DE96930C - - Google Patents
Info
- Publication number
- DE96930C DE96930C DENDAT96930D DE96930DA DE96930C DE 96930 C DE96930 C DE 96930C DE NDAT96930 D DENDAT96930 D DE NDAT96930D DE 96930D A DE96930D A DE 96930DA DE 96930 C DE96930 C DE 96930C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- blue
- dyes
- dye
- dianisidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000975 dye Substances 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 10
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical compound C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 claims description 5
- NUIURNJTPRWVAP-UHFFFAOYSA-N Tolidine Chemical compound C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- UPKAWFACSJWKND-ZXFFUEEESA-J tetrasodium;(6E)-4-amino-6-[[4-[4-[(2Z)-2-(8-amino-1-oxo-5,7-disulfonatonaphthalen-2-ylidene)hydrazinyl]-3-methoxyphenyl]-2-methoxyphenyl]hydrazinylidene]-5-oxonaphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C\1=CC2=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C(N)=C2C(=O)C/1=N/NC(C(OC)=C1)=CC=C1C1=CC=C(N\N=C\2C(C3=C(N)C(=CC(=C3C=C/2)S([O-])(=O)=O)S([O-])(=O)=O)=O)C(OC)=C1 UPKAWFACSJWKND-ZXFFUEEESA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/08—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl
- C09B35/10—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl from two coupling components of the same type
- C09B35/14—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl from two coupling components of the same type from hydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Es hat sich gezeigt, dafs die Ct1 ß4-Dioxyßj-naphtoe'-a2-sulfosäure des Patentes Nr. 84653 sich mit den Tetrazoverbindungen des Dianisidins und Tolidins zu Farbstoffen combiniren läfst, deren werthvolle Eigenschaften analoge bezw. isomere Farbstoffe nicht aufweisen.It has been shown that the Ct 1 ß 4 -Dioxyßj-naphtoe'-a 2 -sulfonic acid of Patent No. 84653 can be combined with the tetrazo compounds of dianisidine and tolidine to form dyes whose valuable properties are analogous or similar. do not have isomeric dyes.
Diese Eigenschaften treten gegenüber den Farbstoffen des Patentes Nr. 75258 (aus der Nigrotinsäure) einerseits dadurch hervor, dafs sie in der Baumwollfärberei unerreichte Nuancen bezüglich Grünstichigkeit und Reinheit erzeugen; aufserdem ist ein besonderer, technisch wichtiger Erfolg darin zu erblicken, dafs die Farbstoffe zur Verwendung in der Halbwollfä'rberei besonders geeignet sind. Während nämlich die Farbstoffe des Patentes Nr. 75258 Halbwolle nur in schwachen und mifsfarbigen Tönen anfärben und somit für die Halbwollfä'rberei unbrauchbar sind, erzeugen die vorliegenden auf der gemischten Faser lebhafte und satte blaue Nuancen.These properties appear compared to the dyes of patent no.75258 (from the Nigrotinic acid), on the one hand, by the fact that it has nuances which are unmatched in cotton dyeing generate greenish tint and purity; there is also a special one that is technically important Success in seeing that the dyes for use in semi-wool dyeing are especially important are suitable. Namely, while the dyes of patent no. 75258 half wool Dye only in weak and mifs-colored shades and therefore suitable for dyeing of semi-wool are useless, the present ones produce vivid and rich on the mixed fiber blue nuances.
Beispiel 1.Example 1.
24 kg Dianisidinbase werden wie üblich in die Tetrazoverbindung übergeführt und in eine sodaalkalische Lösung von 70 kg dioxynaphtoesulfosaurem Natron bei ca. 30 ° einlaufen gelassen. Zunächst bildet sich ein Zwischenproduct, welches in alkalischer Lösung löslich ist, auf Zusatz von Säuren aber ausfällt. Den bis zur Vollendung der Farbstoffbildung alkalisch gehaltenen Ansatz läfst man 24 Stunden stehen, erwärmt auf ca. 8o° und läfst erkalten. Bei genügender Concentration des Ansatzes scheidet sich der Farbstoff in grünlichen Krystallen aus, welche sich in Wasser und concentrirter Schwefelsäure mit grünblauer Farbe lösen. Er färbt Baumwolle und Halbwolle grünstichig blau. Die Färbungen sind alkaliecht, Sodalösung (1:10) bringt sowohl auf den Ausfärbungen als auch in den wässerigen Lösungen keine Veränderung hervor.24 kg of dianisidine base are converted into the tetrazo compound as usual and into a soda-alkaline solution of 70 kg of dioxynaphthoesulfonate of soda was allowed to run in at approx. 30 °. First, an intermediate product is formed which is soluble in an alkaline solution, but precipitates when acids are added. The The batch, which is kept alkaline until the formation of the dye is complete, is allowed to run for 24 hours stand, heated to approx. 80 ° and let cool down. With sufficient concentration of the approach the dye is deposited in greenish crystals, which are in water and dissolve concentrated sulfuric acid with a green-blue color. He dyes cotton and semi-wool greenish blue. The colors are alkaline, soda solution (1:10) brings both no change emerged on the colorations or in the aqueous solutions.
Bei analogem Arbeiten wie im gegebenen Beispiel kann man das Dianisidin durch äquivalente Mengen (21 kg) Tolidin ersetzen und erhält so einen Farbstoff, der ungeheizte Baumwolle blau färbt. Die Färbungen sind sodaecht. Der Farbstoff stellt ein bronzeglänzendes Pulver dar. Wasser und concentrirte Schwefelsäure lösen ihn mit blauer Farbe.When working analogously to the example given, the dianisidine can be replaced by equivalents Substitute quantities (21 kg) of tolidine and thus obtain a dye, the unheated cotton colors blue. The colors are so fast. The dye provides a bronze sheen Powder. Water and concentrated sulfuric acid dissolve it with a blue color.
Anstatt in den beiden Beispielen von vornherein 2 Mol. der Säure zu verwenden, kann man auch erst das Zwischenproduct darstellen und dann das zweite Molecül der Säure zugeben. Instead of using 2 mol of the acid from the outset in the two examples, can the intermediate product can also be presented first and then the second molecule of the acid is added.
In umstehender Tabelle ist die Verschiedenheit der Färbungen zusammengestellt, welche mittelst der analogen Farbstoffe aus den beiden bis jetzt bekannt gewordenen Dioxynaphtoesulfosäuren erzielt werden:The table below shows the differences in coloration, which mean of the analogous dyes from the two dioxynaphthoesulfonic acids that have become known up to now be achieved:
in hellen TönenDyes unheated cotton
in light tones
des Patentes Nr. 670002 moles. Dioxynaphtoesulfonic acid
of patent no. 67000
(nach Angaben der Patentschrift
Nr. 75258)greenish gray
(according to the patent specification
No. 75258)
des Patentes Nr. 846532 moles. Dioxynaphtoesulfonic acid
of Patent No. 84653
Nr. 670002 moles of nigrotinic acid of the patent
No. 67000
(nach Angaben der Patentschrift
Nr. 75258)bluish gray
(according to the patent specification
No. 75258)
des Patentes Nr. 846532 moles. Dioxynaphtoesulfonic acid
of Patent No. 84653
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE96930C true DE96930C (en) |
Family
ID=368020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT96930D Active DE96930C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE96930C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE752164C (en) * | 1941-06-08 | 1953-02-23 | Ig Farbenindustrie Ag | Process for the preparation of tetrakisazo dyes |
-
0
- DE DENDAT96930D patent/DE96930C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE752164C (en) * | 1941-06-08 | 1953-02-23 | Ig Farbenindustrie Ag | Process for the preparation of tetrakisazo dyes |
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