DE880283C - Process for the production of the finest heavy metal powders - Google Patents
Process for the production of the finest heavy metal powdersInfo
- Publication number
- DE880283C DE880283C DEM8984A DEM0008984A DE880283C DE 880283 C DE880283 C DE 880283C DE M8984 A DEM8984 A DE M8984A DE M0008984 A DEM0008984 A DE M0008984A DE 880283 C DE880283 C DE 880283C
- Authority
- DE
- Germany
- Prior art keywords
- heavy metal
- production
- finest
- metal powders
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910001385 heavy metal Inorganic materials 0.000 title claims description 8
- 239000000843 powder Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 150000001805 chlorine compounds Chemical class 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 235000021110 pickles Nutrition 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 3
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Description
Verfahren zur Herstellung von feinsten Schwermetallpulvern Feinste Schwermetallpulver, besonders Eisen- und Nickelpulver, die zur Herstellung von Katalysatoren oder für Dauermagnete gebraucht werden, werden durch Reduktion von ameisensauren Salzen mittels Wasserstoff oder durch Herauslösen des Aluminiums aus dem betreffenden Mischkristall hergestellt. Es ist auch bekannt, durch Reduktion von Schwermetallchloriden, die billiger sind als ameisensaure Salze, mittels Wasserstoff Eisen- und Nickelpulver zu gewinnen. Diese Pulver fallen in Form gut ausgebildeter Kristalle an und besitzen daher keine aktiven Eigenschaften; sie sind weder als Katalysatoren noch als Grundstoff für Weicheisendauermagnete geeignet.Process for the production of the finest heavy metal powders Finest Heavy metal powder, especially iron and nickel powder, used in the manufacture of catalysts or for permanent magnets are used by reducing formic acid Salting by means of hydrogen or by leaching out the aluminum from the relevant Solid solution produced. It is also known to reduce heavy metal chlorides, which are cheaper than formic acid salts, using hydrogen, iron and nickel powder to win. These powders are obtained in the form of well-developed crystals and have therefore no active properties; they are neither as catalysts nor as raw materials suitable for soft iron permanent magnets.
Erfindungsgemäß werden die Schwermetallchloride mit Alkali- oder Erdalkalisalzen, vorzugsweise Chloriden, gemischt und geschmolzen. Behandelt man ein derartiges Erzeugnis oder das geschmolzene Salzgemisch mit Wasserstoff, so bilden sich äußerst feinverteilte, hochaktive Metallpulver.According to the heavy metal chlorides with alkali or alkaline earth salts, preferably chlorides, mixed and melted. If you treat such a product or the molten salt mixture with hydrogen, extremely finely divided, highly active metal powder.
Beispiel Ein Gemisch aus i Mol FeC12 und i Mol Na Cl wird bei 420' geschmolzen und Wasserstoff eingeleitet. Es bildet sich Salzsäure, und die Salzschmelze färbt sich durch feinst ausgeschiedenes Eisen schwarz. Nach dem Erkalten wird der Rückstand in Wasser gelöst und das Eisenpulver abfiltriert. Mischt man dem getrockneten Pulver einige Hundertteile eines Kunststoffes zu und preßt Teile daraus, so erhält man Weicheisendauermagnete.Example A mixture of 1 mole FeC12 and 1 mole Na Cl is melted and hydrogen introduced. Hydrochloric acid and molten salt are formed turns black due to the finely excreted iron. After cooling down, the The residue was dissolved in water and the iron powder was filtered off. If you mix the dried Powder a few hundred parts of a plastic and presses parts out of it, so it gets man soft iron permanent magnets.
Besonders geeignet sind möglichst tief schmelzende Salzgemische, z. B. aus NaCl . KCl . FeCl2. Das FeCl2 kann entsprechend der fortschreitenden Reduktion laufend nachgegeben werden. Das Verfahren ist besonders wirtschaftlich bei Verwendung von Eisenchlorid aus Chloridabfallbeizen, da man dabei außer der Herstellung eines wertvollen Eisenpulvers die Salzsäure wiedergewinnen kann.Salt mixtures which melt as low as possible are particularly suitable, e.g. B. from NaCl. KCl. FeCl2. The FeCl2 can according to the progressive reduction are continuously given in. The process is particularly economical when using ferric chloride from chloride waste pickling, because besides the Manufacture of a valuable iron powder that can recover hydrochloric acid.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEM8984A DE880283C (en) | 1951-03-25 | 1951-03-25 | Process for the production of the finest heavy metal powders |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEM8984A DE880283C (en) | 1951-03-25 | 1951-03-25 | Process for the production of the finest heavy metal powders |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE880283C true DE880283C (en) | 1953-06-22 |
Family
ID=7294450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM8984A Expired DE880283C (en) | 1951-03-25 | 1951-03-25 | Process for the production of the finest heavy metal powders |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE880283C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE933752C (en) * | 1953-01-16 | 1955-10-06 | Degussa | Process and device for the production of finely divided metal oxides |
-
1951
- 1951-03-25 DE DEM8984A patent/DE880283C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE933752C (en) * | 1953-01-16 | 1955-10-06 | Degussa | Process and device for the production of finely divided metal oxides |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE880283C (en) | Process for the production of the finest heavy metal powders | |
| DE116857T1 (en) | METHOD FOR GRANULATING RAW MATERIALS FOR GLASS PRODUCTION. | |
| DE277245T1 (en) | METHOD FOR PRODUCING COMPLEX OXIDES FOR USE IN THE PRODUCTION OF FERRITE. | |
| DE2135234C3 (en) | Filter mass for water treatment | |
| DE612708C (en) | Process for the production of non-baking mixed fertilizers containing ammonium nitrate | |
| DE366187C (en) | Process for the separation of copper from copper-containing alkalis | |
| DE1592368B2 (en) | Process for obtaining ammonia and chlorine from ammonium chloride | |
| DE1492601A1 (en) | Process for the production of Poekelsalz | |
| DE726545C (en) | Process for the production of potash from very dilute solutions, e.g. B. sea water | |
| AT89824B (en) | Process for the preparation of anhydrous magnesium or calcium chloride. | |
| DE2736622A1 (en) | PROCESS FOR TREATMENT OF SOLID MIXTURES, MAINLY CONTAINING FERROUS CHLORIDE, PRODUCED IN THE CHLORINATION OF TITANIUM-CONTAINING RAW MATERIALS, IN PARTICULAR ILMENITE | |
| DE852671C (en) | Production of a hydraulic binder | |
| DE728991C (en) | Process for the manufacture of silica stones | |
| AT211276B (en) | Process for cleaning commercial ferrosilicon and technical silicon | |
| DE733560C (en) | Process for recovering vanadium from slags | |
| AT93185B (en) | Process for preserving calcium hypochlorite. | |
| AT131586B (en) | Process for improving aluminum or aluminum alloys and aluminum-containing alloys. | |
| DE140604C (en) | Process for purifying brine | |
| AT108570B (en) | Process for the production of technically iron-free aluminum-alkali double fluorides. | |
| DE485007C (en) | Process for the production of pure white and finely divided barium or calcium sulfate | |
| DE619749C (en) | Process for the production of metal powders with certain magnetic properties | |
| DE1271097B (en) | Process for the reduction of ferric ions to ferrous ions in an aqueous aluminum salt solution containing ferric and fluoride ions | |
| AT66489B (en) | Chrome tanning process. | |
| DE1517476A1 (en) | Process for neutralizing acidic water | |
| DE575320C (en) | Production of Engel's salt (potassium bicarbonate-magnesium carbonate) |