EA027011B1 - Synergic herbicide compositions - Google Patents

Abstract

The invention relates to a herbicide composition which includes a component (A) and a component (B), the component (A) being the known compound propisochlor and the component (B) being the known compound clomazone, and (A)+(B) being synergistic.

Description

The present invention relates to herbicidal compositions. More specifically, an object of this invention is a composition containing a known compound belonging to the chloroacetamide family, in admixture with a known compound belonging to the isoxazolidinone family.

The first of these compounds is chloroacetamide, called propisochlor: it penetrates through the organs of weeds, located underground, at the stage of germination or seedling stage. On the one hand, it inhibits the synthesis of proteins and nucleic acids, on the other hand, it inhibits root growth. The decrease in the osmotic potential that occurs as a result of such effects causes a rapid death of weeds.

The second active component of the composition of the invention is isoxazolidinone, called clomazone; this active agent inhibits carotenoid biosynthesis; target enzyme not reliably determined. It is a selective herbicide absorbed by roots and sprouts and transported to aboveground organs. Weeds that are sensitive to it emerge, but do not have color. The clomazone molecule belongs to the group of active agents in which rare cases of weed resistance are known; only in the Lobitonidae population in Australia in 1982, resistance to clomazone was detected.

Propisochlor was tested on a large number of cultures; it was stated that it is of great interest in relation to a large number of tested crops, in particular corn, sunflower and rapeseed. The weeds that are found in the crops of these crops and which propisochlor allows you to control are mainly the following:

CEREALS: ESSIOSIOA STIIDASH; 8е1апайр; O1dPapayandshnaPy; Arega yruya Roaappia; 8ogdityaereyeye;

dicotyledons: Sarye 11a Vigya RaiYupy; Atagan11shyge1goG1ekhiy; Söioroystyrr; Maygsapyrr; Sapit Arapie.

Propizochlor can be used at various key stages of plant development, namely, before sowing (including planting), after sowing / before germination, which is its preferred use, or after germination in the early stages of development, in particular corn; in this case, the application of the herbicide should be carried out around the sowing on weeds that have not yet sprouted, or at a very early stage.

Since propisochlor is absorbed by the roots of weeds or all the underground parts of the seedlings, the effectiveness of the product largely depends on soil moisture, when it can rain after application, because the herbicide is absorbed from the liquid phase of the soil. Due to the fact that propisochlor acts on the roots, it can be used to control weeds that have not sprouted from outside and can be controlled during processing; the duration of the product is from 2 to 3 months, depending on the type of soil and climatic conditions. Once in the plant, the product acts by inhibiting elongases and cyclization enzymes of geranyl-geranyl pyrophosphate, which lead to gibberelin.

Propizochlor belongs to the group in which there are no problems of resistance, which gives it great interest. Several rare cases of resistance to the molecules of this group of herbicides have been identified, for example, the resistance of Ecuosostia daShai to butachlor in China, to butachlor and propaniol in Thailand, the resistance of Noconutum to flufenacetate in the United States and BoPitpurit in Australia.

However, propisochlor does not control all weeds present in crops, so it has already been proposed to combine it with a component, such as amicarbazone for corn or dimethenamide-R for rapeseed. Such a combination was also considered as possible in the European patent EP 2094093, however, without specifying for which crops and without examples to determine what results can be expected from such a simultaneous application. In the prior art, it has never been proposed to use propizochlor and clomazone independently of any other herbicide.

The applicant found that the use of propisochlor and clomazone for the same culture provides a synergy of the known and stated effects of these two herbicides, a synergy from which it follows that to achieve the same result, smaller amounts of herbicides can be used than those that can Provide, based on the action of each of these two herbicides, used separately.

Thus, the present invention relates to a herbicidal composition comprising component (A) and component (B), in which component (A) is a known propisochlorine compound according to formula (I)

(I) and component (B) is a known clomazone compound according to formula (II)

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(Ii)

In an embodiment, in the composition of the invention, the K = A / B ratio between the mass amount of component (A) and the mass amount of component (B) is from 10 to 40, preferably from 20 to 30.

In another embodiment, the amount of component (A) used is from 500 to 2200 g / ha (ha is an acronym of hectare, namely 10,000 m ² ).

In another embodiment, the amounts of component (B) used are from 60 to 90 g / ha.

The composition according to the invention can be in the form of dry powders, wettable powders, emulsion concentrates, microemulsions, pastes, granules, granules, dispersible in water, solutions, suspensions, microcapsules.

The composition of the invention may consist of one or more formulations containing the required amounts of component (A) and component (B); or it can be obtained at the time of use by mixing the relative amounts of component (A) and component (B), obtained separately.

The composition of the invention may contain other active ingredients, such as other herbicides, antidotes, fungicides, insecticides, acaricides, fertilizers.

If the composition according to the invention contains at least one herbicide that is not component (A) or (B), one or more of these other herbicides can be selected from the following list: acifluorfen, aclonifen, AKN-7088, amicarbazone, amitrol, anilophos, azafenidine , azimsulfuron, aziprotrin, ΒΑΥ MKN 6561, benazolin, benfluralin, bensulfuron, bentazone, benzfendizone, benzofenap, benzthiazuron, biphenox, bilanafos, bispyribac sodium, bromicyl, butomofen butylbenazylbutamide, butafenosyl butene, butafenasyl butene, butam betamide, clomethoxifene, chloramben, chlorobromuron, chlorobufam, chlorofluorenol, chloridazone, chlorimuron, chloronitrofen, chloroxuron, chlorprofam, chlortal, chlortiamide, cinidone ethyl, cinmethylein, cinosulfuron, clodilomono-clominlamon, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropyl, clodilomonopropol cyanazine, cycloate, cyclosulfamuron, cycloxydime, cyalo-fop-butyl, 2.4-EV. diamuron, dalapon, desmedifam, desmetrin, dichlobenil, dichloroprop, dichloroprop-P, diclofop, diclosulam, diethatyl, diphenoxuron, diphenzokvate, diflufenzopyr, dimefuron, dimepiperate, dimethachlorodimetin dimetin dimetin dimethrin dimethin dimethrin dimethin dimethrin dimethin dithiopyr, 1-eglinazine, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron-methyl, ethidimuron, etiozin (8ΜΥ 1500), ethofumesate, ethoxyfen-ethyl (HC-252), ethoxysulfuron, etobenzanid (52), fenoxaprop, fenoskaprop p , fenuron, flamprop, flamprop-m, flasasulfuron, flora am, fluazazifop, fluaziifop-n, fluazolate (IV 485), flucarbazone-sodium, fluchloralin, flufenpir-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, flumipropyn, fluometuron, fluoroglikofen, fluoronitrofenflupoksam, flupropanate, flupyrsulfuron, flurenol, fluridone, flurochloridone, flurtamone, flutiacet-methyl, fomesafen, foramsulfuron, fosamine, furyloxifene, haloxifop, haloxifop-p-methyl, hexazinone, imazametabenz, imazapyr, imazakine, imazosulfuron, isopropanolox, isopropoloproxopropanolin, isopropoloproxopropanolin Lenacyl, L§830556, MSRV, metamitron, metazachlor, metabenzthiazuron, metazol, metoprotrin, methyldimron, methobenzuron, methobromuron, metosulam, methoxuron, molinate, monalide, monolinuron, naproamipuronon, napamipuronon, napramononon, napramononon norflurazone, orbencarb, oryzaline, oxadiargil, oxasulfuron, oxacyclomephone, oxyfluorfene, pebulate, petanochlor, pentoxazone, phenmedifam, piperofos, primisulfuron, prodiamine, profluazol, profisulfam, pro-propampropampropazpropazpropazapropaz propapazapropaz propapazapropaz propapazapropaz pyraclonyl, pyrazogil (HA8-961), pyrazolinate, pyrazoxifene, pyribenzoxime, pyributicarb, pyridafol, pyridate, pyriftalide, pyriminobac-methyl, pyrithiobac-sodium, quinmerac, quisalofop, quisolofur-pimonomet, pimitrofon-pimonet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitroformon, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofon-pimomet, pimitrofur-pimitron, simisulfonamide , 2,3,6-TBA, TCA-sodium, tebutam, tebutiuron, teraloksidim, terbacil, terbumeton, terbutrin, tenylchlor, thiazafluuron, thiazopyr, thidiazimine, thiobencarb, thiocarbazyl, thioclorim, tralcoxidim, trial triethlusulfon , tritosulfuron, IV1-C4874, vernolate, mesotrione, s lkotrion, tembotrione, smetolahlor, acetochlor, pethoxamid, dimethenamid-p, flufenaset, pretilachlor, thiencarbazone, isoproturon, hortoluron, terbuthylazine, metribuzin, isoxaflutole, pendimethalin, diflufenican, beflubutamid.

In the composition according to the invention, the active substances, including (A) and (B), can comprise from 1 to 90 wt.% And preferably from 5 to 75 wt.% With respect to the total weight of the composition.

A subject of the invention is also the use of at least one herbicidal composition, as defined above, for weed control in crops. Such application can be carried out for weed control after seedlings and / or before seedlings of single-cotyledonous or two-cotyledonous weeds and / or for processing crops, lawns

- 2 027011 and / or as a total herbicide for processing before sowing or removing grass in industrial zones, on railways, at monuments.

This application can, in particular, be carried out for the control of plants or weeds from the following list: AiShop Sheorgakb, Abop1k species, Atbgoka species, Atagayyk, Atshtashk, ApadaShk aguyp species Ltopetus Arpapaguyepk, A1g1p1ehp1p. V1bepkrboka, Sarke11aigka-rak1opk, Seporobsht a1it, Sopuo1ui1ik kersht, Ea1pga ygatopsht, types EiryogYa, RitapaoyyushaPk, Oa1eork1k 1e1gaY1, Oa1shkodasSha1a, SaPpt aragshe, types Oegatit, types NePayPik, types 1roteak, KosYaZsoraba, types atsht, shbegtargositepk, types Maytsapa, MoposPopauadtaPk, Muokobk aguepky Papaver gPoeak, RPakeo1ik aigeik, types Ro1udopit, Royi1asao1egasea, KarPapikgaratkyit, Ko1a1atb1sa, Kiteh spkrik, 8epesyuui1dag1k, §ekata ehaPay 5pba krshoka, 81par1kaguepk1k, §o1apittdgit, types §opsyik 5> 1e11apa teb1a, TP1akr1 aguepke, Uegoshsa types, types of Usha,types Uyu1a, types HayPsht, AedPork 1aiksPi, APC r1ap1ado, A1oresigiktuokigo1bek, types of Areg, AuepaYia, types VgasYapa, types Vgotik, Vyotikite11a1ik, SepsPgikesYpa1ik, types Sotteypa, SupobopbasShop, types Suregik, types P1dIag1a, types EsYpos1oa, E1a1shaOtapbga, E1eosapkasyui1apk, E1eikshe shbyua, E1utik herek, EgadgokIkrboka, EgusYoouShoka, species Itbpk1u1tk, species Ne1egaiyega, species Lep1osP1oa, species Lobit, species Raxitidae species Rna1apk, species Roa, Ploidaeidae, 8, 8, 8.

The use according to the invention can mainly be carried out for processing crops from the group formed by corn, wheat, rapeseed, sunflower, sugar beets, potatoes, soybeans, carrots, pumpkins, zucchini, spinach, horse beans, beans, lupins, watermelon, sowing poppy seeds, peas and tobacco.

Finally, an object of the invention is a method of controlling weeds in crops by applying at least one composition according to the invention.

As an example, below is the composition of the composition according to the invention, which allows to ascertain the presence of synergism of components (A) and (B).

Propisochlor (A) - 720 g,

Clomazone (B) - 30 g,

Emulsifier Sa1codep EN - 60 g,

Emulsifier EtiCodep E360 - 60 g,

Thinner §o1uecco 150 N0 - 100 g,

Rapeseed oil PHU1OGO PHT - up to 1 liter.

The product, ready for use in culture, is prepared as follows: clomazone is introduced into the solvent and shaken until completely dissolved; then propisochlor is introduced and shaken until a clear solution is obtained; then two emulsifiers are introduced into the mixture, followed by rapeseed oil and homogenized. The product thus obtained is stable and does not crystallize upon storage at -10 ° C for 7 days.

To establish the presence of synergism (A) + (B), use the above composition, which is designated (X) to describe the test, but for the test use the code name AB§10HPRS.

As indicated above, the effectiveness (X) should be compared with the effectiveness of the two components (A) and (B). As the code name (A) in the test, Аb§7НРР§ is used, and (B) - Seigit 36C8.

The test products are sprayed to test their effect at the dosages indicated in the following column in the 1st column. Ι-ΙΙΙ (e.g. 2 or 2.5 or 3 l / ha of product (X)). Post-sowing-pre-emergence spraying is carried out on 10 different weeds, the names of which are given in the first three rows of the table. Ι-ΙΙΙ (four test samples (pots or trays) of each weed). These tests were carried out near Nimes (France) under controlled conditions while maintaining optimal soil temperature and humidity. Performance indicators were recorded on days 14, 23 and 30 (only 8 weeds emerged after 14 days and 9 after 23 days).

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Table I

Results 14 days after application

Code weed BAUER AYOMU yo UERAR SERB! Z. VI SNEA AMANE ROSO Scientific Name of Weed A1oresigiztuodigo1 Res HoNishpins! £ 1og aguepzgs SegaphitLzzesR ZeRaseauffFSI ZeporoLip A1big Atagap £ .1giz ge £ go £ 1е Ga11or1a Common name for weed Field foxtail Ryegrasse ital ayan s cue Field veronica Geranium dissected Bristles green Mary white Amaranth thrown back Buckwheat bindweed Date Recorded 01/23/2013 01/23/2013 Ζ3 / 01 / 20Ί 01/23/2013 01/23/2013 01/23/2013 01/23/2013 01/23/2019 Stages of development on a scale Air Force Air Force Air Force Air Force Air Force Air Force Air Force Air Force Macrosta nine nine nine nine nine nine nine nine one Control b, δ 20, δ 28, 8 δ, δ 11.8 8 13.8 2 2 ALZYUNRRS 2 l / ha 60 90 90 thirty 90 fifty fifteen 60 3 AB510NRRS 2,5 l / ha 90 95 90 thirty 90 fifty 80 60 4 AB510NRRS 3 l / ha 90 95 90 thirty 90 70 6-0 40 5 АЪ57НРР5 2 l / ha 35 95 80 0 85 twenty 40 thirty b AB37NRP5 2,5 l / ha 90 95 thirty 0 85 twenty 80 thirty 7 AL57NRP5 3 l / ha 95 95 thirty 0 90 fifty 80 thirty 8 SepChish Zbss 0.16 l / ha 0 0 0 0 0 0 40 0 nine SepNish Zbs 0.2 l / ha 0 0 0 0 0 0 thirty 0 10 sepsheish 36s5 0.25 l / ha 0 0 0 0 0 0 fifty twenty Efficiency calculated in equiv. Co1y In well 5 and 8 (compare f 2} 35 95 thirty 0 85 twenty 64 thirty In conv.b and 9 (compare with memory 90 95 thirty 0 85 twenty 86 thirty In conditions 7 and 10 (compare with 4) 95 95 thirty 0 90 fifty 90 44

The numbers indicated for the untreated control sample (condition 1) correspond to the invasion expressed by the number of plants per m ² . The numbers indicated in the processing conditions (2-10) are given in% efficiency compared to the untreated control sample. Performance indicators calculated by the formula Co1by (at the bottom of the table) should be compared with performance indicators obtained using (X). The values in italics obtained using (X) in 3 tables allow us to conclude that the components of this composition are synergistic.

Table II

Results 23 days after application

Weed Code WOW AOMU yo UERAR Seven 5ETU1 READ AMANE ROSO SAGAR Pull Scientific Name of Weed AYurasmgchztuogigFheyeg B 1 ί | ji ί ί 1 o ϊ «ιτι s-gagaymtf gvestt : 4ΐ.ίΧί5νίΐίζ (ί. Οΐΐίηοροϋίυιη a1b AtagapsNiggeioPehig Haporya ιζοηνοίνιιΐ of SaIshp YOU! ) 6 common weed name Lobster foxtail Ryegrasse Italian Share veronica Geranium dissected Bristles green Mary White Amaranth thrown back Buckwheat bindweed 1dma of rhenium! tenacious Yurt field Date Recorded 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2013 02/01/2011: Stages of development on a scale Air Force Air Force Air Force Air Force Air Force Air Force Air Force Air Force Air Force Air Force Macrosta 12 thirteen 12 12 12 12 eleven 10 10 12 one Control 9.3 25 27.5 9, 3 eleven 13, 5 25 5, 3 4.3 0.3 2 AD510NRRS 2 l /? a twenty 95 90 thirty 95 95 95 70 60 3 AD510NRRS 2, 5 l / ra 82.5 95 96.5 fifty 95 95 95 90 80 4 AD510NRRS 3 l / ra 85 95 96.5 fifty 95 95 95 72.5 75 5 AD57NRR5 2 l / ra 62.5 95 72.5 60 95 thirty 88.8 fifty 60 & AD57NRR5 2, 5 l / ra 82.5 95 76.3 70 90 fifty 86, 3 67.5 60 7 AD57NRR5 3 l / ra 82.5 95 57.5 70 95 65 one hundred 55 62, 5 - 8 SepIdga 36S5 0.16 l / ra 0 0 0 0 thirty 0 0 17.5 - nine SepIdga ZVS5 0.2 l / ra 12.5 fifteen 52,5 0 thirty 0 27.5 62, 5 - 10 SepIdga 36S5 0.25 l / ra 10 twenty 35 0 40 0 47.5 65 - Efficiency calculated in equiv. Co1y B conv. 5 and δ (compare with 2) 63 95 73 60 95 51 89 fifty 67 B conv.b and 9 (compare with 3) 85 96 89 70 90 65 86 76 85 B conv. 7 and 10 (compare with 41 84 96 72 70 95 79 one hundred 76 87

The results obtained for the weed. the degree of invasion is too low (only 0.3 plants / m ² on average for 4 test samples).

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Table III

The results of this test, therefore, show the synergism of the components of the composition (A) + (B). Very weak in relation to Italian ryegrass when applying from 2.5 to 3.0 l / ha in the last record.

Weak, but prolonged, in relation to field veronica when applied from 2.0 to 3.0 l / ha 14 days after application and up to 30 days.

Strong in relation to the bedstalk tenacious in the last record when applied from 2.0 to 2.5 l / ha. Synergism, of course, is also present when applying 3.0 l / ha, but the unexpected value obtained on the 4th test sample (abnormally low efficiency indicator compared to 3 other test samples) when using the product (A) + (B) lowers mean.

Very strong against white marie and buckwheat buckwheat when used from 2.0 to 3.0 l / ha throughout the test.

Claims (12)

CLAIM 1. A herbicidal composition comprising component (A) and component (B), in which component (A) is a known propisochlor compound corresponding to formula (I) and component (B) is a known clomazone compound corresponding to formula (II) ίη5 < (II) wherein the applied amounts of component (A) are from 500 to 2200 g / ha, and the applied amounts of component (B) are from 60 to 90 g / ha and the ratio K = A / B between the mass amount of component (A) and the mass the amount of component (B) is from 10 to 40. 2. The composition according to claim 1, characterized in that it is in the form of dry powders, wettable powders, emulsion concentrates, microemulsions, pastes, granules, granules, dispersible in water, solutions, suspensions, microcapsules. 3. The composition according to any one of claims 1, 2, characterized in that it consists of one or more finished compositions containing the required amounts of component (A) and component (B); or it is obtained at the time of use by mixing the relative amounts of component (A) and component (B), obtained separately. 4. The composition according to any one of claims 1 to 3, characterized in that it contains other active ingredients, such as other herbicides, antidotes, fungicides, insecticides, acaricides, fertilizers. 5. The composition according to claim 4, characterized in that one or more other herbicides that it contains are selected from the following list of herbicides: acifluorfen, aclonifen, AKN-7088, amicarbazone, amitrol, anilofos, azaphenidine, azimsulfuron, aziprotrin, ΒΑΥ MKN 6561, benosaline, benfluralin, bensulfuron, bentazone, benzfendizone, benzofenap, benzthiazuron, biphenox, bilanafos, bispiribac sodium, bromicyl, bromofenoxime, butafenasil, butamifos, butenachlor, butralin, chloromethane, chloromethane, chloromethane, chloromethane, chloromethane, chloromethane bufam, hlorfluorenol, chloridazon, chlorimuron, chloronitrofen, chloroxuron, chlorpropham, chlorthal, chlorthiamid, cinidon - 5,027,011 ethyl, cinmethylein, cinosulfuron, celodim, clodinafop, clomeprop, cloranzulam methyl, cumiluron (1C-940), cyanazine, cycloate, cyclosulfamuron, cycloxydim, cialofop-butyl, 2,4-ΌΒ, diamuron, donaldon desmedifam, desmetrine, dichlobenil, dichloroprop, dichloroprop-P, diclofop, diclosulam, diethylate, diphenoxuron, diphenoxyquat, diflufenzopyr, dimefuron, dimepiperate, dimethachloride, dimetindetindepine dipindetin dipindetin dipindetin dindebin dindetin dibin dithindetin dindebin dindetopine 1glinazine, endotal, ERTS, esprocarb, etalfluralin, etametsulfuron-methyl, ethidimuron, etiosin (8ΜΥ1500), etofumezate, ethoxyphene-ethyl (NS-252), ethoxysulfuron, ethobenzanide (HA 52), fenoxaprop, fenoscaprop-p, phenuron, flamprop, flamprop-m, flazasulfuron, phlozamop, fluazifop , fluazolate (IV 485), flucarbazone-sodium, fluchloralin, flufenpir-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, flumipropyn, fluometuron, fluoroglikofen, fluoronitrofen flupoxam, flupropanate, flupyrsulfuron, flurenol, fluridone, flurochloridone, flurtamone, fluthiacet-methyl, fomesafen, foramsulfuron, fosamine, furyloxifene, haloxifo p, haloxifop-p-methyl, hexazinone, imazametabenz, imazapyr, imazakine, imazosulfuron, indanophan, iodosulfuron, isopropaline, isouron, isoxaben, isoxachlorothol, isoxapyrififop, KPP-421, lenacylazobaz, bac, methazbaz, metazole, metoprotrin, methyldimron, methobenzuron, methobromuron, metosulam, methoxuron, molinate, monalide, monolinuron, naproanilide, napropamide, napthalam, YC330, neburon, nicosulfuron, nipiracloferfonoxulfene, orflorofoxulfene, orbenoforfoxulfan, orbenfoxulfan, orbenfoxulfan, orbenfox oxide, orbenoforbenoxorbene, orbenfoxulfan, orbenfoxulfan, orbenfiloxonforbenoxene orbenoforbase oxorbene, orbenulfene oxorbene, orbenfilofoxulfene, orbenfilofoxulfene, orbenfilofoxulfene, orbenfilofoxulfene, orbenfilofoxulfene, orbene pet nochlor, pentoxazone, fenedmedifam, piperofos, primisulfuron, prodiamine, profluazole, proglinazine, promethone, propacvisafop, propazine, profam, propisamide, prosulfocarb, prosulfuron, pyraclonyl, pyrazogyrne, pyridibyrene pyrazyribyrbenopyrpyrbithiopyrbenopyrbenopyr , pyriftalide, pyriminobac-methyl, pyrithiobac-sodium, quinmerac, quisalofop, quisolofop-p, rimsulfuron, setoxydim, siduron, simethrin, sulfometuron-methyl, 2,3,6-TBA, TCA-sodium, tebutam, tebutiuron, teratraloxydim, terbicyl , terbumeton, terbutrin, tenylchlor, thiazafl damage, thiazopyr, thidiazimine, thiobencarb, thiocarbazyl, thioclorim, tralcoxydim, triallate, traisiflam, trietazine, triflusulfuron-methyl, tritosulfuron, IV1-C4874, vernolate, mesotrione, sulcotrione, metdolone, temdolon, temdolone, temdolon, temdolone flufenaset, pretilachlor, thiencarbazone, isoproturon, hortoluron, terbutilazine, metribuzin, isoxaflutol, pendimethalin, diflufenicanil, beflubutamide. 6. The composition according to any one of claims 4 or 5, characterized in that the active substances, including (A) and (B), can be from 1 to 90 wt.% And preferably from 5 to 75 wt.% In relation to the total weight of the composition. 7. The composition according to claim 1, characterized in that the ratio K = A / B between the mass amount of component (A) and the mass amount of component (B) is from 20 to 30. 8. The use of at least one herbicidal composition according to any one of claims 1 to 7 for weed control in crops. 9. The use of claim 8 for controlling, after germination and / or seedling emergence, with single-cotyledonous or two-cotyledonous weeds and / or for processing crops, lawns and / or as a total herbicide for processing before sowing or removing grass in industrial areas, on iron roads, at the monuments. 10. Use according to any one of claims 8 or 9 for controlling weeds or plants from the following list: AiShoi Sheortakf types Αάοηίδ, Ashto81a types, kinds AtagaiOshk, Ashshshashk, Aiada1Y8 aguei818, types AtNeiyk, AraiekaguegShk, A1pr1ehra1i1e, VSheikryoka, SarkePasha-rakShpk, SyeioroShish a1it, Soiuo1ui1i8 kersht, Ea1iga kyatotit, types EiryogYa, RitapaoGPstaSh, Sa1eor818 1e1ga1sh, SaPi8odasSha1a, SaPit aragshe, types Setatit, types NePaiPshk, types 1roteak, KosPShsorapa, types atsht, Etbegtargositeik, types Ma1psapa, MoiosopauadshaPk, MuokoOk aguegShk, Papaver goeak, Ra8eo1i8 aiteik , species Ploidaudit, Rothschasacataetasea, Karbaeni8 ^ arBaη ^ 8ί ^ it, KSa1atSha, Kiteh spkrik, 8yesyuu1dag18t, Zekta ekPaSh, Sha krshoka, Zhiarchkgeeikkhk, Zoiba, 5 ^ sa kinds νίάιι, types νωΠι, types HaiShini, Aedyork 1ai8ssch Ayksha r1aShado, A1oresigi8tuo8igoMe8, types of Areg, AueiaGaSha, types VtasYapa, types Vgotik, ViYutiBiteIaShB, SeistikestaShk, types SottePia, SuioboibasShoi, types Suregi8, types Oschyapa, types EsPtosYoa, E1aΐ ^ ηаΐ ^^ аηά ^ а, Е1еосЬап8асюи1а1Т8, Е1ей8ше ШШса, Е1ут8 Hereik, Etadtokykryoka, Etusokuoku Shoka, species Ρίιη6π8 ΐν1ί8, Species of Neu-YugaiShega, species of Epiphyllidae, species of Laoish, species of Rashsschp, species of Papa1ag18, species of Roa, Rochededeoοηηοάο8i8, species of Shaparudtaea, species 11. The use according to any one of paragraphs.8-10 for processing a crop from the group formed by corn, wheat, rapeseed, sunflower, sugar beets, potatoes, soybeans, carrots, pumpkin, zucchini, spinach, bean, beans, lupine, watermelon, sowing poppy seeds, peas and tobacco. 12. A method of controlling weeds in crops by applying to the crop at least one composition according to any one of claims 1 to 7.