DK0656810T3 - Catalyst and catalytic process for reducing nitrogen oxides - Google Patents

Catalyst and catalytic process for reducing nitrogen oxides

Info

Publication number
DK0656810T3
DK0656810T3 DK94920994T DK94920994T DK0656810T3 DK 0656810 T3 DK0656810 T3 DK 0656810T3 DK 94920994 T DK94920994 T DK 94920994T DK 94920994 T DK94920994 T DK 94920994T DK 0656810 T3 DK0656810 T3 DK 0656810T3
Authority
DK
Denmark
Prior art keywords
catalyst
nitrogen oxides
reducing nitrogen
catalytic process
catalytic
Prior art date
Application number
DK94920994T
Other languages
Danish (da)
Inventor
Christine Lecuyer
Ahmed Fakche
Edouard Garbowski
Bernard Pommier
Michel Primet
Original Assignee
Gaz De France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaz De France filed Critical Gaz De France
Application granted granted Critical
Publication of DK0656810T3 publication Critical patent/DK0656810T3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/208—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

A catalyst and a catalytic method for reducing nitrogen oxides are disclosed. The catalyst consists of an MFI zeolite exchanged with 0.3-2 wt % of palladium on the basis of the overall weight of the catalyst. Said catalyst and method may be used in any selective catalytic nitrogen oxide reduction method, in particular for treating exhaust gases from natural gas powered vehicles.
DK94920994T 1993-06-30 1994-06-29 Catalyst and catalytic process for reducing nitrogen oxides DK0656810T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9308006A FR2707075B1 (en) 1993-06-30 1993-06-30 NOx reduction catalyst and NOx reduction catalytic process.
PCT/FR1994/000792 WO1995001222A1 (en) 1993-06-30 1994-06-29 Catalyst and catalytic method for reducing nitrogen oxides

Publications (1)

Publication Number Publication Date
DK0656810T3 true DK0656810T3 (en) 1999-09-06

Family

ID=9448752

Family Applications (1)

Application Number Title Priority Date Filing Date
DK94920994T DK0656810T3 (en) 1993-06-30 1994-06-29 Catalyst and catalytic process for reducing nitrogen oxides

Country Status (10)

Country Link
EP (1) EP0656810B1 (en)
JP (1) JPH08500772A (en)
AT (1) ATE175591T1 (en)
CA (1) CA2142889A1 (en)
DE (1) DE69415950T2 (en)
DK (1) DK0656810T3 (en)
ES (1) ES2129131T3 (en)
FR (1) FR2707075B1 (en)
GR (1) GR3029936T3 (en)
WO (1) WO1995001222A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5874646A (en) * 1996-08-07 1999-02-23 Solutia Inc. Preparation of phenol or phenol derivatives
GB201504986D0 (en) * 2015-02-13 2015-05-06 Johnson Matthey Plc Oxidation catalyst for treating a natural gas emission
BR112019000366A2 (en) * 2016-07-12 2019-04-24 Johnson Matthey Public Limited Company oxidation catalyst, exhaust system, and apparatus.

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4176050A (en) * 1978-12-04 1979-11-27 Mobil Oil Corporation Production of high V.I. lubricating oil stock
US4232181A (en) * 1979-06-28 1980-11-04 Norton Company Hydroisomerization of pentane utilizing Pd exchanged mordenite
FR2619319B1 (en) * 1987-08-14 1990-01-12 Inst Francais Du Petrole ALUMINOSILICATE TYPE CATALYST CONTAINING AT LEAST ONE NOBLE METAL AND ITS USE IN ISOMERIZATION OF AN AROMATIC C8 CUT
DE3917890A1 (en) * 1989-06-01 1990-12-06 Steinbach Friedrich SUPPORTED CATALYSTS FOR THE REMOVAL OF NITROGEN OXIDE, CARBON MONOXIDE AND ORGANIC COMPOUNDS FROM EXHAUST GAS
US5171553A (en) * 1991-11-08 1992-12-15 Air Products And Chemicals, Inc. Catalytic decomposition of N2 O

Also Published As

Publication number Publication date
DE69415950D1 (en) 1999-02-25
FR2707075A1 (en) 1995-01-06
ATE175591T1 (en) 1999-01-15
CA2142889A1 (en) 1995-01-12
EP0656810B1 (en) 1999-01-13
WO1995001222A1 (en) 1995-01-12
GR3029936T3 (en) 1999-07-30
ES2129131T3 (en) 1999-06-01
JPH08500772A (en) 1996-01-30
FR2707075B1 (en) 1995-09-22
EP0656810A1 (en) 1995-06-14
DE69415950T2 (en) 1999-08-26

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