DE880524C - Process for increasing the effectiveness of rodent repellants - Google Patents

Process for increasing the effectiveness of rodent repellants

Info

Publication number
DE880524C
DE880524C DESCH3748A DESC003748A DE880524C DE 880524 C DE880524 C DE 880524C DE SCH3748 A DESCH3748 A DE SCH3748A DE SC003748 A DESC003748 A DE SC003748A DE 880524 C DE880524 C DE 880524C
Authority
DE
Germany
Prior art keywords
effectiveness
increasing
parts
water
thiourea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DESCH3748A
Other languages
German (de)
Inventor
Alfred Dr Czyzewski
Max Dr Ehlers
Herbert Dr Schotte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Pharma AG
Original Assignee
Schering AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schering AG filed Critical Schering AG
Priority to DESCH3748A priority Critical patent/DE880524C/en
Application granted granted Critical
Publication of DE880524C publication Critical patent/DE880524C/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Verfahren zur Erhöhung der Wirksamkeit von Nagetierbekämpfungsmitteln Die Bekämpfung von Nagetieren, insbesondere von Ratten und Mäusen, spielt sowohl in der Hygiene wie in der Landwirtschaft eine große Rolle, da diese Tiere einerseits Krankheitsüberträger sind, andererseits lagernde Vorräte beschädigen oder zerstören. Im Laufe der Zeit sind zahlreiche Bekämpfungsmittel bekanntgeworden, unter denen die schlechthin als Gifte bezeichneten chemischen Verbindungen die bedeutendste Rolle spielen. Besonders bewährt haben sich in jüngster Zeit Thioharnstoffverbindungen, wie z. B. Phenylthioharnstoff, Naphthylthioharnstoff, Chlorphenyl-diazo-thioharnstoff. Da diese Thioharnstoffe den Vorzug haben, daß sie für Nagetiere, insbesondere Ratten, wesentlich giftiger sind als für andere Tiere und den Menschen, gestatten sie eine besondere Foim der Anwendung. Während man die bisherigen Giftstoffe zumeist Ködermitteln beimischte, kann man die Thioharnstoffe nach dem sogenannten Giftteppichverfahren anwenden. Dieses Giftteppichverfahren besteht darin, daß man die zweckmäßig mit inerten Stoffen verdünnten Thioharnstoffe auf Rattenwechseln ausstreut- oder in Rattenlöcher einbringt. Wenn sich die Tiere damit äußerlich verschmutzen, bringen sie beim späteren Putzen ihres Felles und ihrer Füße so viel Gift in den Magen-Darm-Traktus, daß die tödliche Dosis leicht überschritten wird. Vorbedingung dazu ist es allerdings, daß die Thioharnstoffzubereitung an einem trockenen Ort ausgestreut wird, damit sie ein ausreichendes Haftvermögen an den Tieren besitzt. Wird die Thioharnstoffzubereitung feucht, haftet sie nicht mehr und die Wirkung bleibt aus.Process for increasing the effectiveness of rodent control agents The control of rodents, particularly rats and mice, both play a role in the hygiene as in the agriculture a big role, as these animals on the one hand Are disease carriers, on the other hand damage or destroy stored supplies. In the course of time numerous pesticides have become known, among them the chemical compounds, known simply as poisons, are the most important Role-play. Recently, thiourea compounds have proven particularly useful, such as B. phenylthiourea, naphthylthiourea, chlorophenyl-diazo-thiourea. Since these thioureas have the advantage that they are useful for rodents, especially rats, are much more poisonous than for other animals and humans, they allow one special foim of application. While the previous toxins are mostly bait mixed in, you can use the so-called poison carpet method to add the thioureas use. This poison carpet method consists in the fact that one expediently with Inert substances diluted thioureas on rat swaps or in Brings rat holes. If the animals get dirty with it, bring them they get so much poison into the gastrointestinal tract when they later clean their fur and their feet, that the lethal dose is easily exceeded. A prerequisite for this is, however, that the thiourea preparation is scattered in a dry place so it has sufficient adherence to the animals. Will the thiourea preparation when damp, it no longer adheres and the effect is absent.

Es wurde nun gefunden, daß man Fraßgifte zur Bekämpfung von Nagetieren, insbesondere Thioharnstoffzubereitungen, besonders wirksam machen kann, wenn man ihr Haftvermögen vergrößert und sie zugleich wasserabstoßend macht. Es ist dann möglich, diese Zubereitungen auch an Stellen zu verwenden, die nicht vor Feuchtigkeit geschütit sind.It has now been found that food poisons can be used to control rodents, especially thiourea preparations, make it particularly effective can if you increase their adhesive power and make them water-repellent at the same time. It is then possible to use these preparations in places that are not are protected from moisture.

Die Erhöhung des Haftvermögens und die M'asserabstoßung erreicht man z. B. dadurch, daß man die Oberfläche der Giftteilchen mit einem Harzüberzug oder mit einem Überzug von fettsaurem Erdalkali-oder anderen Metallen versieht.The increase in the adhesive strength and the mass repellency are achieved z. B. by the fact that the surface of the poison particles with a resin coating or provided with a coating of fatty acid alkaline earth or other metals.

Beispiele i. Man durchfeuchtet eine Mischung von 2o Teilen a-Naphthyl-thioharnstoff und 8o Teilen Schiefermehl mit einer 5 °/oigen Lösung von Cumaronhatz in Benzol. Anschließend vertreibt man das Lösungsmittel. Das verbleibende Pulver besitzt ein vorzügliches Haftvermögen und ist zugleich wasserabstoßend. An Stelle des Cumaronharzes kann man ein beliebiges anderes natürliches oder synthetisches Harz mit ähnlichen Eigenschaften verwenden.Examples i. A mixture of 20 parts of a-naphthyl-thiourea is moistened and 80 parts of slate flour with a 5% solution of coumarone in benzene. The solvent is then driven off. The remaining powder has a excellent adhesion and is at the same time water-repellent. Instead of the coumarone resin you can use any other natural or synthetic resin with similar Use properties.

2. 6o Teile feinstgemahlener Speckstein werden in i5o Teilen Wasser aufgeschlämmt und nach Zusatz von 3 Teilen Rindertalg und i Teil Calciumhydroxyd 1/2 Stunde zum Sieden erhitzt. Nach dem Abkühlen gibt man 3o Teile Phenylthioharnstoff hinzu, saugt ab und trocknet. Es entsteht ein wasserabstoßendes, gut haftendes Pulver. An Stelle des Rindertalges kann ein anderes technisch zugängliches Fett Verwendung finden.2. 60 parts of finely ground soapstone are mixed with 150 parts of water slurried and after adding 3 parts of beef tallow and 1 part of calcium hydroxide Heated to the boil for 1/2 hour. After cooling, 3o parts of phenylthiourea are added added, sucks off and dries. The result is a water-repellent, well-adhering powder. Instead of beef tallow, another technically accessible fat can be used Find.

3. 68 Teile Talkum und 3o Teile a-Naphthylthioharnstoff werden mit 2 Teilen Ölsäure und o,5 Teilen Calciumhydroxyd innigst vermahlen. Danach sind alle Teilchen des so gewonnenen Pulvers wasserabstoßend. Das Pulver haftet sehr gut auch an glatten Flächen. An Stelle der Ölsäure kann eine beliebige Fettsäure mit mehr als 8 C genommen werden.3. 68 parts of talc and 3o parts of a-naphthylthiourea are added Mill 2 parts of oleic acid and 0.5 parts of calcium hydroxide very closely. After that everyone is Particles of the powder obtained in this way are water-repellent. The powder also adheres very well on smooth surfaces. Any fatty acid with more can be used in place of oleic acid can be taken as 8 C.

4. o,5 Teile 3-(a-Acetonyl-benzyl-4-hydroxy-cumarin) werden mit 5 °/o fettsaurem Kalk und 94,5 °/o Gesteinsmehl innig vermahlen. Das so gewonnene Pulver haftet gut an glatten Flächen und stößt das Wasser ab.4. 0.5 parts of 3- (a-acetonyl-benzyl-4-hydroxy-coumarin) are mixed with 5 ° / o fatty acid lime and 94,5 ° / o rock flour thoroughly ground. That won Powder adheres well to smooth surfaces and repels water.

Für die Herstellung solcher Mittel können auch andere Cumarinderivate verwendet werden.Other coumarin derivatives can also be used for the production of such agents be used.

Claims (1)

PATENTANSPRUCH: Verfahren zur Erhöhung der Wirksamkeit von Nagetierbekämpfungsmitteln, dadurch gekennzeichnet, daß man ihr Haftvermögen vergrößert und sie zugleich wasserabstoßend macht, indem man zweckmäßig die Teilchen von Fraßgiften, insbesondere von Thioharnstoffverbindungen, mit dem Überzug eines Harzes oder eines fettsauren Erdalkali- oder anderen Metalls versieht.PATENT CLAIM: Process for increasing the effectiveness of rodent control agents, characterized in that it increases its adhesion and at the same time it is water-repellent makes by expediently the particles of food poisons, in particular of thiourea compounds, with the coating of a resin or a fatty acid alkaline earth metal or other metal provides.
DESCH3748A 1950-08-24 1950-08-24 Process for increasing the effectiveness of rodent repellants Expired DE880524C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DESCH3748A DE880524C (en) 1950-08-24 1950-08-24 Process for increasing the effectiveness of rodent repellants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESCH3748A DE880524C (en) 1950-08-24 1950-08-24 Process for increasing the effectiveness of rodent repellants

Publications (1)

Publication Number Publication Date
DE880524C true DE880524C (en) 1953-06-22

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ID=7423908

Family Applications (1)

Application Number Title Priority Date Filing Date
DESCH3748A Expired DE880524C (en) 1950-08-24 1950-08-24 Process for increasing the effectiveness of rodent repellants

Country Status (1)

Country Link
DE (1) DE880524C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1144531B (en) * 1960-09-14 1963-02-28 Albert Ag Chem Werke Control of rodents living underground, mainly voles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1144531B (en) * 1960-09-14 1963-02-28 Albert Ag Chem Werke Control of rodents living underground, mainly voles

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