EA018962B1 - Способ получения сахаров и спиртов из целлюлозного материала - Google Patents
Способ получения сахаров и спиртов из целлюлозного материала Download PDFInfo
- Publication number
- EA018962B1 EA018962B1 EA201190336A EA201190336A EA018962B1 EA 018962 B1 EA018962 B1 EA 018962B1 EA 201190336 A EA201190336 A EA 201190336A EA 201190336 A EA201190336 A EA 201190336A EA 018962 B1 EA018962 B1 EA 018962B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- acid
- solvent
- extraction solvent
- aqueous
- water
- Prior art date
Links
- 235000000346 sugar Nutrition 0.000 title claims abstract description 68
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title description 11
- 239000002904 solvent Substances 0.000 claims abstract description 151
- 239000002253 acid Substances 0.000 claims abstract description 127
- 238000000605 extraction Methods 0.000 claims abstract description 106
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 150000008163 sugars Chemical class 0.000 claims abstract description 43
- 239000003929 acidic solution Substances 0.000 claims abstract description 38
- 239000011260 aqueous acid Substances 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 238000004064 recycling Methods 0.000 claims abstract description 19
- 229920001542 oligosaccharide Polymers 0.000 claims abstract description 9
- 150000002482 oligosaccharides Chemical class 0.000 claims abstract description 9
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 239000011877 solvent mixture Substances 0.000 claims abstract description 8
- 230000003301 hydrolyzing effect Effects 0.000 claims abstract description 7
- 230000007062 hydrolysis Effects 0.000 claims description 40
- 238000006460 hydrolysis reaction Methods 0.000 claims description 40
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 29
- 238000004821 distillation Methods 0.000 claims description 19
- 238000000855 fermentation Methods 0.000 claims description 18
- 230000004151 fermentation Effects 0.000 claims description 18
- 239000000725 suspension Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 238000009434 installation Methods 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- -1 carbon halide Chemical class 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 23
- 238000003776 cleavage reaction Methods 0.000 abstract description 5
- 239000000413 hydrolysate Substances 0.000 abstract 2
- 239000012071 phase Substances 0.000 description 56
- 239000012074 organic phase Substances 0.000 description 33
- 235000019441 ethanol Nutrition 0.000 description 30
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 23
- 238000000926 separation method Methods 0.000 description 22
- 239000000047 product Substances 0.000 description 21
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 20
- 229920005610 lignin Polymers 0.000 description 20
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 13
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 238000005903 acid hydrolysis reaction Methods 0.000 description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 238000005303 weighing Methods 0.000 description 10
- 238000004817 gas chromatography Methods 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 244000005700 microbiome Species 0.000 description 8
- 150000007522 mineralic acids Chemical class 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000007790 solid phase Substances 0.000 description 8
- 238000002479 acid--base titration Methods 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 238000003109 Karl Fischer titration Methods 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 241000609240 Ambelania acida Species 0.000 description 4
- 239000010905 bagasse Substances 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000002551 biofuel Substances 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 150000008282 halocarbons Chemical group 0.000 description 2
- 150000002402 hexoses Chemical class 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 150000002972 pentoses Chemical class 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000003949 liquefied natural gas Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/06—Ethanol, i.e. non-beverage
- C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
- C12P7/10—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
- C07H1/06—Separation; Purification
- C07H1/08—Separation; Purification from natural products
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
- C13K1/04—Purifying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Zoology (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0910707.9A GB0910707D0 (en) | 2009-06-19 | 2009-06-19 | Method |
| PCT/GB2010/001120 WO2010146331A2 (en) | 2009-06-19 | 2010-06-08 | Method of alcohol production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201190336A1 EA201190336A1 (ru) | 2012-07-30 |
| EA018962B1 true EA018962B1 (ru) | 2013-12-30 |
Family
ID=40972537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201190336A EA018962B1 (ru) | 2009-06-19 | 2010-06-08 | Способ получения сахаров и спиртов из целлюлозного материала |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20120135489A1 (https=) |
| EP (1) | EP2443245A2 (https=) |
| JP (1) | JP2012529903A (https=) |
| CN (1) | CN102459619A (https=) |
| AU (1) | AU2010261615B2 (https=) |
| BR (1) | BRPI1011774A2 (https=) |
| CA (1) | CA2765760C (https=) |
| EA (1) | EA018962B1 (https=) |
| GB (1) | GB0910707D0 (https=) |
| PH (1) | PH12011502621A1 (https=) |
| WO (1) | WO2010146331A2 (https=) |
| ZA (1) | ZA201109376B (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0907879D0 (en) * | 2009-05-07 | 2009-06-24 | Weyland As | Process |
| CN102575422B (zh) * | 2009-07-13 | 2016-08-03 | 贝塔可再生资源公司 | 木质素的高温分离方法 |
| CN103201395B (zh) | 2010-06-26 | 2016-03-02 | 威尔迪亚有限公司 | 糖混合物及其生产和使用方法 |
| IL206678A0 (en) | 2010-06-28 | 2010-12-30 | Hcl Cleantech Ltd | A method for the production of fermentable sugars |
| IL207329A0 (en) | 2010-08-01 | 2010-12-30 | Robert Jansen | A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition |
| IL207945A0 (en) | 2010-09-02 | 2010-12-30 | Robert Jansen | Method for the production of carbohydrates |
| PT106039A (pt) * | 2010-12-09 | 2012-10-26 | Hcl Cleantech Ltd | Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas |
| WO2012137201A1 (en) | 2011-04-07 | 2012-10-11 | Hcl Cleantech Ltd. | Lignocellulose conversion processes and products |
| WO2013055785A1 (en) | 2011-10-10 | 2013-04-18 | Virdia Ltd | Sugar compositions |
| US9493851B2 (en) | 2012-05-03 | 2016-11-15 | Virdia, Inc. | Methods for treating lignocellulosic materials |
| EP2878614A1 (en) * | 2012-05-03 | 2015-06-03 | Virdia Ltd. | Methods for treating lignocellulosic materials |
| FR2998191B1 (fr) * | 2012-11-20 | 2015-10-16 | Ifp Energies Now | Colonne d'extraction liquide liquide utilisant des plateaux equipes d'un element generateur de perte de charge |
| US9657146B2 (en) | 2013-03-14 | 2017-05-23 | Virdia, Inc. | Methods for treating lignocellulosic materials |
| US9850512B2 (en) | 2013-03-15 | 2017-12-26 | The Research Foundation For The State University Of New York | Hydrolysis of cellulosic fines in primary clarified sludge of paper mills and the addition of a surfactant to increase the yield |
| US9297111B1 (en) | 2013-03-15 | 2016-03-29 | Domtar Paper Company, Llc | Methods for the manufacture of cellulose nanocrystals |
| JP6666242B2 (ja) | 2013-05-03 | 2020-03-13 | ヴァーディア， インコーポレイテッド | リグノセルロース系材料処理の方法 |
| KR20160007537A (ko) | 2013-05-03 | 2016-01-20 | 버디아, 인크. | 열안정성 리그닌 분획물의 제조 방법 |
| US10711319B2 (en) * | 2013-12-24 | 2020-07-14 | Silvanova, Llc | Method for treating cellulosic material |
| US9951363B2 (en) | 2014-03-14 | 2018-04-24 | The Research Foundation for the State University of New York College of Environmental Science and Forestry | Enzymatic hydrolysis of old corrugated cardboard (OCC) fines from recycled linerboard mill waste rejects |
| CN109851814B (zh) | 2014-07-09 | 2022-03-11 | 威尔迪亚有限责任公司 | 用于从黑液中分离和精制木质素的方法及其组合物 |
| US11078548B2 (en) | 2015-01-07 | 2021-08-03 | Virdia, Llc | Method for producing xylitol by fermentation |
| BR112017025322A8 (pt) | 2015-05-27 | 2022-08-23 | Virdia Inc | Processos integrados para recuperação de hidrolisato celulósico após hidrólise de polpa de celulose |
| MY181119A (en) * | 2015-06-11 | 2020-12-18 | Petiva Private Ltd | Process for isolating fermentable sugars from the acid hydrolyzate of a material containing cellulose, hemicellulose and lignin |
| CN114214080A (zh) * | 2021-12-20 | 2022-03-22 | 中国矿业大学 | 一种基于太阳能的生物质转化装置 |
| CN117512227B (zh) * | 2023-11-07 | 2025-03-18 | 南京工业大学 | 一种秸秆类木质纤维素经酸法梯度处理制备单糖溶液的工艺 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4608245A (en) * | 1985-10-17 | 1986-08-26 | Gaddy James L | Method of separation of sugars and concentrated sulfuric acid |
| US6007636A (en) * | 1999-01-04 | 1999-12-28 | Lightner; Gene E. | Method to recycle an aqueous acidic liquor used for depolymerization of cellulose |
| WO2002002826A1 (en) * | 2000-07-04 | 2002-01-10 | Knut Helland | Methods for preparing fermentable sugar from cellulose containing raw materials |
| WO2007019505A2 (en) * | 2005-08-05 | 2007-02-15 | The Trustees Of Dartmouth College | Method and apparatus for saccharide precipitation from pretreated lignocellulosic materials |
| WO2010038021A2 (en) * | 2008-10-02 | 2010-04-08 | Weyland As | Method of production of alcohol |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3228985A (en) * | 1961-12-27 | 1966-01-11 | Celanese Corp | Process of purifying methyl ethyl ketone |
-
2009
- 2009-06-19 GB GBGB0910707.9A patent/GB0910707D0/en not_active Ceased
-
2010
- 2010-06-08 CN CN2010800273371A patent/CN102459619A/zh active Pending
- 2010-06-08 EP EP10725247A patent/EP2443245A2/en not_active Withdrawn
- 2010-06-08 US US13/378,655 patent/US20120135489A1/en not_active Abandoned
- 2010-06-08 PH PH1/2011/502621A patent/PH12011502621A1/en unknown
- 2010-06-08 AU AU2010261615A patent/AU2010261615B2/en not_active Ceased
- 2010-06-08 EA EA201190336A patent/EA018962B1/ru not_active IP Right Cessation
- 2010-06-08 WO PCT/GB2010/001120 patent/WO2010146331A2/en not_active Ceased
- 2010-06-08 JP JP2012515550A patent/JP2012529903A/ja active Pending
- 2010-06-08 CA CA2765760A patent/CA2765760C/en active Active
- 2010-06-08 BR BRPI1011774A patent/BRPI1011774A2/pt not_active Application Discontinuation
-
2011
- 2011-12-20 ZA ZA2011/09376A patent/ZA201109376B/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4608245A (en) * | 1985-10-17 | 1986-08-26 | Gaddy James L | Method of separation of sugars and concentrated sulfuric acid |
| US6007636A (en) * | 1999-01-04 | 1999-12-28 | Lightner; Gene E. | Method to recycle an aqueous acidic liquor used for depolymerization of cellulose |
| WO2002002826A1 (en) * | 2000-07-04 | 2002-01-10 | Knut Helland | Methods for preparing fermentable sugar from cellulose containing raw materials |
| WO2007019505A2 (en) * | 2005-08-05 | 2007-02-15 | The Trustees Of Dartmouth College | Method and apparatus for saccharide precipitation from pretreated lignocellulosic materials |
| WO2010038021A2 (en) * | 2008-10-02 | 2010-04-08 | Weyland As | Method of production of alcohol |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2443245A2 (en) | 2012-04-25 |
| US20120135489A1 (en) | 2012-05-31 |
| ZA201109376B (en) | 2013-02-27 |
| EA201190336A1 (ru) | 2012-07-30 |
| GB0910707D0 (en) | 2009-08-05 |
| CA2765760C (en) | 2017-02-07 |
| CA2765760A1 (en) | 2010-12-23 |
| AU2010261615B2 (en) | 2014-04-10 |
| JP2012529903A (ja) | 2012-11-29 |
| CN102459619A (zh) | 2012-05-16 |
| WO2010146331A2 (en) | 2010-12-23 |
| PH12011502621A1 (en) | 2012-11-12 |
| BRPI1011774A2 (pt) | 2015-09-15 |
| WO2010146331A3 (en) | 2011-10-06 |
| AU2010261615A1 (en) | 2012-01-19 |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM RU |