DK2275252T3 - A process for the preparation of flexible valve-adhesive labels - Google Patents

A process for the preparation of flexible valve-adhesive labels Download PDF

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Publication number
DK2275252T3
DK2275252T3 DK10168393.6T DK10168393T DK2275252T3 DK 2275252 T3 DK2275252 T3 DK 2275252T3 DK 10168393 T DK10168393 T DK 10168393T DK 2275252 T3 DK2275252 T3 DK 2275252T3
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DK
Denmark
Prior art keywords
band
blade
adhesive
perimeter
valve
Prior art date
Application number
DK10168393.6T
Other languages
Danish (da)
Inventor
Valerio Binda
Original Assignee
Masterpack S P A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Masterpack S P A filed Critical Masterpack S P A
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Publication of DK2275252T3 publication Critical patent/DK2275252T3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/22Details
    • B65D77/225Pressure relief-valves incorporated in a container wall, e.g. valves comprising at least one elastic element
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31DMAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D1/00Multiple-step processes for making flat articles ; Making flat articles
    • B31D1/02Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags
    • B31D1/021Making adhesive labels having a multilayered structure, e.g. provided on carrier webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31DMAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D1/00Multiple-step processes for making flat articles ; Making flat articles
    • B31D1/02Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags
    • B31D1/026Cutting or perforating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31BMAKING CONTAINERS OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31B70/00Making flexible containers, e.g. envelopes or bags
    • B31B70/74Auxiliary operations
    • B31B70/81Forming or attaching accessories, e.g. opening devices, closures or tear strings
    • B31B70/84Forming or attaching means for filling or dispensing contents, e.g. valves or spouts
    • B31B70/85Applying patches or flexible valve inserts, e.g. applying film-like valves

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Making Paper Articles (AREA)
  • Bag Frames (AREA)

Description

DESCRIPTION
[0001] The present disclosure concerns in general the packaging techniques of foodstuff in particular inside heat sealed airtight flexible film packages that may eventually be warmed up before heating it.
[0002] The practice of packaging foodstuff in airtight packages for preventing contaminations and favor conservation of the preparation is common practice. This type of packaging used in the commerce, delivery or distribution of meals may also be adapted to allow heating/cooking the foodstuff in a hot or microwave oven prior to deliver or serve the heated food still contained in the package. Such a practice is very common in snack-bar, fast-food, restaurants, mess-rooms, automatic food dispensers and alike.
[0003] When heating the content of these airtight packages, an inner overpressure is produced because of the development of vapors (typically water vapor) which inflates the flexible film airtight package to the point of causing its tearing open and/or partial detachment of welded seams or welded edges, unless the flexible film is preventively perforated. In any case the package to be delivered or served after having heated it contents would assume a non integer aspect besides complicating an orderly opening of a flexible sac-like package or the removal of an already pierced or partly detached sealing film of flexible plastic film of a relatively rigid tub or plate like container.
[0004] For preventing these effects of heating the contents of an airtight package, special pressure release valves for the pressurized gaseous substances have been devised, often intended to be pre-applied onto the plastic film with which will be formed the heat sealed flexible sac package or sealed a plate-container of relatively rigid plastic in order to release over pressurized vapors upon exceeding a certain maximum limit pressure thus avoiding uncontrolled tearing or detachment of the hot welded flexible film of the package.
[0005] The document JP-2006-298410 (A) describes a vapor release valve that may be fabricated replicating it over a support ribbon. The fabrication machine separates a portion or segment of the ribbon carrying on it a single valve, removes from it the portion of the supporting ribbon, and apply the adhesive valve in a predetermined area over the inner surface of the flexible film with which the airtight package will be made. Various structures of adhesive label-valve applicable over the outer surface of hot weldable films used for packaging foodstuff, for sealing a release opening of inner over pressurized gaseous substances from the airtight package, are described in the documents: U.S. Patent No. 5,989,608, AU2006219770(A1) , W02006107974(A1), W02004108557(A2), EP1157942(A1). US 2006 0030472 discloses separately manufacturing a plurality of valves, aligning the valves with openings in the bag structures, and securing the aligned valves to the bag structures. Each valve comprises a vent layer which is pervious with respect to expected gasses and a sealed passageway is formed between the vent layer and the container when the valve is secured to the bag structure.
[0006] The composite structures of known adhesive label valves comprising a layer of adhesive and a central shielding membrane adherent to the layer of pressure activated adhesive of the label-valve such to overlay the opening formed through the hot weldable flexible film of the package to prevent contact of the aliment with the adhesive, are relatively costly from the point of view of the efficient use of materials and ease of application over an aperture made through the flexible film with which the hot sealed packages will be made.
[0007] Has been found and is the object of the present application, a novel and efficient fabrication process of flexible adhesive label-valves according to claim 1 that provides for a substantial minimization of wasted materials (chisel) together with a simplification of the processes. Moreover, flexible the adhesive label-valves may be picked-up singularly from a continuous feed carrier ribbon to an automated handling device that eventually apply a picked-up label-valve onto the outer surface of a flexible plastic film ribbon having holes at regular intervals, with which the hot sealed package will be formed.
[0008] Basically, the process of the present disclosure comprises the steps of: 1. a) coupling a carrier sheet or ribbon of a foodstuff compatible polymeric packaging material having an antiadherent coupling surface, to a sheet or ribbon of a polymeric material suitable for packaging foodstuff (foodstuff compatible) having onto its coupling surface a layer of a pressure activated adhesive; 2. b) inciding only the carrier sheet or ribbon of said laminated article once for producing a cut that defines the perimeter of an island portion of the carrier ribbon of size adapted to occlude, superimposing on it, the pressure release hole or cut in the flexible plastic film of formation of the package and a second time in order to produce cut only in the sheet or ribbon with adhesive layer, that defines the perimeter of a valve label strippable off said antiadherent surface of the underlying carrier sheet or ribbon, around the area of the defined island portion, and at least a cut secant the geometric projection of the perimeter of the island portion of carrier sheet or ribbon.
[0009] Exemplary, a continuous laminated ribbon, unwound from a feed roll, is simply subjected to a first incision with a sharp tool of only a carrier ribbon of a polymeric material adapt for packaging foodstuff and having its coupling surface treated in a manner such to make it antiadherent, defining a close perimeter of a shielding membrane island of size adapted to overlie an area exceeding the area of a release hole formed in the hot weldable flexible plastic film, with which will be formed the airtight package of the foodstuff.
[0010] The process of fabrication further comprises a second incision of the ribbon of flexible foodstuff compatible plastic film having a layer of adhesive on its coupling surface, around the geometrical projection of the incision made on the carrier ribbon, for defining the closed perimeter of the adhesive label-valve strippable off the antiadherent carrier ribbon, and at least a cut secant to the geometrical projection of the definition perimeter of the central island portion of the underlying antiadherent carrier ribbon. Of course, the order of execution of the incisions in one and in other plastic ribbons may also be inverted.
[0011] The laminated article so prepared, whether in the form of a ribbon or of a continuous sheet that would be successively sliced to form several distinct feed ribbons is rewound in a roll.
[0012] A continuous ribbon of adhesive label-valves, one after the other, may be commonly unwound in an automated station of application of the adhesive label-valve onto a continuous sheet of hot weldable plastic film with which the airtight packages will be formed. Commonly, a suction cup comes to bear over the back of an adhesive label-valve, holding it during its lift-off the carrier ribbon. This determines the lifting off of label-valve from the carrier ribbon, carrying with it, onto the surface covered with a layer of pressure activated adhesive, the island portion incided in the carrier ribbon. The pick-up arm aligns the label-valve precisely above one of the holes formed in the flexible film of hot weldable material, and finally presses the adhesive label-valve thereon such that the central island portion of carrier ribbon carried with it overlies the hole amply exceeding its perimeter.
[0013] Should, inside the hot sealed package develop an overpressure exceeding a given threshold, the cut secant the projection of the perimeter of the central shielding island of foodstuff compatible flexible plastic carrier sheet that covets the hole in the flexible film of the package provide a preferential failure path of adhesive of the cut edges (part of which extend over the antiadherent central membrane) which causes the release of pressurized gas and vapors reliving the pressure inside the package.
[0014] The threshold of inner overpressure beyond which release of pressurized vapors occurs is set by the adhesive property of the pressure activated adhesive used and characteristics of adhesion of the interested surfaces, by absolute or relative sizing of the different parts that composed the adhesive label-valve (perimeters of definition of the anti adhesive central island portion of carrier ribbon and of the adhesive label-valve dimensions and position and length of the cut secant to the projected perimeter of the central island piece and of the adhesive label-valve, number of secant cuts if more than one) that is applied on the surface of the flexible plastic film used for forming the hut sealed package.
[0015] Preferably the incision of the flexible adhesive label-valve and of the secant cut or cuts of release of the inner overpressure out of then package, may be done using a tool including also arcuated cutters to produce witness incisions for providing an immediate visual check of the integrity of the package, according to common practices in the field.
Fig-1 shows schematically the basic steps and aspects of the process of the present disclosure.
Fig. 2A, 2B and 2C are layout views from above and from below and a cross section of an exemplary embodiment of the adhesive label-valve of the present disclosure.
Fig. 3A, 3B and 3C are layout views from above, from below and in cross section of an alternative exemplary embodiment of adhesive label-valve of the present disclosure.
Fig. 4 and 5 are layout view from above of other exemplary embodiments of adhesive label valves of the present disclosure.
[0016] The ensuing description of several exemplary embodiment of this invention with reference to the attached drawings, has only illustrative purposes and is not intended to limit the innumerable alternative embodiments of the adhesive label-valves made according to the method of the present invention, as would be evident to an expert reader.
[0017] Generally, the carrier film may be of material safe to come in contact with food belonging to the group composed of polypropylene (for example of thickness comprised between about 35 pm and about 60 pm), polyester (for example of thickness comprised between about 25 pm and about 45 pm or of material having equivalent characteristics), the coupling surface of which may be commonly treated with a silicone to make it non adherent or limitately so.
[0018] Also the film used for making the adhesive label may be of material belonging to the group composed of polypropylene (for example of thickness comprised between about 35 pm and about 60 pm), polyester (for example of thickness comprised between about 25 pm and about 45 pm) or of any other material having equivalent characteristics, multilayer laminates of the same materials or singularly coupled with a film of a polyamide (for example of thickness comprised between about 10 pm and about 20 pm).
[0019] The adhesive applied onto the bonding surface of the plastic film of the adhesive label may be a common aqueous base acrylic adhesive or UV reticulating acrylic adhesive mix or an acrylic resin mix in an organic solvent.
[0020] Referring to Fig. 1, a multilayer laminated ribbon 1 composed of a carrier film/adhesive layer/label film unwound from a feed roll E, is subjected to a first incision of only the label film such to define the perimeter of the adhesive label 2 to be eventually lifted off the non adherent carrier film C, and to produce at least a cut 3 within the area defined by the perimetral incision of the label 2. Optionally, more than one arcuated cuts 5 may also be incised, relatively short and spaced from one another and generally distributed uniformly along an inner circumference or perimeter in respect to the outer circumference or perimeter of definition of the adhesive label 2. These optional arcuated cuts (incisions) constitute effective witnesses of integrity (becoming irremediably distorted in case of malicious attempts to remove the adhesive label from the surface on which it will be eventually be applied).
[0021] In a second operating station of the fabrication line, (of course the order of the two incision steps may be inverted), the continuous laminated ribbon 1 is subjected to a second incision on the opposite surface to that of the first incision step, of only the carrier film such to define a island 4 more or less centered in respect to the incided perimeter of the label 2 and such that the definition perimeter of such a incised central island 4 of the carrier film projectively intersecates the cut (or cuts) 3 formed through the thickness of the film of definition of the label 2, remaining contained within the circumference or perimeter along which may be present arcuated integrity witness cuts 5.
[0022] In the shown example, the process may contemplates detachment and disposal of the waste portion of the film with adhesive layer of definition of the labels 2, which may be lifted off the non adherent carrier ribbon C carrying the adhesive label-valves so formed, which may than be rewound in a roll EV. As may be observed, the wasted material is effectively minimized by purposely sizing the width of the carrier film C.
[0023] The EV roll will than be used as feed roll in a common automated station of application of the adhesive label-valves singularly lifted-off the carrier ribbon C, precisely over holes formed in the continuous ribbon of hot weldable flexible plastic film with which will be formed the airtight packages.
[0024] In Fig. 2A, 2B and 2C is illustrated by a layout view from above, a layout view from below and a cross sectional view, an exemplary embodiment of the structure of adhesive label-valve as defined with the novel fabrication process of the present invention.
[0025] A possible alternative embodiment of adhesive label-valve fabricated with the fabrication process of the present invention is illustrated in Fig. 3A 3B and 3C. According to this alternative embodiment, beside a different geometry of the central island portion 4 of the non adherent carrier film C, the view from below shows that in the two zones of incision of the cuts 3 of favored opening of the relief valve device upon exceeding the maximum limit of inner overpressure, the "breaking open" of the label-valve device may be facilitated by freeing from adhesive the two zones 6.
[0026] Fig. 4 and 5 are layouts views from above of other exemplary embodiments of adhesive label-valves made according to the present invention, which may obviously be made in innumerable other geometrical shapes and sizes.
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.
Patent documents cited in the description • JP2006298410A fGOOSi • AU200621977QA1 (0005] • WQ2006107974A1 iOOOSl • WQ2004106557A2 [0005] • EP1'! 57942A1 [0005] • US20060030472A [00051

Claims (7)

1. Fremgangsmåde til fremstilling af fleksible klæbende ventil-labels (EV), som kan tages af et første blad eller bånd (C) med en antiklæbende koblingsflade, som er tilpasset således, at de lægges fladt an mod den udvendige overflade af en fleksibel film af en lufttæt emballage til forsegling af en åbning gennem den fleksible emballagefilm til udløsning af et indvendigt overtryk, omfattende trinnene: a) at koble det første blad eller bånd (C) af et polymermateriale, som kan anvendes sammen med fødevareemballage, med et andet blad eller bånd (E) af et polymermateriale, egnet til emballering af fødevarer, med et lag af et trykaktiveret klæbemiddel på dets koblingsflade til dannelse af en lamineret artikel (C+E); b) at fremstille på den laminerede artikel (C+E) et første snit af udelukkende det første blad eller bånd (C), som definerer perimeteren af et delområde (4) af en størrelse tilpasset til at lukke for trykudløsningsåbningen gennem emballagefilmen, et andet snit af udelukkende det andet blad eller bånd (E), som definerer perimeteren (2) af en ventil-label (EV), som kan rives af det første blad eller bånd (C) omkring snitdelområdet (4), og mindst et tredje snit (3) af udelukkende det andet blad eller bånd (E) af en sekant af det geometriske fremspring af perimeteren af snitdelområdet (4) at det underliggende første blad eller bånd (C); c) hvilken ventil-label (EV), som bærer snitdelområdet (4) af det første blad eller bånd (C), løftes af det første blad eller bånd (C) og påføres den udvendige overflade af den fleksible emballagefilm og lukker for udløsningsåbningen som en ikke-klæbende membran og forhindrer, at klæbemidlet kommer i kontakt med emballagens indhold.A method of producing flexible adhesive valve labels (EV) which can be taken by a first blade or band (C) having an anti-sticking coupling surface adapted to be flattened against the outer surface of a flexible film an airtight package for sealing an opening through the flexible packaging film to release an internal overpressure, comprising the steps of: a) coupling the first sheet or band (C) of a polymeric material which can be used with food packaging with a second sheet or strip (E) of a polymeric material suitable for food packaging with a layer of a pressure-activated adhesive on its coupling surface to form a laminated article (C + E); b) producing on the laminated article (C + E) a first section of only the first blade or strip (C) defining the perimeter of a subarea (4) of a size adapted to close the pressure release opening through the packaging film, a second one; section of exclusively the second blade or band (E) defining the perimeter (2) of a valve label (EV) which can be torn by the first blade or band (C) around the section portion area (4), and at least a third section (3) of only the second blade or band (E) of a secant of the geometric projection of the perimeter of the section portion (4) to the underlying first blade or band (C); c) which valve label (EV) carrying the section portion (4) of the first blade or band (C) is lifted by the first blade or band (C) and applied to the outer surface of the flexible packaging film and closes the release opening as a non-adhesive membrane and prevents the adhesive from coming into contact with the contents of the packaging. 2. Fremgangsmåde ifølge krav 1, hvorved perimeteren af udskæringen, der definerer delpositionen af det første blad eller bånd (C), omgiver perimeteren (2) af trykudløsningsåbningen gennem emballagefilmen.The method of claim 1, wherein the perimeter of the cut defining the sub-position of the first blade or band (C) surrounds the perimeter (2) of the pressure release port through the packaging film. 3. Fremgangsmåde ifølge krav 1, yderligere omfattende dannelsen af tæthedsoverskridelsevisningssnit (5) gennem det andet blad eller bånd (E) i et område geometrisk afgrænset af perimeteren (2) af ventil-labelen (EV) og fremspringet af perimeteren af den underliggende membrandel (4) af det første blad eller bånd (C).The method of claim 1, further comprising the formation of density overrun section (5) through the second blade or band (E) in a region geometrically bounded by the perimeter (2) of the valve label (EV) and the projection of the perimeter of the underlying membrane portion ( 4) of the first leaf or band (C). 4. Fremgangsmåde ifølge krav 1, hvorved det tredje snit eller snit (3) af en sekant af det geometriske fremspring af perimeteren af den underliggende del (4) af det første blad eller bånd (C), der føres langs med klæbesiden af den ventil-label (EV), der er taget af, delvist strækker sig i et klæbefrit område af ventil-labelen (EV).The method of claim 1, wherein the third cut or cut (3) of a secant of the geometric projection of the perimeter of the underlying portion (4) of the first blade or band (C) passed along the adhesive side of the valve detachable (EV) label partially extends into an adhesive-free area of the valve label (EV). 5. Fremgangsmåde ifølge krav 1, hvorved det første blad eller bånd (C) er af et materiale, der hører til gruppen bestående af polypropylen med en tykkelse på mellem 35 og 60 pm og polyester med en tykkelse på mellem 25 og 45 pm, og bladets koblingsflade er fremstillet antiklæbende ved påføring af et silikonemateriale.The method of claim 1, wherein the first sheet or band (C) is of a material belonging to the group consisting of polypropylene having a thickness of between 35 and 60 µm and polyester having a thickness of between 25 and 45 µm, and the blade's coupling surface is made anti-adhesive by applying a silicone material. 6. Fremgangsmåde ifølge krav 1, hvorved det andet blad eller bånd (E) af polymermateriale, egnet til emballering af fødevarer, med et lag af trykaktiveret klæbemiddel på koblingsfladen, er af et materiale, som hører til gruppen bestående af polypropylen med en tykkelse på mellem 35 og 60 pm, polyester med en tykkelse på mellem 25 og 45 pm og laminater af de samme materialer sammen og/eller enkeltvis med en polyamidfilm med en tykkelse på mellem 10 og 20 pm.The method according to claim 1, wherein the second sheet or strip (E) of polymer material suitable for food packaging, with a layer of pressure-activated adhesive on the coupling surface, is of a material belonging to the group consisting of polypropylene having a thickness of between 35 and 60 µm, polyester having a thickness of between 25 and 45 µm, and laminates of the same materials together and / or individually with a polyamide film having a thickness of between 10 and 20 µm. 7. Fremgangsmåde ifølge krav 1, hvorved det tryk-aktiverede klæbemiddel er et akrylklæbemiddel i et vandigt eller organisk opløsningsmiddel.The method of claim 1, wherein the pressure-activated adhesive is an acrylic adhesive in an aqueous or organic solvent.
DK10168393.6T 2009-07-09 2010-07-05 A process for the preparation of flexible valve-adhesive labels DK2275252T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITVA2009A000048A IT1394911B1 (en) 2009-07-09 2009-07-09 FLEXIBLE ADHESIVE LABEL-MANUFACTURING PROCEDURE

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DK2275252T3 true DK2275252T3 (en) 2016-03-29

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EP (1) EP2275252B1 (en)
DK (1) DK2275252T3 (en)
ES (1) ES2566017T3 (en)
IT (1) IT1394911B1 (en)
SM (1) SMT201600137B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20140037U1 (en) 2014-01-27 2015-07-27 Masterpack S P A LABELS - SELF-ADHESIVE VALVE
ITUA20164789A1 (en) * 2016-06-30 2017-12-30 Masterpack S P A ADHESIVE VALVE FOR FOOD CONTAINERS
IT201900005698A1 (en) 2019-04-12 2020-10-12 Masterpack S P A Adhesive valve, foil and food container, support and process for making this adhesive valve or foil
IT201900005678A1 (en) 2019-04-12 2020-10-12 Masterpack S P A Adhesive valve, foil and food container, support and process for making this adhesive valve or foil
IT202000009742A1 (en) 2020-05-04 2021-11-04 Masterpack S P A ADHESIVE VALVE, SHEET AND FOOD CONTAINER, AND A PROCESS FOR MANUFACTURING THESE ADHESIVE VALVE OR SHEET
IT202000016132A1 (en) 2020-07-03 2022-01-03 Masterpack S P A ANTI-PACKING ADHESIVE VALVE, SHEET INCLUDING IT, AND FOOD CONTAINER FORMED WITH THIS SHEET, AND A PROCEDURE FOR MANUFACTURING THEM

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2927722A (en) * 1954-11-10 1960-03-08 Melvin R Metzger Vacuum type valve-equipped containers
US3694287A (en) * 1969-07-11 1972-09-26 Edward C Marshall Pressure sensitive label strip construction and method of making same
US5989608A (en) 1998-07-15 1999-11-23 Mizuno; Maki Food container for cooking with microwave oven
EP1157942A1 (en) 2000-05-22 2001-11-28 KIM, Bang Hyun Packaging for cooking food, having a pressure control system
WO2005000706A1 (en) 2003-05-30 2005-01-06 Avery Dennison Corporation Food bag release valve
US7244223B2 (en) * 2003-05-30 2007-07-17 Avery Dennison Corporation Food bag release valve
GB0504418D0 (en) 2005-03-03 2005-04-06 Ffp Packaging Solutions Ltd Self-venting cover for heatable food package
US7837387B2 (en) 2005-04-06 2010-11-23 Avery Dennison Corporation Evacuatable container
JP2006298410A (en) 2005-04-19 2006-11-02 Masao Ogushi Degassing valve label, and its manufacturing method

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EP2275252A1 (en) 2011-01-19
ITVA20090048A1 (en) 2011-01-10
SMT201600137B (en) 2016-07-01
ES2566017T3 (en) 2016-04-08
EP2275252B1 (en) 2015-12-23
IT1394911B1 (en) 2012-07-20

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