DE98970C - - Google Patents
Info
- Publication number
- DE98970C DE98970C DENDAT98970D DE98970DA DE98970C DE 98970 C DE98970 C DE 98970C DE NDAT98970 D DENDAT98970 D DE NDAT98970D DE 98970D A DE98970D A DE 98970DA DE 98970 C DE98970 C DE 98970C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- dyes
- dioxynaphthalene
- amidonaphthalene
- azoxyaniline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002253 acid Substances 0.000 claims description 18
- 239000000975 dye Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 3
- 230000001264 neutralization Effects 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 230000002378 acidificating Effects 0.000 claims 1
- 239000000987 azo dye Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 3
- 239000001045 blue dye Substances 0.000 description 3
- 150000008049 diazo compounds Chemical class 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-Naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-Diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-Naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 240000007108 Fuchsia magellanica Species 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001047 purple dye Substances 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
[1[1
ETCHESETCHES
PATENTAMT.PATENT OFFICE.
Nach dem Verfahren des Haupt - Patentes Nr. 44045 werden gelbrothe und rothe Farbstoffe erhalten, indem die Diazoverbindungen von m-Azoxyanilin, m-Azoxy-o-toluidin, m-Azoxy-p-toluidin mit a-Naphtol-a-sulfosäure (Piria), β - Naphtoldisulfosäure (R-Säure), Resorcin, Naphtionsä'ure (Piria), ß-Naphtylaminsulfosäure, a-Naphtylamin oder m-Toluylendiamin gekuppelt werden.Following the process of the main patent no. 44045, yellow-red and red colorants become obtained by the diazo compounds of m-azoxyaniline, m-azoxy-o-toluidine, m-azoxy-p-toluidine with a-naphthol-a-sulfonic acid (Piria), β - naphtholedisulfonic acid (R-acid), resorcinol, Naphthic acid (Piria), ß-naphthylamine sulfonic acid, α-naphthylamine or m-tolylenediamine be coupled.
Nach dem Patente Nr. 54655 werden violette Farbstoffe erhalten, wenn m-Azoxyamine durch p-Azoxyanilin ersetzt werden. Alle diese Farbstoffe besitzen die gemeinsame Eigenschaft, Baumwolle nach einem speciellen Verfahren zu färben.According to patent no. 54655, purple dyes are obtained when m-azoxyamines are carried out p-azoxyaniline can be replaced. All of these dyes have the common property To dye cotton using a special process.
Es gelingt dies in mit Kochsalz beinahe gesättigten Lösungen und in Gegenwart bedeutender Mengen von Aetznatron oder Aetzkalk. Es wurde nun gefunden, dafs, wenn p-Azoxyamine als Diazoverbindungen' auf folgende Naphtalinderivate einwirken, nämlich auf Amidonaphtoldisulfosäure H (Patent Nr. 67062) oder Dioxynaphtalinmonosulfosä'ure S (Patent Nr. 67829) blaue Farbstoffe entstehen., welche sich vorzüglich zum Färben der vegetabilischen Faser eignen. Diese Farbstoffe sind in den Patentschriften Nr. 44045 und 54655 nicht vertreten. Aufserdem besitzen sie gröfsere Affinität zur Faser, so dafs die Ausfärbung ohne Zusatz von Aetznatron stattfindet. Eine Zugabe von Kochsalz ist nur in geringen Mengen (etwa bis zu 5 pCt.) erforderlich.This succeeds more significantly in solutions that are almost saturated with table salt and in the presence Quantities of caustic soda or caustic lime. It has now been found that if p-Azoxyamines act as diazo compounds' on the following naphthalene derivatives, namely on Amidonaphthalene disulfonic acid H (Patent No. 67062) or Dioxynaphthalene monosulfonic acid S (Patent No. 67829) blue dyes arise, which are excellent for coloring vegetable Fiber are suitable. These dyes are not in Patent Nos. 44045 and 54655 represent. They also have a greater affinity for the fiber, so that the coloration takes place without the addition of caustic soda. The addition of table salt is only marginal Quantities (up to about 5 pCt.) Required.
Dabei sind diese Farbstoffe gegen Säuren und Alkalien beständig, so dafs die Farben ziemlich dieselben sind, ob in saurem, neutralem oder alkalischem Bade gefärbt wird.These dyes are resistant to acids and alkalis, so are the colors are much the same whether dyeing is done in an acid, neutral, or alkaline bath.
. Man löst 11,4 kg ρ-Azoxyanilin (Schmelzpunkt 187 bis 1890) in 25 kg Chlorwasserstoffsäure von 20° B. und 100 1 kochendem Wasser, verdünnt die Flüssigkeit mit Eis und Wasser auf 600 1 und giebt ihr 7 kg g8procentiges Natriumnitrit in 21 1 Wasser gelöst zu.. 11.4 kg of ρ-azoxyaniline (melting point 187 to 189 0 ) are dissolved in 25 kg of hydrochloric acid at 20 ° B. and 100 liters of boiling water, the liquid is diluted to 600 liters with ice and water and 7 kg of 8 percent sodium nitrite is added to it 1 dissolved water.
Die so erhaltene Lösung von p-Tetrazoxybenzol dient zu folgenden Paarungen.The solution of p-tetrazoxybenzene thus obtained is used for the following pairings.
Man löst 31,9 kg Amidonaphtoldisulfosäure H und 21 kg kohlensaures Natron in 150 1 Wasser, kühlt die Lösung mit Eis und giebt ihr obige Tetrazolösung unter Umrühren zu. Nach einigen Stunden fällt man den Farbstoff mit 15 kg Kochsalz aus. Er bildet ein schwarzes Pulver, das, in Wasser gelöst, Baumwolle ohne vorhergehendes Beizen sowohl in saurem oder alkalischem als in neutralem Bade dunkelblau färbt.31.9 kg of amidonaphthol disulfonic acid H are dissolved and 21 kg of carbonate of soda in 150 l of water, cool the solution with ice and add the above tetrazo solution with stirring. To The dye is precipitated for a few hours using 15 kg of table salt. He forms a black one Powder which, when dissolved in water, cotton without prior pickling, both in acid or more alkaline than in a neutral bath, it turns dark blue.
Man erhält ebenfalls einen blauen Farbstoff, wenn man im Beispiel I die Amidonaphtol-A blue dye is also obtained, if in example I the amidonaphtol
*) Frühere Zusatz - Patente Nr. 44554, 51363, 54529.*) Former additional patents No. 44554, 51363, 54529.
disulfosäure H (Patent Nr. 67062) durch die Dioxynaphtalinmonosulfosäure S (Patent Nr. 67839) ersetzt. Dieses Verfahren unterscheidet sich von jenen des Patentes Nr. 54116 dadurch, dafsdisulfonic acid H (Patent No. 67062) by the dioxynaphthalene monosulfonic acid S (Patent No. 67839) replaced. This procedure is different of those of Patent No. 54116 in that
1. in dem genannten Patente keine Diazoverbindungen von Azoxyaminen zur Anwendung kommen, und dafs1. No diazo compounds of azoxyamines are used in the patents mentioned come, and that
2. der erhaltene Farbstoff ungeheizte Baumwolle leicht färbt, und zwar mit blauer Farbe, während das Verfahren des Patentes Nr. 54116 zu fuchsinrothen, Wolle in saurem Bade färbenden Farbstoffen führt. Wenn in Beispiel I p-Azoxyorthotoluidin statt p-Azoxyanilin zur Anwendung kommt, so entstehen mit Amidonaphtoldisulfosäure H und mit Dioxynaphtalinmonosulfosäure S blaue Farbstoffe. 2. the dye obtained dyes unheated cotton lightly, with a blue color, while the method of Patent No. 54116 on fuchsia, wool in an acid bath coloring dyes. If in Example I p-azoxyorthotoluidine instead of p-azoxyaniline Is used, so with amidonaphthalene disulfonic acid H and with dioxynaphthalene monosulfonic acid S blue dyes are formed.
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE98970C true DE98970C (en) |
Family
ID=369887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT98970D Active DE98970C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE98970C (en) |
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0
- DE DENDAT98970D patent/DE98970C/de active Active
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