DEP0049124DA - Process for the production of rubber compounds - Google Patents
Process for the production of rubber compoundsInfo
- Publication number
- DEP0049124DA DEP0049124DA DEP0049124DA DE P0049124D A DEP0049124D A DE P0049124DA DE P0049124D A DEP0049124D A DE P0049124DA
- Authority
- DE
- Germany
- Prior art keywords
- production
- mixture
- rubber compounds
- minutes
- coal tar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- 150000001875 compounds Chemical class 0.000 title description 2
- 238000000034 method Methods 0.000 title description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 12
- 239000011280 coal tar Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- SGBDRKZSMKKNHE-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C Chemical compound N=C=O.N=C=O.N=C=O.C SGBDRKZSMKKNHE-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 210000000554 iris Anatomy 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- UOJMTSCORVQOHS-UHFFFAOYSA-N pachypodol Natural products COc1cc(ccc1O)C2=C(C)C(=O)c3c(O)cc(C)cc3O2 UOJMTSCORVQOHS-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Description
Prof« J)i% Otto 2ay@r lisa Ite-*, fea$t Gatiar (WideProf «J) i% Otto 2ay @ r lisa Ite- *, fea $ t Gatiar (Wide
To JmIi 1949To JmIi 1949
¥ erf ahre-ö. sur Bex@telltt&g tfö¥ experience-ö. sur Bex @ telltt & g tfö
Torliegeude ÄrfSjsduzi« ltetrifft ein Verfahren aar Hsryob. Kaiatsetmfcaisolsiti^gea» welc&e siaerseits leicht bar sind imä aad«r@rasits einen feohem 6-eiialt an Füll» feoff ©a m±$®m iaad iBfölgeä^SBes haf'te fmlkasi^ate liefern. & laaixd<?it sieh Iseiapielswais® ma harte BitsohmsigeB ft^ teoiitkläcbe ZwQQk® isaer τοιχ 3etofe0ofei®ja®aterle.i» welche la äex Segel einen sehr hohen GteftaXt (80 ^ m^d Kefer) anTorliegeude ÄrfSjsduzi «ltftert a procedure aar Hsryob. Kaiatsetmfcaisolsiti ^ gea »welc & e on the other hand are easy to cash out imä aad« r @ rasits a feohem 6-eiialt of fill »feoff © a m ± $ ®m iaad iBfölgeä ^ SBes haf'te fmlkasi ^ ate deliver. & laaixd <? it see Iseiapielswais® ma harte BitsohmsigeB ft ^ teoii tkläcbe ZwQQk® isaer τοιχ 3etofe0ofei®ja®aterle.i »which la äex sails a very high GteftaXt (80 ^ m ^ d Kefer)
fülletoffea eBtfealtea« Si® g gfülletoffea eBtfealtea «Si® g g
aaf der Mieohw^l^e o4ef Xm Sa«t€i«r erfaräe^t tee h einen ssehr liöB®» Sreftverte?iuoii0 Bieser ken» durch 2ufal&e tföb fslolimacli«yA sq der Miseiixmg Ter ring extaaf der Mieohw ^ l ^ e o4ef Xm Sa «t € i« r erfaräe ^ t tee h a ssehr liöB® »Sreftverte? iuoii 0 Bieser ken» by 2ufal & e tföb fslolimacli «yA sq der Miseiixmg Ter ring ext
irisen aber anier^rseits wiedex1 die 4®s ¥alksaiaa,tes» ^©r alleabut irises on the other side like 1 the 4®s ¥ alksaiaa, tes »^ © r allea
j dass iaaaa ^sI äer Herstellung der gefüiltea Miscfetmgea einen relativ toäea Prösentsata bestimater Weioiiaaciiuagsaittal 2-ssetst> Imiepleleweise etws 15 - 30 $ e bcrjSste@t auf die üte&g« ^aatsdliiik«. Als Wsiciimaefcter werä^a solche toenutsfe, welche r^»ktioa@fi.Mge ftassersto ff atome halten^ b@ä^lel®w®is® im ?#im vonj that iaaaa ^ sI äer production of the gefüiltea Miscfetmgea a relatively toäea Prösentsata destimater Weioiiaaciiuagsaittal 2-ssetst> Imiepleleweise about 15-30 $ e bcrjSste @ t on the üte & g «^ aatsdliiik«. As a Wsiciimaefcter werä ^ a such toenutsfe, which r ^ »ktioa@fi.Mge Fassersto ff atoms hold ^ b @ ä ^ lel®w®is® im? #Im of
gruppen, AaiaofrmppeB ώϊ€ ägl«. Hacii fertigatellwig äer Mischungen werden Aaxm
tionelle orgaaisöfe© Iaooyaaategroups, AaiaofrmppeB ώϊ € Ägl «. Hacii ready-made mixtures are Aaxm
tional organic stoves © Iaooyaaate
Als solche kommen beispielsweise Sripheaylmethantriiaocyanat oder ein iJm^etsuagsprodukt aus einem Mol eines dreiwertigen Alkohols mit drei McI eines !riisocyanats infrage* Derartige Mischungen köxaaea. boc!t leicht in die zur Konfektion bswa Vulkanisation Vorgesehene Form, SoB« in eine Platte bestirnter Stärke gebracht werden» Bei der weiteren Verarbeitung, insbesondere bei der ?ulkanisation, tritt dann aber sine chemische umsetzung swiec^en den Äeichmachern und den pölyfunictioöellen Isocyanaten β in ^1 welch? Vernotzung verläuft uni dadurch bei richtiger Ifosiermig Härte des ¥ulkanisates a'xf ά$η Stand bringtp der ait der« selben Mischung ohne 2usata !?on Weichmacher erreicht worden wäre* Als geeignete feichiaacher kommen beiapielsweiae Fiohtenholzteei-s Steinfeohleateer^-Heiaöli Braunkohleateörpech» infrage.Examples of such compounds are sipheayl methane triisocyanate or an iJm ^ etsuagsprodukt of one mole of a trihydric alcohol with three moles of a riisocyanate. Mixtures of this kind are possible. boc! t easily into the bsw to confection a vulcanization Intended form SoB "be brought into a plate bestirnter strength" ulkanisation In the further processing, especially in the?, but then enters sine chemical implementation SWIEC ^ s the Äeichmachern and pölyfunictioöellen isocyanates β in ^ 1 which? Vernotzung runs uni thus with proper Ifosiermig hardness of ¥ ulkanisates a'xf ά $ η stand brings the p ait the "same mixture without 2usata! ? on plasticizers would have been achieved.
Die ersielte Wirkung wird durcli die folgende stellung erläutertsThe resulting effect is explained by the following position
¥oa Je drei Kilo laturkautschuk ausgelienä wurden folgender Zueanuaenaeteung hergestellt¥ oa Three kilograms of natural rubber were supplied each time the following Zueanuaenaeteung were produced
225,5225.5
245,5245.5
J}er Mischung 2 «UFöe gegen Ende der Xisohwngshersteilung I $ lfclphenylmefchantrlisooyanet sug©mischt»J} er mixture 2 "UFöe towards the end of the production process I $ lfclphenylmefchantrlisooyanet sug © mixes"
Bar jeweilige Kraftferbrauoh betrug;Bar respective Kraftferbrauoh was;
Mischung 1 Mischung 2Mixture 1 Mixture 2
für die Mast'ikafcion desfor the mast'ikafcion of
Sautschuks in &®xi erstenSautschuks in & ®xi first
sechs Mini1.ten tob 24 kW abfallend au^ 12 fewsix mini 1st tob 24 kW sloping au ^ 12 few
Beim JSinmischen von Kaolin»When mixing kaolin »
Steinkohlenteerpeeh9 Stearin-Coal tar peeh 9 stearin
ääm?s und ?ulfeaisitv W inaer-ääm? s and? ulfeaisit v W inaer-
halt zehn Minuten 12 kW 12lasts ten minutes 12 kW 12
Huss Slastik (Dauer 5 Min.) 15 kWHuss Slastik (duration 5 min.) 15 kW
Elastik +
teerheieöl (Daaor 5 Min.) 14 - 15 kWElastic +
Tar hot oil (Daaor 5 min.) 14 - 15 kW
des ßssrusses
(Bauer 27 Mino) 19 kW 15 kWthe ßssrusses
(Farmer 27 min o ) 19 kW 15 kW
$@saaitai8ob,seit 38 Minuten * Während 1? Minuten wurden$ @ saaitai8ob, for 38 minutes * During 1? Minutes
4 kW erspart«4 kW saved «
Wurden die M%aGhmigen erkaltet neu durchgelassen;, so gsrgab »ichIf the poor were allowed to pass through again, cold, "I said."
fm- Mischung 1 40-70 kW, &&n& blieb die Waise fm- mixture 1 40-70 kW, && n & remained the orphan
«l©r kilMTerbrauch tiberstieg Leistung des Antriebsaggregate^.«The kilM consumption exceeded the power of the drive units ^.
für Mischung 2 4-0 - 55 kH als anfängliche Spitzenkraft Iaindem sα Mischung 2 die- obengenannte Menge an Triiso= cyanat ssugeaisciit worden war, ergab die Vulkanisation von 4 HUä Klappe-i in der Presse bei 10 Minuten 4 Atu für Mischung 1 di® Shore-Härte ύοά 86°for mixture 2 4-0 - 55 kH as the initial peak force Iaindem sα mixture 2 the above-mentioned amount of triiso = cyanate was added, the vulcanization of 4 HUä flap-i in the press for 10 minutes resulted in 4 Atu for mixture 1 di® Shore hardness ύοά 86 °
«r " '2 " " w n B5'^«R"'2"" w n B5' ^
« "' 1 di© Schopper Elaatiaität von 33 % « "'1 di © Schopper elaatiaity of 33 %
Festigkelten und Dehnungen lagen naheau gleich.Strengthening and stretching were almost the same.
Claims (1)
Family
ID=
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