EA201071079A1 - METHOD FOR PRODUCING LIQUID HYDROCARBONS FROM NATURAL GAS - Google Patents

METHOD FOR PRODUCING LIQUID HYDROCARBONS FROM NATURAL GAS

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Publication number
EA201071079A1
EA201071079A1 EA201071079A EA201071079A EA201071079A1 EA 201071079 A1 EA201071079 A1 EA 201071079A1 EA 201071079 A EA201071079 A EA 201071079A EA 201071079 A EA201071079 A EA 201071079A EA 201071079 A1 EA201071079 A1 EA 201071079A1
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EA
Eurasian Patent Office
Prior art keywords
synthesis gas
fischer
gas
synthesis
tropsch
Prior art date
Application number
EA201071079A
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Russian (ru)
Other versions
EA017725B1 (en
Inventor
Фуюки Яги
Кенити Кавазуиси
Original Assignee
Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн
Инпекс Корпорейшн
ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН
Джапан Петролеум Эксплорейшн Ко., Лтд.
Космо Ойл Ко., Лтд.
Ниппон Стил Инджиниринг Ко., Лтд.
Тийода Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн, Инпекс Корпорейшн, ДжейЭкс НИППОН ОЙЛ ЭНД ЭНЕРДЖИ КОРПОРЕЙШН, Джапан Петролеум Эксплорейшн Ко., Лтд., Космо Ойл Ко., Лтд., Ниппон Стил Инджиниринг Ко., Лтд., Тийода Корпорейшн filed Critical Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн
Publication of EA201071079A1 publication Critical patent/EA201071079A1/en
Publication of EA017725B1 publication Critical patent/EA017725B1/en

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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/0465—Composition of the impurity
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
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    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam

Abstract

Рассматривается ГВЖ-способ, в котором синтез-газ получают из природного газа, нефть Фишера-Тропша получают из синтез-газа, полученного синтезом Фишера-Тропша, и жидкие углеводороды, составляющие нефтяное топливо, получают дополнительной ее очисткой, в котором на стадии имеет место частичный отвод перед тем, как синтез-газ, полученный на стадии получения синтез-газа, вводится на стадию получения нефти Фишера-Тропша, концентрация водорода синтез-газа, который поступает в отводящую линию, увеличивается реакцией сдвига вода-газ, и затем выделяют водород высокой чистоты, а газ, оставшийся после разделения, рециклируют на вышеуказанную стадию получения синтез-газа для использования в качестве исходного материала для получения синтез-газа. Можно улучшить расходуемое количество исходного материала для способа в целом.The GHL method is considered, in which synthesis gas is obtained from natural gas, Fischer-Tropsch oil is obtained from synthesis gas obtained by the Fischer-Tropsch synthesis, and liquid hydrocarbons that make up the fuel oil are obtained by additional purification, in which at the stage takes place partial withdrawal before the synthesis gas produced in the synthesis gas production stage is introduced into the Fischer-Tropsch oil production stage, the hydrogen concentration of the synthesis gas that enters the branch line is increased by a water-gas shift reaction and then hydrogen is evolved high purity, and the gas remaining after separation is recycled to the above synthesis gas production step for use as a raw material for synthesis gas production. It is possible to improve the consumed amount of starting material for the method as a whole.

EA201071079A 2008-03-14 2009-03-11 Process for producing liquid hydrocarbons from natural gas EA017725B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008065465A JP5424566B2 (en) 2008-03-14 2008-03-14 Method for producing synthesis gas in liquid hydrocarbon production process from natural gas
PCT/JP2009/055217 WO2009113714A1 (en) 2008-03-14 2009-03-11 Process for producing liquid hydrocarbons from natural gas

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EA201071079A1 true EA201071079A1 (en) 2011-04-29
EA017725B1 EA017725B1 (en) 2013-02-28

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US (1) US8268898B2 (en)
EP (1) EP2253585B8 (en)
JP (1) JP5424566B2 (en)
CN (1) CN101970344B (en)
AU (1) AU2009224187B8 (en)
BR (1) BRPI0910334B1 (en)
CA (1) CA2718506C (en)
EA (1) EA017725B1 (en)
EG (1) EG26230A (en)
MY (1) MY150064A (en)
WO (1) WO2009113714A1 (en)
ZA (1) ZA201006261B (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA019982B1 (en) * 2010-03-02 2014-07-30 Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн Synthesis gas production method
JP5887063B2 (en) * 2011-03-30 2016-03-16 独立行政法人石油天然ガス・金属鉱物資源機構 Hydrocarbon synthesis reaction apparatus, start-up method thereof, and hydrocarbon synthesis reaction system
JP5804747B2 (en) * 2011-03-31 2015-11-04 独立行政法人石油天然ガス・金属鉱物資源機構 Method for suppressing metal contamination in syngas production equipment
GB201118465D0 (en) * 2011-10-26 2011-12-07 Compactgtl Plc Gas-to-liquid technology
CN102730637B (en) * 2012-07-17 2014-12-10 武汉凯迪工程技术研究总院有限公司 Comprehensive utilization process for low-carbon-emission Fischer-Tropsch synthesis tail gas
CN104232193A (en) * 2013-06-07 2014-12-24 中国海洋石油总公司 Method for producing methane and co-producing liquid fuel from carbonaceous material
WO2015012623A1 (en) * 2013-07-25 2015-01-29 대우조선해양 주식회사 Method and system for gtl production in fpso
CN105473495A (en) 2013-07-31 2016-04-06 沙特基础工业公司 A process for the production of olefins through fischer-tropsch based synthesis
CN105518111A (en) 2013-07-31 2016-04-20 沙特基础工业公司 A process for the production of olefins through fischer-tropsch based synthesis
WO2015082216A1 (en) 2013-12-02 2015-06-11 Haldor Topsøe A/S A process for conversion of natural gas to hydrocarbon products and a plant for carrying out the process
EP3209408A4 (en) 2014-10-24 2018-07-04 Research Triangle Institute, International Integrated system and method for removing acid gas from a gas stream
KR101694221B1 (en) 2014-12-24 2017-01-09 한국과학기술연구원 A method for praparing synthetic fuel from natural gas of standard gas field by GTL-FPSO system and an equipment for praparing it
US20200180955A1 (en) * 2017-06-27 2020-06-11 L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude Process for high-yield production of hydrogen from a synthesis gas, and debottlenecking of an existing unit
CN107721071A (en) * 2017-10-25 2018-02-23 山西潞安煤基精细化学品有限公司 F T synthetic water phase processor devices
US10738247B2 (en) * 2017-11-15 2020-08-11 Gas Technology Institute Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels
JP2022500545A (en) * 2018-09-11 2022-01-04 ペトロレオ ブラジレイロ ソシエダ アノニマ − ペトロブラス Method of producing liquid hydrocarbon by Fischer-Tropsch process incorporated in refinery
EP3878807A1 (en) * 2020-03-13 2021-09-15 Clariant International Ltd Process for the production of synthesis gas via allothermic gasification with controlled carbon dioxide reduction
JP7122042B1 (en) * 2021-12-22 2022-08-19 独立行政法人石油天然ガス・金属鉱物資源機構 Purge method and system

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2473032A1 (en) * 1980-01-07 1981-07-10 Banquy David PROCESS FOR THE PRODUCTION OF AMMONIA AND THE SYNTHESIS GAS CORRESPONDING
EP0243350A1 (en) 1985-10-21 1987-11-04 Union Carbide Corporation Enhanced hydrogen recovery from effluent gas streams
JPH03242302A (en) * 1990-02-20 1991-10-29 Mitsubishi Kakoki Kaisha Ltd Production of hydrogen and carbon monoxide
NZ242569A (en) * 1991-05-30 1994-07-26 British Petroleum Co Plc Process for the conversion of natural gas into higher hydrocarbons by reforming combined with a fischer-tropsch process
US6147126A (en) * 1998-02-10 2000-11-14 Exxon Research And Engineering Company Gas conversion using hydrogen from syngas gas and hydroconversion tail gas
US6489370B2 (en) * 2000-05-30 2002-12-03 Mitsubishi Heavy Industries, Ltd. Method of manufacturing a synthesis gas to be employed for the synthesis of gasoline, kerosene and gas oil
JP4681101B2 (en) * 2000-05-30 2011-05-11 三菱重工業株式会社 Method for producing synthesis gas for gasoline, light oil and kerosene
US6495610B1 (en) * 2000-06-19 2002-12-17 Imperial Chemical Industries Plc Methanol and hydrocarbons
CN1167650C (en) * 2000-07-17 2004-09-22 中国科学院山西煤炭化学研究所 Process for synthesizing hydrocarbon from syntehtic gas
MY139324A (en) * 2001-06-25 2009-09-30 Shell Int Research Integrated process for hydrocarbon synthesis
CN1417291A (en) * 2001-11-05 2003-05-14 中国科学院大连化学物理研究所 Technological process of preparing diesel oil fraction selectively with Fischer-tropsch synthetic gas
US7168265B2 (en) * 2003-03-27 2007-01-30 Bp Corporation North America Inc. Integrated processing of natural gas into liquid products
US20060106119A1 (en) * 2004-01-12 2006-05-18 Chang-Jie Guo Novel integration for CO and H2 recovery in gas to liquid processes
US7037485B1 (en) * 2004-11-18 2006-05-02 Praxair Technology, Inc. Steam methane reforming method
MY149298A (en) * 2006-03-30 2013-08-30 Nippon Steel Eng Co Ltd Liquid fuel synthesis system
JP4866139B2 (en) * 2006-04-28 2012-02-01 千代田化工建設株式会社 Syngas production method in kerosene production process from natural gas
CN100575457C (en) * 2006-10-08 2009-12-30 神华集团有限责任公司 A kind of Fischer-Tropsch synthesis method
CN101215213B (en) * 2007-12-29 2011-05-25 浙江工业大学 Overcritical Fischer-Tropsck synthesis method

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EP2253585B1 (en) 2016-06-08
CN101970344B (en) 2013-01-23
BRPI0910334B1 (en) 2019-02-05
JP5424566B2 (en) 2014-02-26
EP2253585A1 (en) 2010-11-24
MY150064A (en) 2013-11-29
US8268898B2 (en) 2012-09-18
BRPI0910334A2 (en) 2015-10-06
EA017725B1 (en) 2013-02-28
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US20110003900A1 (en) 2011-01-06
EG26230A (en) 2013-05-02
ZA201006261B (en) 2011-05-25
WO2009113714A1 (en) 2009-09-17
AU2009224187A1 (en) 2009-09-17
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EP2253585A4 (en) 2012-07-11

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