EA201401060A1 - Печь и способ парового риформинга - Google Patents

Печь и способ парового риформинга

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Publication number
EA201401060A1
EA201401060A1 EA201401060A EA201401060A EA201401060A1 EA 201401060 A1 EA201401060 A1 EA 201401060A1 EA 201401060 A EA201401060 A EA 201401060A EA 201401060 A EA201401060 A EA 201401060A EA 201401060 A1 EA201401060 A1 EA 201401060A1
Authority
EA
Eurasian Patent Office
Prior art keywords
pipe
flue gas
defining
gaseous product
combustion chamber
Prior art date
Application number
EA201401060A
Other languages
English (en)
Other versions
EA028765B1 (ru
Inventor
Паола Волпи
Барбара Марико
Лорена Моска
Кристина Гуаццотти
Фабио Проспери
Гаэтано Якуаньелло
Original Assignee
Стамикарбон Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Стамикарбон Б.В. filed Critical Стамикарбон Б.В.
Publication of EA201401060A1 publication Critical patent/EA201401060A1/ru
Publication of EA028765B1 publication Critical patent/EA028765B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00—Apparatus for generating gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00309—Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Печь (1) риформинга содержит камеру сгорания (100) и по меньшей мере один узел (200) тройной трубы, включающий в себя трубу (220) дымовых газов, охватывающую реакционную трубу (240), охватывающую трубу (260) газообразного продукта. Реакционная труба (240) проходит между нижним концом (244), определяющим впускное отверстие (245) реакционного газа, и замкнутым верхним концом (242). Труба (260) газообразного продукта проходит между верхним концом (262), определяющим впускное отверстие (263) газообразного продукта, и нижним концом (264), определяющим выпускное отверстие (265) газообразного продукта. Труба (220) дымовых газов проходит между верхним концом (222), определяющим впускное отверстие (223) дымовых газов, и нижним концом (224), определяющим выпускное отверстие (225) дымовых газов. Межтрубное пространство (250) между реакционной трубой (240) и трубой (260) газообразного продукта содержит катализатор (252). Камера сгорания (100) охватывает верхнюю половину (226, 246, 266) по меньшей мере одного узла (200) тройной трубы, тогда как его нижняя половина (228, 248, 268) расположена вне и ниже камеры сгорания, и снабжена по меньшей мере одной горелкой (110), расположенной внутри камеры сгорания и снаружи трубы (220) дымовых газов. Верхняя половина (226) трубы дымовых газов, по существу, экранирует реакционную трубу (240) от теплового излучения и выброса открытого пламени горелки. Изобретение также относится к способу парового риформинга.
EA201401060A 2012-03-26 2013-03-26 Печь и способ парового риформинга EA028765B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12161221.2 2012-03-26
EP12161221 2012-03-26
PCT/NL2013/050223 WO2013147598A1 (en) 2012-03-26 2013-03-26 Steam reformer furnace, and method for the same

Publications (2)

Publication Number Publication Date
EA201401060A1 true EA201401060A1 (ru) 2015-03-31
EA028765B1 EA028765B1 (ru) 2017-12-29

Family

ID=48050222

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201401060A EA028765B1 (ru) 2012-03-26 2013-03-26 Печь и способ парового риформинга

Country Status (5)

Country Link
US (1) US9145298B2 (ru)
EP (1) EP2830994B1 (ru)
EA (1) EA028765B1 (ru)
MX (1) MX351385B (ru)
WO (1) WO2013147598A1 (ru)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9145299B2 (en) 2013-12-13 2015-09-29 King Fahd University Of Petroleum And Minerals Steam methane reforming reactor of shell and tube type with cylindrical slots
US9843062B2 (en) 2016-03-23 2017-12-12 Energyield Llc Vortex tube reformer for hydrogen production, separation, and integrated use
US9840413B2 (en) 2015-05-18 2017-12-12 Energyield Llc Integrated reformer and syngas separator
EP3181218A1 (de) * 2015-12-15 2017-06-21 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Produktgassammelleitungssystem für einen dampfreformer
US10626014B2 (en) * 2017-07-25 2020-04-21 Praxiar Technology, Inc. Reactor packing with preferential flow catalyst
JP6944349B2 (ja) * 2017-11-09 2021-10-06 エア・ウォーター株式会社 水素発生装置
JP2019205975A (ja) * 2018-05-30 2019-12-05 大同特殊鋼株式会社 雰囲気ガス発生装置
US11806705B2 (en) 2018-06-28 2023-11-07 Haldor Topsøe A/S Catalytic reactor comprising metal radiation surfaces
ES2941038T3 (es) * 2019-11-13 2023-05-16 Air Liquide Horno reformador para llevar a cabo un proceso endotérmico

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4216575A (en) * 1979-02-01 1980-08-12 Noranda Mines Limited Method of reforming the fins of a finned tube
US5935531A (en) 1993-10-29 1999-08-10 Mannesmann Aktiengesellschaft Catalytic reactor for endothermic reactions
AU5386999A (en) 1999-08-13 2001-03-13 Technip Kti S.P.A. Catalyst tubes for endothermic reaction especially for the production of hydrogen and syngas
ATE302736T1 (de) 2000-09-20 2005-09-15 Air Prod & Chem Vorrichtung und verfahren zur reformierung von kohlenwasserstoff
DE10119083C1 (de) * 2001-04-19 2002-11-28 Joachim Alfred Wuenning Kompakt-Dampf-Reformer

Also Published As

Publication number Publication date
MX2014011565A (es) 2015-04-08
EP2830994B1 (en) 2018-08-29
US9145298B2 (en) 2015-09-29
MX351385B (es) 2017-10-11
EP2830994A1 (en) 2015-02-04
EA028765B1 (ru) 2017-12-29
WO2013147598A1 (en) 2013-10-03
US20150048277A1 (en) 2015-02-19

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