DE850974C - Process for producing shiny surfaces on objects made of aluminum and aluminum alloys - Google Patents

Process for producing shiny surfaces on objects made of aluminum and aluminum alloys

Info

Publication number
DE850974C
DE850974C DESCH5674A DESC005674A DE850974C DE 850974 C DE850974 C DE 850974C DE SCH5674 A DESCH5674 A DE SCH5674A DE SC005674 A DESC005674 A DE SC005674A DE 850974 C DE850974 C DE 850974C
Authority
DE
Germany
Prior art keywords
aluminum
acid
objects made
shiny surfaces
baths
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DESCH5674A
Other languages
German (de)
Inventor
Nicolai Dr Budiloff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Pharma AG
Original Assignee
Schering AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schering AG filed Critical Schering AG
Priority to DESCH5674A priority Critical patent/DE850974C/en
Application granted granted Critical
Publication of DE850974C publication Critical patent/DE850974C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F3/00Brightening metals by chemical means
    • C23F3/02Light metals
    • C23F3/03Light metals with acidic solutions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)
  • Chemical Treatment Of Metals (AREA)

Description

Verfahren zur Erzeugung glänzender Oberflächen auf Gegenständen aus Aluminium und Aluminiumlegierungen 1:; sind lrcreits verschiedene Verfahren bekannt- geworden, mittels denen es gelingt, durch Ein- tauchen von Gegenständen * aus :Aluminium und seinen Leierungen in saure Bäder, insbesondere solche, die' aus Mischungen von Salpetersäure und I'liosliliors<iui-e bestehen, diesen eine -lätizende, liolicrtc ()1>crH:irhc zu verleihen. 1)1e Tauchdauer schwankt zwischen t_# Sekunden und io Minuten. Während bei Teinlierattiren 111s zu 138°, normaler- weise für Aluminium zwischen jo und 95°, ge- ar@i,it:t @@ird. 13c1 l@einaluminium war die erhaltene Politur hufriedigend, wenn die Polierbäder Phos- phorsätirc und Salpetersäure enthielten, während k1tl>ferhaltige Legierungen, bei denen im übrigen eine Hiii-cre "Tauchdauer erforderlich war, nur un- gleichni;il.lir ati#-egritten bzw. geätzt wurden und außerdem eine minderwertige Politur erhalten Wurde, die mit einem blauen Film bedeckt erschien (Metalloberfläche, Ausgabe B, 2. ,Jahr-. 195o, lieft i t, S. 168). Nlan setzte daher diesen Bädern Essigsäure zu und konnte auf diese N'°ise besser- Resultate erzielen. Derartige Bäder verändern jedoch ihre Zusammensetzung durch Verdanipfungs- \ erlöste, insbesondere der l-ssigsäure. l@ntgegen der Annahme, da13 Alumiiliuinlegiertin- gen und insbesondere solche,, die Kupfer enthalten. nur in Bädern aus Mischungen von Salpetersaure. Phosphorsäure und Essigsäure poliert werden hüti- nen, wurde iiberrasclienderweise gefunden, dal3 Altiininium und insbesondere seine kupferhaltigen Legierungen in einem Säuregemisch von Schwefel- s:iurc, 1'liosl,liors:ini-e und Salpetersäure clleiliiscli poliert «-erden können. Das Mischungsverhältnis dieser Säuren kann in weitem Umfang variiert werden; so haben sich z. B. Mischungsverhältnisse der folgenden Art bewährt: Schwefelsäure von etwa io bis 6o %, Phosphorsäure von etwa 7o bis 30 0/0, Salpetersäure von etwa 2o bis io%.Process for producing shiny surfaces on objects made of aluminum and aluminum alloys 1:; different processes are already known- by means of which it is possible to submerging objects * from: aluminum and his lyric in acid baths, in particular those 'made up of mixtures of nitric acid and I'liosliliors <iui-e exist, this one -latizende, liolicrtc () 1> crH: to lend irhc. 1) 1st dive duration fluctuates between t_ # seconds and io minutes. While in Teinlierattiren 111s at 138 °, normal- way for aluminum between jo and 95 °, ar @ i, it: t @@ ird. 13c1 l @ one aluminum was the one obtained The polishing is satisfactory if the polishing baths are phosphorous phorsätirc and nitric acid contained while K1tl> ferhaltige alloys, in which in the rest a hiii-cre "duration of diving was required, only un- Gleichni; il.lir ati # -read or etched and also received an inferior polish Was that appeared covered with a blue film (Metal surface, edition B, 2nd, year-. 195o, ran it, p. 168). Nlan therefore continued these baths Acetic acid and was able to respond better to this Get results. Change such baths however, their composition by evaporation \ redeemed, especially the liquid acid. Contrary to the assumption that aluminum alloyed genes and especially those that contain copper. only in baths made from mixtures of nitric acid. Phosphoric acid and acetic acid are polished carefully It was surprisingly found that3 Altiininium and especially its copperous Alloys in an acid mixture of sulfur s: iurc, 1'liosl, liors: ini-e and nitric acid clleiliiscli polished «-be able to earth. The mixing ratio of these acids can be varied widely; so have z. B. Proven mixing ratios of the following type: sulfuric acid from about 10 to 6o%, phosphoric acid from about 7o to 30%, nitric acid from about 20 to 10%.

Die anzuwendenden Temperaturen sowie die Tauchdauer sind die bereits für solche Tauchbäder bekannten und liegen beispielsweise zwischen 6o bis ioo ° bei einer Tauchdauer bis zu io Minuten.The temperatures to be used and the duration of the immersion are those already known for such immersion baths and are, for example, between 60 and 100 ° with a dive duration of up to 10 minutes.

Das Verfahren sei an folgenden Beispielen erläutert, wobei eine kupferhaltige Legierung verwendet wurde und diese bei einer Temperatur von etwa 9o° etwa 5 Minuten in ein Bad folgender Zusammensetzung eingetaucht wurde: 1. 55 0/0 Schwefelsäure, 35 % Phosphorsäure, io °/o Salpetersäure, 2. 15 % Schwefelsäure, 70 % Phosphorsäure, 15 % Salpetersäure. ' Es wurden hierbei polierte Oberflächen von hohem Glanz erhalten, die der eines Glanzchromniederschlages ähneln. Die so erhaltenen Oberflächen lassen sich weiter zur Erhärtung der Oberfläche elektrochemisch oder chemisch oxv-dieren. Man kann sie auch chemisch färben und lackieren.The process is illustrated by the following examples, one containing copper Alloy was used and this at a temperature of about 90 ° for about 5 minutes was immersed in a bath of the following composition: 1. 55% sulfuric acid, 35% phosphoric acid, 10% nitric acid, 2. 15% sulfuric acid, 70% phosphoric acid, 15% nitric acid. '' Here, polished surfaces with a high gloss were obtained, which resemble that of a bright chrome deposit. Leave the surfaces thus obtained further oxidize electrochemically or chemically to harden the surface. They can also be chemically colored and varnished.

Claims (3)

PATENTANSPRÜCHE: i. Verfahren zur Erzeugung glänzender Oberflächen auf Gegenständen aus Aluminium und Aluminiumlegierungen, insbesondere von solchen, die Kupfer enthalten, durch Eintauchen in Bäder, die Salpetersäure und Phosphorsäure enthalten, dadurch gekennzeichnet, daß die Bäder einen Zusatz von Schwefelsäure besitzen. PATENT CLAIMS: i. Process for producing shiny surfaces on objects made of aluminum and aluminum alloys, in particular those containing copper, by immersion in baths containing nitric acid and phosphoric acid, characterized in that the baths have an addition of sulfuric acid. 2. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß der Gehalt an Schwefelsäure etwa io bis 6o °/o beträgt. 2. The method according to claim i, characterized in that the content of Sulfuric acid is about 10 to 60%. 3. Verfahren nach Anspruch i und 2, dadurch gekennzeichnet, daß die Gegenstände bei einer Temperatur -vorzugsweise zwischen 6o und ioo° zu behandeln sind.3. The method according to claim i and 2, characterized characterized in that the objects are at a temperature -preferably between 6o and ioo ° are to be treated.
DESCH5674A 1951-01-13 1951-01-13 Process for producing shiny surfaces on objects made of aluminum and aluminum alloys Expired DE850974C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DESCH5674A DE850974C (en) 1951-01-13 1951-01-13 Process for producing shiny surfaces on objects made of aluminum and aluminum alloys

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESCH5674A DE850974C (en) 1951-01-13 1951-01-13 Process for producing shiny surfaces on objects made of aluminum and aluminum alloys

Publications (1)

Publication Number Publication Date
DE850974C true DE850974C (en) 1952-09-29

Family

ID=7424582

Family Applications (1)

Application Number Title Priority Date Filing Date
DESCH5674A Expired DE850974C (en) 1951-01-13 1951-01-13 Process for producing shiny surfaces on objects made of aluminum and aluminum alloys

Country Status (1)

Country Link
DE (1) DE850974C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1247806B (en) * 1959-02-04 1967-08-17 Minbrite Holdings Ltd Aqueous solution and process for glazing and brightening aluminum

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1247806B (en) * 1959-02-04 1967-08-17 Minbrite Holdings Ltd Aqueous solution and process for glazing and brightening aluminum

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