DK1406725T3 - Perovskites comprising noble metals and their use as catalysts - Google Patents
Perovskites comprising noble metals and their use as catalysts Download PDFInfo
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- DK1406725T3 DK1406725T3 DK02764701.5T DK02764701T DK1406725T3 DK 1406725 T3 DK1406725 T3 DK 1406725T3 DK 02764701 T DK02764701 T DK 02764701T DK 1406725 T3 DK1406725 T3 DK 1406725T3
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- barium
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- 239000003054 catalyst Substances 0.000 title claims description 20
- 229910000510 noble metal Inorganic materials 0.000 title description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 22
- 229910052763 palladium Inorganic materials 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 14
- 230000003197 catalytic effect Effects 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 229910052703 rhodium Inorganic materials 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 230000036961 partial effect Effects 0.000 claims description 5
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 238000007084 catalytic combustion reaction Methods 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000006104 solid solution Substances 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 51
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 36
- 239000000243 solution Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 19
- 229910052788 barium Inorganic materials 0.000 description 14
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 14
- 229960004106 citric acid Drugs 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 239000010948 rhodium Substances 0.000 description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000000908 ammonium hydroxide Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 6
- 229910001868 water Inorganic materials 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000002823 nitrates Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 238000010668 complexation reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 241000894007 species Species 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- LXNAVEXFUKBNMK-UHFFFAOYSA-N acetic acid;palladium Chemical compound [Pd].CC(O)=O.CC(O)=O LXNAVEXFUKBNMK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229960002303 citric acid monohydrate Drugs 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- ZGSOBQAJAUGRBK-UHFFFAOYSA-N propan-2-olate;zirconium(4+) Chemical compound [Zr+4].CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-] ZGSOBQAJAUGRBK-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- SVOOVMQUISJERI-UHFFFAOYSA-K rhodium(3+);triacetate Chemical compound [Rh+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SVOOVMQUISJERI-UHFFFAOYSA-K 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/002—Compounds containing, besides ruthenium, rhodium, palladium, osmium, iridium, or platinum, two or more other elements, with the exception of oxygen or hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C01P2002/00—Crystal-structural characteristics
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- C01P2002/34—Three-dimensional structures perovskite-type (ABO3)
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- C01P2002/54—Solid solutions containing elements as dopants one element only
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/525—Perovskite
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Description
DESCRIPTION
[0001] This invention concerns solid solutions with a perovskite structure comprising noble metals, which are useful as catalysts in combustion reactions and, in general, in oxidation processes at high temperature (production of syngas, olefins, elimination of VOC and unburned emission from motor-vehicles).
[0002] Perovskites are ceramic materials formed by the combination of metallic elements with non-metallic elements (usually oxygen) placed in a certain crystalline structure. Their name derives from the specific mineral 'Perovskite' (CaTi03). From a technological point of view, Perovskites are of considerable interest because the single crystalline structure can exhibit a wide range of properties.
[0003] In their ideal structure perovskites have a general formula ABX3 and consist of cubes composed of two metallic cations (A & B) and a non-metallic anion (X) in the ratio 1:1:3. In the cubic cell cations A are bigger and are co-ordinated with twelve X anions, while cations B, wfnich are smaller, are co-ordinated with sixXanions (Fig. 1).
[0004] The high symmetry of the atomic disposition imposes some constraints on the dimension of the ions within the structure, as shown by Goldschmidt [1]; it is therefore important to bear in mind the dimension of the element in the various oxidation states and in the different co-ordination numbers Table 1) [2].
Table 1 [2]
[0005] Inspection of the scientific and patent literature shows that current syntheses very often involve a rare earth element in position A, and a transition element (such as Fe, Mn, Co, Ni, Cr) in position B, and that very few perovskites containing noble metals in a high oxidation state have been synthesised up to now.
[0006] Materials with a perovskitic structure having the general formula Α^Γΐ-χΒχΡ3 are now found where: A is Ba; B is Pt, Ir, Pd, Rh; zis 1; xis in the range 0.01 to 0.8; [0007] The materials according to this invention in which B is Pd are particularly suitable as catalysts for the catalytic combustion of methane for power application. Catalysts based on supported Pd are currently the only ones displaying a catalytic activity for methane combustion high enough to light-off the reaction at low temperature inlet conditions, low contact times and lean fuel concentrations characteristic of modern gas turbines fed with natural gas. Another favourable characteristic of these systems is the negligible volatility of the various species of Pd (metal, oxide, hydroxide) below 1000°C.
[0008] The catalysts based on supported Pd of the current technology display a complex hysteresis cycle which transforms the Pd into a metallic state which is catalytically inactive at high temperatures, with a further re-oxidation to PdO at lower temperatures (Fig. 2) [3], [0009] Figure 2 [4] shows this hysteresis cycle for a typical catalyst based on Pd supported on alumina.
[0010] The catalyst 10 heated to 980°C (curve 1), cooled to 200°C (curve 2), heated again to 980°C (curve 3) and cooled to 200°C (curve 4). All the steps were carried out at 5°C/min.
[0011] The catalyst subjected to an air flow starts loosing weight at temperatures of around 400°C; this weight loss is due to the loss of water chemisorbed on the surface. At temperatures higher than 800°C the rate of weight loss is suddenly increased due to the transformation of PdO to Pd, which starts at this temperature and which is completed at 970°C. During a first cooling in air the sample only starts to gain weight below 570°C and down to 380°C, but not all the weight lost in the previous step is recovered. When the sample is heated again a small weight loss is observed between 700°C and 980°C, with a further gain during the cooling step similar to that of the previous cycle.
[0012] A certain degree of reduction of Pd together with its oxidised species is desirable because the first catalytic step involves dissociation of the C-H bond, which occurs on reduced species, whereas the further oxidation steps occur on the oxidised species [5].
[0013] For the above reasons it could be advantageous to utilise palladium in a high oxidation state that is fully reducible to the metallic state only at temperatures higher than those foreseen for an industrial operation (=1300°C).
[0014] This goal has been realised with the present invention, which allows for the insertion of palladium in a high melting perovskite of the BaZr-|.x Pdxp3 type. Attention has been drawn in a previous patent (6) to the high melting point (=2600°C) of the systems with a perovskite structure based on BaZrC>3.
[0015] One of the favourable characteristic of the barium-based systems is the limited production they permit of NOx: recent studies have shown that barium has the ability to decompose NOxto N2 and O2, so that the barium-based systems proposed here may be of general applicability for all the combustion processes aiming at limiting NOx emission - including those for motor-vehicles.
[0016] The materials of the present invention for which B is Rh are particularly suitable as catalysts for the partial oxidation of methane to syngas (CPO).
[0017] The two main technologies for the production of syngas are steam preforming of methane or virgin naphtha, and the non- catalytic autothermal processes.
[0018] Steam preforming involves as a first step, after the elimination of the sulphur containing compounds, the use of large scale catalytic reactors, prone to the formation of carbon, and with complex problems of downstream heat recovery.
[0019] The non-catalytic autothermal processes, on the other hand, involves very high temperatures in order to avoid the formation of carbon. As a consequence the use of a O2/CH4 ratio higher than the stoichiometric value and equal to about 0.7 becomes necessary, leading to the undesired formation of H2O and CO2 which reduces the efficiencies of subsequent syntheses.
[0020] Various solutions have been proposed in order to overcome the above drawbacks, among which catalytic partial oxidation appears to be one of the most promising for the following reasons: 1. 1) It involves carrying out the oxidation reaction, CH4 + 0.5 O2 —> CO + 2¾. at oxygen concentrations close to stoichiometric, and at lower temperatures (around 800-900°) thereby resulting in greater syngas yields, both in respect of methane and oxygen; 2. 2) The oxidation reactions are very fast, involving very high space-velocities; yields are high, with contact times of the order of milliseconds: the reactors may therefore be very small; 3. 3) The partial oxidation reaction leads to a production H2/CO ratio equal to 2, and therefore more suited to both Fischer-Tropsch and methanol syntheses; 4. 4) The process is very fast, and being catalytic makes it possible to control better the carbon formation.
[0021] The most promising catalysts for the above goals are those containing rhodium in a high melting and non-acidic matrix, such as those of the BaZr-|.xRhx03 systems proposed here.
[0022] The materials of the present invention may be prepared with suitable modifications to the citrate method described in [6].
[0023] The citrate route is a wet method for the synthesis of mixed oxides, vtfiich was proposed by Delmon and co-workers in the late nineteen sixties as an alternative to co-precipitation and to the ceramic method for the manufacture of high tech ceramic materials and catalysts [7, 8, 9, 10, 11, 12], [0024] This method offers a number of advantages, in particular it makes it possible to obtain: s» mixed oxides over a wide range of composition; > good control of the stoichiometry; > an excellent interspersion of the elements in final product; > very small grain size materials.
[0025] The first step of the proposed preparation method consists of the preparation of an aqueous solution of the nitrates of the required metals with citric acid (in a ratio of 1 equivalent of citric acid per equivalent of cation) and if necessary ammonium hydroxide.
[0026] The solution obtained is then concentrated by evaporation in a rotavapor and dried under vacuum until a meringue-type spongy solid is obtained, which may easily be ground to an amorphous powder.
[0027] Calcination then follows, which eliminates the organic substance and yields the desired oxides: a microcrystalline solid is obtained, with the ions well interspersed, often in a monophasic system.
[0028] The starting salts generally used in the original method were nitrates, because of their good solubility. However problems arise with these solutions during concentration, drying and calcination, due to the evolution of nitrogen oxides. Nitrogen oxides, in addition to being toxic and corrosive to the materials of the oven, may lead to a sudden decomposition of the organic substance, possibly resulting in an explosion or fire hazard. This occurs particularly when cations are present (such as those of Mn, Fe, Co, Cu and Ag), which may catalyse the oxidation of the organic substance.
[0029] The proposed method (anticipated in previous patents [6, 13, 14, 15]) has now been modified and improved in order to make it more widely applicable and less hazardous.
[0030] In the new method: nitrates are not used as starting salts, particularly in the presence of elements displaying a high catalytic activity for the combustion of the organic materials; the decomposition is carried out in milder conditions than in the original citrate route, thus involving: a lean oxygen gas flow (1.5% O2) and a low temperature (T ~350°C).
[0031] The method described in this invention combines the advantages of the wet methods with the possibility of utilising readily available reagents which are among the cheapest for the elements to be complexed; they are also easy to handle during the preparation, particularly in terms of temperature control.
[0032] The process envisages the following steps: - Preparation of the solution [0033] A clear solution containing the required elements is prepared using citric acid and ammonium hydroxide. The preparation then involves some special features which may be essential for achieving the final result. For example: as complexation is usually favoured by low temperatures, because of the low energy of activation in concentrated solutions, the use of externally ice-cooled solutions is preferred to favour the complexation of the cations and to reduce evaporation of ammonia. The dissolution of the noble metals, in particular palladium, is assisted by the presence of oxidising substances: in view of this, if the synthesis makes use of barium, for example, it may be convenient to use Ba02, otherwise H2O2 may be used. For the preparation of solutions containing Zr it is possible to use Zr isopropoxide (in an isopropanol solution) or hydrated zirconia. If Zr isopropoxide is used, it is necessary to carry out its hydrolysis by boiling it in a citric acid solution for a few hours until a clear solution is obtained - Concentration and drying of the overall solution [0034] The concentration may be carried out in a rotavapor. The viscous material that is obtained after this operation is then dried in a vacuum oven, typically at up to 200-220°C, in order to obtain a solid with a meringue-like consistency. This solid is then crushed and sieved in order to obtain a fine powder - with particle dimensions lower than, say 0.4 mm ("lOOmesh).
[0035] The initial overall solution could also be spray-dried, ideally utilising a fluid, such as CO2, under supercritic conditions; alternatively it may be employed for the impregnation of a support, such as silica or alumina, in order to produce a supported catalyst.
Decomposition of the organic substance [0036] The powders obtained from the previous step contain a high percentage of organic material which should be decomposed by oxidation. Best results are obtained utilising mild conditions, involving, for example, a flow of N2 containing 1.5% O2. The decomposition starts at around 330 to 390°C, and the progress of the reaction can be monitored either by a continuous measure of the powder temperature or by computing the oxygen consumption from the measured oxygen concentration in the outlet flow from the reactor. The powders at this stage contain mainly an amorphous phase characterised by a good interspersion of the elements.
[0037] They may also contain a small percentage of carbon, particularly in form of carbonates. - Final calcination [0038] A further step of calcination at high temperature (up to, say, 800-1000°C) is then performed in order to attain full crystallisation of the powders (11). The powders so obtained are of reliable stoichiometry and, in contrast to what occurs with other technologies, free of impurities.
[0039] In conclusion, the proposed variant of the citrate method of this invention allows for the preparation of aqueous solutions in citric acid and ammonia of very many elements of the periodic table without making use of nitrate salts. The interspersion in solution at atomic scale provides the best pre-condition for a good interspersion of the dried powder and, eventually, of the calcined powder, because the decomposition of the organic part is performed under mild conditions with good temperature control and in the absence of nitrates.
[0040] The following examples illustrate the invention in a greater detail.
Examples 1-2. Preparation of BaZri_xPdx03, BaZr-|_xRhx03.
[0041] The following reagents were used, in quantities reported in tables 2, 3, 4, 5, >- Zirconium isopropoxide solution, Zr(C3H70)4, in isopropyl alcohol (20.4% Zr b.w.), with density 1.044 g/cm3, (Aldrich); > Citric acid monohydrate, C6H807*H20, (99.8% b.w.), (Carlo Erba); > Ammonium hydroxide, NH4OH, (25% NH3 b.w.), with density 0.91 g/cm3, (Merck); > Barium peroxide, BaC>2, (92.66% b.w., the rest being BaO), (Materials Research, MRC); > Palladium II acetate, Pd(C2H302)2, (48.11% Pd b.w.), (Chempur); > Rhodium II acetate (36.59% Rh b.w.) (Reacton);
Example 1: BaZri.vPdvO^ preparation [0042] Two separate solutions are prepared and then mixed together: one containing dissolved zirconium and the other barium. Palladium is mixed directly into the solution containing barium in order to facilitate the dissolution: as indicated above, the oxidising properties of barium peroxide allow for an easy dissolution of palladium. This reduction in the number of solutions to be prepared results in lower costs in the event of case of scale-up of the process.
Table 2: Quantities of the reagents to be used for the zirconium solution for obtaining 20 g of final catalyst.
Table 3: Quantities of the reagents to be used for the barium and palladium solution for obtaining 20 g of final catalyst.
[0043] The first to be dissolved is zirconium. The citric acid solution is added to the zirconium isopropoxide, the products of hydrolysis being kept boiling under vigorous stirring conditions. The dissolution occurs in about eight hours. The iced-cooled ammonium hydroxide solution is then added to the zirconium solution, also previously ice-cooled.
[0044] The dissolution of barium peroxide requires a strong excess of citric acid compared to that proposed for the traditional citrate route.
[0045] A citric acid solution is prepared in the quantity necessary for the dissolution of both barium and palladium. Barium peroxide is slowly added with stirring to the citric acid solution at room temperature in order to minimise the formation of lumps. A slow and controlled development of small bubbles of oxygen is observed. As soon as the barium is dissolved, palladium acetate is added. The vessel is then ice-cooled and the calculated amount of ammonium hydroxide solution is added.
[0046] A transparent solution is obtained which is added to the cold zirconium solution previously prepared. The solution is then concentrated in a rotavapor.
[0047] The preparation described above is carried out for all the BaZr-i.xPdxOa samples.
Example 2: BaZri.vRhyO^ preparation [0048]
Table 4: Quantities of the reagents to be used for the zirconium solution for obtaining 20 g of final catalyst.
Table 5: Quantities of the reagents to be used for the barium and rhodium solution for obtaining 20 g of final catalyst
[0049] The zirconium solution is prepared in a similar way to that described for the palladium containing systems. The barium containing solution is also prepared in a similar way, and the citric acid computed for the complexation of rhodium is directly added to the citric acid computed for barium, as before. Rhodium acetate followed by ammonium hydroxide are then added to the solution containing barium. The transparent solution so obtained is then concentrated in a rotavapor.
Example 3: Characterisation of the BaZr-|.x Pd^CK samples [0050] Figure 3 shows the XRD diffractograms of various BaZr-|_xPdx03 samples calcined at 800°C for 4 hours.
[0051] It can be seen that the sample corresponding to the stoichiometry of BaPdC>3 (i.e. with 36.6 Pd b.w.) shows a diffractogram that is rather different from the others. This sample, when calcined at higher temperatures, does not form the perovskite phase; this confirms that the presence of a certain quantity of zirconium in the oxide is necessary in order to obtain this phase - as indicated in the first claim.
[0052] The various phases were identified by the search-match method (JCPDS data base) while the phase compositions and cell parameters were determined with great accuracy by full profile fitting refinement (Rietvield method) (16), using the Hill&Howard procedure (17), the WYRIET program and the structural data necessary from ICDS (18), thus obtaining the quantitative phase compositions shown in table 6.
Table 6
[0053] Cell parameters of the perovskite phase were determined, to forth decimal place precision, for samples containing palladium from 0 to 20% b.w. Table 7 gives the values found.
Table 7
[0054] The unusually precise determination of the cell parameters, due to an excellent fitting of the experimental data, shows unequivocally that the cell is perfectly cubic, with zirconium and palladium completely randomly distributed among the sites B of the perovskite. The steady decrease of the cell parameter with the increase of the noble metal content inside the structure, as shown in the previous table, and in Figure 4, indicates that the noble metal is present in a high oxidation state, probably as Pd+4. Indeed it should be recalled that only Pd44 in octahedral co-ordination presents an anionic radius (75.5 pm) smaller than the ionic radius of Zr44 in the same co-ordination (86 pm).
[0055] The presence of palladium within the structure in a high oxidation state reveals its lesser tendency to be reduced to the metallic state, with consequential deactivation, as seems to be confirmed by the high temperature thermogravimetric data.
[0056] It is possible to maximise the surface area of the samples by drying them under vacuum and low water partial pressure conditions at a temperature of up to about 200°C. This can be done either by employing very long drying times or by periodically purging the vacuum oven with dry air (by, say, introducing an air flow at regular interval, followed by full vacuum periods).
[0057] Catalytic activity data for the combustion of methane have been obtained for samples for which the surface areas have yet to be optimised. To perform these tests, 0.4 g of catalyst are mixed with 0.8 g of quartz, (140-200 mesh) and placed inside a quartz microreactor with internal diameter 8 mm. A layer of quartz particles, within the 20-30 mesh range and 12 cm thick, are then placed above the catalytic bed.
[0058] A gaseous, constant composition stream is fed to the reactor at a constant flow rate, and the appropriate temperaturetime profile is applied: > Inlet gas composition
Methane: 1 %, Oxygen: 4%, Nitrogen: 95%; > Flow 24 L/h [0059] Figure 5 reports the temperature at which 20% conversion is reached in runs employing both a gradually increasing and a gradually decreasing temperature.
[0060] Figures 6 and 7 show the results of thermogravimetric analysis (TGA) performed on the 15% b.w. Pd sample. It is noteworthy that the first onset of reduction of palladium occurs at about 100°C higher than in the following cycles in which PdO 7 supported on the perovskite should be present. In other words it confirms that the perovskite stabilizes palladium by making its reduction more difficult than in simply supported palladium.
[0061] The BaZro.6015^0.398503 sample (15% b.w. of Pd) was calcined at 1200°C in an oven operating with static air. Table 1 gives the quantitative phase composition measured and Table 2 the cell parameter (a) and cell volume (V). It shows that only about 50% of the palladium is extracted from the perovskite and transformed at room temperature into PdO. This means that the other half of palladium is still within the perovskite structure at 1200°C. The cell parameter is significantly increased with respect to the same sample calcined at 800°C, in agreement with the decreased content of palladium within the perovskite phase.
Example 4: Characterisation of the BaZr-i.vRhvO^ samples [0062] Table 8 shows the cell parameters as a function of x These data show a constant and regular decrease of the cell parameters. As in the palladium containing systems, these rhodium containing systems show that rhodium is present in a high oxidation state, probably as Rh+4.
Table 8
Thermal stability tests [0063] Numerous tests of thermal stability ware performed at various stages of the preparation and for different sample compositions: on the solution and on dried samples at various temperatures. Tests were performed with a differential scanning calorimeter DSC Mettler 800, using stainless steel closed crucibles, from room temperature up to 780°C in air, and with a heating rate of 10°C. All the samples showed a good stability and may therefore be handled safely. This is in contrast to current literature warnings that, for example, BaC>2 should not be mixed with water: such restrictions need not apply for water solutions of citric acid, which allow for the complexation of barium with a gradual and controlled release of oxygen in the form of small gas bubbles, thereby ensuring safe working.
REFERENCES
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REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard.
Patent documents cited in the description • ITMI962011A (00641 • WOf 6047Q7A Γ00641 • DE1933331 [0064) • WQ701330SA Γ00641 • EP91024Q4W [00641 • EP9001823W (00641 • ITMI932704A [00641
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Claims (9)
1. Materials having a perovskite structure in the form of solid solutions of the general formula: AzZri-xBx03 wherein A is Ba, B is Pt, Ir, Pd or Rh, Z is 1, X is in the range from 0.01 to 0, eighth
2. Materials according to claim 1, wherein B is Pd or Rh.
3. Materials according to claim 2, taken from BaZri.xPdxC> 3 BaZri.xRhxC '3.
4. Use of the materials according to claims 1-3 as catalysts.
5. Use according to claim 4 as a catalyst for the catalytic combustion of methane for energy uses.
6. The use of claim 4 for the catalytic partial oxidation of methane to synthesis gas.
7. Use according to claim 4 for catalytic converters for catalytic silencers for motor vehicles.
8. Use according to claim 4 to catalysts for the elimination of VOC.
9. Use according to claim 4 for the oxidation of light alkanes into the corresponding ole-veneer.
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JPH07116519A (en) | 1993-10-20 | 1995-05-09 | Toyota Central Res & Dev Lab Inc | Exhaust gas purifying material and purifying method of exhaust gas |
JPH0866621A (en) | 1994-06-20 | 1996-03-12 | Toyota Central Res & Dev Lab Inc | Method for removing nitrogen oxide |
CA2298850A1 (en) | 1999-02-17 | 2000-08-17 | Matsushita Electric Industrial Co., Ltd. | Mixed ionic conductor and device using the same |
US6517693B2 (en) * | 2000-02-14 | 2003-02-11 | Matsushita Electric Industrial Co., Ltd. | Ion conductor |
-
2001
- 2001-07-17 IT IT2001MI001519A patent/ITMI20011519A1/en unknown
-
2002
- 2002-07-16 ES ES02764701.5T patent/ES2535502T3/en not_active Expired - Lifetime
- 2002-07-16 US US10/483,775 patent/US7166267B2/en not_active Expired - Fee Related
- 2002-07-16 DK DK02764701.5T patent/DK1406725T3/en active
- 2002-07-16 EP EP02764701.5A patent/EP1406725B1/en not_active Expired - Lifetime
- 2002-07-16 WO PCT/EP2002/007906 patent/WO2003008095A2/en not_active Application Discontinuation
- 2002-07-16 AU AU2002328904A patent/AU2002328904A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20040202598A1 (en) | 2004-10-14 |
AU2002328904A1 (en) | 2003-03-03 |
WO2003008095A2 (en) | 2003-01-30 |
EP1406725A2 (en) | 2004-04-14 |
ES2535502T3 (en) | 2015-05-12 |
EP1406725B1 (en) | 2015-01-28 |
WO2003008095A3 (en) | 2003-10-16 |
ITMI20011519A1 (en) | 2003-01-17 |
ITMI20011519A0 (en) | 2001-07-17 |
US7166267B2 (en) | 2007-01-23 |
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