EA201300779A1 - METHOD FOR REMOVAL OF SERIOUSLY CONTAINING POLLUTIONS FROM GAS FLOW - Google Patents

METHOD FOR REMOVAL OF SERIOUSLY CONTAINING POLLUTIONS FROM GAS FLOW

Info

Publication number
EA201300779A1
EA201300779A1 EA201300779A EA201300779A EA201300779A1 EA 201300779 A1 EA201300779 A1 EA 201300779A1 EA 201300779 A EA201300779 A EA 201300779A EA 201300779 A EA201300779 A EA 201300779A EA 201300779 A1 EA201300779 A1 EA 201300779A1
Authority
EA
Eurasian Patent Office
Prior art keywords
gaseous stream
sulfur dioxide
sulfur
hydrogen sulfide
heat
Prior art date
Application number
EA201300779A
Other languages
Russian (ru)
Inventor
Диего Патрисио Валенсуэла
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA201300779A1 publication Critical patent/EA201300779A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • B01D53/8615Mixtures of hydrogen sulfide and sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • B01D53/8618Mixtures of hydrogen sulfide and carbon dioxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0426Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
    • C01B17/0434Catalyst compositions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Способ удаления серосодержащих загрязнений, в том числе сероводорода, из газообразного потока, который включает стадии, где газообразный поток подвергается окислительной обработке; тепло отводится из полученного газообразного потока; сероводород из указанного охлажденного газообразного потока каталитически взаимодействует с диоксидом серы при повышенной температуре, чтобы получить газообразный поток, который содержит серу и воду; выделяют серу из полученного таким образом газообразного потока, обедненного сероводородом, и подвергают указанный поток окислительной обработке; тепло отводится из полученного таким образом газообразного потока, обогащенного диоксидом серы; серосодержащий остаточный углеводородный продукт подвергают окислительной обработке, чтобы получить газообразный поток, который содержит диоксид серы; тепло отводится из указанного газообразного потока, который содержит диоксид серы; оба потока, содержащих диоксид серы, обрабатывают в процессе закаливания; из полученного газообразного потока поглощают диоксид серы, чтобы получить поглощающий растворитель, обогащенный диоксидом серы, который регенерируют; и полученный газообразный поток, обогащенный диоксидом серы, используют в качестве источника диоксида серы для процесса Клауса.A method for removing sulfur-containing contaminants, including hydrogen sulfide, from a gaseous stream, which includes stages where the gaseous stream is subjected to oxidative treatment; heat is removed from the resulting gaseous stream; hydrogen sulfide from said cooled gaseous stream is catalytically reacted with sulfur dioxide at elevated temperature to produce a gaseous stream that contains sulfur and water; separating sulfur from the thus obtained gaseous stream depleted in hydrogen sulfide, and subjecting the specified stream to oxidative treatment; heat is removed from the thus obtained gaseous stream enriched in sulfur dioxide; the sulfur-containing residual hydrocarbon product is subjected to an oxidative treatment to obtain a gaseous stream that contains sulfur dioxide; heat is removed from the specified gaseous stream, which contains sulfur dioxide; both streams containing sulfur dioxide are treated in the hardening process; sulfur dioxide is absorbed from the obtained gaseous stream to obtain an absorbing solvent enriched in sulfur dioxide, which is recovered; and the resulting sulfur dioxide-rich gaseous stream is used as a sulfur dioxide source for the Claus process.

EA201300779A 2010-12-31 2011-12-28 METHOD FOR REMOVAL OF SERIOUSLY CONTAINING POLLUTIONS FROM GAS FLOW EA201300779A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10197457 2010-12-31
PCT/EP2011/074179 WO2012089776A1 (en) 2010-12-31 2011-12-28 Process for removing sulphur-containing contaminants from a gas stream

Publications (1)

Publication Number Publication Date
EA201300779A1 true EA201300779A1 (en) 2014-03-31

Family

ID=43888629

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201300779A EA201300779A1 (en) 2010-12-31 2011-12-28 METHOD FOR REMOVAL OF SERIOUSLY CONTAINING POLLUTIONS FROM GAS FLOW

Country Status (4)

Country Link
EP (1) EP2658632A1 (en)
CA (1) CA2823228A1 (en)
EA (1) EA201300779A1 (en)
WO (1) WO2012089776A1 (en)

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AU2013371876A1 (en) 2012-12-10 2015-07-02 Total Sa Integrated process to recover high quality native CO2 from a sour gas comprising H2S and CO2
AU2015336109B2 (en) 2014-10-24 2020-11-19 Research Triangle Institute Integrated system and method for removing acid gas from a gas stream
CN108472574B (en) * 2015-12-29 2022-04-29 环球油品公司 Method and apparatus for recovering light hydrocarbons by sponge absorption
US10696906B2 (en) 2017-09-29 2020-06-30 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
PL3963260T3 (en) 2019-05-03 2023-10-09 Topsoe A/S Method for production of elemental sulfur and sulfuric acid
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
CA3109606C (en) 2020-02-19 2022-12-06 Marathon Petroleum Company Lp Low sulfur fuel oil blends for paraffinic resid stability and associated methods
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US20220268694A1 (en) 2021-02-25 2022-08-25 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11692141B2 (en) 2021-10-10 2023-07-04 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
CA3188122A1 (en) 2022-01-31 2023-07-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

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DE2531930A1 (en) * 1975-07-17 1977-01-20 Metallgesellschaft Ag PROCESS FOR THE RECOVERY OF ELEMENTARY SULFUR FROM GASES RICH IN CARBON DIOXIDE, SULFUR COMPOUNDS AND POLLUTIONS
FR2481145A1 (en) 1980-04-23 1981-10-30 Rhone Poulenc Ind PROCESS FOR PRODUCING CATALYSTS OR TITANIUM OXIDE-BASED CATALYST SURFACE SUPPORTS AND THEIR CATALYSIS CLAUS APPLICATIONS
FR2501532B1 (en) * 1981-03-13 1985-12-13 Rhone Poulenc Spec Chim CATALYST AND METHOD FOR THE TREATMENT OF INDUSTRIAL WASTE GASES CONTAINING SULFUR COMPOUNDS
CA2201004C (en) * 1997-03-25 2001-11-27 Cansolv Technologies, Inc. Safe storage and transportation of sulfur dioxide
GB0021409D0 (en) * 2000-08-31 2000-10-18 Boc Group Plc Treatment of a gas stream containing hydrogen sulphide

Also Published As

Publication number Publication date
WO2012089776A1 (en) 2012-07-05
EP2658632A1 (en) 2013-11-06
CA2823228A1 (en) 2012-07-05

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