DE743728C - Process for the production of metallization patterns by metal vapor deposition in a vacuum - Google Patents

Process for the production of metallization patterns by metal vapor deposition in a vacuum

Info

Publication number
DE743728C
DE743728C DEB197856D DEB0197856D DE743728C DE 743728 C DE743728 C DE 743728C DE B197856 D DEB197856 D DE B197856D DE B0197856 D DEB0197856 D DE B0197856D DE 743728 C DE743728 C DE 743728C
Authority
DE
Germany
Prior art keywords
condensation
metal vapor
vacuum
local heating
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB197856D
Other languages
German (de)
Inventor
Dr-Ing Eberhardt Traub
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL64341D priority Critical patent/NL64341C/xx
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Priority to DEB197856D priority patent/DE743728C/en
Application granted granted Critical
Publication of DE743728C publication Critical patent/DE743728C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • C23C14/042Coating on selected surface areas, e.g. using masks using masks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/04Producing precipitations
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/30Electron-beam or ion-beam tubes for localised treatment of objects
    • H01J37/305Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching
    • H01J37/3053Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching for evaporating or etching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Description

Verfahren zur Herstellung von Metallisierungsmustern durch Metallbedampfung im Vakuum Bei der Herstellung von dünnen Metallschichten durch Bedampfen von Unterlagen im Vakuum sind oft Muster erwünscht, d. h. die Metallschicht soll nicht gleichmäßig zusammenhängen, sondern an gewissen Stellen soll die Unterlage von Metall frei bleiben. Dieses wurde bisher in der Weise ausgeführt, daß man den Metalldampf von den freizuhaltenden Stellen durch Schablonen abhielt.- Beider Metallisierung laufender Bänder ist es jedoch umständlich, entsprechende Schablonen mitlaufen zu lassen. Auch wachsen die freien Stellen der Schablonen leicht mit Metall zu, da die Schablonen ja selbst dem Metalldampf ausgesetzt sind, sie müssen daher öfter ausgewechselt und gereinigt werden, um sauber begrenzte Muster zu ermöglichen.Process for the production of metallization patterns by metal vapor deposition in a vacuum In the production of thin metal layers by vapor deposition on substrates Patterns are often desired in a vacuum; H. the metal layer should not be uniform related, but at certain points the base should remain free of metal. This has so far been carried out in such a way that the metal vapor to be kept free Restrained places by templates However, it is difficult to run the corresponding templates. They grow too Free areas of the stencils can be easily covered with metal, since the stencils themselves are exposed to metal vapor, so they have to be replaced and cleaned more often to enable neatly delimited patterns.

Es wurde vorgeschlagen, an den von Metall freizulassenden Stellen Stoffe aufzutragen, die eine Bedampfung verhindern, z. B. öle und Fette lassen sich hierzu zweckmäßig auf die Unterlagebänder in jeder gewünschten Form auftragen. Zu diesem Zweck trägt man dünnste Schichten z. B. mit Druckwalzen- auf. - . Gemäß der Erfindung enthält nun die Unterlage selbst einen kondensationshindernden Stoff in solcher Menge, daß er an der Oberfläche der Unterlage in so geringer Konzentration vorhanden ist, daß er die Kondensation des Metalldampfes nicht verhindern kann. Durch lokale Erwärmung gelangt der kondensationshindernde Stoff in wirksamen Mengen an die Oberfläche der Unterlage und verhindert nun .die Kondensation des Metalldampfes an den Stellen., die man zum Zwecke der Bemusterung ausgewählt hatte.It has been suggested to be in the places to be exposed by metal To apply substances that prevent vaporization, e.g. B. oils and fats can For this purpose, it is advisable to apply it to the underlay tape in any desired shape. to for this purpose one wears the thinnest layers z. B. with pressure rollers. -. According to the Invention now contains a condensation-preventing substance in the pad itself such an amount that it is in such a low concentration on the surface of the substrate is present that it cannot prevent the condensation of the metal vapor. The anti-condensation substance arrives in effective quantities through local heating to the surface of the base and now prevents condensation of the metal vapor in the places that had been selected for the purpose of sampling.

Ein zu metallisierendes Band wird z. B. dadurch mit einem kondensationshindernden Stoff versehen, daß man gleichzeitig einen dünnen Lacküberzug aufträgt, welcher den kondensationshindernden Stoff in Form eines Lösungsmittels oder Weichmachers (C51) enthält. Das C51 ist nun an der Oberfläche des lackierten Bandes gar nicht oder in so geringer Konzentration vorhanden, daß es eine nachfolgende Metallbedampfung dieses Bandes nicht stören kann und die Unterlage an allen Stellen gleichmäßigen Metallbelag erhalten würde. ... . 1. A band to be metallized is z. B. thereby provided with a condensation-preventing substance that a thin lacquer coating is applied at the same time, which contains the condensation-preventing substance in the form of a solvent or plasticizer (C51). The C51 is now not present on the surface of the lacquered tape or is present in such a low concentration that it cannot interfere with subsequent metal vapor deposition of this tape and the base would have a uniform metal coating at all points. ... 1.

Druckt man jetzt durch Berührung z. B. mit einem wärfen S"tentpel ein Muster auf die lackierte Unterlage, so gelangt das 01 als konderi'sati@@ttsTi'in@lerri@Ier Stoff an die Oberfläche und verhindert an den bedruckten Stellen die Metallisierung. Diese Stellen bleiben von Metallbelag frei.If you now press z. B. with a warfen S "tentpel a sample on the lacquered surface, the 01 arrives as konderi'sati @@ ttsTi'in @ lerri @ Ier Fabric to the surface and prevents metallization on the printed areas. These areas remain free of metal deposits.

Kondensationshindernde Schichten brau nur äußerst dünn zu sein, z. B. von mole rer Größenordnung. Die Konzentration 6,1 #. Schichten läßt sich daher leicht mit einfach&b: Mitteln dosieren. Die Muster -neigen saubere Abgrenzungen, cla die an der Oberfläche im Vakuum verdampfende Menge des kondensationshindernden Stoffes verschwindend klein ist. Es kann nämlich bei zu stark aufgetragenen hondensa.tionsliindernden Schichten die lletallbedanipfung auch neben den von Metall freizulassenden Stellen gestört werden, weil der kondensationshindernde Stoff im Vakuum selbst größere Dampfmengen abgeben `kann. Bei den nach dein vorstehenden Verfahren erzeugten äußerst dünnen Schichten ist die Gefahr der Erschwerung einer Kondensation an den -Nachbarstellen nicht vorhanden.Anti-condensation layers only need to be extremely thin, e.g. B. of mole rer order of magnitude. The concentration 6.1 #. Layers can therefore be easily dosed with simple & b: means. The patterns tend to have clean delimitations, since the amount of the condensation-preventing substance evaporating on the surface in a vacuum is negligibly small. If the condensation-reducing layers are applied too thickly, the metal-to-metal contact can also be disturbed in addition to the areas to be left free of metal, because the condensation-preventing substance itself can give off large amounts of vapor in a vacuum. With the extremely thin layers produced by the above process, there is no risk of condensation being made difficult at the neighboring points.

Die Wärmeerzeugung an bestimmten begrenzten Stellen kann außer mit warmen Stempeln auch mit Elektronenstrahlen z. B. erfolgen, die man aus bekannten Erzeugern kommend in ebenfalls bekannter Weise steuern kann. Werden die Elektronenstrahlen z. B. durch magnetische Linsen in Strahlenbündel zusammengefaßt und in einem Brennfleck vereinigt, so kann der Brennfleck bzw. das Strahlenbündel bewegt werden, und nur die voni Brennfleck getroffenen Stellen auf der Unterlage werden erwärmt. In entsprechender Weise können Wärmestrahlen angewendet und gesteuert werden, z. B. in der Art wie beim Mechau-Projektor die optischen Strahlen projiziert «-erden.The heat generation in certain limited places can except with warm stamps also with electron beams z. B. be done, which is known from Generators can control coming in a known manner as well. Will the electron beams z. B. summarized by magnetic lenses in bundles of rays and in a focal spot combined, the focal spot or the bundle of rays can be moved, and only the areas on the substrate hit by the focal point are heated. In appropriate Heat rays can be applied and controlled, e.g. B. in the manner of in the Mechau projector, the optical beams are projected «-erden.

Claims (3)

PATENTANSPRÜCHE: i. Verfahren zur Herstellung von Metallisierungsinustern durch Metallbedampfung im Vakuum, dadurch gekennzeichnet, daß in die zu metallisierende Unterlage selbst ein kondensationshindernder Stoff in solcher Menge eingebracht wird, daß er an der Oberfläche der Unterlage in so ge-. ringe r Konzentration vorhanden ist, daß er die Kondensation des Metallclainpfes nicht verhindern kann, und daß er durch lokale Erwärmung vor der il,letallbedanipfting in wirksamer 1lenge an die Oberfläche gelangt und dort an gewissen Stellen die Kondensation des 1letalldampfes verhindert. PATENT CLAIMS: i. Process for the production of metallization patterns by metal vapor deposition in a vacuum, characterized in that in the to be metallized Underlay itself introduced a condensation-preventing substance in such an amount is that he is on the surface of the pad in such a way. rings for concentration is that it cannot prevent the condensation of the metal pan, and that he by local heating in front of the il, letallbedanipfting in effective 1lenge to the Surface and there at certain points the condensation of the metal vapor prevented. 2. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß die lokale Erwärmung durch Bedrucken- mit erwärmten Stempeln erfolgt. 2. The method according to claim i, characterized in that the local Heating takes place by printing with heated stamps. 3. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß die lokale Erwärmung durch Elektronenstrahlen erfolgt. .f. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß die lokale Erwärmung durch Wärmestrahlen erfolgt. Zur Abgrenzung des Annieldungsgegenstandes vom Stand der Technik sind im Erteilungsverfahren keine Druckschriften in Betracht gezogen worden.3. The method according to claim i, characterized in that the local heating is carried out by electron beams. .f. Method according to claim i, characterized in that the local heating takes place by heat rays. To distinguish the object of sale from the stand Due to the technology, no publications are considered in the granting procedure been.
DEB197856D 1942-04-09 1942-04-09 Process for the production of metallization patterns by metal vapor deposition in a vacuum Expired DE743728C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NL64341D NL64341C (en) 1942-04-09
DEB197856D DE743728C (en) 1942-04-09 1942-04-09 Process for the production of metallization patterns by metal vapor deposition in a vacuum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB197856D DE743728C (en) 1942-04-09 1942-04-09 Process for the production of metallization patterns by metal vapor deposition in a vacuum

Publications (1)

Publication Number Publication Date
DE743728C true DE743728C (en) 1944-12-18

Family

ID=7012020

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB197856D Expired DE743728C (en) 1942-04-09 1942-04-09 Process for the production of metallization patterns by metal vapor deposition in a vacuum

Country Status (2)

Country Link
DE (1) DE743728C (en)
NL (1) NL64341C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE949724C (en) * 1952-03-09 1956-09-27 Franke & Heidecke Fabrik Photo Process for generating characters that only become visible when breathing on
DE1263449B (en) * 1959-04-08 1968-03-14 Siemens Ag Process for the production of metallized insulating foils

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE949724C (en) * 1952-03-09 1956-09-27 Franke & Heidecke Fabrik Photo Process for generating characters that only become visible when breathing on
DE1263449B (en) * 1959-04-08 1968-03-14 Siemens Ag Process for the production of metallized insulating foils

Also Published As

Publication number Publication date
NL64341C (en)

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