DE875431C - Process for obtaining a pepper substitute - Google Patents

Process for obtaining a pepper substitute

Info

Publication number
DE875431C
DE875431C DEB4485D DEB0004485D DE875431C DE 875431 C DE875431 C DE 875431C DE B4485 D DEB4485 D DE B4485D DE B0004485 D DEB0004485 D DE B0004485D DE 875431 C DE875431 C DE 875431C
Authority
DE
Germany
Prior art keywords
pepper
substitute
obtaining
fatty acid
acid mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB4485D
Other languages
German (de)
Inventor
Erich Dipl-Chem Dr Rabald
Fritz Dipl-Chem Dr Voeller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roche Diagnostics GmbH
Original Assignee
Boehringer Mannheim GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehringer Mannheim GmbH filed Critical Boehringer Mannheim GmbH
Priority to DEB4485D priority Critical patent/DE875431C/en
Priority to DK164242AA priority patent/DK63288C/en
Application granted granted Critical
Publication of DE875431C publication Critical patent/DE875431C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10—Natural spices, flavouring agents or condiments; Extracts thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Verfahren zur Gewinnung eines Pfefferaustauschstoffes Zusatz zum Patent 8&S3 380 Gemäß dem Verfahren des Patents 853 380 erhält man unter Verwendung der die Säuren mit etwa 7 bis 15 C-At.omen umfassenden Fraktion des bei der bekannten Oxydation von Paraffin zur Gewinnung synthetischer Fette abfallenden Säuregemisches einen vollgültigen Pfefferaustauschstoff. Es besteht darin, ,daß man dieses Fettsäuregemisch mit 3-Methoxy-4-oxybenzylamin in an sich üblicher Weise zur Umsetzung bringt.Process for obtaining a pepper substitute Addition to patent 8 & S3 380 According to the process of patent 853 380, a mixture of acids is obtained using the acid mixture comprising the acids with about 7 to 15 carbon atoms during the known oxidation of paraffin to obtain synthetic fats fully valid pepper substitute. It consists in reacting this fatty acid mixture with 3-methoxy-4-oxybenzylamine in a conventional manner.

Es wurde nun gefunden, daß man in noch glatterer Weise zu dem Verfahrensprodukt gelangen kann, wenn man das genannte Fettsäuregemisch über .die Säurechloride und -,ami,de mittels Formaldehyd in die entsprechenden Methylole Überführt und die letzteren mit Guajacol umsetzt.It has now been found that the process product can be obtained in an even smoother manner can reach if you said fatty acid mixture over .the acid chlorides and -, ami, de converted into the corresponding methylols by means of formaldehyde and the latter reacted with guaiacol.

Beispiel Läßt man auf das Gemisch, von Fettsäurechloriden, das man aus der die Säuren mit etwa 7 bis 15 C -Atomen umfassenden Fraktion des bei der Oxydation von Paraffin abfallenden Säuregemisches auf übliche Weise erhält, überschüssiges wäßriges Ammoniak einwirken, so erhält man die entsprechenden Mischfettsäureamide als ölige dickflüssige Masse. Dieses Produkt -liefert beim Stehen-' lassen mit q.ä°ai@gerarmärdehydlosting (die entsprechendenMethylole folgender Zusammensetzung: R.Co.NHGH2.#O-H.- _..-(R/Mischfettsäurerest- C7-Ci5)-: - . -- -- . 25 g dieses Reaktionsproduktes werden einer Lösung von- 1:2,5, g Guaj acol in 5o .ccm absolutem Alkohol in Gegenwart konz. Schwefelsäure oder :auch von wasserfreiem Zinkchlorid zugesetzt und mehrere Tage bei Temperaturen unter -zo° stehengelassen. Der Alkohol wird dann unter vermin dertem Druck aib.destilliert, der Rückstand in Äther,: aufgenommen und ,die ätherische Lösung his zur Entfernung der Schwefelsäure bzw. des Zinkchlorids mit Wasser ausgewaschen. Nicht - umgesetzte Methylole trennt man von MischfettsäUreamid- durch Lösung des- letzteren in Methylenchlorid. Man erhält auf diese Weise das gleiche Ptodukt wie gemäß .dem Beispiel des Hauptpatents.EXAMPLE If excess aqueous ammonia is allowed to act on the mixture of fatty acid chlorides, which is obtained in the usual manner from the fraction of the acid mixture containing acids with about 7 to 15 carbon atoms, the corresponding mixed fatty acid amides are obtained as an oily thick mass. This product -supplies when standing- 'leave with q.ä°ai@gerarmärdehydlosting (the corresponding methylols with the following composition: R.Co.NHGH2. # OH.- _..- (R / mixed fatty acid residue- C7-Ci5) -: -. 25 g of this reaction product are added to a solution of 1: 2.5 g of guaiacol in 5o .ccm of absolute alcohol in the presence of concentrated sulfuric acid or anhydrous zinc chloride and for several days at temperatures below -zo ° The alcohol is then distilled off under reduced pressure, the residue is taken up in ether and the ethereal solution is washed out with water until the sulfuric acid or zinc chloride is removed the latter in methylene chloride. In this way the same product is obtained as according to the example of the main patent.

Claims (1)

PATENTANSPRUCH: Verfahren zur Gewinnung eines Pfefferaustauschstoffesunter Verwendung der die Säuren mit etwa 7 bis 15 C-Atomen umfassenden Fraktion des durch Oxydation von Paraffin erhaltenen Fettsäuregemisches in Albänderung des .Patentes 853 38o, dadurch gekennzeichnet, daß man das genannte Fettsäuregemisch über die Säureamide in die entsprechenden Methylole überführt und ~die letzteren mit Guajacol zur Umsetzung bringt. PATENT CLAIM: Process for obtaining a pepper substitute using the fraction of the fatty acid mixture obtained by oxidation of paraffin, comprising the acids with about 7 to 15 carbon atoms, in the modification of patent 853 38o, characterized in that said fatty acid mixture is converted into the corresponding acid amides Converted methylols and ~ brings the latter to reaction with guaiacol.
DEB4485D 1941-07-29 1941-07-29 Process for obtaining a pepper substitute Expired DE875431C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEB4485D DE875431C (en) 1941-07-29 1941-07-29 Process for obtaining a pepper substitute
DK164242AA DK63288C (en) 1941-07-29 1942-02-21 Procedure for the Preparation of Substances for Pepper Spices.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB4485D DE875431C (en) 1941-07-29 1941-07-29 Process for obtaining a pepper substitute

Publications (1)

Publication Number Publication Date
DE875431C true DE875431C (en) 1953-05-04

Family

ID=6953684

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB4485D Expired DE875431C (en) 1941-07-29 1941-07-29 Process for obtaining a pepper substitute

Country Status (2)

Country Link
DE (1) DE875431C (en)
DK (1) DK63288C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE964328C (en) * 1950-10-22 1957-05-23 Karl Thomae G M B H Chem Pharm Process for the production of crystallized vanillylamides

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE964328C (en) * 1950-10-22 1957-05-23 Karl Thomae G M B H Chem Pharm Process for the production of crystallized vanillylamides

Also Published As

Publication number Publication date
DK63288C (en) 1945-03-19

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