DE951886C - Fixative for hair curls - Google Patents

Fixative for hair curls

Info

Publication number
DE951886C
DE951886C DESCH9881A DESC009881A DE951886C DE 951886 C DE951886 C DE 951886C DE SCH9881 A DESCH9881 A DE SCH9881A DE SC009881 A DESC009881 A DE SC009881A DE 951886 C DE951886 C DE 951886C
Authority
DE
Germany
Prior art keywords
hair
fixative
agent according
contain
fixing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DESCH9881A
Other languages
German (de)
Inventor
Johannes Saphir
Dr Edwin Kramer
Ernst-Ludwig Roehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hans Schwarzkopf and Henkel GmbH
Original Assignee
Hans Schwarzkopf and Henkel GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hans Schwarzkopf and Henkel GmbH filed Critical Hans Schwarzkopf and Henkel GmbH
Priority to DESCH9881A priority Critical patent/DE951886C/en
Application granted granted Critical
Publication of DE951886C publication Critical patent/DE951886C/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20Halogens; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22Peroxides; Oxygen; Ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/08Preparations for bleaching the hair

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Fixiermittel für die Haarwellung Es ist bekannt, dem menschlichen Haar durch Einwirkung alkalischer Lösungen reduzierender Verbindungen eine andere Form zu geben, d. h. glattes Haar zu krausen und zu wellen oder krauses Haar zu glätten. Nach Einwirkung dieser Lösungen wird das Haar geformt. Das erweichte, geformte Haar wird durch eine oxydative Nachbehandlung wieder erhärtet bzw. in den elastischen Zustand übergeführt. Als Oxydationsmittel sind Wasserstoffsuperoxyd, dieses abspaltende Verbindungen usw. im Gebrauch. Auch Bromate sind hierfür vorgeschlagen worden.Fixative for hair curl It is known to the human Hair by the action of alkaline solutions of reducing compounds is another To give shape, d. H. Frizzy and wavy straight hair, or frizzy hair smooth. After exposure to these solutions, the hair is shaped. The softened, shaped Hair is hardened again by an oxidative treatment or in the elastic State transferred. Hydrogen peroxide is used as an oxidizing agent, this splitting off Connections etc. in use. Bromates have also been proposed for this purpose.

Bromate haben jedoch den Nachteil, daß sie mit organischen Substanzen verpuffen. Auch die geringen Mengen, die durch Abtropfen der Flüssigkeit auf Kleidung und Wäsche gelangen, neigen nach dem Trocknen zu sehr raschem, fast spontanem Verbrennen.However, bromates have the disadvantage that they can with organic substances fizzle out. Even the small amounts that drip off the liquid on clothing and laundry, tend to burn very quickly, almost spontaneously, after drying.

Erfindungsgemäß werden Fixiermittel, die Halogensauerstoffsäuren bzw. deren Salze, z. B. Bromate, enthalten, mit entflammungshemmenden Stoffen versetzt. Hierfür kommen vorzugsweise in Betracht Ammoniumsalze, wie Ammoniumphosphat, Diammoniumhydrophosphat, Ammoniumchlorid, Ammoniumsulfat, Ammoniumborat. Durch diese Stoffzusätze wird die Feuergefährlichkeit z. B. von Bromaten im Rahmen der kosmetischen Anwendung vermindert oder beseitigt.According to the invention, fixatives, the halogenated oxygen acids or their salts, e.g. B. bromates, contain, mixed with flame retardants. For this purpose, ammonium salts such as ammonium phosphate, diammonium hydrophosphate, Ammonium chloride, ammonium sulfate, ammonium borate. These additives make the Fire hazard z. B. reduced by bromates in the context of cosmetic use or eliminated.

Wenn entflammungshemmende Stoffe, wie Alaun, angewandt werden sollen, die den pH-Wert des Fixiermittels zu niedrig einstellen würden, erhöht man den pH-Wert durch Zusatz geeigneter an sich bekannter Puffermittel oder -gemische auf oder über den zulässigen Schwellenwert; dieser Schwellenwert liegt bei etwa 5,5.If flame retardants such as alum are to be used, which is the pH of the fixative would set too low the pH is increased by adding suitable buffering agents known per se or - mixtures at or above the permissible threshold; this threshold lies at about 5.5.

Überraschenderweise zeigte es sich, daß durch diese Zusätze, namentlich Ammoniumsalze, z. B. Ammoniumsalze der Phosphorsäuren, außerdem besondere kosmetische Effekte, insbesondere festere Krausen, erzielt werden. Vielleicht ist diese Wirkung auf folgenden Umstand zurückzuführen: Fixiermittel, die Bromate od. dgl. enthalten, müssen an sich in neutraler oder schwach saurer Lösung angewandt werden, weil Bromate od. dgl. in stärker saurem Medium verhältnismäßig leicht zersetzt werden. Daher kann das Haar durch den Fixierungsvorgang nicht seine natürlichen elastischen Eigenschaften zurückerlangen. Die erwähnten Zusätze wirken offenbar als Puffermittel und somit im Sinne der Wiederherstellung der natürlichen Elastizität des Haares.Surprisingly, it was found that these additions, namely Ammonium salts, e.g. B. ammonium salts of phosphoric acids, also special cosmetic Effects, in particular firmer frills, can be achieved. Maybe this is the effect attributable to the following circumstance: fixatives containing bromates or the like, must be used in neutral or weakly acidic solution because bromates od. The like. Are relatively easily decomposed in a more acidic medium. Therefore the hair cannot retain its natural elastic properties due to the fixation process get back. The additives mentioned apparently act as a buffering agent and thus in the sense of restoring the natural elasticity of the hair.

Beim Fixieren einer Dauerwelle oder sonstigen Formveränderungen des Haares sind Zusätze von Netzmitteln, z. B. Fettalkoholsulfonaten, üblich. Diese steigern die Gefährlichkeit von Bromaten und ähnlichen Verbindungen erheblich und bilden mit diesen ganz besonders gefährliche und leicht brennbare Mischungen, welche damit imprägnierte Kleider hochbrennbar machen.When fixing a permanent wave or other changes in the shape of the Hair are additives of wetting agents, z. B. fatty alcohol sulfonates, common. These increase the danger of bromates and similar compounds considerably and form with these particularly dangerous and easily flammable mixtures, which make impregnated clothes highly combustible.

Es wurde nun festgestellt, daß die genannten entflammungshemmenden Stoffe ausreichen, um auch Zumischungen von Netzmitteln gefahrlos zu machen. Es stellte sich dabei heraus, daß beispielsweise die Kombination von Bromat mit Fettalkoholsulfonat und Diammoniumhydrophosphaten, zusammen gelöst und auf Filtrierpapier eingedunstet, eine geringere Verbrennungsneigung zeigt als Fettalkoholsulfonat mit Bromat bzw. Phosphat mit Bromat. Durch den Zusatz der Stoffe gemäß der Erfindung wird die Brandgefahr vollkommen beseitigt. Beispiele i. 4,00% Natriumbromat 1,5 0/0 Laurylalkoholsulfonat 4,0 0/0 Di-ammoniumhydrophosphat 2. 4,00/, Natriumbromat 1,5 % Laurylalkoholsulfonat 4,0 0/0 Ammoniumchlorid In gleicher -Weise läßt sich die feuergefährliche Wirkung der Chlorite, Chlorate und jodate herabsetzen und eine Anwendung für den hier vorliegenden Zweck ermöglichen. 3. 3,5 % Natriumchlorit 1,50110 Fettsäuremethyltaurid 4,0 % Di-ammoniumhydrophosphat 4. 5,0% Natriumjodat 2,5 0/0 Alkylarylsulfonat 3,0 % Ammonsulfat 5. 315% HC104 (perchlorsäure) i,o 0/0 Laurylalkoholsulfat 3,5 0lo Ammonsulfat Die Differenz zu ioo ist in allen fünf Beispielen Wasser. Etwa 75 ccm der Lösungen werden mit einem Schwamm oder Pinsel auf das zu fixierende Haar aufgetragen. Nach entsprechender Wirkzeit, mindestens aber bis zur vollständigen Oxydation der freien S H-Gruppen im Keratin zu - S - S-Brücken, wird das Haar ausgespült.It has now been found that the aforementioned flame retardant Substances are sufficient to make the admixture of wetting agents safe. It It turned out that, for example, the combination of bromate with fatty alcohol sulfonate and diammonium hydrophosphates, dissolved together and evaporated on filter paper, shows a lower tendency to burn than fatty alcohol sulfonate with bromate or Phosphate with bromate. The addition of the substances according to the invention increases the risk of fire completely eliminated. Examples i. 4.00% sodium bromate 1.5 0/0 lauryl alcohol sulfonate 4.0 0/0 di-ammonium hydrophosphate 2. 4.00 /, sodium bromate 1.5% lauryl alcohol sulfonate 4.0 0/0 ammonium chloride In the same way, the flammable effect the chlorite, chlorate and iodate degrade and an application for the present here Enable purpose. 3. 3.5% sodium chlorite 1.50110 fatty acid methyl tauride 4.0% di-ammonium hydrophosphate 4.50% sodium iodate 2.5 0/0 alkylarylsulfonate 3.0% ammonium sulfate 5. 315% HC104 (perchloric acid) i, o 0/0 Lauryl alcohol sulfate 3.5 0lo ammonium sulfate The difference to ioo is in all five examples of water. About 75 cc of the solutions are made with a sponge or brush applied to the hair to be fixed. After the appropriate working time, at least but until the free S H groups in the keratin are completely oxidized to - S - S-bridges, the hair is rinsed out.

Man kann auch die Mittel gemäß den Beispielen mit Wasser weiter verdünnen, z. B. etwa Zoo ccm auf =1, ansetzen und damit das Haar bis zur vollständigen Fixierung der Krause spülen.You can also further dilute the agents according to the examples with water, z. B. about zoo ccm to = 1, apply and thus the hair until it is completely fixed rinse the frill.

Die in den Beispielen genannten und ähnliche Salzgemische können auch trocken verpackt und gefahrlos versandt werden; sie sind vor dem Gebrauch leicht in der erforderlichen Menge Wasser lösbar.The salt mixtures mentioned in the examples and similar can also packed dry and safely shipped; they are light before use soluble in the required amount of water.

Es wird dadurch an Verpackungsmitteln und Fracht gespart.This saves packaging material and freight.

Claims (3)

PATENTANSPRÜCHE: i. Fixiermittel für die Haarwellung, die Halogensauerstoffsäuren bzw. deren Salze enthalten und die nach der alkalischen reduzierenden Vorbehandlung angewendet werden, gekennzeichnet durch einen Gehalt an entflammungshemmenden Stoffen. PATENT CLAIMS: i. Fixatives for hair curls, the halogenated oxygen acids or contain their salts and those after the alkaline reducing pretreatment are used, characterized by a content of flame-retardant substances. 2. Fixiermittel nach Anspruch i, dadurch gekennzeichnet, daß diese außerdem Netzmittel und Emulgiermittel, wie Fettalkoholsulfonate, Fettsäurekondensationsprodukte, Polyglykole und deren Derivate, enthalten. 2. Fixing agent according to claim i, characterized in that it also has wetting agents and emulsifiers such as fatty alcohol sulfonates, fatty acid condensation products, polyglycols and their derivatives. 3. Fixiermittel nach Anspruch i und 2, dadurch gekennzeichnet, daß diese außerdem haarpflegende Stoffe, wie Lecithin, Cholesterin, enthalten. In Betracht gezogene Druckschriften: USA.-Patentschriften Nr. 2 531359, 2 540 494; französische Patentschriften Nr. 665 464, 686 144; deutsche Patentschrift Nr. 743 246: Buchheister-Ottersbach: Vorschriftenbuch für Drogisten, 1949, S. 549, 550.3. Fixing agent according to claim i and 2, characterized in that they also contain hair care substances such as lecithin, cholesterol. References considered: U.S. Patents Nos. 2,531,359, 2,540,494; French Patent Nos. 665 464, 686 144; German patent specification No. 743 246: Buchheister-Ottersbach: Handbuch für Drogisten, 1949, pp. 549, 550.
DESCH9881A 1952-07-01 1952-07-01 Fixative for hair curls Expired DE951886C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DESCH9881A DE951886C (en) 1952-07-01 1952-07-01 Fixative for hair curls

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESCH9881A DE951886C (en) 1952-07-01 1952-07-01 Fixative for hair curls

Publications (1)

Publication Number Publication Date
DE951886C true DE951886C (en) 1956-11-08

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DE (1) DE951886C (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR665464A (en) * 1927-12-10 1929-09-19 Ig Farbenindustrie Ag Flame retardants and extinguishers
FR686144A (en) * 1929-12-10 1930-07-22 I G Sa Flame retardant solution for articles made of fibrous materials
DE743246C (en) * 1937-02-10 1943-12-21 Franz Stroeher Ag Means for producing practically unchangeable changes in the shape of the hair
US2540494A (en) * 1949-09-03 1951-02-06 Milton H Schwarz Permanent hair waving
US9531359B1 (en) * 2015-10-08 2016-12-27 Peregrine Semiconductor Corporation Multi-state attenuator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR665464A (en) * 1927-12-10 1929-09-19 Ig Farbenindustrie Ag Flame retardants and extinguishers
FR686144A (en) * 1929-12-10 1930-07-22 I G Sa Flame retardant solution for articles made of fibrous materials
DE743246C (en) * 1937-02-10 1943-12-21 Franz Stroeher Ag Means for producing practically unchangeable changes in the shape of the hair
US2540494A (en) * 1949-09-03 1951-02-06 Milton H Schwarz Permanent hair waving
US9531359B1 (en) * 2015-10-08 2016-12-27 Peregrine Semiconductor Corporation Multi-state attenuator

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