DK2150403T3 - Varmeisolerende strukturer - Google Patents

Varmeisolerende strukturer Download PDF

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Publication number
DK2150403T3
DK2150403T3 DK08737136.5T DK08737136T DK2150403T3 DK 2150403 T3 DK2150403 T3 DK 2150403T3 DK 08737136 T DK08737136 T DK 08737136T DK 2150403 T3 DK2150403 T3 DK 2150403T3
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DK
Denmark
Prior art keywords
contain
phenolic resin
structure according
layer
outer layer
Prior art date
Application number
DK08737136.5T
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English (en)
Inventor
Simon Harry Shepherd
Peter John Mellersh
Original Assignee
Advanced Insulation Ltd
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Publication of DK2150403T3 publication Critical patent/DK2150403T3/da

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/02Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/028Composition or method of fixing a thermally insulating material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B2038/0052Other operations not otherwise provided for
    • B32B2038/0076Curing, vulcanising, cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/105Ceramic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0285Condensation resins of aldehydes, e.g. with phenols, ureas, melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/206Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/542Shear strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971Preformed hollow element-containing
    • Y10T428/249974Metal- or silicon-containing element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249986Void-containing component contains also a solid fiber or solid particle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • Y10T428/24999Inorganic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • Y10T428/249991Synthetic resin or natural rubbers

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Thermal Insulation (AREA)

Claims (14)

1. Varmeisoleringsstruktur, som påføres et substrat til brug under vandet, hvor strukturen indeholder et fleksibelt indvendigt bindelag, som kan forbindes med substratet, hvor bindelaget er reaktionsproduktet af et første materiale, som indeholder en koldhærdende phenolharpiks, og et andet materiale, som indeholder en partiel phosphatester; et skumisolerende lag, som er reaktionsproduktet af en koldhærdende syntetisk phenolharpiks og en partiel phosphate-ster, og som indeholder mellem 15 og 30% glascenospherer og op til 20% af en nitrilbutadien-gummiblødgøringsmiddel, og et udvendigt beskyttende lag, som er reaktionsproduktet afen koldhærdende harpiks og en partiel phospha-tester.
2. Struktur ifølge krav 1, hvor bindelagets første materiale indeholder mellem 0,5 og 2,5% af silan-koblingsmidlet, og det isolerende lag og/eller udvendige lag kan indeholde op til 2,5% af silan-koblingsmidlet.
3. Struktur ifølge et hvilket som helst af de foregående krav, hvor bindelagets første materiale indeholder 50 - 75 vægt% phenolharpiks, og kan indeholde 65 - 70% phenolharpiks.
4. Struktur ifølge et hvilket som helst af de foregående krav, hvor phenolhar-piksen af bindelagets første materiale er en resol-phenolharpiks, kan have et vandindhold, der ikke er større end 16%, og/eller kan indeholde op til 2% et-handiol som blødgører.
5. Struktur ifølge et hvilket som helst af de foregående krav, hvor bindelagets første materiale indeholder op til 2% af et anti-perlingmiddel, kan indeholde mellem 1 og 4% røget silica, kan indeholde mellem 15 og 30% cenospherer, og kan nærmere bestemt indeholde mellem 23 og 28% cenospherer.
6. Struktur ifølge et hvilket som helst af de foregående krav, hvor cenosphere-skallerer en blanding af hvilken som helst af zirconium-, titan-, aluminium- eller jernoxider, og hvor cenosphererne kan have SG på mellem 0,005 og 0,02.
7. Struktur ifølge et hvilket som helst af de foregående krav, hvor bindelagets andet materiale indeholder hvilken som helst af: mellem 90 og 98% partiel phosphatester; op til 1% sulfonsyre som hærdningsaccelerator; og/eller op til 10% vand.
8. Struktur ifølge et hvilket som helst af de foregående krav, hvor hvilken som helst af: forholdet af første til andet materiale af bindelaget er mellem 5:1 og 10:1; forholdet af isolerende lag af første materiale til andet materiale er mellem 4:1 og 10:1; og/eller forholdet af første til andet materiale i det udvendige lag er mellem 10:1 og 20:1.
9. Struktur ifølge et hvilket som helst af de foregående krav, hvor : det isolerende lag af det første materiale indeholder mellem 35 og 75% phenolharpiks, og nærmere bestemt kan indeholde mellem 50 og 70% phenolharpiks; hvor phenolharpiksen af det isolerende lag af det første materiale kan være en re-sol-phenolharpiks; og/eller kan have et vandindhold, der ikke er større end 16%.
10. Struktur ifølge et hvilket som helst af de foregående krav, hvor det isolerende lag af det første materiale indeholder op til 7% diethyl-phosphonat som blødgører, og kan indeholde mellem 6 og 6.5% diethyl-phosphonat som blødgører.
11. Struktur ifølge et hvilket som helst af de foregående krav, hvor det isolerende lag af det første materiale indeholder: op til 2,5% af silan-koblingsmidlet; kan indeholde op til 5% glasstrenge, som kan være mellem 3 og 12mm lange, og kan være mellem 5 og 7mm lange; og kan indeholde op til 5% zirconiumdi-oxidfibre.
12. Struktur ifølge et hvilket som helst af de foregående krav, hvor det isolerende lag af andet materiale indeholder op til 3% para toluolsulfonsyre som hærdningsaccelerator; og kan indeholde vand.
13. Struktur ifølge et hvilket som helst af de foregående krav, hvor: det udvendige lag af det første materiale indeholder mellem 50 og 100% phenolharpiks, og kan indeholde mellem 63 og 69% phenolharpiks, phenolharpiksen af det udvendige lag af det første materiale kan være en resol-phenolharpiks; phenolharpiksen af det udvendige lag af det første materiale kan have et vandindhold, der ikke er større end 16%; det udvendige lag af det første materiale kan indeholde op til 2,5% af et silankoblingsmiddel; det udvendige lag af det første materiale kan indeholde op til 1% ethandiol; og/eller det udvendige lag af det første materiale kan indeholde op til 4% røget silica.
14. Struktur ifølge et hvilket som helst af de foregående krav, hvor fiberforstærkning indeholdes i det udvendige lag, og fibrene kan være af glas, Kevlar eller carbon.
DK08737136.5T 2007-05-02 2008-04-30 Varmeisolerende strukturer DK2150403T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0708471A GB2448901A (en) 2007-05-02 2007-05-02 Thermal Insulation Structure
PCT/GB2008/001498 WO2008135724A2 (en) 2007-05-02 2008-04-30 Thermal insulating structures

Publications (1)

Publication Number Publication Date
DK2150403T3 true DK2150403T3 (da) 2018-10-29

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US (1) US9067382B2 (da)
EP (1) EP2150403B1 (da)
DK (1) DK2150403T3 (da)
ES (1) ES2691648T3 (da)
GB (2) GB2448901A (da)
WO (1) WO2008135724A2 (da)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014014723A2 (en) * 2012-07-17 2014-01-23 Momentive Specialty Chemicals Inc. Flame resistant composite structure
DE102012109704A1 (de) * 2012-10-11 2014-04-17 Epcos Ag Keramisches Bauelement mit Schutzschicht und Verfahren zu dessen Herstellung
US10550220B2 (en) 2015-03-19 2020-02-04 Zephyros, Inc. Esterified acids for use in polymeric materials

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US3787351A (en) * 1972-02-28 1974-01-22 Minnesota Mining & Mfg Use of soluble fluoroaliphatic oligomers in resin composite articles
GB2150495B (en) 1983-11-25 1987-04-08 Bristol Composite Mat Structural panel
US4595623A (en) * 1984-05-07 1986-06-17 Hughes Aircraft Company Fiber-reinforced syntactic foam composites and method of forming same
GB9312926D0 (en) * 1993-06-23 1993-08-04 Alderley Materials Ltd Duplex and sandwich fire resistant materials and fire protective coatings from lightweight cold curing syntactic foams
US5665295A (en) * 1994-08-04 1997-09-09 Teijin Limited Process for the production of composite molded article
US6058979A (en) * 1997-07-23 2000-05-09 Cuming Corporation Subsea pipeline insulation
EP1090066A1 (en) * 1998-05-01 2001-04-11 Textron Systems Corporation Epoxy-syntactic-foam-insulated metal pipes
JP3243461B2 (ja) * 1999-07-30 2002-01-07 川崎重工業株式会社 サンドイッチ構造
CA2399736A1 (en) 2000-02-07 2001-08-16 Nagoya Oilchemical Co., Ltd. A molding material and a molded article
AUPQ824100A0 (en) * 2000-06-20 2000-07-13 De Toffol, Roberto A method of manufacturing syntactic foam
GB2391600B (en) * 2001-04-27 2005-09-21 Fiberspar Corp Buoyancy control systems for tubes
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US7087703B2 (en) * 2004-07-26 2006-08-08 Georgia-Pacific Resins, Inc. Phenolic resin compositions containing etherified hardeners
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Publication number Publication date
WO2008135724A3 (en) 2009-04-02
EP2150403B1 (en) 2018-08-01
US20100129637A1 (en) 2010-05-27
GB0708471D0 (en) 2007-06-06
EP2150403A2 (en) 2010-02-10
GB2463813B (en) 2012-01-04
GB0920841D0 (en) 2010-01-13
WO2008135724A2 (en) 2008-11-13
GB2448901A (en) 2008-11-05
GB2463813A (en) 2010-03-31
US9067382B2 (en) 2015-06-30
ES2691648T3 (es) 2018-11-28

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