EA038661B1 - Синтетические пуццоланы - Google Patents
Синтетические пуццоланы Download PDFInfo
- Publication number
- EA038661B1 EA038661B1 EA201892209A EA201892209A EA038661B1 EA 038661 B1 EA038661 B1 EA 038661B1 EA 201892209 A EA201892209 A EA 201892209A EA 201892209 A EA201892209 A EA 201892209A EA 038661 B1 EA038661 B1 EA 038661B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- synthetic
- pozzolan
- reaction
- composition
- precursor
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 50
- 238000000034 method Methods 0.000 claims abstract description 49
- 230000008569 process Effects 0.000 claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims description 97
- 239000012071 phase Substances 0.000 claims description 91
- 239000002243 precursor Substances 0.000 claims description 56
- 239000004568 cement Substances 0.000 claims description 48
- 238000006243 chemical reaction Methods 0.000 claims description 38
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 37
- 229910001719 melilite Inorganic materials 0.000 claims description 36
- 239000010433 feldspar Substances 0.000 claims description 33
- 239000011575 calcium Substances 0.000 claims description 31
- 239000002994 raw material Substances 0.000 claims description 27
- 239000000126 substance Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000012190 activator Substances 0.000 claims description 25
- 239000011396 hydraulic cement Substances 0.000 claims description 23
- 229910052661 anorthite Inorganic materials 0.000 claims description 18
- 229910052742 iron Inorganic materials 0.000 claims description 17
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 claims description 14
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 229910052656 albite Inorganic materials 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229910052655 plagioclase feldspar Inorganic materials 0.000 claims description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- 239000003153 chemical reaction reagent Substances 0.000 claims description 10
- 235000006408 oxalic acid Nutrition 0.000 claims description 10
- 229910052652 orthoclase Inorganic materials 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 238000003746 solid phase reaction Methods 0.000 claims description 9
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 8
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 7
- 229910019443 NaSi Inorganic materials 0.000 claims description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 7
- 238000004458 analytical method Methods 0.000 claims description 7
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000004571 lime Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- -1 hydroxides alkali metals Chemical class 0.000 claims description 6
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 description 57
- 235000010755 mineral Nutrition 0.000 description 57
- 229910052500 inorganic mineral Inorganic materials 0.000 description 56
- 239000004567 concrete Substances 0.000 description 32
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- 235000012241 calcium silicate Nutrition 0.000 description 21
- 229910052918 calcium silicate Inorganic materials 0.000 description 20
- 239000000047 product Substances 0.000 description 20
- 239000011398 Portland cement Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 18
- 239000011230 binding agent Substances 0.000 description 16
- 239000010881 fly ash Substances 0.000 description 16
- 239000006227 byproduct Substances 0.000 description 15
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 15
- 239000000378 calcium silicate Substances 0.000 description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 239000002893 slag Substances 0.000 description 13
- 239000011734 sodium Substances 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000011777 magnesium Substances 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- 206010012812 Diffuse cutaneous mastocytosis Diseases 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- 239000002699 waste material Substances 0.000 description 11
- 229910052604 silicate mineral Inorganic materials 0.000 description 10
- BYFGZMCJNACEKR-UHFFFAOYSA-N Al2O Inorganic materials [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 235000012239 silicon dioxide Nutrition 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229910052700 potassium Inorganic materials 0.000 description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 7
- 229910004283 SiO 4 Inorganic materials 0.000 description 7
- 235000012215 calcium aluminium silicate Nutrition 0.000 description 7
- 229910052681 coesite Inorganic materials 0.000 description 7
- 229910052906 cristobalite Inorganic materials 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 229910052609 olivine Inorganic materials 0.000 description 7
- 239000006104 solid solution Substances 0.000 description 7
- 229910052682 stishovite Inorganic materials 0.000 description 7
- 229910052905 tridymite Inorganic materials 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- 239000000404 calcium aluminium silicate Substances 0.000 description 6
- WNCYAPRTYDMSFP-UHFFFAOYSA-N calcium aluminosilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O WNCYAPRTYDMSFP-UHFFFAOYSA-N 0.000 description 6
- 229940078583 calcium aluminosilicate Drugs 0.000 description 6
- 235000011116 calcium hydroxide Nutrition 0.000 description 6
- JHLNERQLKQQLRZ-UHFFFAOYSA-N calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 description 6
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000010450 olivine Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 235000019738 Limestone Nutrition 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000011411 calcium sulfoaluminate cement Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- 238000010587 phase diagram Methods 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- MVWDJLOUEUAWIE-UHFFFAOYSA-N O=C=O.O=C=O Chemical compound O=C=O.O=C=O MVWDJLOUEUAWIE-UHFFFAOYSA-N 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 239000006028 limestone Substances 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 229910021487 silica fume Inorganic materials 0.000 description 4
- 239000010456 wollastonite Substances 0.000 description 4
- 229910052882 wollastonite Inorganic materials 0.000 description 4
- 229910004762 CaSiO Inorganic materials 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 3
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 3
- 239000002956 ash Substances 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000002734 clay mineral Substances 0.000 description 3
- 238000001541 differential confocal microscopy Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910052653 anorthoclase Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- 229910001653 ettringite Inorganic materials 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000007704 wet chemistry method Methods 0.000 description 2
- 229910001720 Åkermanite Inorganic materials 0.000 description 2
- XYQHCDPZBXIAGW-UHFFFAOYSA-N Andesine Natural products COC(=O)C1=Cc2ccc3c(CCN(C)C)cc(OC)c(O)c3c2C(=O)O1 XYQHCDPZBXIAGW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910052658 andesine Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012237 artificial material Substances 0.000 description 1
- 229910052639 augite Inorganic materials 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000012707 chemical precursor Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 208000018459 dissociative disease Diseases 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 229910001678 gehlenite Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052638 hedenbergite Inorganic materials 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910052659 labradorite Inorganic materials 0.000 description 1
- 239000011018 labradorite Substances 0.000 description 1
- 229910052907 leucite Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 229910052651 microcline Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 210000004944 mitochondria-rich cell Anatomy 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 239000004058 oil shale Substances 0.000 description 1
- 229910052657 oligoclase Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000005335 volcanic glass Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/041—Aluminium silicates other than clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/043—Alkaline-earth metal silicates, e.g. wollastonite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
- C04B28/186—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type containing formed Ca-silicates before the final hardening step
- C04B28/188—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type containing formed Ca-silicates before the final hardening step the Ca-silicates being present in the starting mixture
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/12—Natural pozzuolanas; Natural pozzuolana cements; Artificial pozzuolanas or artificial pozzuolana cements other than those obtained from waste or combustion residues, e.g. burned clay; Treating inorganic materials to improve their pozzuolanic characteristics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/345—Hydraulic cements not provided for in one of the groups C04B7/02 - C04B7/34
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
- Y02P40/18—Carbon capture and storage [CCS]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662332318P | 2016-05-05 | 2016-05-05 | |
| PCT/US2017/031200 WO2017192938A1 (en) | 2016-05-05 | 2017-05-05 | Synthetic pozzolans |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201892209A1 EA201892209A1 (ru) | 2019-05-31 |
| EA038661B1 true EA038661B1 (ru) | 2021-09-30 |
Family
ID=60203582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201892209A EA038661B1 (ru) | 2016-05-05 | 2017-05-05 | Синтетические пуццоланы |
Country Status (9)
| Country | Link |
|---|---|
| US (4) | US10662116B2 (enExample) |
| EP (1) | EP3452423A4 (enExample) |
| JP (1) | JP7019599B2 (enExample) |
| CN (1) | CN109415256B (enExample) |
| BR (1) | BR112018072656B1 (enExample) |
| CA (1) | CA3022523A1 (enExample) |
| EA (1) | EA038661B1 (enExample) |
| SA (1) | SA518400367B1 (enExample) |
| WO (1) | WO2017192938A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10428217B2 (en) * | 2015-03-17 | 2019-10-01 | Steven D. Arnold | Liquid pothole filler composition and method |
| CA3011251C (en) * | 2016-01-19 | 2023-02-28 | Solidia Technologies, Inc. | Novel cement chemistries |
| CA3022523A1 (en) * | 2016-05-05 | 2017-11-09 | Solidia Technologies, Inc. | Synthetic pozzolans |
| BR112019019790A2 (pt) | 2017-03-23 | 2020-04-22 | Solidia Technologies Inc | cimentos e concretos baseados em silicato de cálcio carbonatável tendo aditivos minerais, e seus métodos de uso |
| WO2019101811A1 (en) | 2017-11-21 | 2019-05-31 | Holcim Technology Ltd | Compositions and method to improve the durability of calcium silicate-based cements and concretes |
| US11667573B2 (en) | 2017-11-21 | 2023-06-06 | Solidia Technologies, Inc | Compositions and method to improve the strength development of calcium silicate-based cements and concretes |
| EP3713894A1 (en) | 2017-11-21 | 2020-09-30 | Solidia Technologies, Inc. | Compositions and method to improve the aesthetics of calcium silicate-based cements and concretes |
| BR112020017195A2 (pt) * | 2018-02-22 | 2020-12-22 | Solidia Technologies, Inc. | Técnicas químicas para cimento |
| WO2019222602A1 (en) | 2018-05-18 | 2019-11-21 | California Institute Of Technology | Process to convert reduced sulfur species and water into hydrogen and sulfuric acid |
| EP3715013A1 (en) * | 2019-03-29 | 2020-09-30 | Imertech Sas | Wollastonite substitute |
| EP3953123B8 (en) | 2019-04-12 | 2025-07-23 | Carbicrete Inc. | Carbonation curing method to produce wet-cast slag-based concrete products |
| JP7490669B2 (ja) | 2019-04-12 | 2024-05-27 | カービクリート インコーポレイテッド | 湿式鋳造スラグ系コンクリート製品の製造 |
| AU2020330562A1 (en) * | 2019-08-13 | 2022-03-03 | Brimstone Energy Inc. | Process to make calcium oxide or ordinary portland cement from calcium bearing rocks and minerals |
| US11358304B2 (en) | 2019-12-10 | 2022-06-14 | Carbicrete Inc | Systems and methods for curing a precast concrete product |
| WO2021243441A1 (en) | 2020-06-03 | 2021-12-09 | Carbicrete Inc. | Method for making carbonated precast concrete products with enhanced durability |
| BR112023005661A2 (pt) * | 2020-10-27 | 2023-05-09 | Fct Holdings Pty Ltd | Método de produção de argila ativada/calcinada com aluminoferrita cálcica ou ferrita cálcica e composição de argila obtida pelo método |
| CN112962003A (zh) * | 2021-02-03 | 2021-06-15 | 同济大学 | 一种可自生成微纳米级保护层的混合增强铝基复合材料 |
| CN112981189A (zh) * | 2021-02-03 | 2021-06-18 | 同济大学 | 一种可自生成纳米级网状保护层的混合增强铝基复合材料 |
| CN113526884B (zh) * | 2021-08-03 | 2022-09-02 | 敦煌研究院 | 一种水硬性石灰材料、制备方法及其应用 |
| EP4155279A1 (en) | 2021-09-22 | 2023-03-29 | HeidelbergCement AG | Method for manufacturing supplementary cementitious material |
| CN114455877B (zh) * | 2022-02-11 | 2022-09-09 | 陕西睿智环保建材有限公司 | 一种复合硅酸盐材料及其制备方法、应用 |
| US12384952B2 (en) | 2022-05-18 | 2025-08-12 | Schlumberger Technology Corporation | Composite cement compositions and methods of cementing and/or treating wells drilled with water-based drilling fluids |
| WO2023225394A1 (en) | 2022-05-20 | 2023-11-23 | Schlumberger Technology Corporation | Lightweight composite cement compositions and methods of cementing wells with said compositions |
| CN116282054B (zh) * | 2022-11-22 | 2025-01-07 | 广西化工研究院有限公司 | 一种高效增量剂硅酸铝钙颜料及其制备方法与应用 |
| US12077709B2 (en) * | 2022-12-02 | 2024-09-03 | Schlumberger Technology Corporation | Cement slurry compositions comprising pozzolanic cement additives and methods for improving development of compressive strengths in the cement slurry compositions |
| WO2024247879A1 (ja) * | 2023-06-01 | 2024-12-05 | パナソニックIpマネジメント株式会社 | 情報処理方法、情報処理システム、及びプログラム |
| WO2025024556A1 (en) * | 2023-07-24 | 2025-01-30 | The Curators Of The University Of Missouri | Multi-fold carbon-negative organic alternative cement |
| CN117209173A (zh) * | 2023-09-15 | 2023-12-12 | 北京工业大学 | 一种缓凝型碱激发高钙硅铝质复合水泥及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5554352A (en) * | 1995-05-09 | 1996-09-10 | Construction Material Resources | Processed silica as a natural pozzolan for use as a cementitious component in concrete and concrete products |
| US20030233962A1 (en) * | 2002-06-21 | 2003-12-25 | Dongell Jonathan E. | Pozzolan modified portland cement compositions and admixtures therefor |
| US20120085265A1 (en) * | 2009-06-17 | 2012-04-12 | Lafarge | Industrial process for the production of a clinker with a high content of belite |
| US20120152153A1 (en) * | 2010-12-17 | 2012-06-21 | The Catholic University Of America | Geopolymer composite for ultra high performance concrete |
| US20140283712A1 (en) * | 2011-08-18 | 2014-09-25 | Heidelbergcement Ag | Method for producing ternesite-belite calcium sulfoaluminate clinker |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60155561A (ja) * | 1984-10-12 | 1985-08-15 | 日本インシュレーション株式会社 | 水性スラリ− |
| US6264736B1 (en) * | 1997-10-15 | 2001-07-24 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Pressure-assisted molding and carbonation of cementitious materials |
| JP3212590B1 (ja) * | 2000-07-04 | 2001-09-25 | クリオン株式会社 | 調湿建材 |
| US20090239429A1 (en) * | 2007-03-21 | 2009-09-24 | Kipp Michael D | Sound Attenuation Building Material And System |
| EP2708520A1 (de) | 2012-09-14 | 2014-03-19 | Cemex Research Group AG | Verfahren zur Herstellung von Zuschlag sowie von Kalziumcarbonat aus Beton-Gesteinskörnung sowie eine Vorrichtung zur Durchführung des Verfahrens |
| CN107108361A (zh) * | 2014-08-04 | 2017-08-29 | 索里迪亚科技公司 | 可碳酸盐化的硅酸钙组合物及其方法 |
| EP3201156B1 (en) * | 2014-10-03 | 2023-11-29 | Solidia Technologies, Inc. | Carbonatable calcium silicate cement composition containing hydraulic contaminants |
| CA3011251C (en) * | 2016-01-19 | 2023-02-28 | Solidia Technologies, Inc. | Novel cement chemistries |
| CA3022523A1 (en) * | 2016-05-05 | 2017-11-09 | Solidia Technologies, Inc. | Synthetic pozzolans |
| EP3466901A1 (en) | 2017-10-09 | 2019-04-10 | HeidelbergCement AG | Method for manufacturing binders hardening by hydration and carbonation |
| EP3498681A1 (en) | 2017-12-13 | 2019-06-19 | HeidelbergCement AG | Use of carbonated recycled concrete fines as supplementary cementitious material |
-
2017
- 2017-05-05 CA CA3022523A patent/CA3022523A1/en active Pending
- 2017-05-05 CN CN201780041022.4A patent/CN109415256B/zh active Active
- 2017-05-05 JP JP2018557834A patent/JP7019599B2/ja not_active Expired - Fee Related
- 2017-05-05 EP EP17793408.0A patent/EP3452423A4/en not_active Withdrawn
- 2017-05-05 EA EA201892209A patent/EA038661B1/ru unknown
- 2017-05-05 WO PCT/US2017/031200 patent/WO2017192938A1/en not_active Ceased
- 2017-05-05 US US15/587,705 patent/US10662116B2/en active Active
- 2017-05-05 BR BR112018072656-7A patent/BR112018072656B1/pt active IP Right Grant
-
2018
- 2018-11-04 SA SA518400367A patent/SA518400367B1/ar unknown
-
2020
- 2020-02-21 US US16/797,770 patent/US20200189974A1/en not_active Abandoned
- 2020-04-21 US US16/854,367 patent/US11731906B2/en active Active
-
2023
- 2023-06-29 US US18/216,368 patent/US20230339814A1/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5554352A (en) * | 1995-05-09 | 1996-09-10 | Construction Material Resources | Processed silica as a natural pozzolan for use as a cementitious component in concrete and concrete products |
| US20030233962A1 (en) * | 2002-06-21 | 2003-12-25 | Dongell Jonathan E. | Pozzolan modified portland cement compositions and admixtures therefor |
| US20120085265A1 (en) * | 2009-06-17 | 2012-04-12 | Lafarge | Industrial process for the production of a clinker with a high content of belite |
| US20120152153A1 (en) * | 2010-12-17 | 2012-06-21 | The Catholic University Of America | Geopolymer composite for ultra high performance concrete |
| US20140283712A1 (en) * | 2011-08-18 | 2014-09-25 | Heidelbergcement Ag | Method for producing ternesite-belite calcium sulfoaluminate clinker |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109415256B (zh) | 2021-09-10 |
| EA201892209A1 (ru) | 2019-05-31 |
| SA518400367B1 (ar) | 2022-06-15 |
| WO2017192938A1 (en) | 2017-11-09 |
| US10662116B2 (en) | 2020-05-26 |
| EP3452423A4 (en) | 2019-11-20 |
| US20200189974A1 (en) | 2020-06-18 |
| US20200247717A1 (en) | 2020-08-06 |
| BR112018072656B1 (pt) | 2024-03-05 |
| US20170320781A1 (en) | 2017-11-09 |
| CA3022523A1 (en) | 2017-11-09 |
| JP7019599B2 (ja) | 2022-02-15 |
| CN109415256A (zh) | 2019-03-01 |
| JP2019517979A (ja) | 2019-06-27 |
| BR112018072656A2 (pt) | 2019-02-19 |
| EP3452423A1 (en) | 2019-03-13 |
| US20230339814A1 (en) | 2023-10-26 |
| US11731906B2 (en) | 2023-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11731906B2 (en) | Synthetic pozzolans | |
| CA2908543C (en) | Method of enhancing the latent hydraulic and/or pozzolanic reactivity of materials | |
| Reig et al. | Properties and microstructure of alkali-activated red clay brick waste | |
| Moraes et al. | Increasing the sustainability of alkali-activated binders: The use of sugar cane straw ash (SCSA) | |
| US20230382792A1 (en) | Production of supplementary cementitious materials through wet carbonation method | |
| RU2005122313A (ru) | Сиалитный бинарный мокрый цемент, способ его получения и использования | |
| Manjunath et al. | Alkali-activated concrete systems: A state of art | |
| Harrison et al. | New cements based on the addition of reactive magnesia to Portland cement with or without added pozzolan | |
| CA3227936A1 (en) | Method for manufacturing supplementary cementitious material | |
| Villca et al. | Lime/pozzolan/geopolymer systems: Performance in pastes and mortars | |
| CN118076560A (zh) | 一种辅助胶凝材料的制备方法及其制备的辅助胶凝材料 | |
| Kurdowski | Mineral additions for cement production | |
| Baki | Enhancing the reactivity of natural minerals as supplementary cementitious materials for low-carbon binders | |
| Kamath et al. | Microstructure Properties of Popular Alkali-Activated Pastes Cured in Ambient Temperature. Buildings 2023, 13, 858 | |
| WO2025129096A1 (en) | Cementitious materials and additives containing aluminum and/or siliceous materials and methods of making thereof | |
| KR101129393B1 (ko) | 고로슬래그 시멘트 제조방법 및 이 방법에 의해 제조된 고로슬래그 시멘트 | |
| Bahhou et al. | Using Calcined Marls as Non-Common Supplementary Cementitious Materials—A Critical Review. Minerals 2021, 11, 517 | |
| Lei et al. | journal homepage: www. elsevier. com/locate/jobe | |
| Sharma et al. | Performance of One-Part Geopolymer | |
| JP2025135041A (ja) | セメント混和材、セメント組成物、および水硬性組成物 | |
| Gartner | How to Make Cement and Concretes with Lower CO2 Emissions | |
| Li et al. | Low-temperature synthesis of superfine α-CS from calcium carbide residue and diatomite for enhanced CO2 sequestration and mechanical performance | |
| De Weerdt et al. | Ternary Blended Cements with Fly Ash and Limestone. Part I: Activation of Fly Ash State of the art | |
| Matamba Jibikila et al. | Characterization of material for cement production in Mbuji-Mayi area (DR Congo) | |
| Bezerra et al. | Cleaner Engineering and Technology |