EA034087B1 - Система и способ производства сжиженного природного газа с удалением парникового газа - Google Patents
Система и способ производства сжиженного природного газа с удалением парникового газа Download PDFInfo
- Publication number
- EA034087B1 EA034087B1 EA201890309A EA201890309A EA034087B1 EA 034087 B1 EA034087 B1 EA 034087B1 EA 201890309 A EA201890309 A EA 201890309A EA 201890309 A EA201890309 A EA 201890309A EA 034087 B1 EA034087 B1 EA 034087B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- stream
- nitrogen
- natural gas
- pressure
- heat exchanger
- Prior art date
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- 239000005431 greenhouse gas Substances 0.000 title claims abstract description 111
- 239000003949 liquefied natural gas Substances 0.000 title claims abstract description 102
- 238000000034 method Methods 0.000 title claims abstract description 44
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 291
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 141
- 239000003507 refrigerant Substances 0.000 claims abstract description 35
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 328
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- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 7
- 239000001294 propane Substances 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
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- 230000005484 gravity Effects 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 13
- 239000000356 contaminant Substances 0.000 abstract description 5
- 238000001816 cooling Methods 0.000 description 47
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
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- 239000003795 chemical substances by application Substances 0.000 description 10
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- 229910001868 water Inorganic materials 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
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- 238000011109 contamination Methods 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
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- 230000008016 vaporization Effects 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
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- 239000000443 aerosol Substances 0.000 description 1
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- 230000009931 harmful effect Effects 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
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- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/08—Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixtures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
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- F25J1/007—Primary atmospheric gases, mixtures thereof
- F25J1/0072—Nitrogen
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- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
- F25J1/0249—Controlling refrigerant inventory, i.e. composition or quantity
- F25J1/025—Details related to the refrigerant production or treatment, e.g. make-up supply from feed gas itself
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/42—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/60—Natural gas or synthetic natural gas [SNG]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/02—Mixing or blending of fluids to yield a certain product
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
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- Filling Or Discharging Of Gas Storage Vessels (AREA)
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| TWI608206B (zh) | 2015-07-15 | 2017-12-11 | 艾克頌美孚上游研究公司 | 藉由預冷卻天然氣供給流以增加效率的液化天然氣(lng)生產系統 |
| EP3390940B1 (en) | 2015-12-14 | 2019-12-25 | Exxonmobil Upstream Research Company | Method of natural gas liquefaction on lng carriers storing liquid nitrogen |
| CN108369061B (zh) | 2015-12-14 | 2020-05-22 | 埃克森美孚上游研究公司 | 使用液化氮从液化天然气中分离氮的方法和系统 |
| US20180231305A1 (en) * | 2017-02-13 | 2018-08-16 | Fritz Pierre, JR. | Increasing Efficiency in an LNG Production System by Pre-Cooling a Natural Gas Feed Stream |
| EP3586057B1 (en) * | 2017-02-24 | 2022-09-14 | ExxonMobil Upstream Research Company | Method of purging a dual purpose lng/lin storage tank |
| US11002481B2 (en) * | 2017-03-20 | 2021-05-11 | Sustainable Energy Solutions, Inc. | Method for removing a foulant from a gas stream without external refrigeration |
| GB2571946A (en) * | 2018-03-13 | 2019-09-18 | Linde Ag | Method for operating a feed gas processing plant |
| WO2019177705A1 (en) * | 2018-03-14 | 2019-09-19 | Exxonmobil Upstream Research Company | Method and system for liquefaction of natural gas using liquid nitrogen |
| AU2019281725B2 (en) | 2018-06-07 | 2022-03-17 | Exxonmobil Upstream Research Company | Pretreatment and pre-cooling of natural gas by high pressure compression and expansion |
| JP7100762B2 (ja) | 2018-08-14 | 2022-07-13 | エクソンモービル アップストリーム リサーチ カンパニー | 天然ガス液化施設における混合冷媒の保存方法 |
| US11555651B2 (en) | 2018-08-22 | 2023-01-17 | Exxonmobil Upstream Research Company | Managing make-up gas composition variation for a high pressure expander process |
| AU2019325914B2 (en) | 2018-08-22 | 2023-01-19 | ExxonMobil Technology and Engineering Company | Primary loop start-up method for a high pressure expander process |
| WO2020040953A2 (en) | 2018-08-22 | 2020-02-27 | Exxonmobil Upstream Research Company | Heat exchanger configuration for a high pressure expander process and a method of natural gas liquefaction using the same |
| WO2020106397A1 (en) | 2018-11-20 | 2020-05-28 | Exxonmobil Upstream Research Company | Methods and apparatus for improving multi-plate scraped heat exchangers |
| WO2020106394A1 (en) | 2018-11-20 | 2020-05-28 | Exxonmobil Upstream Research Company | Poly refrigerated integrated cycle operation using solid-tolerant heat exchangers |
| US11668524B2 (en) | 2019-01-30 | 2023-06-06 | Exxonmobil Upstream Research Company | Methods for removal of moisture from LNG refrigerant |
| US11415348B2 (en) | 2019-01-30 | 2022-08-16 | Exxonmobil Upstream Research Company | Methods for removal of moisture from LNG refrigerant |
| US11465093B2 (en) | 2019-08-19 | 2022-10-11 | Exxonmobil Upstream Research Company | Compliant composite heat exchangers |
| US20210063083A1 (en) | 2019-08-29 | 2021-03-04 | Exxonmobil Upstream Research Company | Liquefaction of Production Gas |
| EP4031821A1 (en) | 2019-09-19 | 2022-07-27 | ExxonMobil Upstream Research Company | Pretreatment and pre-cooling of natural gas by high pressure compression and expansion |
| JP7326483B2 (ja) | 2019-09-19 | 2023-08-15 | エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー | 高圧圧縮及び膨張による天然ガスの前処理及び予冷 |
| JP7326485B2 (ja) | 2019-09-19 | 2023-08-15 | エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー | 高圧圧縮及び膨張による天然ガスの前処理、予冷及び凝縮物回収 |
| US11083994B2 (en) | 2019-09-20 | 2021-08-10 | Exxonmobil Upstream Research Company | Removal of acid gases from a gas stream, with O2 enrichment for acid gas capture and sequestration |
| WO2021061253A1 (en) | 2019-09-24 | 2021-04-01 | Exxonmobil Upstream Research Company | Cargo stripping features for dual-purpose cryogenic tanks on ships or floating storage units for lng and liquid nitrogen |
| RU2732998C1 (ru) * | 2020-01-20 | 2020-09-28 | Андрей Владиславович Курочкин | Установка низкотемпературного фракционирования для комплексной подготовки газа с выработкой сжиженного природного газа |
| RU2758362C1 (ru) * | 2021-03-10 | 2021-10-28 | Андрей Владиславович Курочкин | Установка комплексной подготовки газа с повышенным извлечением газового конденсата и выработкой сжиженного природного газа |
| WO2025191184A1 (en) * | 2024-03-15 | 2025-09-18 | Macaw Energies Limited | Transportable micro-scale liquid natural gas (lng) liquefaction plant and method |
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-
2016
- 2016-06-07 TW TW105117989A patent/TWI606221B/zh active
- 2016-06-14 WO PCT/US2016/037375 patent/WO2017011123A1/en not_active Ceased
- 2016-06-14 AU AU2016294175A patent/AU2016294175B2/en active Active
- 2016-06-14 CA CA2991940A patent/CA2991940C/en active Active
- 2016-06-14 JP JP2018501311A patent/JP6539405B2/ja active Active
- 2016-06-14 US US15/182,035 patent/US10480854B2/en active Active
- 2016-06-14 EA EA201890309A patent/EA034087B1/ru not_active IP Right Cessation
- 2016-06-14 CA CA3059159A patent/CA3059159C/en active Active
- 2016-06-14 KR KR1020187004247A patent/KR102064167B1/ko active Active
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- 2016-06-14 EP EP18177726.9A patent/EP3396283B1/en active Active
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2019
- 2019-01-14 AU AU2019200234A patent/AU2019200234B2/en active Active
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| US10480854B2 (en) | 2019-11-19 |
| WO2017011123A1 (en) | 2017-01-19 |
| KR102064167B1 (ko) | 2020-01-09 |
| EP3396283A1 (en) | 2018-10-31 |
| CA3059159A1 (en) | 2017-01-19 |
| KR20180030116A (ko) | 2018-03-21 |
| EP3322950B1 (en) | 2019-11-27 |
| EP3396283B1 (en) | 2020-09-02 |
| US20170016667A1 (en) | 2017-01-19 |
| EA201890309A1 (ru) | 2018-05-31 |
| AU2016294175A1 (en) | 2018-02-08 |
| CA2991940A1 (en) | 2017-01-19 |
| JP2018522194A (ja) | 2018-08-09 |
| AU2019200234B2 (en) | 2019-08-01 |
| EP3322950A1 (en) | 2018-05-23 |
| AU2019200234A8 (en) | 2019-08-01 |
| JP6539405B2 (ja) | 2019-07-03 |
| AU2019200234A1 (en) | 2019-01-31 |
| TW201713909A (zh) | 2017-04-16 |
| CA2991940C (en) | 2019-12-31 |
| AU2016294175B2 (en) | 2018-12-13 |
| TWI606221B (zh) | 2017-11-21 |
| CA3059159C (en) | 2021-06-15 |
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