DE974585C - Electrolytic cell, in particular capacitor or rectifier - Google Patents
Electrolytic cell, in particular capacitor or rectifierInfo
- Publication number
- DE974585C DE974585C DET4573A DET0004573A DE974585C DE 974585 C DE974585 C DE 974585C DE T4573 A DET4573 A DE T4573A DE T0004573 A DET0004573 A DE T0004573A DE 974585 C DE974585 C DE 974585C
- Authority
- DE
- Germany
- Prior art keywords
- electrolytic cell
- electrolyte
- cell according
- electrolytic
- rectifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003990 capacitor Substances 0.000 title claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 16
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000003518 caustics Substances 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 239000004327 boric acid Substances 0.000 description 2
- -1 boric acid ester Chemical class 0.000 description 2
- 150000004780 naphthols Chemical class 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electrolytic Production Of Metals (AREA)
Description
Elektrolytische Zelle, insbesondere Kondensator oder Gleichrichter Die Erfindung bezieht sich auf eine elektrolytische Zelle, insbesondere auf einen elektrolytischen Kondensator oder elektrolytischen Gleichrichter, mit mindestens einer formierten Elektrode aus einem Ventilmetall, insbesondere aus Aluminium, und einem Elektrolyt.Electrolytic cell, especially capacitor or rectifier The invention relates to an electrolytic cell, in particular to one electrolytic capacitor or electrolytic rectifier, with at least a formed electrode made of a valve metal, in particular aluminum, and an electrolyte.
Bekannt sind elektrolytische Zellen mit phenolhaltigen Elektrolyten, die bessere Formiereigenschaften zeigen als die am häufigsten verwendeten Borsäureesterelektrolyte. Die elektrolytischen Zellen mit dem flüssigen Phenolelektrolyt haben ähnlich wie die Zellen mit Borsäureester bei Zimmertemperatur gute elektrische Eigenschaften, die sich jedoch mit steigender Temperatur verschlechtern. Der Verlustwinkel und der Reststrom nehmen mit steigender Temperatur zu, so daß diese Zellen für den Dauerbetrieb mit höheren Wechselspannungen nicht geeignet sind.Electrolytic cells with phenol-containing electrolytes are known, which show better forming properties than the most frequently used boric acid ester electrolytes. The electrolytic cells with the liquid phenol electrolyte have similar to the cells with boric acid ester have good electrical properties at room temperature, which, however, deteriorate with increasing temperature. The angle of loss and the residual current increase with increasing temperature, so that these cells are suitable for continuous operation with higher AC voltages are not suitable.
Die Aufgabe der vorliegenden Erfindung besteht darin, diese Nachteile zu beseitigen und eine elektrolytische Zelle herzustellen, die bei höheren Temperaturen, insbesondere bei ioo bis 3oo°C, so betriebsfähig ist wie etwa die bekannte elektrolytische Zelle mit Phenolelektrolyt bei Zimmertemperatur.The object of the present invention is to overcome these disadvantages to eliminate and to produce an electrolytic cell which, at higher temperatures, especially at 100 to 300 ° C, is as operational as the well-known electrolytic Cell with phenolic electrolyte at room temperature.
Erfindungsgemäß wird dies dadurch erreicht, daß als Elektrolyt für die elektrolytische Zelle a- oder ß-Naphthol verwendet ist.According to the invention this is achieved in that as an electrolyte for the electrolytic cell a- or ß-naphthol is used.
Diese Naphthole haben bei ioo°C etwa die gleichen Eigenschaften wie Phenol bei Zimmertemperatur. Mit diesen Naphtholen ist ein Elektrolyt herstellbar, der bei etwa ioo°C einen Dampfdruck und eine Ionenbeweglichkeit hat wie der Phenolelektrolyt bei Zimmertemperatur. Eine elektrolytische Zelle, die bei den höheren Temperaturen so gute Eigenschaften hat wie die elektrolytische Zelle mit Phenolelektrolyt bei Zimmertemperatur, ist für Dauerbetrieb mit höheren Wechselspannungen geeignet, da die Verlustwärme wegen der großen Temperaturdifferenz zwischen der Zelle und der Umgebung leicht abgeführt werden kann.At 100 ° C these naphthols have roughly the same properties as Phenol at room temperature. An electrolyte can be produced with these naphthols, which at about 100 ° C has a vapor pressure and a Ion mobility like the phenol electrolyte at room temperature. An electrolytic cell that has as good properties as the electrolytic cell at higher temperatures with phenol electrolyte at room temperature, is for continuous operation with higher AC voltages suitable because the heat loss due to the large temperature difference between the Cell and the environment can be easily removed.
Die wirtschaftliche Bedeutung der elektrolytischen Zelle gemäß der Erfindung wird durch die erzielbaren geringen Abmessungen und durch die niedrigeren Preise gegenüber den bekannten Wechselstromkondensatoren und Gleichrichtern begründet.The economic importance of the electrolytic cell according to the Invention is achieved by the small dimensions and by the lower Justified prices compared to the well-known AC capacitors and rectifiers.
Vorteilhafte Weiterbildungen des Gegenstandes der Erfindung bestehen darin, daß der Naphtholelektrolyt geeignete Zusätze von Glykol, Glycerin und bzw. oder Ätzalkalien enthält, um die Leitfähigkeit, den Schmelzpunkt und Siedepunkt des Elektrolyts zu verändern, und daß ferner die Kathode aus unformiertem Aluminium oder aus einem Leiter, der keine Deckschichten bildet, z. B. Kohle, besteht oder Überzüge aus Chrom oder Silber besitzt.There are advantageous developments of the subject matter of the invention in that the naphthol electrolyte suitable additives of glycol, glycerine and or or contains caustic alkalis to increase conductivity, melting point and boiling point of the electrolyte to change, and that also the cathode made of unformed aluminum or from a conductor that does not form cover layers, e.g. B. coal, or Has chrome or silver coatings.
Ein weiteres Anwendungsgebiet der elektrolytischen Zelle ergibt sich aus der Eigenschaft, daß der Reststrom an der oberen Grenze der Formierspannung selbst nur durch geringe Spannungserhöhungen stark ansteigt. Diese steilen Kennlinien können zur Gleichrichtung von Hoch- und Niederfrequenzschwingungen ausgenutzt werden, und durch einen besonders geeigneten Aufbau der Schichten lassen sich in dem betreffenden Spannungsbereich zweckmäßige Änderungen der Kennlinien erreichen. Den Arbeitsbereich der Spannung, also die Formierspannung, kann man vorteilhaft auch niedrig wählen. Der Elektrolyt soll eine möglichst geringe Deformierung der Schichten der elektrolytischen Zelle erlauben. Diese elektrolytischen Zellen können wegen des steilen Anstiegs des Reststromes oberhalb der Formierspannung auch zur Spannungsstabilisierung verwendet werden.Another field of application of the electrolytic cell arises from the property that the residual current is at the upper limit of the forming voltage increases sharply even due to small increases in voltage. These steep characteristics can be used to rectify high and low frequency vibrations, and through a particularly suitable structure of the layers, in the relevant Achieve appropriate changes in the characteristic curves in the voltage range. The work area the voltage, i.e. the forming voltage, can advantageously also be chosen to be low. The electrolyte should deform the electrolytic layers as little as possible Allow cell. These electrolytic cells can because of the steep rise of the residual current above the forming voltage is also used for voltage stabilization will.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DET4573A DE974585C (en) | 1951-07-18 | 1951-07-18 | Electrolytic cell, in particular capacitor or rectifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DET4573A DE974585C (en) | 1951-07-18 | 1951-07-18 | Electrolytic cell, in particular capacitor or rectifier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE974585C true DE974585C (en) | 1961-02-16 |
Family
ID=7544687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DET4573A Expired DE974585C (en) | 1951-07-18 | 1951-07-18 | Electrolytic cell, in particular capacitor or rectifier |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE974585C (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR372851A (en) * | 1906-12-22 | 1907-04-20 | Octave Rochefort | Improvement in electric valves |
| FR556287A (en) * | 1921-12-21 | 1923-07-16 | Electrolytic capacitor | |
| FR26470E (en) * | 1922-02-08 | 1924-01-03 | Electrolytic capacitor | |
| DE498822C (en) * | 1925-07-04 | 1930-05-28 | Raoul Felice Bossini | Electrolytic rectifier |
| US2024240A (en) * | 1934-04-19 | 1935-12-17 | Ralph D Mershon | Electrolytic rectifier and condenser |
| GB475833A (en) * | 1936-10-01 | 1937-11-26 | Philips Nv | Improvements in and relating to electrolytic condensers |
| US2109634A (en) * | 1936-05-14 | 1938-03-01 | Gen Motors Corp | Cathode for foil filming |
| US2290997A (en) * | 1931-02-26 | 1942-07-28 | Sprague Specialties Co | Electrolytic device |
| DE736838C (en) * | 1935-03-21 | 1943-06-29 | Siemens Ag | Electrolyte, especially for electrolytic capacitors |
| DE829336C (en) * | 1950-03-08 | 1952-01-24 | Siemens & Halske A G | Forming or operating electrolyte for electrolytic capacitors, especially high-voltage dry electrolytic capacitors |
-
1951
- 1951-07-18 DE DET4573A patent/DE974585C/en not_active Expired
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR372851A (en) * | 1906-12-22 | 1907-04-20 | Octave Rochefort | Improvement in electric valves |
| FR556287A (en) * | 1921-12-21 | 1923-07-16 | Electrolytic capacitor | |
| FR26470E (en) * | 1922-02-08 | 1924-01-03 | Electrolytic capacitor | |
| DE498822C (en) * | 1925-07-04 | 1930-05-28 | Raoul Felice Bossini | Electrolytic rectifier |
| US2290997A (en) * | 1931-02-26 | 1942-07-28 | Sprague Specialties Co | Electrolytic device |
| US2024240A (en) * | 1934-04-19 | 1935-12-17 | Ralph D Mershon | Electrolytic rectifier and condenser |
| DE736838C (en) * | 1935-03-21 | 1943-06-29 | Siemens Ag | Electrolyte, especially for electrolytic capacitors |
| US2109634A (en) * | 1936-05-14 | 1938-03-01 | Gen Motors Corp | Cathode for foil filming |
| GB475833A (en) * | 1936-10-01 | 1937-11-26 | Philips Nv | Improvements in and relating to electrolytic condensers |
| DE829336C (en) * | 1950-03-08 | 1952-01-24 | Siemens & Halske A G | Forming or operating electrolyte for electrolytic capacitors, especially high-voltage dry electrolytic capacitors |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE974585C (en) | Electrolytic cell, in particular capacitor or rectifier | |
| DE2234618C3 (en) | Electrolytic capacitor and method of making its electrodes | |
| CH246109A (en) | Process for the production of metal electrodes of electrical capacitors coated with non-conductive reaction products. | |
| DE1805383B2 (en) | Electrolyte for electrolytic capacitors with aluminum anodes | |
| DE743235C (en) | Electrolyte for electrical cells, especially electrolytic capacitors | |
| AT127584B (en) | Capacitor. | |
| DE720445C (en) | Process for the production of dry plate rectifiers with a light metal as the base electrode material and dry plate rectifiers produced according to this process | |
| DE1464641A1 (en) | Electrical device with cooling arrangement | |
| DE1191911B (en) | Electric capacitor with burnout coverings | |
| AT144836B (en) | Electrolytic capacitor. | |
| DE614021C (en) | Device for avoiding inadmissible heating of the resistance material of highly loaded high-resistance resistors | |
| DE2543079A1 (en) | PROCESS FOR MANUFACTURING SOLID STATE CAPACITORS | |
| DE595622C (en) | Insulation resistant to elevated temperatures, especially for the slot conductors of electrical machines | |
| DE757281C (en) | Electrically asymmetrically conductive system, in particular dry rectifier, with a barrier layer between the semiconductor and the carrier electrode and a method for its production | |
| DE1098101B (en) | Operating electrolyte for a tantalum electrolytic capacitor | |
| DE1439190C (en) | Electric capacitor | |
| DE970257C (en) | Process for the production of self-healing electrical capacitors | |
| DE974298C (en) | Method of manufacturing an electrolytic capacitor | |
| AT205564B (en) | Pressed insulating part made of glass | |
| AT147430B (en) | Electric power cable. | |
| DE202018100063U1 (en) | graphs capacitor | |
| DE861136C (en) | Process for the production of electrodes, especially for electrolytic capacitors, and electrolytic capacitors | |
| DE590675C (en) | Cell switch | |
| DE567816C (en) | Metallic protective coating at the connection points between a high-voltage conductor and a non-conductor | |
| DE911300C (en) | Electrolytic wound capacitor |