons into high-octane gasoline and/or aromatic hydrocarbons |
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2016
- 2016-10-28 EA EA201650034A patent/EA033290B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EA033290B1 (en) | 2019-09-30 |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM BY KG TJ TM |