DE80758C - - Google Patents
Info
- Publication number
- DE80758C DE80758C DENDAT80758D DE80758DA DE80758C DE 80758 C DE80758 C DE 80758C DE NDAT80758 D DENDAT80758 D DE NDAT80758D DE 80758D A DE80758D A DE 80758DA DE 80758 C DE80758 C DE 80758C
- Authority
- DE
- Germany
- Prior art keywords
- toluidine
- dye
- nitrosomonoethyl
- nitrosomonomethyl
- replaced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NEWWJAMSPMOBAS-UHFFFAOYSA-N N-ethyl-N-(2-methylphenyl)nitrous amide Chemical compound CCN(N=O)C1=CC=CC=C1C NEWWJAMSPMOBAS-UHFFFAOYSA-N 0.000 claims description 4
- LGDPTPLJZGPOJL-UHFFFAOYSA-N N,N-dimethyl-2-nitrosoaniline Chemical group CN(C)C1=CC=CC=C1N=O LGDPTPLJZGPOJL-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- -1 Nitrosomonomethyl- Chemical group 0.000 claims description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N Diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 claims 1
- 239000001044 red dye Substances 0.000 claims 1
- 239000000975 dye Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- MWHUIOFIRPAVBJ-UHFFFAOYSA-N N-methyl-N-(2-methylphenyl)nitrous amide Chemical compound O=NN(C)C1=CC=CC=C1C MWHUIOFIRPAVBJ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B17/00—Azine dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
In der Patentschrift Nr. 69188 wurde gezeigt, dafs durch Einwirkung von Nitrosodimethylanilin auf m-Amidodimethyl-p-toluidin ein rother basischer Farbstoff von sehr werthvollen Eigenschaften entsteht.In the patent specification No. 69188 it was shown that by the action of nitrosodimethylaniline on m-amidodimethyl-p-toluidine a red basic dye of very valuable value Properties arises.
Wenn man in dem Verfahren der Patentschrift Nr. 69188 das Nitrosodimethylanilin durch Nitrosomonomethyl - ο - toluidin oder Nitrosomonoäthyl-o-toluidin ersetzt, so entstehen basische Farbstoffe von viel rötherer Nuance, als sie die im Haupt - Patent beschriebenen Farbstoffe besitzen. Sie zeigen den Farbenton des Safranins und übertreffen dieses an Seife- und Sodaechtheit. In concentrirter Schwefelsäure lösen sie sich mit grüner Farbe, die beim Verdünnen mit Wasser nach Blau und Roth umschlägt. Aus der wässerigen Lösung des salzsauren Salzes- wird die Basis mit Soda nicht gefällt.When using the nitrosodimethylaniline replaced by nitrosomonomethyl - ο - toluidine or nitrosomonoethyl-o-toluidine, so arise basic dyes of a much redder shade than those described in the main patent Own dyes. They show the color tone of saffranine and surpass it in terms of soap and soda fastness. In concentrated Sulfuric acid dissolve with a green color, which changes to blue and red when diluted with water. From the aqueous solution of the hydrochloric acid salt - the base is not precipitated with soda.
ι 5 kg m-Amidodimethyl-p-toluidin, gelöst in 80 kg Sprit, werden mit 18 kg Nitrosomonoäthyl-o-toluidin und 11 kg Salzsäure von 210B.ι 5 kg of m-amidodimethyl-p-toluidine, dissolved in 80 kg of fuel, with 18 kg of nitrosomonoethyl-o-toluidine and 11 kg of hydrochloric acid of 21 0 B.
mehrere Stunden zum Sieden erhitzt, bis alle Nitrosoverbindung verbraucht ist und der gebildete Farbstoff in wässeriger Lösung die Nuance des Safranins zeigt. Bei genügender Concentration der alkoholischen Lösung krystallisirt der Farbstoff beim Erkalten aus.Heated to the boil for several hours until all the nitroso compound is consumed and the formed Dye in aqueous solution shows the nuance of saffranine. With enough Concentration of the alcoholic solution, the dye crystallizes out on cooling.
Statt in alkoholischer Lösung kann der Farbstoff auch in Essigsäurelösung oder durch Verschmelzen der beiden Componenten erhalten werden.Instead of in alcoholic solution, the dye can also be in acetic acid solution or by Fusion of the two components can be obtained.
Ersetzt man in obiger Vorschrift das Nitrosomonoäthyl-o-toluidin durch die äquivalente Menge Nitrosomonomethyl-o-toluidin, so erhält man einen Farbstoff von etwas gelberer Nuance und ganz ähnlichen Eigenschaften.If the nitrosomonoethyl-o-toluidine is replaced by the equivalent in the above procedure Amount of nitrosomonomethyl-o-toluidine, one obtains a dye with a slightly more yellow shade and very similar properties.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE80758C true DE80758C (en) |
Family
ID=353286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT80758D Active DE80758C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE80758C (en) |
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0
- DE DENDAT80758D patent/DE80758C/de active Active
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