DE953063C - Process for improving the exhaust gas fastness of colored cellulose derivatives - Google Patents

Process for improving the exhaust gas fastness of colored cellulose derivatives

Info

Publication number
DE953063C
DE953063C DEB30202A DEB0030202A DE953063C DE 953063 C DE953063 C DE 953063C DE B30202 A DEB30202 A DE B30202A DE B0030202 A DEB0030202 A DE B0030202A DE 953063 C DE953063 C DE 953063C
Authority
DE
Germany
Prior art keywords
cellulose derivatives
exhaust gas
improving
gas fastness
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB30202A
Other languages
German (de)
Inventor
Dr Julius Eisele
Wilhelm Federkiel
Dr Robert Gehm
Dr Karl Maier
Dr Curt Schuster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB30202A priority Critical patent/DE953063C/en
Application granted granted Critical
Publication of DE953063C publication Critical patent/DE953063C/en
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6426—Heterocyclic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6492—(Thio)urethanes; (Di)(thio)carbamic acid derivatives; Thiuramdisulfide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Description

AUSGEGEBEN AM 29. NOVEMBER 1956ISSUED NOVEMBER 29, 1956

INTERNAT. KLASSE D 06 ρ INTERNAT. CLASS D 06 ρ

. B 30202 IVb18m . B 30202 IVb18m

sind als Erfinder genannt wordenhave been named as inventors

CellulosederivateCellulose derivatives

Zusatz zum Patent 949Addendum to patent 949

Patentanmeldung bekanntgemacht am 24. Mai 1956Patent application published May 24, 1956

Patenterteilung bekanntgemacht am 8. November 1956Patent issued November 8, 1956

Gegenstand des Patents 949 562 ist ein Verfahren zur Verbesserung der Abgasechtheit gefärbter Cellulosederivate, bei dem man diese vor oder nach dem Färben oder im Färbebad selbst mit ideinen Mengen von Carbonsäureestern von Oxyalkyl aminen behandelt. Diese aminogruppenhaltigen Ester können auch in die zu färbenden Cellulosederivate eingesponnen werden.The subject of patent 949 562 is a method for improving the exhaust gas fastness of dyed products Cellulose derivatives, which you can use before or after dyeing or in the dye bath itself i amounts of carboxylic acid esters of oxyalkyl amines treated. These amino group-containing esters can also be used in the cellulose derivatives to be colored are spun.

Es wurde nun gefunden, daß man eine ähnlich wirksame Verbesserung der Abgasechtheit gefärbter Cellulosederivate auch erreichen kann, wenn man an Stelle der im Hauptpatent genannten aminogruppenhaltigen Ester aminogruppenhaltige Ketone verwendet.It has now been found that there is a similarly effective improvement in the exhaust gas fastness of dyed products Cellulose derivatives can also be achieved if instead of the amino groups mentioned in the main patent Ester amino-containing ketones are used.

Geeignete Ketone dieser Art sind z.B. das N, N-Dimethyl-(2-benzoyläthyl)-amin, das 2-(N, N-Dimethylaminomethyl)-cyclohexanon, das N, N-(Bis-2-benzöyläthyl)-methylamin, das N-(^-Benzoyläthyl)-pyrrolidin oder -piperidin und das N, N'-Bis-(2-benzoyläthyl) -piperazin.Suitable ketones of this type are, for example, N, N-dimethyl- (2-benzoylethyl) amine, 2- (N, N-dimethylaminomethyl) cyclohexanone, N, N- (bis-2-benzoylethyl) methylamine, the N - (^ - benzoylethyl) pyrrolidine or piperidine and the N, N'-bis (2-benzoylethyl) -piperazine.

Besonders geeignet sind auch solche Ketone, die man z.B. durch Umsetzen von a, ^-ungesättigten Ketonen, wie Vinylmethylketon, mit primären oder sekundären Aminen, wie 4, 4'-Diaminodicyclohexylmethan oder -äthan, herstellen kann. Die aminogruppenhaltigen Ketone können außerdem auch Ester- und bzw. oder Nitrilgruppen enthalten.Those ketones which can be prepared, for example, by reacting α, ^ -unsaturated ketones, such as vinyl methyl ketone, with primary or secondary amines, such as 4,4'-diaminodicyclohexylmethane or ethane, are also particularly suitable. The ketones containing amino groups can also contain ester and / or nitrile groups.

Im übrigen verfährt man wie im Hauptpatent beschrieben. Otherwise the procedure is as described in the main patent.

Beispiel 1example 1

1000 g eines Acetatreyongewebes werden in 301 eines wäßrigen Bades, das 10 g feinverteiltes 1, 4-D1-1000 g of an acetate red fabric are in 301 an aqueous bath containing 10 g of finely divided 1,4-D1-

(methylamino)-anthrachinon und 45 g feinverteütes N, N-Bis-(2-benzoyläthyl)-methylamin enthält, eine Stunde bei 8o° bewegt. Dann wird das Gewebe in üblicher Weise gespült und fertiggestellt. Man erhält eine Sehr gut abgasechte hellblaue Färbung.Contains (methylamino) anthraquinone and 45 g of finely dispersed N, N-bis (2-benzoylethyl) methylamine, a Hour moved at 8o °. The fabric is then rinsed and finished in the usual way. You get a light blue color which is very resistant to emissions.

Beispiel 2Example 2

Zu einer Spinnmasse, die aus einer Lösung vonTo a spinning mass made from a solution of

1000 kg Acetylcellulose in Aceton besteht, gibt man eine acetonische Lösung von 30 kg N, N'-Bis-(2- benzoyläthyl)-piperazin und verspinnt die Masse dann in üblicher Weise zu Fäden.1000 kg of acetyl cellulose in acetone is added to an acetone solution of 30 kg of N, N'-bis (2-benzoylethyl) piperazine and then spun the mass into threads in the usual way.

60 kg der so erhaltenen Fäden werden in 12001 eines wäßrigen Färbebades, in welchem 2 kg feinverteiltes 1, 4, 5-Triaminoanthrachinon suspendiert sind, ι Stunde bei 750 gefärbt. Man erhält eine gut abgasechte tiefblaue Färbung.60 kg of the filaments thus obtained an aqueous dye bath, in which 2 kg of finely divided 1, 4, 5-Triaminoanthrachinon are suspended in 12001 are colored ι hour at 75 0th The result is a deep blue coloration which is well-fume-proof.

Beispiel 3Example 3

100 g eines Acetatreyonstranges werden in 21 Wasser, das 0,5 g feinverteütes 1, 4-Diaminoanthrachinon enthält, 1 Stunde bei 80° gefärbt. Nach dem Spülen trägt man den Strang in 2 1 eines frischen Bades ein, das 2 g des Einwirkungsproduktes von Vinylmethylketon auf N, N'-Bis-(propionitrüo)-4, 4'-diaminodicyclohexylmethan in feiner Dispersion enthält, und bewegt ihn in diesem Bade weitere 20 Minuten bei 75°. Nach dem üblichen Fertigstellen erhält man eine sehr gut abgasechte hell violette Färbung.100 g of an acetate red strand are in 21 Water containing 0.5 g of finely dispersed 1,4-diaminoanthraquinone, colored at 80 ° for 1 hour. After this Rinse one carries the strand in 2 l of a fresh bath, the 2 g of the action product from Vinyl methyl ketone on N, N'-bis (propionitro) -4, 4'-diaminodicyclohexylmethane in fine dispersion contains, and moves it in this bath for a further 20 minutes at 75 °. Receives after the usual finishing you get a very good emission-fast light purple color.

Beispiel 4Example 4

100 g eines Acetatreyongewebes werden in 4I eines wäßrigen Bades, das 1 g feinverteütes i-Amino-2-methoxy-4-oxyanthrachinon und 6 g feinverteütes UmsetzungspToduktes von Vinylmethylketon mit 4,4'-Diaminodicyclohexyhnethan enthält, 1 Stunde bei 85 ° bewegt und dann gespült. Man erhält eine leuchtende Rosafärbung von sehr guter Abgasechtheit.100 g of an Acetatreyonewebes are in 4I one aqueous bath containing 1 g of finely dispersed i-amino-2-methoxy-4-oxyanthraquinone and 6 g of finely dispersed reaction product of vinyl methyl ketone with 4,4'-diaminodicyclohexyl methane contains, 1 hour agitated at 85 ° and then rinsed. A bright pink color with very good exhaust gas fastness is obtained.

Beispiel 5Example 5

100 g eines Acetatreyongewebes werden in 41 eines wäßrigen Bades, das 1 g feinverteütes i-Amino-2-methoxy-4-oxyanthrachinon und 6 g N-(2-Benzoyläthyl)-pyrrolidin enthält, wie im Beispiel 4 gefärbt. Man erhält eine ähnlich abgasechte Rosafärbung.100 g of an acetate red fabric are in 41 one aqueous bath containing 1 g of finely dispersed i-amino-2-methoxy-4-oxyanthraquinone and contains 6 g of N- (2-benzoylethyl) pyrrolidine, colored as in Example 4. A pink coloration similar to that of exhaust fumes is obtained.

Beispiel 6Example 6

1000 g eines Acetatreyongewebes werden in 201 eines wäßrigen Bades, das 20 g feinverteütes i-Amino-4-(methylamino)-anthrachinon-2-carbonsäureamidund 40 g feinverteütes 2-(N, N-Dimethylaminomethyl)-cyclohexanon enthält, 50 Minuten bei 80° gefärbt. Die nach dem Spülen und Fertigsteüen erhaltene blaue Färbung ist. gut abgasecht.1000 g of an acetate red fabric are used in 201 an aqueous bath containing 20 g of finely dispersed i-amino-4- (methylamino) -anthraquinone-2-carboxamide and 40 g finely dispersed 2- (N, N-dimethylaminomethyl) -cyclohexanone contains, stained at 80 ° for 50 minutes. The blue one obtained after rinsing and finishing Coloring is. good emission-proof.

Claims (1)

Patentanspruch:Claim: Weiterbildung des Verfahrens des Patents 949 562 zur Verbesserung der Abgasechtheit von gefärbten Cellulosederivaten, dadurch gekennzeichnet, daß man den Cellulosederivaten vor oder nach dem Färben oder im Färbebad selbst an Stelle der im Hauptpatent verwendeten aminogruppenhaltigen Carbonsäureester kleine Mengen von aminogruppenhaltigen Ketonen einverleibt. Further development of the method of patent 949 562 to improve the exhaust gas resistance of colored cellulose derivatives, characterized in that the cellulose derivatives are in front of or after dyeing or in the dye bath itself instead of those used in the main patent amino-containing carboxylic acid esters incorporated small amounts of amino-containing ketones. © 609527/494 5.56 (609 694 11.56) © 609527/494 5.56 (609 694 11.56)
DEB30202A 1954-02-05 1954-03-18 Process for improving the exhaust gas fastness of colored cellulose derivatives Expired DE953063C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB30202A DE953063C (en) 1954-02-05 1954-03-18 Process for improving the exhaust gas fastness of colored cellulose derivatives

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE780764X 1954-02-05
DEB30202A DE953063C (en) 1954-02-05 1954-03-18 Process for improving the exhaust gas fastness of colored cellulose derivatives
DE782785X 1954-09-17

Publications (1)

Publication Number Publication Date
DE953063C true DE953063C (en) 1956-11-29

Family

ID=27207431

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB30202A Expired DE953063C (en) 1954-02-05 1954-03-18 Process for improving the exhaust gas fastness of colored cellulose derivatives

Country Status (1)

Country Link
DE (1) DE953063C (en)

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