DK150992B - ELEVATIVE, PLEASANT AND PENDANT EFFECTIVE PRODUCT AND THE USE OF THE PRODUCT - Google Patents
ELEVATIVE, PLEASANT AND PENDANT EFFECTIVE PRODUCT AND THE USE OF THE PRODUCT Download PDFInfo
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- DK150992B DK150992B DK052475AA DK52475A DK150992B DK 150992 B DK150992 B DK 150992B DK 052475A A DK052475A A DK 052475AA DK 52475 A DK52475 A DK 52475A DK 150992 B DK150992 B DK 150992B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
150992150992
Opfindelsen angår et multifunktionelt stof- eller tøjblødgørende og blegende produkt, som blødgør vasketøj, reducerer eller eliminerer statisk vedhængning af syntetiske stoffer og accelererer rensningen af vasketøj.The invention relates to a multifunctional fabric or fabric softening and bleaching product which softens laundry, reduces or eliminates static adhesion of synthetic fabrics and accelerates the cleaning of laundry.
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Anvendelsen af talrige og diverse kemiske stoffer og specielt cationiske forbindelser scm blødgøringsmidler for tekstilprodukter, er velkendt i teknikken. Det er også velkendt, at udnytte sådanne materialers blødgørende virkning under vaskeoperationen og specielt i vaskeprocessens skylleperiode. Denne tek- 2 150992 nik er blevet nødvendiggjort af den kendsgerning, at de tidligere anvendte blødgøringsmidler, der hovedsagelig har været af cationisk karakter, ikke er forligelige med den væsentligste detergenttype, som anvendtes i vaskeperioden. Ved hjemmevask har man i langt de 5 fleste tilfælde anvendt anioniske detergenter. Det har vist sig, at endog spor af anioniske materialer resulterer i et bundfald, som reducerer de nævnte cationiske stofblødgøringsmidlers effektivitet. Denne godtgjorte uforligelighed har nødvendiggjort anvendelsen af cationiske quaternære blødgøringsmidler i forbindelse med vask i 10 skylleperioden efter skylning flere gange for at befri det vaskede tøj for spor af anionisk detergent.The use of numerous and various chemical substances and especially cationic compounds in plasticizers for textile products is well known in the art. It is also well known to utilize the softening effect of such materials during the washing operation and especially during the rinsing period of the washing process. This technique has been necessitated by the fact that the previously used plasticizers, which have mainly been cationic, are not compatible with the major detergent type used during the wash period. Anionic detergents have been used in the vast majority of cases in home washing. It has been found that even traces of anionic materials result in a precipitate which reduces the effectiveness of said cationic fabric softeners. This demonstrated incompatibility has necessitated the use of cationic quaternary plasticizers for washing during the rinse period after rinsing several times to free the washed clothing from traces of anionic detergent.
ligeledes tilsættes blegemidler sædvanligvis til vasketøjet som et særskilt trin i løbet af vaskeoperationen. Det fremgår således, at 15 det hidtil har været nødvendigt med to særskilte produkter og to særskilte tilsætninger i forbindelse med vaskeoperationen.likewise, bleaching agents are usually added to the laundry as a separate step during the washing operation. Thus, it appears that so far two separate products and two separate additives have been necessary in connection with the washing operation.
Det har nu vist sig, at et enkelt multifunktionelt produkt, der er forligelig med organiske detergenter,med fordel kan sættes til vas-20 ketøjet under vaskeperioden, hvilket produkt i hovedsagen omfatter et cationisk blødgøringsmiddel og et uorganisk peroxygenblegemiddel. Det foreliggende produkt, som fortrinsvis er partikelformet,bevirker, at vasketøj behandlet dermed,blødgøres, bliver antistatisk, bliver renset i forøget grad og befries for pletter.It has now been found that a single multifunctional product compatible with organic detergents can advantageously be added to the laundry during the washing period, which essentially comprises a cationic plasticizer and an inorganic peroxygen bleach. The present product, which is preferably particulate, causes the laundry treated therewith to soften, to become antistatic, to be purified to an increased extent and to free from stains.
— -J- -J
Formålet med den foreliggende opfindelse er følgelig at tilvejebringe et stofblødgørende og blegende produkt med antistatiske egenskaber, hvilket produkt er forligelig med organiske detergenter inklusive anioniske og ikke-ionogene detergenter.Accordingly, the object of the present invention is to provide a fabric softening and bleaching product with antistatic properties, which product is compatible with organic detergents including anionic and nonionic detergents.
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Stofblødgørings-, blege- og antivedhængningsproduktet ifølge opfindelsen er ejendommelig ved det i krav l's kendetegnende del anførte.The fabric softening, bleaching and antifouling product of the invention is characterized by the characterizing part of claim 1.
Opfindelsen angår også en fremgangsmåde til samtidig blegning, blød-35 gøring og eliminering af vedhængningsegenskaberne, hvilken fremgangsmåde er ejendommelig ved det i kvav 7's kendetegnende del angivne.The invention also relates to a method for simultaneous bleaching, softening and elimination of the adhesive properties, which method is characterized by the characterizing part of claim 7.
De cationiske tekstilblødgøringsforbindelser, der er nyttige i produktet ifølge opfindelsen, er kendte handelsprodukter og omfatter 40 cationiske blødgøringsmidler valgt blandt de nitrogenholdige for- 3 150992 blødgøringsmidler indeholdende mindst én gruppe med 8-22 carbon-atomer og mindst én gruppe med 12 - 22 carbonatomer.The cationic fabric softeners useful in the product of the invention are known commercial products and comprise 40 cationic plasticizers selected from the nitrogenous plasticizers containing at least one group of 8-22 carbon atoms and at least one group of 12-22 carbon atoms.
Almindeligvis har de kvaternære ammoniumblødgøringsmidler følgende 5 formler: 10 r R-!. R3 + X- 15 R1 (CH2CH20)nH + ^ N X- R2/ "'R3 20 Γ N — R1-/ X-Generally, the quaternary ammonium plasticizers have the following formulas: 10 R R3 + X- R1 (CH2CH2O) nH + ^ N X- R2 / "R3 20 Γ N - R1- / X-
R^ (CH9CH90) HR4 (CH9CH90) H
25 - ^ ^ n -i hvori R·*· er en langkædet alifatisk gruppe med 8-22 carbonatomer, 2 R er en langkædet alifatisk gruppe med 8-22 carbonatomer eller en lavere alkylgruppe med 1-4 carbonatomer eller en aryl- eller aral= 5 4- kylgruppe, R og R^ er lavere alkylgrupper, n er et tal mellem 1 30 og 15,og X er en vandopløselig saltdannende anion, såsom et halo= genid, d.v.s. chlorid, bromid, iodid, et sulfat, acetat, hydroxid, methosulfat eller lignende uorganisk eller organisk opløseliggøren-de mono- eller dibasisk gruppe. Eksempler på kvaternære ammoniumblødgøringsmidler der er velegnede til anvendelse i produktet ifølge 35 den foreliggende opfindelse omfatter følgende: hydrogeneret ditalg= dimethylammoniumchlorid, ethoxyleret distearyldimethylammoniumchlc= rid, l-hydroxyethyl-l-methyl-2-heptadecylimidazoliumchlorid, dime= thyldistearylammoniumchlorid, trimethylstearylammoniumbromid, cetyl= trimethylammoniumchlorid, di-kokosdimethylammoniumchlorid, cetylpy= 150992 4 ridiniumchlorid, højere-alkyl-dimethylbenzylammoniumchlorid, di-iso= butylphenoxyethoxyethyldimethylbenzylammoniumchlorid, laurylisoqui= noliniumbromid, distearyldimethyl-quaternær-ammoniumbromid, distea= ryldimethyl-quaternær-ammoniummethylsulfat, dikokosdimethyl-quater= 5 nær-ammoniumchlorid, dimethylarachidyl, behenyl-quaternær-ammonium= chlorid, di-(soya)-dimethylammoniumchlorid og di(kokos)dimethylammo= niumchlorid, benzyldimethylstearylammoniumchlorid etc.25 is a long chain aliphatic group of 8-22 carbon atoms, 2 R is a long chain aliphatic group of 8-22 carbon atoms or a lower alkyl group of 1-4 carbon atoms or an aryl or aral = 5 4-cooling group, R and R 2 are lower alkyl groups, n is a number between 1 and 15 and X is a water-soluble salt-forming anion such as a halide genide, i.e. chloride, bromide, iodide, a sulfate, acetate, hydroxide, methosulfate or the like inorganic or organically soluble mono- or dibasic group. Examples of quaternary ammonium plasticizers suitable for use in the product of the present invention include the following: hydrogenated ditalgium = dimethylammonium chloride, ethoxylated distearyl dimethylammonium chloride, 1-hydroxyethyl-1-methyl-2-heptadecylimidazolammonium ammonium chloride, dime = ,, di-coco dimethyl ammonium chloride, cetylpy = 150992 4 rhidinium chloride, higher-alkyl-dimethylbenzylammonium chloride, di-iso = butylphenoxyethoxyethyldimethylbenzylammonium chloride, laurylisoqui = nolinium bromide, distearyldimethyl-quaternary dimethylarachidyl, behenyl quaternary ammonium = chloride, di- (soy) -dimethylammonium chloride and di (coconut) dimethylammonium chloride, benzyldimethylstearylammonium chloride, etc.
Når udtrykket "kokos" anvendes omfatter det fedtsyregrupper dannet 10 i kokosoliefedtsyrer. Sådanne syrer indeholder fra ca. 8-18 carbon-atomer pr. molekyle overvejende i C^4 s7ren·When the term "coconut" is used, it includes fatty acid groups formed in coconut oil fatty acids. Such acids contain from ca. 8-18 carbon atoms per molecule predominantly in C
En væsentlig bestanddel i det foreliggende blødgøringsprodukt er en uorganisk blegende peroxygenforbindelse. Enhver af de i teknikken 15 som blegemidler anvendte peroxidforbindelser er velegnede til anvendelse heri, og som typiske eksempler, der ikke indebærer nogen begrænsning, skal nævnes uorganiske persalte f.eks. perborater, per= carbonater, perphosphater, persilicater, persulfater, hydrogenperoxid, natriumperoxid og lignende. Som man vil forstå,kan specielle omstæn- 20 digheder give anledning til,at der anvendes en speciel type peroxid-forbindelse,f.eks. kan overvejelser i forbindelse med forligelighed, blegevirkning, aktivt oxygenindhold etc. have betydning fer hvilken forbindelse,der anvendes. I hvert tilfælde opnås der særligt gunstige resultater ved anvendelsen af alkalimetalperboratet såsom natriumper= borat, idet forbindelser af denne type har vist sig at tillade opnåelsen af de bedst mulige resultater med hensyn til blegningsvirkning, koncentrationseffektivitet og lignende.An essential component of the present softening product is an inorganic bleaching peroxygen compound. Any of the peroxide compounds used in the technique 15 as bleaching agents are suitable for use herein, and as typical examples which do not involve any limitation, mention should be made of inorganic persaltes, e.g. perborates, per = carbonates, perphosphates, persilicates, persulfates, hydrogen peroxide, sodium peroxide and the like. As will be appreciated, particular circumstances may give rise to the use of a particular type of peroxide compound, e.g. For example, considerations related to compatibility, bleaching, active oxygen content, etc. may matter which compound is used. In each case, particularly favorable results are obtained from the use of the alkali metal perborate such as sodium perborate, as compounds of this type have been found to allow the best possible results in bleaching effect, concentration efficiency and the like.
Den foreliggende opfindelse påtænker desuden anvendelsen af det 30 cationiske blødgøringsmiddel og/eller peroxidforbindelser i blanding indeholdende to eller flere, idet det tilrådelige i at gå således frem, primært afhænger af fabrikantens krav. I hvert tilfælde udgør dette specielle hjælpestof et effektivt middel for fabrikanten til at kapitalisere de gunstige egenskaber, som karakteriserer hver af 35 en række cationiske og/eller peroxygen-forbindelser. Når de tilveje- 5 150992 bringes i form af et simpelt blegemiddelprodukt,kan de involverede bestanddele simpelt hen omfatte en blanding af peroxidforbindelsen og den cationiske forbindelse i de anførte relative molære mængder. Andre bestanddele kan indgå i mindre mængder, d.v.s. fra O til 5fo 5 og fortrinsvis fra 0,1 til 3 vægt^ af produktet, idet sådanne bestanddele uden nogen begrænsning omfatter phosphater til pH-værdiregule-ring, olfaktivmidler, optiske klaremidler og farvestoffer etc. Hvor blegemiddelproduktet påtænkes fremstillet i tabletform, kan der til at lette tablettens henfald tilsættes materialer af sådanne typer 10 som majsstivelse. Mulige bestanddele af den foregående type vil blive beskrevet nærmere i det følgende.The present invention further contemplates the use of the cationic plasticizer and / or peroxide compounds in blends containing two or more, the advisability of thus proceeding primarily depending upon the manufacturer's requirements. In each case, this particular auxiliary constitutes an effective means for the manufacturer to capitalize on the favorable properties which characterize each of a variety of cationic and / or peroxygen compounds. When provided in the form of a simple bleach product, the ingredients involved may simply comprise a mixture of the peroxide compound and the cationic compound in the relative molar amounts indicated. Other constituents may be included in smaller amounts, i.e. from about 0 to about 5 and preferably from about 0.1 to about 3 weight percent of the product, such constituents including, without limitation, phosphates for pH control, olfactants, optical brighteners and dyes, etc. Where the bleach product is contemplated manufactured in tablet form, to facilitate the decay of the tablet, materials of such types as corn starch are added. Possible constituents of the foregoing type will be described in more detail below.
Det foreliggende produkt er specielt gunstigt på grund af, at det gør det muligt at tilvejebringe et tøj- eller stofprodukt med et 15 blødere greb, forbedret absorptionsevne, vedvarende hvidhed, bedre pletfjernelse samt eliminering af statisk elektricitet i syntetiske stoffer og lignende. Misfarvning og gulning af stoffer såvel som afkortningen af den nyttige levetid for stoffer, der normalt kan tilskrives blegende forbindelser ved ældning, elimineres ved hjælp af 20 det foreliggende produkt.The present product is particularly favorable in that it allows to provide a fabric or fabric product with a softer grip, improved absorbency, persistent whiteness, better stain removal and elimination of static electricity in synthetic fabrics and the like. Discoloration and yellowing of substances, as well as the shortening of the useful life of substances which can normally be attributed to bleaching compounds by aging, are eliminated by the present product.
Vægtforhold på 10:1 - 1:1 af uorganisk peroxygenblegemiddel:cationisk blødgøringsmiddel viser sig at være mest effektiv som et fremragende multifunktionelt behandlingsprodukt, som er i stand til at bibringe 25 dermed behandlede stoffer bedre blødheds-, blegnings- og antivedhæng-ningeegenskaber. Der er imidlertid også blevet opnået gunstige resultater, hvor vægtforholdet blegemiddel:cationisk blødgøringsmid-del er 17:1 - 1:4. Mængderne af hver bestanddel kan varieres for at hindre blegnings-, blødgørings- og antistatisk virkning.10: 1 - 1: 1 weight ratio of inorganic peroxygen bleach: cationic plasticizer proves to be most effective as an excellent multifunctional treatment product capable of imparting 25 better softness, bleaching and antifouling properties to the thus treated fabrics. However, favorable results have also been obtained where the weight ratio of bleach: cationic plasticizer is 17: 1 - 1: 4. The amounts of each component can be varied to prevent bleaching, softening and antistatic effects.
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Fremgangsmåden til behandling af stoffer med de foreliggende blødgørende produkter afhænger ikke af temperaturen, og kan udmærket gennemføres med kolde eller varme vaskeopløsninger. Fremgangsmåden kan også gennemføres under anvendelse af vand med en rimelig hårdheds-35 grad, selv om anvendelsen af blødere vaskevand naturligvis foretrækkes .The process for treating substances with the present emollients does not depend on the temperature and can be very well carried out with cold or hot washing solutions. The process can also be carried out using water of a reasonable degree of hardness, although the use of softer wash water is of course preferred.
Det blødgørende-blegende og vedhængningsmodvirkende produkt ifølge den foreliggende opfindelse kan også indeholde mindre mængder af klaremidler, blånelse, germicider, parfumer, fortyndingsmidler 6 150992 eller andre additiver, som ikke påvirker det omhandlede produkts., blødgørende, hvidgørende og vedhængningsmodvirkende egenskaber.The softening bleaching and pendant antifouling product of the present invention may also contain minor amounts of brightening agents, bleaching, germicides, perfumes, diluents, or other additives which do not affect the product's softening, whitening and pendant antifouling properties.
Dette produkt fremstilles fortrinsvis ved tørblanding af bestand-5 delene til fremstilling af et fritstrømmende pulver. Peroxygen-blegemidler og det cationiske blødgøringsmiddel kan i partikelform sættes til vaskevandet samtidig med det organiske detergent eller builderholdige detergent. Det kan imidlertid også tørblandes med sprøjtetørret detergent- eller builderholdig detergentpulver før 10 tilsætning til vaskevandet. Det foreliggende produkt kan være kornet eller pulvervormet eller det kan have pilleform eller en anden egnet form. Mængden af cationisk blødgøringsmiddel beregnet på vaskemiddelproduktets samlede vægt kan være 3-20$; og mængden af per= oxygenblegemiddel kan udgøre ca. 5-50$ og fortrinsvis 20-40$ af 15 den samlede vægt.This product is preferably prepared by dry mixing the ingredients to produce a free flowing powder. Peroxygen bleaches and the cationic plasticizer can be added in particulate form to the wash water simultaneously with the organic detergent or builder-containing detergent. However, it can also be dry mixed with spray-dried detergent or builder-containing detergent powder prior to addition to the wash water. The present product may be granular or powdered or it may be pill form or other suitable form. The amount of cationic plasticizer calculated on the total weight of the detergent product may be $ 3-20; and the amount of per = oxygen bleach may amount to approx. $ 5-50 and preferably $ 20-40 of the total weight.
Opfindelsen har hidtil fundet sin største anvendelse i forbindelse med blødgøring og blegning af bomuldsstoffer, stoffer fremstillet af andre cellulosefibre, f.eks. rayon eller andre tekstilfibre, f.The invention has so far found its greatest use in the softening and bleaching of cotton fabrics, fabrics made from other cellulose fibers, e.g. rayon or other textile fibers, f.
20 eks. nylon, silke, uld, polyethylenterephthalat, celluloseacetat, acrylonitrilpolymere eller -copolymere eller blandinger af to eller flere af disse fibre (f.eks. bomuld-polyester-blandinger). Dette blødgørende-blegende og vedhængningsmodvirkende produkt kan tilføres til stoffet i et vandbad, enten under vaskeperioden ved vask 25 eller som en særlig og særskilt blødgørings- og blegningsoperation. Da dette blødgørende-blegende produkt er forligelig med anioniske og ikke-ionogene detergenter sættes det fortrinsvis til vaskevandet under vask. I brug sættes 90 g af det blødgørende-blegende produkt til en automatisk vaskemaskine eller lignende behandlingsbeholder 30 indeholdende 35 1 vand og med en sædvanlig tøjportion (ca. 6-8 pounds). Større eller mindre mængder kan imidlertid anvendes til at opnå den ønskede grad af blødhed, hvidhed og antistatiske egenskaber afhængig af vandtemperaturen, vandets hårdhed, vandmængden og tøj-mængden etc.20, for example, nylon, silk, wool, polyethylene terephthalate, cellulose acetate, acrylonitrile polymers or copolymers or mixtures of two or more of these fibers (e.g., cotton-polyester blends). This softening-bleaching and adhesive-antagonizing product can be applied to the fabric in a water bath, either during the wash period at wash 25 or as a special and separate softening and bleaching operation. Since this softening-bleaching product is compatible with anionic and nonionic detergents, it is preferably added to the wash water during washing. In use, 90 g of the softening-bleaching product is added to an automatic washing machine or similar treatment container 30 containing 35 l of water and with a usual cloth portion (about 6-8 pounds). However, larger or smaller amounts can be used to achieve the desired degree of softness, whiteness and antistatic properties depending on the water temperature, the hardness of the water, the amount of water and the amount of clothing, etc.
De følgende eksempler har til hensigt at illustrere den foreliggende opfindelse. Alle dele er vægtdele medmindre andet er angivet. I eksemplerne er trykket atmosfærisk tryk medmindre andet er angivet.The following examples are intended to illustrate the present invention. All parts are parts by weight unless otherwise indicated. In the examples, the pressure is atmospheric pressure unless otherwise indicated.
35 7 15099235 7 150992
Eksempel 1Example 1
Bestanddele $ 1. Arosurf ΪΑ-100 (blødgøringsmiddel) 10$ 5 Natriumperborat 25$ 2, Sprøjtetørrede basiskorn 65$ 1. Et pulverformet produkt fra Ashland Chemical Co., indeholdende mindst 94$ dimethyldistearylammoniumchlorid.Ingredients $ 1. Arosurf ΪΑ-100 (plasticizer) 10 $ 5 Sodium perborate 25 $ 2, Syringe dried base grains $ 65 1. A powdered product from Ashland Chemical Co. containing at least $ 94 dimethyl distearyl ammonium chloride.
2. Indeholder 16,7$ natriumsilicattørstof (1:2,35) 16,7$ natriumcarbonat 57,7$ natriumsulfat 15 3,3$ ci4_c:i5 lineær alkoholethoxylat (11E0) 5,6$ optiske klaremidler og fugt.2. Contains $ 16.7 sodium silicate solids (1: 2.35) 16.7 $ sodium carbonate 57.7 $ sodium sulfate 15 3.3 $ ci4_c: i5 linear alcohol ethoxylate (11E0) $ 5.6 optical brighteners and moisture.
De enkelte komponenter tørblandes, og det resulterende produkt anven-20 des ved vaskningen af tøj. Adskillige prøver af bomuldsfrotté, PP-bomuld og polyester/PP-bomuld (PP = Permanent Press finish) udsættes for fem efter hinanden følgende 10 minutters vaskninger i vand med en vandhårdhed på 150 ppm ved 48,8°C med et kraftigt virkende detergent indeholdende 10$ natrium-lineær-tridecylbenzensulfonat, 25 2$ C-^-C-^ fedtalkohol med gennemsnitlig 11 ethy len oxidgrupper, 2$ blandet natriumkokos/talgfedtsyresæbe, 35$ pentanatriumtripolyphos= phat, 7$ natriumsilicat (Na20:Si02 forhold 1:2,35), 0,5$ natrium= carboxymethylcellulose og resten natriumsulfat plus 90 g af ovennævnte produkt.The individual components are dry mixed and the resulting product is used in the washing of clothes. Several samples of cotton terry, PP cotton and polyester / PP cotton (PP = Permanent Press finish) are subjected to five consecutive 10-minute washes in water with a water hardness of 150 ppm at 48.8 ° C with a powerful acting detergent containing 10 $ sodium linear tridecylbenzenesulfonate, 25 2 $ C - C - 3 fatty alcohol with an average of 11 ethyl oxide groups, 2 $ mixed sodium coconut / tallow fatty acid soap, 35 $ pentane sodium tripolyphos = phate, 7 $ sodium silicate (Na 2 O: SiO 2 ratio 1: 2 , 35), $ 0.5 sodium = carboxymethyl cellulose and the rest sodium sulfate plus 90 g of the above product.
3030
Den endelige blødhedsbedømmelse af prøverne var 10++ efter en skala fra 1-10, hvor 1 betegner ingen blødhed og 10 betegner fremragende blødhed, idet en værdi på 5 kræves til marginalblødhed og 8 betegner ønskelig blødhed. Den antistatiske virkning på det syntetiske stof 35 var meget god.The final softness rating of the samples was 10 ++ on a scale of 1-10, with 1 denoting no softness and 10 denoting excellent softness, a value of 5 being required for marginal softness and 8 denoting desirable softness. The antistatic effect on the synthetic substance 35 was very good.
Sammenligningsforsøg gennemført med detergent alene, detergent plus blødgøringsmiddel og detergent plus chlorox-blegemiddel gav følgende resultater: g 150992Comparative experiments performed with detergent alone, detergent plus plasticizer and detergent plus chlorox bleach gave the following results: g 150992
JABSIi IJABSIi I
Frotté blødheds- Syntetisk stof anti-Vaskemiddelprodukt_bedømmelse_statisk virkningTerry Softness Synthetic Fabric Anti-Detergent Product_ Rating_Static Effect
Detergent og produkt fra eksempel 1 ICr meget godDetergent and product of Example 1 ICr very good
Detergent alene 1 nul 5 Detergent + blødgøringsmiddel 10 rimelig-nogen ved hængningDetergent alone 1 zero 5 Detergent + plasticizer 10 reasonable - no hang
Detergent + chlorox blegemiddel 5 ringe - kraftig ved hængningDetergent + chlorox bleach 5 rings - powerful for hanging
Desuden blev detergentets rensevirkning og evne til at fjerne pletter forøget ved nærværelsen af det foreliggende produkt.In addition, the detergent cleansing effect and ability to remove stains was increased in the presence of the present product.
Det er således klart, at den samtidige anvendelse af det cationiske blødgøringsmiddel, specielt af den quaternære ammoniumtype, og per= 15 oxygenblegemidlet giver en fuldstændig uventet synergistisk rensevirkning, idet de blødgørende egenskaber deraf forøges.Thus, it is clear that the concomitant use of the cationic plasticizer, especially of the quaternary ammonium type, and the per = 15 oxygen bleach gives a completely unexpected synergistic cleaning effect, increasing its softening properties.
Vægtforholdet af peroxygenblegemiddel til cationisk blødgøringsmiddel heri er 2,5:1.The weight ratio of peroxygen bleach to cationic plasticizer herein is 2.5: 1.
2020
Eksempel 2Example 2
Arosurf TA-100 indholdet fra eksempel 1 formindskes til 5$, natrium= perboratindholdet forøges til 35$ og de sprøjtetørrede basiskorn reduceres til 60$.The Arosurf TA-100 content of Example 1 is reduced to $ 5, the sodium = perborate content is increased to $ 35 and the spray dried base grains are reduced to $ 60.
Stof behandlet i overensstemmelse med fremgangsmåden fra eksempel 1 med dette produkt, som repræsenterer et vægtforhold af blegemiddel til blødgøringsmiddel på 7:1 opnåede en blødhedsbedømmelse på 8, en meget god antistatisk virkning og fremragende pletfjernelse.Fabric treated in accordance with the procedure of Example 1 with this product, which represents a bleach to bleach weight ratio of 7: 1, achieved a softness rating of 8, a very good antistatic effect and excellent stain removal.
Det er således klart, at ændring af forholdet af blegemiddel til blødgøringsmiddel indenfor bestemte grænser giver varierende grader af blødhed og pletfjernelse.Thus, it is clear that changing the ratio of bleach to plasticizer within certain boundaries gives varying degrees of softness and stain removal.
Eksempel 5 35 9 150992Example 5 35 9 150992
Yaskningsmetoden fra eksempel 1 blev anvendt bortset fra at stoffet blev udsat for én 10 minutters vaskeperiode under anvendelse af 95 g af det før nævnte kraftigt virkende detergent plus 10 g blødgørings-middel og 20 g natriumperborat (et forhold blegemiddel:cationisk 5 forbindelse på 2:1) på forskellige pletter under anvendelse af 4 prøver plettet med blåbærtærtefyld, 4 prøver plettet med ler, 4 prøver plettet med potteplantejord, 1 strimmel stof med flere pletter og 4 frottehåndklæder med følgende resultater: 10 Effektiviteten af pletfjernelsen bestemmes ved reflektionskoefficient-aflæsninger, Rd (anti-genudfældning) på stoffet, under anvendelse af et Gardner Color-differencemeter, hvori højere Rd-værdier er tegn på forøget hvidhed; Rb (fluorescens) måler klarhed og højere værdier angiver større hvidhed, a = rødhed (+), grønt (-); og b = 'blåhed (-), 15 gul (+).The washing method of Example 1 was used except that the fabric was subjected to one 10 minute wash period using 95 g of the aforementioned powerful detergent plus 10 g of plasticizer and 20 g of sodium perborate (a ratio of bleach: cationic compound of 2: 1) on different stains using 4 specimens stained with blueberry pie filling, 4 specimens stained with clay, 4 specimens stained with potted soil, 1 strip of multi-stained fabric and 4 terry towels with the following results: 10 The efficiency of stain removal is determined by reflection coefficient readings, Rd (anti-re-precipitation) on the fabric, using a Gardner Color differential meter, wherein higher Rd values are indicative of increased whiteness; Rb (fluorescence) measures clarity and higher values indicate greater whiteness, a = redness (+), green (-); and b = blueness (-), yellow (+).
TABEL II·TABLE II ·
Blødhedsbe-Blødhedsbe-
Plet_Produkt_Rd_a_b_Rt dømmelse 70Plet_Product_Rd_a_b_Rt judgment 70
Blåbærtærte- detergent + fyld blødgøringsmiddel 71,6 .-1,4 +5,4 " detergent + 2:1 perboratiblødgø- 79,8 -0,9 +5,4 ringsmiddel 25 Ler detergent + blødgøringsmiddel 69,9 +5,5 +10,4 " detergent + 2:1 perborat:blødgø- 73,7 +2,6 +9,4 ringsmiddelBlueberry Pie Detergent + Fill Softener 71.6.-1.4 + 5.4 "Detergent + 2: 1 Perborate Softener 79.8 -0.9 +5.4 Annulant 25 Clay Detergent + Softener 69.9 +5.5 +10.4 "Detergent + 2: 1 Perborate: Soften- 73.7 + 2.6 +9.4 Ring Agent
Urtepottejord detergent + blødgøringsmiddel 79,0 -0,5 +6,2 " detergent + 2:1 perborat:blødgø- 76,5 -1,0 +4,7 ringsmiddelHerbal Pot Soil Detergent + Softener 79.0 -0.5 + 6.2 "Detergent + 2: 1 Perborate: Soften 76.5 -1.0 + 4.7 Agents
Erottéhånd- detergent + 35 klæder blødgøringsmiddel 91,0 +1,1 -2,0 291 10 " detergent + 2:1 perborat:blødgø- 92,4 +1,4 -3,0 321 8 ringsmiddel 10 150992 IABEL II (fortsat)Erotic Hand Detergent + 35 Cloth Softener 91.0 +1.1 -2.0 291 10 "Detergent + 2: 1 Perborate: Softener 92.4 +1.4 -3.0 321 8 Detergent 10 150992 IABEL II (continued )
Blødhedsbe-Blødhedsbe-
Plet_Produkt_Rd_a_b_Rb dømmelsePlet_Product_Rd_a_b_Rb judgment
Strimler med flere pletterMultiple stain strips
Bleget Greige detergent + 5 blødgøringsmiddel 88,1 -1,0 +2,4 " " detergent + 2:1 blegemiddel:blød- 88,6 -1,0 +2,1 gøringsmiddelBleached Greige Detergent + 5 Softener 88.1 -1.0 + 2.4 "" Detergent + 2: 1 Bleach: Soften 88.6 -1.0 + 2.1 Softener
Bleget olie- detergent + agtig blødgøringsmiddel 36,8 +0,3 +3,6 10 " " detergent + 2:1 blegemiddel:blød- 41,8 +0,2 +3,7 gøringsmiddel Hæmoglobin detergent + blødgøringsmiddel 60,9 +1,2 +9,4 15 " detergent +2:1 blegemiddel:blød- 37,2 +2,9 +13,0 gøringsmiddel CMS (kokos- detergent + mælk, sukker) blødgøringsmiddel 47,8 +5,4 +9,7 20 CMS (kokos- detergent + 2:1 mælk, sukker) blegemiddel:blød- 50,2 +5,3 +9,2 gøringsmiddel BM1 (blod, detergent + mælk, blæk) blødgøringsmiddel 31,0 0,0 +3,3 9C, BM1 (blod, detergent + 2:1 mælk, blæk) blegemiddel:blød- 17,3 +0,2 +3,2 gøri'ngsmiddelBleached oil detergent + softener 36.8 +0.3 +3.6 10 "" detergent + 2: 1 bleach: softener 41.8 + 0.2 +3.7 softener Hemoglobin detergent + softener 60.9 + 1.2 + 9.4 15 "Detergent +2: 1 Bleach: Soft 37.2 + 2.9 +13.0 Soothing CMS (Coconut Detergent + Milk, Sugar) Softener 47.8 + 5.4 +9 , 7 20 CMS (coconut detergent + 2: 1 milk, sugar) bleach: soft 50.2 +5.3 +9.2 softener BM1 (blood, detergent + milk, ink) plasticizer 31.0 0.0 + 3.3 9C, BM1 (blood, detergent + 2: 1 milk, ink) bleach: soft 17.3 + 0.2 +3.2 lubricant
Olieagtig detergent + blødgøringsmiddel 26,7 -0,6 -2,6 " detergent + 2:1 30 blegemiddel:blød- 28,6 -0,7 -2,6 gøringsmiddelOily Detergent + Softener 26.7 -0.6 -2.6 "Detergent + 2: 1 Bleach: Soften 28.6 -0.7 -2.6 Softener
Greige detergent + blødgøringsmiddel 71,4 +1,0 +11,8 " detergent +2:1 blegemiddel:blød- 72,0 +0,8 +11,8 gøringsmiddel Rødvin detergent + blødgøringsmiddel 64,1 +2,1 +5,8 11 150992 TABEL II (fortsat)Greige Detergent + Softener 71.4 +1.0 + 11.8 "Detergent +2: 1 Bleach: Soften 72.0 +0.8 +11.8 Softener Red Wine Detergent + Softener 64.1 + 2.1 +5 , 8 11 150992 TABLE II (continued)
Blødhedsbe-Blødhedsbe-
Plet_Produkt_Rd_a_b_Rb dømmelse Rødvin detergent +2:1 blegemiddel:blød- 65,5 +2,5 +6,6 gøringsmiddel 5 Ovennævnte resultater viser klart fremragende rensning og pletfjernelse ved de fleste pletter inklusive lerpletter, blåbærtærteplet-ter, rødvinspletter, kokos-, mælke- og sukkerpletter og olieagtige pletter med undtagelse af urtepottejord-, blod-, mælk- og blækpletter.Stain_Product_Rd_a_b_Rb judgment Red wine detergent +2: 1 bleach: soft- 65.5 +2.5 +6.6 curing agent 5 The above results clearly show excellent cleansing and stain removal for most stains including clay stains, blueberry pie stains, red wine stains, coconut, coconut, - and sugar stains and oily stains with the exception of herb pots, blood, milk and ink stains.
1010
Eksempel 4Example 4
En portion rene assorterede stoffer blev vasket én gang i overensstemmelse med den i eksempel 1 anførte fremgangsmåde og maskintørret 15 il time under anvendelse af 95 g af det i eksempel 1 specificerede kraftigt virkende rensemiddel plus 110 g chlorox; 95 g detergent plus 90 g af produktet fra eksempel 2; 95 g detergent plus 90 g af produktet fra eksempel 1 og 95 g detergent plus 90 g cationisk blød-gøringsmiddel og derefter måltes rensevirkning, blødgøringsvirkning 20 og antistatisk virkning, således som det fremgår af den følgende tabel:A portion of pure assorted fabrics was washed once in accordance with the procedure of Example 1 and machine dried 15 µl using 95 g of the powerful cleaning agent specified in Example 1 plus 110 g of chlorox; 95 g of detergent plus 90 g of the product of Example 2; 95 g of detergent plus 90 g of the product of Examples 1 and 95 g of detergent plus 90 g of cationic softener and then purification effect, softening effect 20 and antistatic effect were measured as shown in the following table:
TABEL IIITABLE III
25 Produkt_Stof_Rd a b Rb Blødhed Antistatisk25 Product_Stand_Rd a b Rb Softness Antistatic
Detergent + bomuld 92,0 +0,9 -5,1 287 ringe- chlorox nylon 97,6 -0,9 +2,5 059 meget kraftig kraftig dacron vedhængning og PP-bomuld 87,7 +0,2 0,0 184 statiskDetergent + cotton 92.0 + 0.9 -5.1 287 ring-chlorox nylon 97.6 -0.9 +2.5 059 very strong heavy duty dacron pendant and PP cotton 87.7 +0.2 0.0 184 static
Protté-hånd- 30 klæder 94,1 +l,o -4,7 358 4Towel towels 94.1 + l, o -4.7 358 4
Detergent + bomuld 92,1 +1,0 -5,5 502 meget god eksempel 2 nylon 96,2 +0,7 +2,5 078 kraftig dacron PP-bomuld 87,7 +0,4-0,2 207Detergent + Cotton 92.1 + 1.0 -5.5 502 Very Good Example 2 Nylon 96.2 + 0.7 + 2.5 078 Heavy Dacron PP Cotton 87.7 + 0.4-0.2 207
Protté-hånd- klæder 92,0 +0,9-2,9 559 8 12 150992 TABEL III (fortsat)Towel towels 92.0 + 0.9-2.9 559 8 12 150992 TABLE III (continued)
Produkt_Stof_Rd a b Rb Blødhed AntistatiskProduct_Fabric_Rd a b Rb Softness Antistatic
Detergent + bomuld 92,0 +0,9 -2,7 275 rimelig- blødgørings- nylon 87,3 -1,4 +2,4 053 nogen ved- middel kraftig dacron hængning PP-bomuld 87,3 +0,3 +0,3 177 frotté-hånd- 91,7 +0,8 -2,6 327 10+ klæderDetergent + cotton 92.0 + 0.9 -2.7 275 reasonable-softening nylon 87.3 -1.4 + 2.4 053 any by strong dacron hanging PP cotton 87.3 +0.3 + 0.3 177 terry towels- 91.7 + 0.8 -2.6 327 10+ cloths
Detergent + bomuld 91,9 +0,9 -3,4 297 meget god eksempel 1 nylon 96,1 +1,0 +2,7 0,66 kraftig dacron PP-bomuld 89,8 0,0 0,0 199Detergent + Cotton 91.9 +0.9 -3.4 297 Very Good Example 1 Nylon 96.1 +1.0 + 2.7 0.66 Heavy Dacron PP Cotton 89.8 0.0 0.0 199
Frotté-hånd- 92,1 +0,8 -3,0 340 10++ 10 klæderTowel hand 92.1 + 0.8 -3.0 340 10 ++ 10 cloths
Den samlede virkning af produkterne ifølge den foreliggende opfindelse var god med fremragende kvaliteter i a, b, Rb, blødhed og antistatiske egenskaber udvist af produktet fra eksempel 1.The overall effect of the products of the present invention was good with excellent grades in a, b, Rb, softness and antistatic properties exhibited by the product of Example 1.
1515
Eksempel 5Example 5
Til produktet fra eksempel 1 blev der sat 0,2$ citronparfume og indholdet af sprøjtetørrede basiskom blev justeret tilsvarende.To the product of Example 1, 0.2 $ lemon perfume was added and the content of spray dried base bowl was adjusted accordingly.
20 Stof behandlet dermed udviste fremragende hvidhed, blødhed og antistatiske egenskaber.20 Substance treated thus exhibited excellent whiteness, softness and antistatic properties.
Eksempel 6 25 Til produktet fra eksempel 2 blev der sat 0,2$ citronparfume og indholdet af de sprøjtetørrede basiskorn blev justeret tilsvarende. Dette produkt havde også fremragende blegnings-, blødgørings-og antivedhæftningsegenskaber.Example 6 To the product of Example 2, 0.2 $ lemon perfume was added and the content of the spray dried base grains was adjusted accordingly. This product also had excellent bleaching, softening and anti-sticking properties.
30 Eksempel 7Example 7
Natriumpercarbonat blev anvendt i stedet for natriumperboratindhol-det i eksempel 5 med de samme gunstige resultater som med det per= boratholdige produkt.Sodium percarbonate was used in place of the sodium perborate content of Example 5 with the same favorable results as with the per borate-containing product.
3535
Eksempel 8Example 8
Natriumpercarbonat blev anvendt i stedet for natriumperboratkompo-Sodium percarbonate was used instead of sodium perborate composition.
Claims (10)
Applications Claiming Priority (2)
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US44714074A | 1974-03-01 | 1974-03-01 | |
US44714074 | 1974-03-01 |
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DK52475A DK52475A (en) | 1975-10-27 |
DK150992B true DK150992B (en) | 1987-10-05 |
DK150992C DK150992C (en) | 1988-06-13 |
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DK052475A DK150992C (en) | 1974-03-01 | 1975-02-13 | ELEVATIVE, PLEASANT AND PENDANT EFFECTIVE PRODUCT AND THE USE OF THE PRODUCT |
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AU (1) | AU7809475A (en) |
BE (1) | BE826162A (en) |
CA (1) | CA1060604A (en) |
CH (1) | CH608048A5 (en) |
DE (1) | DE2506516A1 (en) |
DK (1) | DK150992C (en) |
FR (1) | FR2262712B1 (en) |
IT (1) | IT1029826B (en) |
NL (1) | NL7502447A (en) |
SE (1) | SE426853B (en) |
ZA (1) | ZA75747B (en) |
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GB1557568A (en) * | 1976-09-20 | 1979-12-12 | Procter & Gamble | Laundry composition comprising an agglomerate of a cationic surfactant and a bleach activator |
US4166794A (en) * | 1978-05-25 | 1979-09-04 | Colgate-Palmolive Company | Liquid bleach-softener compositions |
Citations (1)
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US3749674A (en) * | 1971-02-22 | 1973-07-31 | Procter & Gamble | Bleach compositions |
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US3749673A (en) * | 1971-02-22 | 1973-07-31 | Procter & Gamble | Bleach-fabric softener compositions |
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1975
- 1975-02-05 ZA ZA00750747A patent/ZA75747B/en unknown
- 1975-02-11 AU AU78094/75A patent/AU7809475A/en not_active Expired - Fee Related
- 1975-02-13 DK DK052475A patent/DK150992C/en active
- 1975-02-15 DE DE19752506516 patent/DE2506516A1/en not_active Withdrawn
- 1975-02-21 IT IT48294/75A patent/IT1029826B/en active
- 1975-02-24 CA CA220,649A patent/CA1060604A/en not_active Expired
- 1975-02-25 SE SE7502086A patent/SE426853B/en not_active IP Right Cessation
- 1975-02-27 FR FR757506144A patent/FR2262712B1/fr not_active Expired
- 1975-02-28 NL NL7502447A patent/NL7502447A/en not_active Application Discontinuation
- 1975-02-28 BE BE153899A patent/BE826162A/en unknown
- 1975-02-28 CH CH257375A patent/CH608048A5/en not_active IP Right Cessation
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US3749674A (en) * | 1971-02-22 | 1973-07-31 | Procter & Gamble | Bleach compositions |
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CA1060604A (en) | 1979-08-21 |
IT1029826B (en) | 1979-03-20 |
BE826162A (en) | 1975-06-16 |
ZA75747B (en) | 1976-09-29 |
SE426853B (en) | 1983-02-14 |
AU7809475A (en) | 1976-08-12 |
SE7502086L (en) | 1975-09-02 |
DK52475A (en) | 1975-10-27 |
DE2506516A1 (en) | 1975-09-04 |
NL7502447A (en) | 1975-09-03 |
FR2262712B1 (en) | 1979-02-09 |
FR2262712A1 (en) | 1975-09-26 |
DK150992C (en) | 1988-06-13 |
CH608048A5 (en) | 1978-12-15 |
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