DK108689A - PROCEDURE FOR PREPARING Aqueous POLYALKYLMETHACRYLATE DISTRIBUTIONS BY EMULSION POLYMERIZATION IN TWO STEPS AND USE THEREOF FOR TRAELAK - Google Patents
PROCEDURE FOR PREPARING Aqueous POLYALKYLMETHACRYLATE DISTRIBUTIONS BY EMULSION POLYMERIZATION IN TWO STEPS AND USE THEREOF FOR TRAELAKInfo
- Publication number
- DK108689A DK108689A DK108689A DK108689A DK108689A DK 108689 A DK108689 A DK 108689A DK 108689 A DK108689 A DK 108689A DK 108689 A DK108689 A DK 108689A DK 108689 A DK108689 A DK 108689A
- Authority
- DK
- Denmark
- Prior art keywords
- weight
- methacrylate
- dispersion
- carbon atoms
- dicarboxylic acids
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
Abstract
A process for the preparation of aqueous dispersions of alkyl methacrylate copolymers with mono- and/or dicarboxylic acids containing from 3 to 6 carbon atoms by stepwise emulsion copolymerisation in the presence of conventional water-soluble, free radical-forming polymerisation initiators and in the presence of conventional emulsifiers at conventional polymerisation temperatures is characterised in that 85.25-37.5% by weight of methyl methacrylate, 14.75-62.5% by weight of n-butyl methacrylate and/or isobutyl methacrylate, 1-5% by weight of alpha , beta -monoolefinically unsaturated mono- and/or dicarboxylic acids containing 3-6 carbon atoms, and 0-5% by weight of amides of alpha , beta -monoolefinically unsaturated mono- and/or dicarboxylic acids containing 3-5 carbon atoms, are polymerised in aqueous emulsion in two steps in such a manner that the dispersion has a minimum film-forming temperature of 65-110 DEG C and a light transparency of at least 85%. This dispersion is used together with a further polyalkyl methacrylate dispersion, but one which has a minimum film-forming temperature of from 20 to 60 DEG C, as a binder in wood paints.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3807531A DE3807531A1 (en) | 1988-03-08 | 1988-03-08 | PRODUCTION OF AQUEOUS POLYALKYL METHACRYLATE DISPERSIONS BY EMULSION POLYMERIZATION IN TWO STAGES AND THEIR USE IN WOODEN VARNISHES |
Publications (2)
Publication Number | Publication Date |
---|---|
DK108689D0 DK108689D0 (en) | 1989-03-07 |
DK108689A true DK108689A (en) | 1989-09-09 |
Family
ID=6349132
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK108689A DK108689A (en) | 1988-03-08 | 1989-03-07 | PROCEDURE FOR PREPARING Aqueous POLYALKYLMETHACRYLATE DISTRIBUTIONS BY EMULSION POLYMERIZATION IN TWO STEPS AND USE THEREOF FOR TRAELAK |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0332011B1 (en) |
JP (1) | JPH026511A (en) |
AT (1) | ATE69244T1 (en) |
AU (1) | AU3106489A (en) |
DE (2) | DE3807531A1 (en) |
DK (1) | DK108689A (en) |
ES (1) | ES2026707T3 (en) |
FI (1) | FI891101A (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5635564A (en) * | 1988-12-09 | 1997-06-03 | Basf Lacke + Farben, Ag | Preparation of a multicoat coating, water-thinnable coating compositions, water-thinnable emulsion polymers and preparation of water-thinnable emulsion polymers |
DE3841540A1 (en) * | 1988-12-09 | 1990-06-13 | Basf Lacke & Farben | METHOD FOR PRODUCING A MULTILAYER COATING, WATER-DUMBABLE COATING COMPOSITIONS, WATER-DUMBABLE EMULSION POLYMERS AND METHOD FOR PRODUCING WATER-DUMPABLE EMULSION POLYMERS |
DE3843965A1 (en) * | 1988-12-24 | 1990-07-12 | Roehm Gmbh | MULTI-PHASE, AQUEOUS PLASTIC DISPERSION AND THEIR USE IN COATING AGENTS |
DE3902103A1 (en) * | 1989-01-25 | 1990-08-02 | Roehm Gmbh | BINDER FOR WAESSED GLOSSY COLORS |
US5035944A (en) * | 1989-11-13 | 1991-07-30 | Rohm And Haas Company | Method for treating substrates |
DE3942804A1 (en) * | 1989-12-23 | 1991-06-27 | Basf Lacke & Farben | METHOD FOR PRODUCING A MULTILAYER COATING |
US5149729A (en) * | 1990-05-01 | 1992-09-22 | Ppg Industries, Inc. | Waterborne acrylic stain composition containing core-shell grafted polymers |
BR9104402A (en) * | 1991-10-10 | 1993-04-20 | Glasurit Do Brasil Limitada | WATER DILUTABLE EMULSION POLYMER, PROCESS FOR THE PREPARATION OF A WATER DILUTABLE EMULSION POLYMER, WATER COATING COMPOSITION AND POLYMER USE |
DE4213964A1 (en) * | 1992-04-29 | 1993-11-04 | Basf Ag | AQUEOUS POLYMER DISPERSIONS |
DE4336206A1 (en) * | 1993-10-23 | 1995-04-27 | Hoechst Ag | Aqueous self-crosslinking polyurethane-vinyl hybrid dispersions |
DE4340648A1 (en) * | 1993-11-30 | 1995-06-01 | Hoechst Ag | Aqueous polymer dispersions as binders for block-resistant, scratch-resistant and chemical-resistant coatings |
DE19609509B4 (en) * | 1996-03-11 | 2006-11-02 | Celanese Emulsions Gmbh | Aqueous polymer dispersions as a binder for elastic block and scratch resistant coatings |
AU771383B2 (en) | 1998-12-08 | 2004-03-18 | Rohm And Haas Company | Dirt pickup resistant coating binder and coatings |
KR100357961B1 (en) * | 2000-08-04 | 2002-10-25 | 삼성에스디아이 주식회사 | Method for preparing acryl emulsion |
CN103601837B (en) * | 2013-11-15 | 2015-10-28 | 杭州海维特化工科技有限公司 | A kind of polyacrylate dispersion and preparation method |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE806279A (en) * | 1972-11-16 | 1974-04-19 | Du Pont | AQUEOUS THERMOSETTING ACRYLIC ENAMEL |
US4385152A (en) * | 1979-11-06 | 1983-05-24 | Boyack Robert M | Acrylic polymer emulsion |
-
1988
- 1988-03-08 DE DE3807531A patent/DE3807531A1/en not_active Withdrawn
-
1989
- 1989-02-28 EP EP89103443A patent/EP0332011B1/en not_active Expired - Lifetime
- 1989-02-28 ES ES198989103443T patent/ES2026707T3/en not_active Expired - Lifetime
- 1989-02-28 DE DE8989103443T patent/DE58900423D1/en not_active Expired - Lifetime
- 1989-02-28 AT AT89103443T patent/ATE69244T1/en not_active IP Right Cessation
- 1989-03-06 JP JP1052195A patent/JPH026511A/en active Pending
- 1989-03-07 AU AU31064/89A patent/AU3106489A/en not_active Abandoned
- 1989-03-07 DK DK108689A patent/DK108689A/en not_active Application Discontinuation
- 1989-03-08 FI FI891101A patent/FI891101A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
FI891101A (en) | 1989-09-09 |
EP0332011B1 (en) | 1991-11-06 |
ES2026707T3 (en) | 1992-05-01 |
DK108689D0 (en) | 1989-03-07 |
FI891101A0 (en) | 1989-03-08 |
AU3106489A (en) | 1989-09-14 |
DE58900423D1 (en) | 1991-12-12 |
EP0332011A1 (en) | 1989-09-13 |
DE3807531A1 (en) | 1989-09-21 |
ATE69244T1 (en) | 1991-11-15 |
JPH026511A (en) | 1990-01-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AHB | Application shelved due to non-payment |