DK163978B - PROCEDURES AND PLANTS FOR CONTINUOUS HEATING AND PACKAGING OF A PUMPY FOOD PRODUCT - Google Patents
PROCEDURES AND PLANTS FOR CONTINUOUS HEATING AND PACKAGING OF A PUMPY FOOD PRODUCT Download PDFInfo
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- DK163978B DK163978B DK240287A DK240287A DK163978B DK 163978 B DK163978 B DK 163978B DK 240287 A DK240287 A DK 240287A DK 240287 A DK240287 A DK 240287A DK 163978 B DK163978 B DK 163978B
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- DK
- Denmark
- Prior art keywords
- product
- chamber
- pressure
- packaging
- conduit
- Prior art date
Links
- 238000004806 packaging method and process Methods 0.000 title claims description 32
- 235000013305 food Nutrition 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 17
- 238000010438 heat treatment Methods 0.000 title claims description 16
- 238000011049 filling Methods 0.000 claims description 14
- 230000001954 sterilising effect Effects 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims 4
- 229920002457 flexible plastic Polymers 0.000 claims 1
- 238000012856 packing Methods 0.000 claims 1
- 239000002985 plastic film Substances 0.000 claims 1
- 238000010791 quenching Methods 0.000 claims 1
- 230000000171 quenching effect Effects 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000009924 canning Methods 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 235000013547 stew Nutrition 0.000 description 2
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 235000002568 Capsicum frutescens Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 238000005276 aerator Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000009459 flexible packaging Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/02—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by heating materials in packages which are progressively transported, continuously or stepwise, through the apparatus
- A23L3/04—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by heating materials in packages which are progressively transported, continuously or stepwise, through the apparatus with packages on endless chain or band conveyors
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/003—Control or safety devices for sterilisation or pasteurisation systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
- B65B55/02—Sterilising, e.g. of complete packages
- B65B55/12—Sterilising contents prior to, or during, packaging
- B65B55/14—Sterilising contents prior to, or during, packaging by heat
Description
DK 163978 BDK 163978 B
Den foreliggende opfindelse angår et anlæg af den i indledningen til krav 1 angivne art og en fremgangsmåde af den i indledningen til krav 9 angivne art til opvarmning, emballering og sterilisation af pumpelige, partikelformige 5 fødevareprodukter.The present invention relates to a plant of the kind set forth in the preamble of claim 1 and to a method of the kind set forth in the preamble of claim 9 for heating, packaging and sterilizing pumpable particulate food products.
Dåsekonservering af fødevareprodukter såsom supper, gryderetter, chilier og andre emner er sædvanlige og veletablerede processer. En almindelig klage over sådanne dåsefødevarer angår imidlertid den unaturlige smag, der må tilskri-10 ves dåsekonserveringsprocesserne. Det vil sige, at det er absolut væsentligt, at disse produkter steriliseres tilstrækkeligt for at undgå ødelæggelse, og som en følge heraf har man ved behandlingen været tilbøjelig til at overkoge produkterne for at sikre korrekt sterilisation. Dette skaber igen 15 den overkogte, unaturlige smag, der er karakteristisk for så mange konserves.Cans canning food products such as soups, casseroles, chilies and other items are common and well-established processes. However, a common complaint about such canned foods concerns the unnatural taste that must be attributed to the canning processes. That is, it is essential that these products are sufficiently sterilized to avoid destruction, and as a result, the treatment has tended to overcook the products to ensure proper sterilization. This in turn creates the overcooked, unnatural taste characteristic of so many preserves.
US patentskrift nr. 3.241.475 omhandler en dåsekonserveringsprocedure, der er noget forskellig fra den konventionelle metode. Fremgangsmåden og apparatet, der er be-20 skrevet i dette patentskrift, er blevet udnyttet kommercielt i et antal år som den såkaldte "Flash 18" proces. Ved denne metode pumpes en fødevare, som skal behandles, først gennem et par serieforbundne, ovenstrøms tilførselspumper af vin-getypen, hvorpå produktet enten passerer gennem en indirekte 25 varmevekslerkogeenhed eller gennem en zone med dampinjektion.U.S. Patent No. 3,241,475 discloses a can preservation procedure somewhat different from the conventional method. The method and apparatus described in this patent have been used commercially for a number of years as the so-called "Flash 18" process. In this method, a food to be processed is first pumped through a pair of series-connected, upstream wine-type feed pumps, on which the product either passes through an indirect heat exchanger unit or through a vapor injection zone.
Derpå kan der tilsættes yderligere fugtighed til produktet, og det føres gennem endnu en modtrykspumpe af vingetypen.Then additional moisture can be added to the product and passed through yet another wing-type pump.
På dette tidspunkt kan produktet passere gennem en lynafluf-ter med henblik på at sænke produkttrykket og -temperaturen, 30 hvorpå produktet passerer gennem en fjerde pumpe af vingetypen og ledes til et emballeringskammer. Selve emballeringskammeret har form som en forholdsvis stor, undertryk stående bygning, der rummer dåsekonserveringsudstyr og anlægspersonel. I kammeret fyldes produktet fra aflufteren 35 på dåser på den sædvanlige måde og sendes så til en steriliserings- og afkølingsstation udvendigt for kammeret.At this point, the product may pass through a lightning aerator to lower the product pressure and temperature, whereupon the product passes through a fourth wing-type pump and is directed to a packaging chamber. The packaging chamber itself takes the form of a relatively large, suppressed standing building containing canning equipment and plant personnel. In the chamber, the product from the vent 35 is filled into cans in the usual manner and then sent to a sterilization and cooling station outside the chamber.
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22
Mens den beskrevne "Flash 18" proces har været i brug i et antal år, frembyder den et antal problemer med hensyn til produktsammenhæng, navnlig når det drejer sig om produkter indeholdende store partikler. Specielt skaber 5 brugen af flere pumper af vingetypen til fremdrivning af produktet gennem behandlingsledningen og etablering af modtryk inden i denne uundgåeligt væsentlige trykvariationer og en uensartet trykgradient gennem produktledningen. Som en følge heraf må der med henblik på at undgå førtidig brat-10 kogning (flashing) af produktet være en væsentlig trykforskel mellem damptrykket inden i de indirekte varmevekslerkapper eller som injiceret og produkttrykket. I praksis har denne trykforskel været i området fra 1,0 til 1,4 atm. Ydermere er det, for så vidt som denne høje trykforskel etableres inden 15 i produktledningen, i de fleste tilfælde nødvendigt at lyn-aflufte produktet før det kommer ind i det under tryk stående fyldekammer. En sådan afluftning frembyder naturligvis en anden zone med hurtig trykændring inden i produktledningen ovenstrøms for fyldekammeret og kan i og for sig forringe 20 partikelsammenhængen.While the described "Flash 18" process has been in use for a number of years, it presents a number of problems with regard to product cohesion, especially in the case of products containing large particles. In particular, 5 creates the use of multiple wing-type pumps to propel the product through the treatment line and establish back pressure within this inevitably significant pressure variation and a uniform pressure gradient through the product line. As a result, in order to avoid premature flashing of the product, there must be a significant pressure difference between the vapor pressure within the indirect heat exchanger caps or as injected and the product pressure. In practice, this pressure difference has been in the range of 1.0 to 1.4 atm. Furthermore, insofar as this high pressure difference is established before 15 in the product line, in most cases it is necessary to lightly vent the product before entering the pressurized filling chamber. Such venting, of course, provides another zone of rapid pressure change within the product conduit upstream of the filling chamber and can in itself impair the particle coherence.
Den foreliggende opfindelses formål er at tilvejebringe et anlæg af den i indledningen til krav i angivne art og en fremgangsmåde af den i indledningen til krav 9 angivne art, med hvilke man undgår disse problemer, og med hvilke 25 fødevareproduktet uden brug af indskudte pumper og uden risiko for overkogning og bratkogning med de deraf følgende ulemper såsom sprængning af større partikelformige bestanddele af fødevareproduktet og andre organoleptiske forringelser af dette kan føres fra pumpen gennem produktafgivel-30 sesledningen til dennes åbne afgivelsesende.The object of the present invention is to provide a plant of the kind set forth in the preamble of claims of the kind and a method of the kind set forth in the preamble of claim 9 with which to avoid these problems and with which the food product without the use of inserted pumps and without risk of overcooking and boiling with the resulting disadvantages such as bursting of larger particulate constituents of the food product and other organoleptic degradations thereof can be passed from the pump through the product delivery line to its open release end.
Dette opnås for anlæggets vedkommende ved det i den kendetegnende del af krav l angivne og for fremgangsmådens vedkommende ved det i den kendetegnende del af krav 9 angivne.This is achieved in the case of the plant by the characterizing part of claim 1 and by the method of the characterizing part of claim 9.
35 Herved føres fødevareproduktet gennem produktafgivel sesledningen som en i hovedsagen sammenhængende prop under35 Hereby, the food product is passed through the product delivery line as a substantially continuous plug underneath.
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3 jævnt aftagende tryk, uden at der kan forekomme nogen dampudvikling i eller fra produktet, idet overtrykket i kammeret, der let kan styres efter behov, tilvejebringer det hertil nødvendige modtryk.3, evenly decreasing pressure without any vapor evolution in or from the product, the overpressure in the chamber, which can be easily controlled as required, provides the necessary back pressure.
5 Foretrukne træk hos anlægget ifølge opfindelsen er angivet i de uselvstændige krav 2 til 8, og en foretrukken foranstaltning i forbindelse med fremgangsmåden ifølge opfindelsen er angivet i det uselvstændige krav 10.Preferred features of the plant according to the invention are set out in the dependent claims 2 to 8, and a preferred measure in connection with the method according to the invention is set out in the dependent claim 10.
Opfindelsen skal i det følgende beskrives nærmere, 10 idet der henvises til tegningen, på hvilken fig. 1 viser en noget skematisk perspektivisk gengivelse af et opvarmnings-, emballerings- og steriliseringsanlæg ifølge den foreliggende opfindelse, fig. 2 en skematisk, lodret snitgengivelse visende 15 det emballeringskammer, der udgør en del af det i fig. 1 gengivne anlæg, og fig. 3 en gengivelse svarende til den i fig. 2 viste men afbildende et emballeringskammer rummende konventionelt udstyr til fyldning og forsegling af konservesdåser i mod-20 sætning til det i fig. 2 viste udstyr til formning, fyldning og forsegling af emballager af bøjelig folie.The invention will now be described in more detail, with reference to the drawing, in which 1 is a somewhat schematic perspective view of a heating, packaging and sterilizing system of the present invention; FIG. 2 is a schematic, vertical sectional view showing the packaging chamber forming part of the embodiment of FIG. 1, and FIG. 3 is a view similar to that of FIG. 2, but depicting a packaging chamber containing conventional equipment for filling and sealing canisters in contrast to the one shown in FIG. 2 for forming, filling and sealing flexible foil packaging.
På tegningen omfatter et anlæg 10 ifølge opfindelsen generelt forklaret en ovenstrøms produktopvarmningsenhed 12, et emballeringskammer 14, der kan sættes under tryk, en 25 kontinuerlig koger/køler 16, der er funktionelt koblet til kammeret 14, og en produktafgivelsesledning 18.In the drawing, a plant 10 according to the invention generally comprises an upstream product heating unit 12, a pressurized packaging chamber 14, a continuous boiler / cooler 16 which is functionally coupled to the chamber 14, and a product delivery line 18.
Mere detaljeret indbefatter enheden 12 en ovenstrøms dobbeltstempelfødevarepumpe 20, som er udformet til at kunne fungere med en konstant strømningshastighed og afgive en 30 kontinuerlig strøm af et fødevareprodukt. Den afbildede pumpe er af den art, der markedsføres af Marlen Research Corporation i Overland Park, Kansas, USA til partikelformige fødevareprodukter. Der er ligeledes tilvejebragt et par produktkedler 22 og 24 i nærheden af pumpen 20, som ved 35 passende rør 26 og 28 er koblede til pumpens tilgang. På denne måde tilvejebringer kedlerne kooperativt en kontinuer-In more detail, the unit 12 includes an upstream dual piston food pump 20 which is designed to operate at a constant flow rate and deliver a continuous stream of a food product. The pump depicted is of the kind marketed by Marlen Research Corporation in Overland Park, Kansas, USA for particulate food products. A pair of product boilers 22 and 24 are also provided in the vicinity of the pump 20, which are connected to the pump inlet by suitable tubes 26 and 28. In this way, the boilers cooperatively provide a continuous
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4 lig produktstrøm til pumpen på en portions-kontinuerlig basis.4 equal product flow to the pump on a batch continuous basis.
Den ovenstrøms ende af ledningen 18 er direkte koblet til afgangen fra pumpen 20. Det indledende afsnit af den 5 samlede ledning 18 er igen koblet til tilgangen til en skematisk gengivet varmeveksler 32 med skrabet overflade. Den sidstnævnte varmeveksler er af den art, der markedsføres af Cherry Burrell Company og omfatter udvendige dampkapper til indirekte opvarmning af produkt, som passerer gennem var-10 meveksleren. Selv om det ikke er udtrykkeligt vist på tegningen, vil det forstås, at der kunne være tilvejebragt én eller flere af disse varmevekslerenheder. Når der anvendes flere enheder, vil disse være forbundet i serie.The upstream end of conduit 18 is directly coupled to the outlet of pump 20. The initial portion of the overall conduit 18 is again coupled to the inlet of a schematically rendered scraper surface 32. The latter heat exchanger is of the kind marketed by the Cherry Burrell Company and includes exterior steam hoods for indirect heating of product passing through the heat exchanger. Although not explicitly shown in the drawings, it will be appreciated that one or more of these heat exchanger units may be provided. When multiple devices are used, these will be connected in series.
I alle tilfælde er ledningen 18 koblet til afgangen 15 fra varmeveksleren 32 og strækker sig som vist til den øvre væg af kammeret 14. Et lodret afgivelsesrør 34 er forbundet med den tilgrænsende ende af ledningen 18 med den åbne ende af røret 34 i forbindelse med det indre af kammeret 14 (se fig. 2) . Ydermere er en produktrecirkuleringsledning 36 20 funktionelt koblet til det lodrette rør 34, og der er tilvejebragt en ventil 38 til at lede produktstrømmen enten nedad gennem røret 34 eller gennem recirkulationsledningen.In all cases, the conduit 18 is coupled to the outlet 15 of the heat exchanger 32 and extends as shown to the upper wall of the chamber 14. A vertical discharge tube 34 is connected to the adjacent end of conduit 18 to the open end of the tube 34 in connection with it. interior of chamber 14 (see Fig. 2). In addition, a product recycling line 36 20 is functionally coupled to the vertical tube 34 and a valve 38 is provided to direct the product flow either downwardly through the tube 34 or through the recycling line.
Af fig. 1 vil det ses, at recirkulationsledningen er udformet til at afgive produkt til hver af kedlerne 22 eller 24 efter 25 ønske, og der er tilvejebragt passende ventiler til dette formål.In FIG. 1, it will be seen that the recirculation line is designed to deliver product to each of the boilers 22 or 24 as desired, and appropriate valves are provided for this purpose.
Kammeret 14 foreligger i form af en opretstående, tætnet, hul konstruktion af en størrelse, der kan rumme emballeringsudstyr, der generelt er angivet ved henvisnings-30 betegnelsen 40 (se fig. 2). I den gengivne form er emballeringsudstyret 40 udformet til at forme, fylde og forsegle fleksible emballager dannet af en kontinuerlig bane 42 af en emballeringsfolie af syntetisk harpiks. Sådant forme-, fylde- og forseglingsudstyr er velkendt og er omhandlet i 35 US-patentskrift nr. 2.160.367, hvortil der herom henvises. Desuden er emballeringsudstyret 40, skønt det ikke er udtryk-The chamber 14 is in the form of an upright, sealed, hollow construction of a size capable of accommodating packaging equipment generally indicated by the reference numeral 40 (see Fig. 2). In the rendered form, the packaging equipment 40 is designed to mold, fill and seal flexible packages formed by a continuous web 42 of a synthetic resin packaging film. Such molding, filling and sealing equipment is well known and is disclosed in U.S. Patent No. 2,160,367, to which reference is made. Furthermore, although not expressive, the packaging equipment is 40
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5 keligt vist, udformet til at fylde de enkelte emballager med nitrogen eller anden indifferent gas, som det kan være ønskeligt, når der er tale om visse fødevareprodukter.5, designed to fill the individual packages with nitrogen or other inert gas, as may be desirable in the case of certain food products.
Det samlede kammer 14 er yderligere udstyret med 5 kraftdrevne organer såsom en luftkompressor 44 til at etablere overatmosfæriske tryktilstande inden i det indre af kammeret. Størrelsen af dette overatmosfæriske tryk varierer med et produkt, der behandles, men vil typisk ligge fra 0,7 til 3,5 ato. En med en ventil forsynet aflastningsledning 10 46 er ligeledes i forbindelse med det indre af kammeret 14 med henblik på at tillade selektiv trykaflastning af kammeret efter behov.The assembled chamber 14 is further equipped with 5 power-driven means such as an air compressor 44 to establish over-atmospheric pressure states within the interior of the chamber. The magnitude of this over-atmospheric pressure varies with a product being treated, but will typically range from 0.7 to 3.5 ato. A valve relief line 10 46 is also connected to the interior of the chamber 14 to allow selective pressure relief of the chamber as required.
Af fig. 1 vil det ses, at der er tilvejebragt en adgangsdør 48 til kammeret 14 med henblik på at tillade 15 selektiv adgang for vedligeholdelsespersonel til det indre af kammeret. Imidlertid er kammeret ikke udformet for normalt arbejde i og omkring det automatiske emballeringsudstyr 40.In FIG. 1, it will be seen that an access door 48 to the chamber 14 is provided to allow 15 selective access for maintenance personnel to the interior of the chamber. However, the chamber is not designed for normal work in and around the automatic packaging equipment 40.
Til dette formål er et styrepanel 50 beliggende uden for kammeret 14 for at tillade operatørstyring af emballerings-20 apparatet 40 uden indtrængning i kammeret 14.For this purpose, a control panel 50 is located outside the chamber 14 to allow operator control of the packaging apparatus 40 without penetration into the chamber 14.
Den kontinuerlige koger/køler 16 er en konventionel enhed af den art, der er beskrevet i en salgsbrochure distribueret af Rexham Company i Rockford, Illinois, USA under betegnelsen "Hydrolock Continuous Cooker/Cooler". Der hen-25 vises herom til denne brochure. Kort forklaret er koger/kø-lerindretningen imidlertid udformet til at modtage indiduelle emballager af fødevareprodukter med henblik på at underkaste disse kortvarig højtemperatursterilisation efterfulgt af køling og trykaflastning til omgivelsernes temperatur og 30 tryk. Af fig. 1 og 2 vil det ses, at et kontinuerligt transportbånd 52 tjener til funktionelt at forbinde det indre kammer 14 og koger/køleren 16. Som vist passerer dette bånd gennem bunden af kammeret 14 (idet der er tilvejebragt en passende, konventionel luftsluse for at opretholde den over-35 atmosfæriske tryktilstand inden i kammeret) med henblik på at modtage og transportere individuelle emballager 54 medThe continuous boiler / cooler 16 is a conventional unit of the kind described in a sales brochure distributed by the Rexham Company in Rockford, Illinois, USA under the designation "Hydrolock Continuous Cooker / Cooler". Reference is made to this brochure. Briefly, however, the boiler / cooler device is designed to receive individual packaging of food products in order to subject these short-term high temperature sterilization followed by cooling and pressure relief to ambient temperature and pressure. In FIG. 1 and 2, it will be seen that a continuous conveyor belt 52 serves to functionally connect the inner chamber 14 and the boiler / cooler 16. As shown, this belt passes through the bottom of the chamber 14 (providing an appropriate conventional airlock to maintain the over-atmospheric pressure state within the chamber) for receiving and transporting individual packages 54 with
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6 fødevareprodukt. Disse emballager transporteres derpå via båndet til koger/køleren for passende yderligere behandling deri.6 food product. These packages are then transported via the belt to the boiler / cooler for appropriate further processing therein.
Selv om der i fig. 1 og 2 er vist et emballeringsap-5 parat 40 udformet til at producere fleksible emballager af posetypen, er opfindelsen ikke begrænset hertil. Specielt kan der om ønsket også tilvebringes et noget større kammer 14a til at rumme konventionelt dåsekonserveringsudstyr 54.Although in FIG. 1 and 2 are shown a packaging apparatus 40 designed to produce flexible packaging of the bag type, the invention is not limited thereto. Specifically, if desired, a somewhat larger chamber 14a may also be provided to accommodate conventional canning equipment 54.
Her strækker det lodrette afgivelsesrør 34 sig igen gennem 10 kammeret 14a1 s øvre væg med den åbne ende af afgivelsesrøret i forbindelse med det indre af kammeret. På lignende måde er et udluftningsrør 46a koblet til kammeret 14a.Here, the vertical delivery tube 34 extends again through the upper wall of the chamber 14a1 with the open end of the delivery tube communicating with the interior of the chamber. Similarly, a vent tube 46a is coupled to the chamber 14a.
Udstyret 54 er udformet til at modtage tomme beholdere 56 gennem en med vinger forsynet luftsluse 58, hvorpå be-15 holderne fyldes ved en station 60 og forsegles ved en station 62. De færdige beholdere passerer så gennem en anden luftsluse 64 til den kontinuerlige koger/køler 16 til nedenstrøms sterilisation og køling.The equipment 54 is designed to receive empty containers 56 through a winged air lock 58, whereupon the containers are filled at a station 60 and sealed at a station 62. The finished containers then pass through another air lock 64 to the continuous boiler. cooler 16 for downstream sterilization and cooling.
Overatmosfæriske trykbetingelser inden i kammeret 20 14a etableres ved hjælp af den kraftdrevne kompressor 44a, som det let vil forstås af fagmanden.Over-atmospheric pressure conditions within the chamber 20 14a are established by the force-driven compressor 44a, as will be readily understood by those skilled in the art.
En særlig fordel ved den foreliggende opfindelse stammer fra den omstændighed, at ledningen 18 står i åben forbindelse med det indre af emballeringskammeret, som kan 25 sættes under tryk. Som en følge heraf skaber de overatmosfæriske trykforhold inden i kammeret modtryksbetingelser inden i ledningen 18, som modvirker strømning af fødevareprodukt. Ledningen (og i givet fald varmevekslerorganerne) er udformet til i samvirke med pumpeanordningen og kammerets 30 trykpålægningsorganer at etablere en i det væsentlige ensartet aftagende trykgradient langs hele længden af ledningen fra pumpeanordningen 20 til afgangsenden af afgivelsesrøret 34. Det skal i denne forbindelse bemærkes, at ledningen 18 er fuldstændig fri for kraftdrevne pumper eller lignende 35 foranstaltninger til at skabe modtryk i skarp kontrast til det anlæg, der er omhandlet i US patentskrift nr. 3.241.475.A particular advantage of the present invention arises from the fact that the conduit 18 is in open communication with the interior of the packaging chamber which can be pressurized. As a result, the over-atmospheric pressure conditions within the chamber create counterpressure conditions within the conduit 18, which discourages food product flow. The conduit (and, where appropriate, the heat exchanger means) is designed to establish, in cooperation with the pumping device and the pressure applying means of the chamber 30, a substantially uniform decreasing pressure gradient along the entire length of the conduit from the pumping device 20 to the outlet end of the delivery tube 34. It should be noted in this connection that line 18 is completely free of power-driven pumps or similar means to create a counter-pressure in sharp contrast to the plant disclosed in U.S. Patent No. 3,241,475.
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77
Dette sikerer ligeledes, at produktstrømmen inden i ledningen 18 i det væsentlige er af proptypen med henblik på at undgå sprængning af partikler.This also ensures that the product flow within the conduit 18 is substantially of the plug type in order to avoid particle bursting.
Det har i praksis vist sig, at der kan opretholdes 5 en ensartet aftagende trykgradient, som ikke varierer mere end ca. 10 procent pr. længdeenhed af ledningen 18 sammenlignet med den samlede gennemsnitsgradient. Det vil sige, at hvis man betragter en hypotetisk situation med en ledning med en effektiv længde på 3 meter og et samlet trykfald 10 mellem afgangen fra pumpen 20 og udledningsenden af røret 34 på 1,4 ato, ville gennemsnitstrykgradienten over hele ledningen 18 være 1,4/3 ato/m eller 0,46 ato/m. Under disse forudsætninger foretrækkes det, at trykgradienten for hver 30 cm (Feet) længde af ledningen 18 inden for denne længde 15 ikke bør variere mere end 10 procent fra det samlede gennemsnit på 0,46 ato/m, eller fra 0,41-0,51 ato/m.In practice, it has been found that a uniform decreasing pressure gradient can be maintained which does not vary more than approx. 10 per cent. length unit of line 18 compared to the overall average gradient. That is, considering a hypothetical situation with a conduit with an effective length of 3 meters and a total pressure drop 10 between the outlet of the pump 20 and the discharge end of the tube 34 of 1.4 ato, the average pressure gradient over the entire conduit 18 would be 1 , 4/3 ato / m or 0.46 ato / m. Under these conditions, it is preferred that the pressure gradient for each 30 cm (Feet) length of line 18 within this length 15 should not vary more than 10 percent from the overall average of 0.46 ato / m, or from 0.41-0. , 51 ato / m.
I de tilfælde, hvor der anvendes indirekte dampfødede varmeveksleranordninger, bør damptrykket af dampen, som tilføres varmevekslerkapperne, være mindst 0,35 atm, og 20 fortrinsvis 0,35-0,7 atm under det tilsvarende produkttryk inden i ledningen 18 og varmeveksleren. På denne måde er det muligt at sikre, at der ikke forekommer nogen uønsket bratkogning (flashing) af produktet, mens man ikke desto mindre holder behandlingsbetingelserne så nænsomme som muligt 25 med henblik på at forøge produktsammenhængen og de organo-leptiske egenskaber af det endelige emballerede materiale.In the case where indirect steam-fed heat exchanger devices are used, the vapor pressure of the steam supplied to the heat exchanger sheaths should be at least 0.35 atm and preferably 0.35-0.7 atm under the corresponding product pressure within line 18 and the heat exchanger. In this way, it is possible to ensure that no unwanted flashing of the product occurs, while still keeping the processing conditions as low as possible in order to increase the product coherence and organoleptic properties of the final packaged material.
Eksemplerexamples
De følgende specielle eksempler på det foretrukne 30 apparatur og foretrukne fremgangsmåder ifølge opfindelsen illustrerer typiske behandlingsmetoder for tre typer fødevareprodukter, som skal opvarmes, emballeres og steriliseres ved anvendelse af det i fig. 1 og 2 viste apparat. I alle tilfælde er pumpen en Marlen A629 dobbeltstempelpumpe, som 35 markedsføres af Marlen Research Corporation i Overland Park,The following particular examples of the preferred apparatus and methods of the invention illustrate typical processing methods for three types of food products to be heated, packaged and sterilized using the method of FIG. 1 and 2. In all cases, the pump is a Marlen A629 double-piston pump, marketed by the Marlen Research Corporation of Overland Park,
Kansas, USA drevet med en konstant strømningshastighed. DerKansas, USA powered at a constant flow rate. there
DK 163978 BDK 163978 B
8 er anvendt to serieforbundne varmevekslere, som er konventionelle enheder med skrabet overflade såsom de, der forhandles af Cherry Burrell Company. Produktledningen fra pumpen til det under tryk stående emballeringskammer er 2 5 tommer (50,8 mm) i diameter og er fri for modtrykspumper og væsentlige strømningsbegrænsninger.8 are used two series connected heat exchangers which are conventional scraped surface units such as those sold by the Cherry Burrell Company. The product line from the pump to the pressurized packaging chamber is 25 inches (50.8 mm) in diameter and is free of back pressure pumps and significant flow restrictions.
I. HACHIS AF HAKKET OKSEKØDI. HACHIS OF CHICKEN BEEF
Opskrift Procent 10 Dobbelthakket okseafpudsning 60,0Recipe Percent 10 Double-chopped beef stew 60.0
Dehydrerede kartofler 12,0Dehydrated potatoes 12.0
Salt 2,0Salt 2.0
Sukker 1,0Sugar 1.0
Krydderier 0,7 15 Vand 24.3 100,0Spices 0.7 15 Water 24.3 100.0
Varmevekslersystemet indstilles til at tilvejebringe vand ved 124°C med en strømningshastighed på 7,3 kg/minut.The heat exchanger system is set to provide water at 124 ° C at a flow rate of 7.3 kg / minute.
20 Derpå suges den blandede, forvarmede hachisopskrift ved tilnærmelsesvis 65° C ind i stempel fyldningskammeret i Mar-lenpumpen og pumpes til varmeveksleren med 7,3 kg/minut. Modtrykket på produktet leveres af det under tryk stående emballeringskammer. Dette kammer holdes ved 1,8 ato, hvilket 25 medfører tilnærmelsesvis 2,5 ato produkttryk ved indgangen til produktrøret fra Marlenpumpen. Der anvendes tilstrækkelig opvarmningsoverflade og længde af holderøret til at tilvejebringe opvarmning fra 65°C til fyldningstemperaturen på 124°C, mens kappeopvarmningsdampen holdes på mindst 0,35 30 atm (og fortrinsvis på 0,35-0,70 atm) under det tilsvarende produkttryk.Then the mixed, preheated hachis recipe at approximately 65 ° C is sucked into the plunger filling chamber of the Marlen pump and pumped to the heat exchanger at 7.3 kg / minute. The back pressure on the product is supplied by the pressurized packaging chamber. This chamber is held at 1.8 ato, which causes approximately 2.5 ato product pressure at the entrance to the product pipe from the Marlen pump. Sufficient heating surface and length of the holding tube are used to provide heating from 65 ° C to the filling temperature of 124 ° C while keeping the jacket heating vapor at least 0.35 30 atm (and preferably 0.35-0.70 atm) under the corresponding product pressure .
På grund af den nøjagtige styring af både modtryk og produktstrømningshastighed, som anlægget tilvejebringer, holder trykforskellen produkttrykket tilstrækkeligt højt 35 til, at det overstiger væskefasedamptrykket ved de temperaturer, produktet kommer ud for ved opvarmningsoverfladenDue to the precise control of both back pressure and product flow rate provided by the plant, the pressure difference keeps the product pressure sufficiently high to exceed the liquid phase vapor pressure at the temperatures reached by the heating surface.
DK 163978 BDK 163978 B
9 under opvarmningsfasen. Derfor kommer man ikke ud for nogen bratkogning (flashing) eller kogning af produktet.9 during the heating phase. Therefore, no flashing or boiling of the product occurs.
Produktet fyldes så ved 124"C i formede, fleksible ustive beholdere. Opvarmet nitrogengas tilsættes kontinuer-5 ligt sammen med produktet til beholderen under fyldnings-og forseglingsperioden for at tilvejebringe en indifferent gasatmosfære af nitrogen.The product is then filled at 124 ° C into shaped, flexible, unstable containers. Heated nitrogen gas is continuously added with the product to the container during the filling and sealing period to provide an inert gas atmosphere of nitrogen.
De fyldte beholdere føres så til et steril isations/af-kølingskammer og holdes i en 124°C dampatmosfære ved 1,8 10 ato i fem minutter for at sikre sterilisation. Efter sterilisation afkøles de under et 1,3 ato tryk, som gradvis reduceres til atmosfæretryk (0 ato) mens produktet køles fra 124 til 100°C. Den endelige sprøjtekøling til 38*0 fuldføres ved atmosfæretryk.The filled containers are then fed to a sterile isation / cooling chamber and kept in a 124 ° C steam atmosphere at 1.8 10 ato for five minutes to ensure sterilization. After sterilization, they are cooled under a 1.3 ato pressure which is gradually reduced to atmospheric pressure (0 ato) while the product is cooled from 124 to 100 ° C. The final spray cooling to 38 * 0 is completed at atmospheric pressure.
1515
II. OKSEGRYDEII. BEEF STEW
Opskrift ProcentRecipe Percent
Okseterninger 29,0Ox Dice 29.0
Kartofler 33,0 20 Gulerødder 10,0 Løg 5,0Potatoes 33.0 20 Carrots 10.0 Onions 5.0
Krydderier 4,5Spices 4.5
Vand 18,5 100,0 25Water 18.5 100.0 25
Opskriften blandes og opvarmes til tilnærmelsesvis 63 “C og suges så fra kedlerne ind i stempelfyldningskammeret i Marlenpumpen. Samtidig indstilles varmeveksleren til at tilvejebringe vand ved 1249C og 7,3 kg/minut. Produktet 30 pumpes til varmevekslerne med 7,3 kg/minut. Modtryk påføres anlægget ved anvendelse af trykket i emballeringskammeret, som holdes ved 2,1 ato. Dette modtryk resulterer i tilnærmelsesvis 2,8 ato ved indgangen fra pumpen til produktrørledningen. Den første varmeveksler med skrabet overflade 35 anvender tilnærmelsesvis 133“C varm damp og den anden tilnærmelsesvis 130“C varm damp for at tilvejebringe en produkt-The recipe is mixed and heated to approximately 63 ° C and then sucked from the boilers into the piston filling chamber of the Marlen pump. At the same time, the heat exchanger is set to provide water at 1249C and 7.3 kg / minute. The product 30 is pumped to the heat exchanger at 7.3 kg / minute. Back pressure is applied to the plant using the pressure in the packaging chamber which is held at 2.1 ato. This back pressure results in approximately 2.8 ato at the inlet from the pump to the product pipeline. The first scraped surface heat exchanger 35 uses approximately 133 ° C of hot steam and the second approximately 130 ° C of hot steam to provide a product.
DK 163978 BDK 163978 B
10 temperatur på 124°C til fyldningskammeret. Produktet fyldes i formede, fleksible, ustive beholdere. Under fyldningsperioden tilsættes opvarmet nitrogengas kontinuerligt sammen med produktet indtil forseglingsperioden.10 of 124 ° C to the filling chamber. The product is filled in shaped, flexible, unstable containers. During the filling period, heated nitrogen gas is continuously added with the product until the sealing period.
5 De fyldte, forseglede beholdere holdes ved 2,1 ato i en 124°C dampatmosfære i seks minutter for at fuldføre sterilisationen. Efter sterilisationen køles beholderne under et tryk på 1,3 ato, som gradvis reduceres til atmosfæretryk (0 ato), mens produktet køles fra 124 til 100°C. Den endelige 10 sprøjtekøling til 38°C udføres ved atmosfæretryk.5 The filled, sealed containers are kept at 2.1 ato in a 124 ° C steam atmosphere for six minutes to complete sterilization. After sterilization, the vessels are cooled under a pressure of 1.3 ato which is gradually reduced to atmospheric pressure (0 ato) while the product is cooled from 124 to 100 ° C. The final 10 spray cooling to 38 ° C is performed at atmospheric pressure.
III. PÆRETERNINGER I FRUGTSAFTIII. FRUIT DUTIES IN FRUIT
Opskrift Procent Pæreterninger (12,5 mm) 80,0 15 14° Brix sucroseopløsning 20,0 100,0Recipe Per cent Pear cubes (12.5 mm) 80.0 15 14 ° Brix sucrose solution 20.0 100.0
Varmevekslersystemet indstilles til at tilvejebringe 96°C varmt vand ved en strømningshastighed på 7,3 kg/minut.The heat exchanger system is set to provide 96 ° C of hot water at a flow rate of 7.3 kg / minute.
20 Så suges den blandede opskrift fra kedelen (ved tilnærmelsesvis 27°C) ind i stempelfyldningskammeret i Marlenpumpen.20 Then the mixed recipe from the boiler (at approximately 27 ° C) is sucked into the piston filling chamber of the Marlen pump.
I den næste stempelcyklus erstattes vandet med produkt under anvendelse af den samme pumpningshastighed. Modtryk på produktet blev leveret af det under tryk stående emballerings-25 kammer, som blev holdt på 0,7 ato. Dette tryk tilvejebringer tilnærmelsesvis 1,4 ato ved rørledningens indgang fra Marlenpumpen. Produktet opvarmes til 96“ C uden at overstige den 115°C damptemperatur, der leveres til varmevekslerne.In the next piston cycle, the water is replaced with product using the same pumping rate. Back pressure on the product was provided by the pressurized packaging chamber which was held at 0.7 ato. This pressure provides approximately 1.4 ato at the pipeline's inlet from the Marlen pump. The product is heated to 96 ° C without exceeding the 115 ° C vapor temperature supplied to the heat exchangers.
Produkt ved 96°C fyldes i formede, ustive beholdere 30 i kammeret ved 0,7 ato. Efter fyldning og forsegling holdes beholderne i en 96°C varm atmosfære ved 0,7 ato i tre minutter for at fuldføre sterilisationsprocessen. Efter sterilisation køles de under et tryk på 0,35 ato, som gradvis reduceres til atmosfæretryk (0 ato) , hvorpå produktet sprøjtekø-35 les til tilnærmelsesvis 38°C.Product at 96 ° C is filled into shaped, unstable containers 30 in the chamber at 0.7 ato. After filling and sealing, the vessels are kept in a 96 ° C hot atmosphere at 0.7 ato for three minutes to complete the sterilization process. After sterilization, they are cooled under a pressure of 0.35 ato which is gradually reduced to atmospheric pressure (0 ato) and the product is then cooled to approximately 38 ° C.
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US06/868,950 US4674267A (en) | 1986-05-30 | 1986-05-30 | Processing and packaging system for flexible containers |
US86895086 | 1986-05-30 |
Publications (4)
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DK240287D0 DK240287D0 (en) | 1987-05-12 |
DK240287A DK240287A (en) | 1987-12-01 |
DK163978B true DK163978B (en) | 1992-04-27 |
DK163978C DK163978C (en) | 1992-09-28 |
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DK240287A DK163978C (en) | 1986-05-30 | 1987-05-12 | PROCEDURES AND PLANTS FOR CONTINUOUS HEATING AND PACKAGING OF A PUMPABLE FOOD PRODUCT |
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US (1) | US4674267A (en) |
EP (1) | EP0247310B1 (en) |
JP (1) | JP2636242B2 (en) |
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AR (1) | AR247165A1 (en) |
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GR (1) | GR3000596T3 (en) |
MX (1) | MX168751B (en) |
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US4993134A (en) * | 1988-05-17 | 1991-02-19 | Ford Motor Company | Making a fractured powder metal connecting rod |
US5228394A (en) * | 1990-11-02 | 1993-07-20 | Kabushiki Kaisha Kobeseikosho | Processing apparatus for food materials |
US5141408A (en) * | 1990-11-09 | 1992-08-25 | Prc | Product pumping apparatus |
US5422130A (en) * | 1992-11-04 | 1995-06-06 | Pressure Pack, Inc. | Commercially sterile food packaging system |
US5797436A (en) * | 1995-06-26 | 1998-08-25 | Oden Corporation | Liquid filling machine technical field |
TW407122B (en) * | 1998-02-19 | 2000-10-01 | Shintaku Kogyo K K | The autoclaving treatment of the plastic container and the apparatus thereof |
EP1909595A4 (en) * | 2005-07-19 | 2009-06-10 | Conagra Foods Inc | Extended refrigerated shelf life mashed potatoes |
ITBO20060275A1 (en) * | 2006-04-13 | 2007-10-14 | Arcotronics Technologies Srl | PACKAGING MACHINE |
NL1031750C2 (en) * | 2006-05-04 | 2007-11-06 | Otb Group Bv | Method and device for sterilizing contact lenses. |
US20090291174A1 (en) * | 2008-03-13 | 2009-11-26 | Portage Plastics Corporation | High pressure pasteurizable/ultra-high pressure sterilizable food processing container and method |
DE102011103767A1 (en) * | 2011-03-01 | 2012-09-06 | Hipp & Co | Filling line with a filler for a vessel and a method for filling vessels |
US20170290358A1 (en) * | 2016-04-08 | 2017-10-12 | John Bean Technologies Corporation | System and method for automated, continuous high temperature sterilization and filling of food products |
KR102091193B1 (en) * | 2018-11-02 | 2020-03-19 | 한영자동포장기계 주식회사 | Spout pouch type liquid filling apparatus having pipe heating structur |
CN109911335A (en) * | 2019-01-31 | 2019-06-21 | 浙江壹草堂生物科技有限公司 | One kind being based on greenhouse gardening culture medium bulking system |
CN110140849A (en) * | 2019-04-24 | 2019-08-20 | 江苏新美星包装机械股份有限公司 | It is a kind of for the continuity super high temperature sterilizing technology containing particle beverage |
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US2029303A (en) * | 1930-08-27 | 1936-02-04 | American Can Co | Apparatus for and method of canning |
US2540120A (en) * | 1941-06-10 | 1951-02-06 | American Can Co | Apparatus for filling and sealing containers |
US2684803A (en) * | 1951-05-08 | 1954-07-27 | American Can Co | Machine for weighing, filling, and sealing products into containers |
US2685520A (en) * | 1951-07-23 | 1954-08-03 | Dole Eng Co James | Apparatus and method for preserving products in sealed containers |
US2870024A (en) * | 1954-12-16 | 1959-01-20 | Dole Eng Co James | Preserving products in sealed containers |
US3138178A (en) * | 1959-10-12 | 1964-06-23 | Martin William Mck | Aseptic canning system |
US3241475A (en) * | 1960-12-27 | 1966-03-22 | Swift & Co | Canning |
US3235388A (en) * | 1963-02-06 | 1966-02-15 | Swift & Co | Method for producing food product |
US3255690A (en) * | 1963-12-30 | 1966-06-14 | Swift & Co | Pressure chamber structure |
US3232770A (en) * | 1965-02-15 | 1966-02-01 | Swift & Co | Method of sterilizing and canning food material |
US3477192A (en) * | 1967-03-02 | 1969-11-11 | American Cyanamid Co | Container filling process |
US3718082A (en) * | 1971-04-20 | 1973-02-27 | S Lipoma | Apparatus for continuous electromagnetic sterilization |
FR2184458A1 (en) * | 1972-05-15 | 1973-12-28 | Thimonnier & Cie | |
SE373022C (en) * | 1973-05-21 | 1976-12-16 | Alfa Laval Ab | APPARATUS FOR IMPLEMENTING AN ESSENTIAL UNIFORM TREATMENT OF A SUBSTANCE, SPEC EN VETSKA |
CH630242A5 (en) * | 1978-02-10 | 1982-06-15 | Donald Graham Glen | PROCESS AND INSTALLATION FOR CONTINUOUSLY WHITENING AND STERILIZING PIECE FOOD PRODUCTS. |
SE429092B (en) * | 1980-10-30 | 1983-08-15 | Tetra Pak Dev | WAY TO PREPARE AND PACKAGE FOOD PRODUCTS, PREFERRED FISH PRODUCTS WITH LONG HALLABILITY |
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US4637936A (en) * | 1984-08-10 | 1987-01-20 | Marlen Research Corporation | Aspetic food processing apparatus and method |
-
1986
- 1986-05-30 US US06/868,950 patent/US4674267A/en not_active Expired - Lifetime
-
1987
- 1987-03-21 EP EP87104183A patent/EP0247310B1/en not_active Expired - Lifetime
- 1987-03-21 ES ES87104183T patent/ES2016093B3/en not_active Expired - Lifetime
- 1987-03-21 AT AT87104183T patent/ATE52979T1/en active
- 1987-03-21 DE DE8787104183T patent/DE3762834D1/en not_active Expired - Fee Related
- 1987-03-23 AU AU70517/87A patent/AU578179B2/en not_active Ceased
- 1987-04-06 CA CA000533903A patent/CA1267066A/en not_active Expired - Fee Related
- 1987-05-02 AR AR87307623A patent/AR247165A1/en active
- 1987-05-12 DK DK240287A patent/DK163978C/en active
- 1987-05-25 MX MX006620A patent/MX168751B/en unknown
- 1987-05-25 NO NO872178A patent/NO177584C/en unknown
- 1987-05-28 FI FI872385A patent/FI82819C/en not_active IP Right Cessation
- 1987-05-29 BR BR8702780A patent/BR8702780A/en not_active IP Right Cessation
- 1987-05-30 JP JP62137584A patent/JP2636242B2/en not_active Expired - Lifetime
- 1987-05-30 CN CN87103910A patent/CN1010934B/en not_active Expired
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1990
- 1990-06-28 GR GR90400415T patent/GR3000596T3/en unknown
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FI82819C (en) | 1991-04-25 |
NO872178D0 (en) | 1987-05-25 |
JP2636242B2 (en) | 1997-07-30 |
DE3762834D1 (en) | 1990-06-28 |
US4674267A (en) | 1987-06-23 |
ES2016093B3 (en) | 1990-10-16 |
EP0247310B1 (en) | 1990-05-23 |
ATE52979T1 (en) | 1990-06-15 |
NO872178L (en) | 1987-12-01 |
FI872385A0 (en) | 1987-05-28 |
FI82819B (en) | 1991-01-15 |
AU578179B2 (en) | 1988-10-13 |
NO177584C (en) | 1995-10-18 |
DK163978C (en) | 1992-09-28 |
CN1010934B (en) | 1990-12-26 |
GR3000596T3 (en) | 1991-07-31 |
EP0247310A1 (en) | 1987-12-02 |
CA1267066A (en) | 1990-03-27 |
JPS62296866A (en) | 1987-12-24 |
DK240287A (en) | 1987-12-01 |
DK240287D0 (en) | 1987-05-12 |
NO177584B (en) | 1995-07-10 |
BR8702780A (en) | 1988-03-01 |
CN87103910A (en) | 1988-02-17 |
MX168751B (en) | 1993-06-07 |
FI872385A (en) | 1987-12-01 |
AU7051787A (en) | 1987-12-03 |
AR247165A1 (en) | 1994-11-30 |
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