DE249490C - - Google Patents
Info
- Publication number
- DE249490C DE249490C DENDAT249490D DE249490DA DE249490C DE 249490 C DE249490 C DE 249490C DE NDAT249490 D DENDAT249490 D DE NDAT249490D DE 249490D A DE249490D A DE 249490DA DE 249490 C DE249490 C DE 249490C
- Authority
- DE
- Germany
- Prior art keywords
- chloro
- diazo compound
- solution
- black
- diazo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000975 dye Substances 0.000 claims description 7
- 150000008049 diazo compounds Chemical class 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 210000002268 Wool Anatomy 0.000 claims description 4
- 239000003929 acidic solution Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating Effects 0.000 description 2
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-Nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 description 1
- UJZOHHSRILPGAX-UHFFFAOYSA-N 5-chloro-2-phenylmethoxyaniline Chemical compound NC1=CC(Cl)=CC=C1OCC1=CC=CC=C1 UJZOHHSRILPGAX-UHFFFAOYSA-N 0.000 description 1
- ASMGJACQANYOIZ-UHFFFAOYSA-N 5-chloro-2-phenylmethoxyaniline;hydrochloride Chemical compound Cl.NC1=CC(Cl)=CC=C1OCC1=CC=CC=C1 ASMGJACQANYOIZ-UHFFFAOYSA-N 0.000 description 1
- QYFYIOWLBSPSDM-UHFFFAOYSA-N 6-aminonaphthalen-1-ol Chemical compound OC1=CC=CC2=CC(N)=CC=C21 QYFYIOWLBSPSDM-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001808 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002035 prolonged Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
- C09B33/02—Disazo dyes
- C09B33/08—Disazo dyes in which the coupling component is a hydroxy-amino compound
- C09B33/10—Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
PATENTAMT.PATENT OFFICE.
f. PATENTSCHRIFTf. PATENT DOCUMENT
- M 249490 KLASSE 22«. GRUPPE- M 249490 CLASS 22 «. GROUP
Es wurde gefunden, daß wertvolle wasch-, walk- und dekaturechte schwarze Wollfarbstoffe gewonnen werden, wenn peri-Aminonaphtolsulfosäuren, die sich zweimal mit Diazoverbindungen zu vereinigen vermögen, zuerst in saurer Lösung mit einer beliebigen Diazoverbindung und darauf in alkalischer Lösung mit der Diazoverbindung des 4-Chlor-2-aminophenolbenzyläthers, der in der PatentschriftIt has been found that valuable black wool dyes that are washable, milled and decade-fast obtained when peri-aminonaphthol sulfonic acids, which are twice with diazo compounds able to combine, first in acidic solution with any diazo compound and then in alkaline solution with the diazo compound of 4-chloro-2-aminophenol benzyl ether, that in the patent specification
ίο 142899 beschrieben ist, gekuppelt werden. Die so erhaltenen Farbstoffe färben Wolle in saurem Bade in schwarzen Tönen an. Die Färbungen sind wasch-, walk- und dekaturecht. Diese Eigenschaften bedingen einenίο 142899 is described, must be coupled. the The dyes obtained in this way dye wool in an acidic bath in black tones. The colors are washable, milled and decorative. These qualities require you
ig großen technischen Fortschritt.ig great technical progress.
Die neuen Farbstoffe zeigen im besonderen eine wesentlich bessere Waschechtheit als die bekannten analogen Kombinationsprodukte der Patentschriften 65651, 81241 und 214496. Die Echtheitseigenschaften werden durch die Einführung des 4-Chlor-2-aminophenolbenzylätherrestes bedeutend verbessert.The new dyes show in particular a much better wash fastness than that known analog combination products of patents 65651, 81241 and 214496. The Fastness properties are enhanced by the introduction of the 4-chloro-2-aminophenolbenzylätherrestes significantly improved.
Namentlich wird die Waschechtheit, die bei den bekannten Handelsmarken vom Naphtolblauschwarztypus als für die heutigen Verhältnisse nicht mehr genügend bekannt ist, derartig gesteigert, daß dadurch ein wesentlicher technischer Fortschritt erzielt wird.In particular, the wash fastness is that of the well-known trademarks of the naphtol blue black type than is no longer sufficiently known for today's conditions, such increased so that a significant technical advance is achieved.
13,8 kg p-Nitranilin werden in bekannter Weise diazotiert und in mineralsaurer Lösung mit 34 kg des frisch gefällten sauren Natriumsalzes der ι · 8 · 3 · 6-Aminonaphtoldisulfosäure vereinigt. Wenn nach längerem Rühren die Kupplung beendet ist, wird mittels Soda oder Natronlauge neutralisiert und nach Zusatz von überschüssiger Soda eine aus 27 kg salzsaurem 4-Chlor-2-aminophenolbenzyläther, 20 kg Salzsäure von 30 Prozent und 7 kg Natriumnitrit in etwa 300 1 Wasser erhaltene Diazolösung zulaufen gelassen.13.8 kg of p-nitroaniline are known in Way diazotized and in mineral acid solution with 34 kg of the freshly precipitated acid sodium salt the ι · 8 · 3 · 6-aminonaphthol disulfonic acid united. When the coupling is complete after prolonged stirring, soda or Sodium hydroxide solution is neutralized and, after the addition of excess soda, one from 27 kg of hydrochloric acid 4-chloro-2-aminophenol benzyl ether, 20 kg hydrochloric acid of 30 percent and 7 kg sodium nitrite run in diazo solution obtained in about 300 l of water.
Der Farbstoff bildet sich sofort und scheidet sich größtenteils ab. Nach einiger Zeit wird gelinde erwärmt und nach Zusatz von wenig Kochsalz nitriert. Der Farbstoff färbt Wolle in saurem Bade violettschwarz.The dye forms immediately and largely separates out. After some time is gently heated and nitrated after adding a little table salt. The dye stains Wool in an acidic bath purple-black.
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Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE249490C true DE249490C (en) |
Family
ID=508107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT249490D Active DE249490C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE249490C (en) |
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0
- DE DENDAT249490D patent/DE249490C/de active Active
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