DK0463947T3 - New sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers - Google Patents

New sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers

Info

Publication number
DK0463947T3
DK0463947T3 DK91401685.2T DK91401685T DK0463947T3 DK 0463947 T3 DK0463947 T3 DK 0463947T3 DK 91401685 T DK91401685 T DK 91401685T DK 0463947 T3 DK0463947 T3 DK 0463947T3
Authority
DK
Denmark
Prior art keywords
meth
acrylate
alkyl
new
reaction
Prior art date
Application number
DK91401685.2T
Other languages
Danish (da)
Inventor
Martine Cerf
Jean-Luc Mieloszynski
Daniel Paquer
Original Assignee
Atochem Elf Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa
Application granted granted Critical
Publication of DK0463947T3 publication Critical patent/DK0463947T3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/38—Esters containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/54—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Process for the preparation of a (meth)acrylate (VI) where G = -CH2SR' (R' = alkyl which may carry an OH functional group, in which case Q = alkyl, or else H); or G = H or CH3, in which case Q = -(CH2)n-SxOyZ (1 </= n </= 12; 1 </= x </= 3; 0 </= y </= 2; and Z = alkyl, cycloalkyl, alkenyl, aryl, alkylaryl, aralkyl or heterocyclic ring which may carry an ester functional group), by reaction of a (meth)acrylate (VII), where R = H, CH3 or -CH2X (X = Hal and Q = alkali metal or alkyl) with a sulphur compound R'SH or ZS(CH2)nX, the said reaction being carried out in an at least partially aqueous medium at 50-100 DEG C or in an organic solvent whose b.p. < 100 DEG C, in the presence of at least one polymerisation inhibitor and of at least one phase transfer agent and resulting, when R = H or CH3, in a (meth)acrylate (VI-a) where G = H or CH3 and y = 0, in which case this first reaction may be followed by an oxidation reaction at approximately 10-60 DEG C, to obtain a (meth)acrylate (VI) where y > 0. <IMAGE>
DK91401685.2T 1990-06-27 1991-06-21 New sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers DK0463947T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9008109A FR2663928B1 (en) 1990-06-27 1990-06-27 NOVEL SULFUR ACRYLIC COMPOUNDS, A PROCESS FOR THEIR PREPARATION AND THEIR APPLICATION TO THE SYNTHESIS OF NEW POLYMERS.

Publications (1)

Publication Number Publication Date
DK0463947T3 true DK0463947T3 (en) 1995-12-04

Family

ID=9398075

Family Applications (1)

Application Number Title Priority Date Filing Date
DK91401685.2T DK0463947T3 (en) 1990-06-27 1991-06-21 New sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers

Country Status (9)

Country Link
EP (1) EP0463947B1 (en)
JP (1) JPH0778100B2 (en)
AT (1) ATE129491T1 (en)
CA (1) CA2045736C (en)
DE (1) DE69114054T2 (en)
DK (1) DK0463947T3 (en)
ES (1) ES2078469T3 (en)
FR (1) FR2663928B1 (en)
GR (1) GR3018473T3 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2687400A1 (en) * 1992-02-17 1993-08-20 Atochem Elf Sa NOVEL (METH) ACRYLIC COMPOUNDS, PROCESS FOR PREPARING THEM AND THEIR USE IN THE SYNTHESIS OF NOVEL POLYMERS.
FR2771740B1 (en) * 1997-12-01 1999-12-31 Atochem Elf Sa METHACRYLIC SULFUR MONOMERS AND THEIR PREPARATION
TWI360535B (en) 2007-08-30 2012-03-21 Univ Nat Sun Yat Sen Sulfur-containing compound, method of preparation
US8741966B2 (en) 2007-11-09 2014-06-03 Pronova Biopharma Norge As Lipid compounds for use in cosmetic products, as food supplement or as a medicament
EP2147910A1 (en) 2008-07-15 2010-01-27 Pronova BioPharma Norge AS Novel lipid compounds
MX366137B (en) 2009-05-08 2019-06-28 Pronova Biopharma Norge As Polyunsaturated fatty acids for the treatment of diseases related to cardiovascular, metabolic and inflammatory disease areas.
MX350720B (en) 2010-11-05 2017-09-14 Pronova Biopharma Norge As Methods of treatment using lipid compounds.
EP2961384B1 (en) 2013-02-28 2019-08-28 Basf As A composition comprising a lipid compound, a triglyceride, and a surfactant, and methods of using the same
JP6784696B2 (en) 2015-04-28 2020-11-11 プロノヴァ バイオファーマ ノルゲ エーエス Use of structurally fortified fatty acids containing sulfur for the prevention and / or treatment of non-alcoholic steatohepatitis
US11925614B2 (en) 2017-12-06 2024-03-12 Basf As Fatty acid derivatives for treating non-alcoholic steatohepatitis

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432128A1 (en) * 1972-04-13 1974-06-15 М. А. Коршунов, Р. Г. Кузовлева , И. В. Фураева METHOD OF OBTAINING ALKYL (ALKENYL) THIOMETHYL ACRYLATE OR METHACRYLATE
JPS5052027A (en) * 1973-09-11 1975-05-09
DE2638386A1 (en) * 1976-08-26 1978-03-02 Basf Ag WATER-SOLUBLE, CURABLE ACRYLIC COPOLYMERS, METHOD FOR THEIR PRODUCTION AND THEIR USE
JPS5735561A (en) * 1980-08-13 1982-02-26 Sumitomo Chem Co Ltd Novel alpha- mercaptomethyl acrylic acid derivative
JPS58194801A (en) * 1982-05-07 1983-11-12 Daicel Chem Ind Ltd Plant growth suppressing agent
JPS59134748A (en) * 1983-01-18 1984-08-02 Daicel Chem Ind Ltd Beta-substituted-alpha-methylenepropionic acid ester
JPS59212752A (en) * 1983-05-19 1984-12-01 Fuji Photo Film Co Ltd Medium material for electrophoresis
EP0190993B1 (en) * 1985-01-30 1989-11-08 Ciba-Geigy Ag Perfluoroalkylsulfonoalkyl acrylates and methacrylates, process for their preparation and their use

Also Published As

Publication number Publication date
ATE129491T1 (en) 1995-11-15
FR2663928B1 (en) 1994-04-08
GR3018473T3 (en) 1996-03-31
DE69114054D1 (en) 1995-11-30
DE69114054T2 (en) 1996-06-13
FR2663928A1 (en) 1992-01-03
JPH0778100B2 (en) 1995-08-23
ES2078469T3 (en) 1995-12-16
CA2045736A1 (en) 1991-12-28
EP0463947A1 (en) 1992-01-02
EP0463947B1 (en) 1995-10-25
CA2045736C (en) 2001-04-10
JPH04356510A (en) 1992-12-10

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