DE973061C - Steel for seamless tubes - Google Patents

Steel for seamless tubes

Info

Publication number
DE973061C
DE973061C DED10822D DED0010822D DE973061C DE 973061 C DE973061 C DE 973061C DE D10822 D DED10822 D DE D10822D DE D0010822 D DED0010822 D DE D0010822D DE 973061 C DE973061 C DE 973061C
Authority
DE
Germany
Prior art keywords
steel
carbon
seamless tubes
iron
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DED10822D
Other languages
German (de)
Inventor
Ewald Dr Baerlecken
Hermann-Josef Dr Schiffler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phoenix Rheinrohr AG
Original Assignee
Phoenix Rheinrohr AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phoenix Rheinrohr AG filed Critical Phoenix Rheinrohr AG
Priority to DED10822D priority Critical patent/DE973061C/en
Application granted granted Critical
Publication of DE973061C publication Critical patent/DE973061C/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Steel (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Heat Treatment Of Articles (AREA)

Description

Stahl für nahtlose Rohre Die Herstellung von nahtlosen Rohren aus unlegierten, mittellegierten und selbst hochlegierten Stählen bereitet heute im allgemeinen keine Schwierigkeiten. Bei schwer zu verarbeitenden Stahllegierungen bieten die verschiedenen Rohrherstellungsverfahren durch ihre unterschiedliche Verformungsarbeit oft genug einen Ausweg, um wenigstens nach einem der Verfahren nahtlose Rohre herstellen zu können. Das bedeutet aber immer noch eine Beschränkung auf einen bestimmten Verformungsprozeß.Steel for seamless tubes The manufacture of seamless tubes unalloyed, medium-alloyed and even high-alloy steels are currently being prepared in generally no difficulties. For steel alloys that are difficult to process are offered by the various pipe manufacturing processes due to their different deformation work often enough a way out to produce seamless tubes by at least one of the processes to be able to. But that still means a restriction to a specific deformation process.

Während sich die niedriggekohlten unlegierten Stähle nach allen bekannten Rohrwalzverfahren ohne Schwierigkeiten verarbeiten lassen, treten erhebliche Schwierigkeiten auf, sobald der Kohlenstoff durch starke Karbidbildner wie Titan, Zirkonium, Tantal, Niob und Vanadin abgebunden ist. Es ist hierbei allerdings Voraussetzung, daß die Menge des karbidbildenden Elementes so groß gewählt wird, daß der Gesamtkohlenstoff an diese Elemente gebunden ist. Die notwendigen Mengenanteile sind bekannt.While the low-carbon non-alloy steels are known to all Allowing tube rolling processes to be processed without difficulty, considerable difficulties arise as soon as the carbon is replaced by strong carbide formers such as titanium, zirconium, tantalum, Niobium and vanadium is set. However, it is a prerequisite that the Amount of the carbide-forming element is chosen so large that the total carbon is bound to these elements. The necessary proportions are known.

Es ist hierbei gleich, ob die Abbindung des Kohlenstoffs nur durch ein Element erfolgt oder durch Mischung der vorgenannten Elemente, wobei natürlich die Verhältniszahlen entsprechend den Anteilen der einzelnen Komponenten zu wählen sind. Ein Stahl z. B. mit folgender Zusammensetzung: 0,o6 % Kohlenstoff, o,43 % Titan, 0,015°/o Phosphor, o,28 % Silizium, 0,34 % Mangan, o,oi % Schwefel, verursachte bei dem Stiefel- und Schrägwalzverfahren so große Schwierigkeiten, daß etwa 500/, des eingesetzten Materials im Lochapparat ausfielen. Auch durch Änderung der Walztemperatur konnte keine Verbesserung der Verwalzbarkeit erzielt werden. Senkte man den Zusatz an karbidbildenden Elementen, so daß noch ein Teil des Kohlenstoffs als Eisenkarbid vorlag, so ließ sich das Material anstandslos verwalten.It does not matter whether the carbon is only bound by one element or by a mixture of the aforementioned elements, whereby the ratios must of course be selected according to the proportions of the individual components. A steel z. B. with the following composition: 0.06% carbon, o, 43% titanium, 0.015% phosphorus, o, 28% silicon, 0.34% manganese, o, oi% sulfur, caused so great difficulties with the boot and skew rolling process that about 500 % of the material used failed in the punching apparatus. Even by changing the rolling temperature, no improvement in the manageability could be achieved. If the addition of carbide-forming elements was reduced so that part of the carbon was still present as iron carbide, the material could be administered without any problem.

In manchen Fällen kann aber auf eine völlige Abbindung des Kohlenstoffs nicht verzichtet werden. Da bei Stählen mit vollständig abgebundenem Kohlenstoffgehalt die Schwierigkeiten - unabhängig vom Rohrwalzverfahren auftreten, wurde eine große Anzahl von Versuchen durchgeführt mit dem Ziel, durch Änderung der Stahlzusammensetzung die Verformungsarbeit zu erleichtern. Hierbei wurde überraschend festgestellt, daß durch o,7 bis 20/, Mangan die Warmverformungsfähigkeit auf das bei unlegierten Kohlenstoffstählen bekannte Maß zurückgeführt wird.In some cases, however, it can be due to a complete setting of the carbon not be waived. As with steels with a completely set carbon content the difficulties - regardless of the pipe rolling process, became a major one Number of tests carried out with the aim of changing the steel composition to facilitate the deformation work. It was surprisingly found that 0.7 to 20 /, Manganese reduces the hot workability to that of unalloyed carbon steels known measure is traced back.

Ein Stahl mit folgender Zusammensetzung: 0,o6 % Kohlenstoff, 0,37 % Titan, i,oo % Mangan, 0,34 % Silizium, 0,0040/0 Schwefel, 0,012% Phosphor, ließ sich einwandfrei zu Rohren verwalten, wobei das Ausbringen ioo % war.A steel with the following composition: 0.06% carbon, 0.37 % titanium, i, oo% manganese, 0.34% silicon, 0.0040 / 0 sulfur, 0.012% phosphorus, could be managed perfectly to pipes, whereby the output was 100%.

Es ist nach diesem Ergebnis möglich, schlecht oder gar nicht zu nahtlosen Rohren zu verarbeitende Stahllegierungen durch einen Zusatz von Mangan in ihrer Warmverformungsfähigkeit zu beeinflussen, ohne daß dadurch die kennzeichnenden Merkmale der Ursprungslegierung verändert werden.It is possible after this result to be poorly or not at all seamless Tubes to be processed steel alloys by adding manganese in their To influence hot deformability without affecting the characteristic features the original alloy can be changed.

Erfindungsgemäß werden demnach Stähle, deren Kohlenstoff durch einen oder mehrere starke Karbidbildner wie Titan, Vanadin, Zirkonium, Niob und Tantal abgebunden ist, mit 0,7 bis 2 0/0, vorzugsweise 10/0, Mangan, Rest Eisen mit den üblichen Verunreinigungen als Werkstoff für nahtlose nach dem Stiefel- bzw. Schrägwalzverfahren herzustellende Rohre verwendet.According to the invention, steels whose carbon is bound by one or more strong carbide formers such as titanium, vanadium, zirconium, niobium and tantalum are therefore manganese with 0.7 to 2%, preferably 10/0, the remainder being iron with the usual impurities as Material used for seamless pipes to be produced by the boot or cross-rolling process.

Die erfindungsgemäß zu verwendenden Stahllegierungen sind an sich nicht Gegenstand der Erfindung, ebensowenig wie die bekannte Verwendung von Stahllegierungen mit 0,15 bis etwa 1% Si und bis zu 2 % Mn sowie gegebenenfalls Zusätzen von Cu, V, Mo, W, Cr usw. zur Herstellung preßgeschweißter Gegenstände, z. B. preßgeschweißter Rohre.The steel alloys to be used according to the invention are per se not the subject of the invention, just as little as the known use of steel alloys with 0.15 to about 1% Si and up to 2% Mn and optionally additions of Cu, V, Mo, W, Cr etc. for the manufacture of pressure welded objects, e.g. B. pressure welded Tube.

Überdies treten die bei der Herstellung nahtloser Rohre sich ergebenden Schwierigkeiten bei der Herstellung preßgeschweißter Rohre nicht auf.In addition, there are those resulting from the manufacture of seamless tubes Difficulties in the manufacture of pressure-welded pipes do not arise.

Claims (1)

PATENTANSPRUCH: Verwendung von Stählen, deren Kohlenstoff durch einen oder mehrere starke Karbidbildner wie Titan, Vanadin, Zirkonium, Niob und Tantal abgebunden ist, mit o,7 bis 2%, vorzugsweise T0/0, Mangan, Rest Eisen mit den üblichen Verunreinigungen als Werkstoff für nahtlose nach dem Stiefel-bzw. Schrägwalzverfahren herzustellende Rohre. In Betracht gezogene Druckschriften: Deutsche Patentschriften- Nr. _ 692 _ 226,_ 64q. 132, 687 503; österreichische Patentschrift Nr. 143 62o; französische Patentschrift Nr. 743 357; Archiv für das Eisenhüttenwesen, 1932/33, S. 24 bis 32 (Werkstoffausschuß 182) ; 1937, S. 145 bis 152; 1938/39 S. 33 bis 37; Stahl -Eisen, 54, 1934, S. 462 bis 466; Techn. Mitteilungen Krupp, 1934/35, Heft 3, S. Too bis 1o2; Forschungsbericht, T, 1938, S. 67, 68; Rapatz, Die Edelstähle, 1925, S.71; Grützner, Eisen- und Stahllegierungen, 1932, S. 2o, 2i; i. Ergänzungsband, 1935, S. T2.PATENT CLAIM: Use of steels whose carbon is bound by one or more strong carbide formers such as titanium, vanadium, zirconium, niobium and tantalum, with 0.7 to 2%, preferably T0 / 0, manganese, the remainder iron with the usual impurities as the material for seamless after the boot or. Pipes to be produced in cross-rolling process. Considered publications: German Patent Nos. 692 226, 64q. 132, 687 503; Austrian Patent No. 143 62o; French Patent No. 743 357; Archiv für das Eisenhüttenwesen, 1932/33, pp. 24 to 32 (Material Committee 182); 1937, pp. 145 to 152; 1938/39 pp. 33 to 37; Stahl -Eisen, 54, 1934, pp. 462 to 466; Techn. Mitteilungen Krupp, 1934/35, Issue 3, pp. Too to 1o2; Research Report, T, 1938, pp. 67, 68; Rapatz, Die Stainless Steel, 1925, p.71; Grützner, iron and steel alloys, 1932, pp. 2o, 2i; i. Supplementary volume, 1935, p. T2.
DED10822D 1941-02-20 1941-02-20 Steel for seamless tubes Expired DE973061C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DED10822D DE973061C (en) 1941-02-20 1941-02-20 Steel for seamless tubes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED10822D DE973061C (en) 1941-02-20 1941-02-20 Steel for seamless tubes

Publications (1)

Publication Number Publication Date
DE973061C true DE973061C (en) 1959-11-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2543461A1 (en) * 1983-03-28 1984-10-05 Mannesmann Ag PROCESS FOR MANUFACTURING SOLDERED STEEL TUBES

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR743357A (en) * 1933-03-29
AT143620B (en) * 1932-12-08 1935-11-25 Krupp Ag Manufacture of objects that must be resistant to attack by decarburizing gases, especially at high temperatures and pressures.
DE644132C (en) * 1931-04-03 1937-04-24 Mannesmann Ag The use of steels with higher silicon and manganese contents for the production of highly stressed pipes, containers, etc.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR743357A (en) * 1933-03-29
DE644132C (en) * 1931-04-03 1937-04-24 Mannesmann Ag The use of steels with higher silicon and manganese contents for the production of highly stressed pipes, containers, etc.
AT143620B (en) * 1932-12-08 1935-11-25 Krupp Ag Manufacture of objects that must be resistant to attack by decarburizing gases, especially at high temperatures and pressures.
DE687503C (en) * 1932-12-08 1940-01-31 Fried Krupp Akt Ges Manufacture of items that have to be resistant to attack by decarburizing gases
DE692226C (en) * 1932-12-08 1940-06-15 Fried Krupp Akt Ges Containers and container parts for the splitting hydrogenation of oils and coals as well as for ammonia synthesis, which have to be resistant to the decarburizing attack of hydrogen and hydrogen-containing gas mixtures at high temperatures and pressures

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2543461A1 (en) * 1983-03-28 1984-10-05 Mannesmann Ag PROCESS FOR MANUFACTURING SOLDERED STEEL TUBES

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