DE898942C - Paste-like detergent and process for its manufacture - Google Patents

Paste-like detergent and process for its manufacture

Info

Publication number
DE898942C
DE898942C DEL5762D DEL0005762D DE898942C DE 898942 C DE898942 C DE 898942C DE L5762 D DEL5762 D DE L5762D DE L0005762 D DEL0005762 D DE L0005762D DE 898942 C DE898942 C DE 898942C
Authority
DE
Germany
Prior art keywords
paste
hydroxides
gelatinous
detergent
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEL5762D
Other languages
German (de)
Inventor
Carl Dr Dussel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aug Luhn & Co GmbH
Original Assignee
Aug Luhn & Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aug Luhn & Co GmbH filed Critical Aug Luhn & Co GmbH
Priority to DEL5762D priority Critical patent/DE898942C/en
Application granted granted Critical
Publication of DE898942C publication Critical patent/DE898942C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Pastenartiges Reinigungsmittel und Verfahren zu seiner Herstellung In der Seifenindustrie wird neuerdings hauptsächlich das sogenannte Mers.olat (Alkalisalz der durch Sulfochlorierung höherer aliphatischer Kohlenwasserstoffe gewonnenen Sulfonsäuren) als Austauschstoff verwendet.Paste-like detergent and process for its manufacture In the soap industry, the so-called Mers.olat (alkali salt the sulfonic acids obtained by sulfochlorination of higher aliphatic hydrocarbons) used as a substitute.

Zwecks bequemer Handhabung und Dosierung ist bei Reinigungsmitteln die Pastenform erwünscht. Die Verwendung üblicher organischer Duellkörper in gequollenem Zustand, wie Stärkeprodukte, Celluloseäther, z. B. Methyl- und Äthylcellulose oder celluloseglykolsaures Natrium, oder polyacrylsaures Natrium, zur Erzielung eines pastenförmigen Zustands scheitert bei dem handelsüblichen Mersolat an dem Umstand, daß diese Gallerten beim Zusatz von sogenanntem Mersolat entquellen, wodurch das gebundene Wasser größtenteils frei wird.For the purpose of convenient handling and dosing, detergents are used the paste form is desirable. The use of common organic dueling bodies in swollen Condition, such as starch products, cellulose ethers, e.g. B. methyl and ethyl cellulose or Sodium cellulose glycolate, or sodium polyacrylate, to obtain a pasty state fails with the commercially available Mersolat due to the fact that these jellies swell when so-called mersolate is added, whereby the bound water is largely released.

Man hat daher bis zur Erzielung der Pastenform einen Zusatz von Natronseife einer hochmolekularen, gesättigten Fettsäure gemacht. Damit wird aber das Bestreben, tunlichst ohne Fette auszukommen, teilweise zunichte gemacht.You therefore have to add soda soap until the paste form is obtained made of a high molecular weight, saturated fatty acid. But this becomes the endeavor Get along without fats if possible, partially ruined.

Es wurde nun gefunden, daß man auf einfache Weise Pasten aus handelsüblichem @Mersolat erhält, wenn man mit diesem anorganische, gallertartige Hydroxyde, z. B. die Hydroxyde des Magnesiums, Aluminiums, Zinks oder Zinns, vermischt. Man erhält auf diese Weise ein pastenförmiges Gemisch von überraschend guter Reinigungswirkung, indem das an sich .geringe Schmutztragevermögen des sogenannten IMersolats durch die bedeutende Emulsionskraft der zugefügten Hydroxyde wesentlich erhöht wird.It has now been found that you can easily paste from commercially available @Mersolate is obtained if you use this inorganic, gelatinous hydroxides, e.g. B. the hydroxides of magnesium, aluminum, zinc or tin, mixed. You get in this way a paste-like mixture with a surprisingly good cleaning effect, by the inherently low dirt-carrying capacity of the so-called IMersolats is significantly increased by the significant emulsifying power of the added hydroxides.

Zuweilen erweist es sich als -zweckmäßig, die gallertartige Hydroxyde vor dem 'Vermischen mit dem sogenannten Mersolat auf schwach alkalische Reaktion zwischen pH = 8 und PH = 11 einzustellen. Dadurch wird die Reinigungswirkung noch weiter erhöht.Sometimes it turns out to be useful, the gelatinous hydroxide before mixing with the so-called Mersolat for a weak alkaline reaction set between pH = 8 and PH = 11. This will increase the cleaning effect further increased.

Selbstverständlich kann die erhaltene Paste noch mit anderen üblichen Zusätzen versehen werden, um ihre Reinigungswirkung noch weiter zu steigern; nämlich mit anderen bekannten Netzmitteln, wie Sulfonaten anderer Art oder Seifen, oder mit Reibkörpern verschiedenster Art, wie.Quarzmehl, gemahlene Kreide oder Bimsstein, Holzmehl oder Gummipulver, um eine Scheuerwirkung zu erzielen. Beispiel 94 kg Aluminiumhydroxyd, wie es als feuchter Filterkuchen bei der Filtration durch Filterpressen anfällt, wird mittels Alkali auf einen pH-Wert von 9 eingestellt und dann mit 6 kg handelsüblichem Mersolat (5o°/o Sulfonsäure) vermischt und zu einer Paste verrührt. Dieser Paste kann zur Erhöhung der Scheuerwirkung noch 2o kg Quarzmehl hinzugefügt werden.Of course, the paste obtained can be combined with other customary Additives are provided in order to increase their cleaning effect even further; namely with other known wetting agents, such as sulphonates of other types or soaps, or with various types of friction bodies, such as quartz powder, ground chalk or pumice stone, Wood flour or rubber powder to create a scrubbing effect. Example 94 kg aluminum hydroxide, as it is obtained as a moist filter cake during filtration through filter presses, is adjusted to a pH value of 9 with alkali and then with 6 kg of commercially available Mersolate (50% sulfonic acid) mixed and stirred into a paste. This paste 2o kg of quartz powder can be added to increase the scrubbing effect.

Claims (1)

PATENTANSPRÜCHE: i. Pastenartiges Reinigungsmittel auf der Grundlage eines Alkalisalzes der :durch Sulfochlorierung höherer aliphatischerKohlenwasserstoffe gewonnenen Sulfonsäuren, gekennzeichnet durch den Gehalt an anorganischen, gallertartigen Hydroxyden mehrwertiger Metalle. Verfahren zur Herstellung des Reinigungsmittels nach Anspruch i, dadurch gekennzeichnet, daß die zuzusetzenden anorganischen, gallertartigen,Hydroxyde auf schwach alkalische Reaktion (pH-Wert etwa 8 bis ii) eingestellt werden. Angezogene Druckschriften: Deutsche Patentschrift Nr. 319 933; USA.-Patentschrift Nr. 70436q.; französische Patentschrift Nr. 849 393. PATENT CLAIMS: i. Paste-like cleaning agent based on an alkali salt of the: sulfonic acids obtained by sulfochlorination of higher aliphatic hydrocarbons, characterized by the content of inorganic, gelatinous hydroxides of polyvalent metals. Process for the production of the cleaning agent according to claim i, characterized in that the inorganic, gelatinous, hydroxides to be added are adjusted to a weakly alkaline reaction (pH value approximately 8 to ii). Cited publications: German Patent No. 319,933; U.S. Patent No. 70436q .; French patent specification No. 849 393.
DEL5762D 1942-11-24 1942-11-24 Paste-like detergent and process for its manufacture Expired DE898942C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEL5762D DE898942C (en) 1942-11-24 1942-11-24 Paste-like detergent and process for its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEL5762D DE898942C (en) 1942-11-24 1942-11-24 Paste-like detergent and process for its manufacture

Publications (1)

Publication Number Publication Date
DE898942C true DE898942C (en) 1953-12-07

Family

ID=7256901

Family Applications (1)

Application Number Title Priority Date Filing Date
DEL5762D Expired DE898942C (en) 1942-11-24 1942-11-24 Paste-like detergent and process for its manufacture

Country Status (1)

Country Link
DE (1) DE898942C (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US704364A (en) * 1901-11-04 1902-07-08 Harry C Peffer Soap.
DE319933C (en) * 1916-08-24 1920-03-27 Max Buchner Dr Methods of washing and cleaning
FR849393A (en) * 1938-06-28 1939-11-22 Detergent and similar compositions, their preparation process and their applications

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US704364A (en) * 1901-11-04 1902-07-08 Harry C Peffer Soap.
DE319933C (en) * 1916-08-24 1920-03-27 Max Buchner Dr Methods of washing and cleaning
FR849393A (en) * 1938-06-28 1939-11-22 Detergent and similar compositions, their preparation process and their applications

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