DE73179C - Representation of copper oxide - Google Patents
Representation of copper oxideInfo
- Publication number
- DE73179C DE73179C DENDAT73179D DE73179DA DE73179C DE 73179 C DE73179 C DE 73179C DE NDAT73179 D DENDAT73179 D DE NDAT73179D DE 73179D A DE73179D A DE 73179DA DE 73179 C DE73179 C DE 73179C
- Authority
- DE
- Germany
- Prior art keywords
- copper
- copper oxide
- chloride
- oxide
- representation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005751 Copper oxide Substances 0.000 title claims description 10
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 title claims description 10
- 229910000431 copper oxide Inorganic materials 0.000 title claims description 10
- 239000010949 copper Substances 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- ORTQZVOHEJQUHG-UHFFFAOYSA-L Copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims 1
- 235000012255 calcium oxide Nutrition 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- 239000000460 chlorine Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- BERDEBHAJNAUOM-UHFFFAOYSA-N Copper(I) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 229940112669 cuprous oxide Drugs 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QLOLFVLPQSFYEU-UHFFFAOYSA-L C([O-])([O-])=O.[Cu+2]=O Chemical compound C([O-])([O-])=O.[Cu+2]=O QLOLFVLPQSFYEU-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N Copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 239000005752 Copper oxychloride Substances 0.000 description 1
- PSAQTDRCTCPMOX-UHFFFAOYSA-J [Cl-].[Ca+2].[Cu](Cl)Cl.[Cl-] Chemical compound [Cl-].[Ca+2].[Cu](Cl)Cl.[Cl-] PSAQTDRCTCPMOX-UHFFFAOYSA-J 0.000 description 1
- KRZVGTCBOODHEX-UHFFFAOYSA-N [Cu]=O.C(O)(O)=O Chemical compound [Cu]=O.C(O)(O)=O KRZVGTCBOODHEX-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 1
- -1 copper chlorine Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0069—Leaching or slurrying with acids or salts thereof containing halogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
PATENTSCHRIFTPATENT LETTERING
KLASSE 40: Hüttenwesen.CLASS 40: Metallurgy.
Dr. KARL HOEPFNER in FRANKFURT a. M. Darstellung von Kupferoxydul. Dr. KARL HOEPFNER in FRANKFURT a. M. Representation of copper oxide.
Patentirt im Deutschen Reiche vom 19. Juli 1892 ab.Patented in the German Empire on July 19, 1892.
Kupferoxydul gewinnt man nach vorliegender Erfindung aus Erzen und Hüttenproducten in folgender Weise:-According to the present invention, copper oxide is obtained from ores and metallurgical products in the following way: -
Gemahlene schwefelkupferhaltige Erze und Hüttenproducte werden durch eine zweckmäfsig erwärmte Lösung von Kupferchlorid in Kochsalzlauge oder überhaupt einer Lauge, welche Kupferchlorür reichlich zu lösen vermag, am besten aber durch eine Chlorcalcium - Kupferchloridlauge von ihrem Kupfergehalt befreit. Dabei entsteht in der Lauge Kupferchlorür. Diese Kupferchlorürlauge wird von dem Erz getrennt und darauf von mit aufgelöstem Silber, Wismuth, Eisen, sowie von Arsen, Antimon, Blei etc. durch Kupfer, Kupferoxydul, Kupferoxydulcarbonat bezw. Kupferoxychlorür, Sauerstoff oder aber durch Alkalien, alkalische Erden oder deren Carbonate oder Sulfide möglichst befreit.Ground ores containing copper sulphide and metallurgical products are made expedient by a heated solution of copper chloride in sodium chloride solution or any alkali at all, which Can dissolve copper chloride in abundance, but best with a calcium chloride copper chloride solution freed from their copper content. This creates copper chloride in the lye. This copper chlorine liquor is made up of the ore separated and then from dissolved silver, bismuth, iron, as well as from arsenic, antimony, Lead etc. by copper, copper oxide, copper oxide carbonate respectively. Copper oxychloride, oxygen or by alkalis, alkaline earths or their carbonates or sulfides if possible freed.
Die erhaltene reine Kupferchlorürlauge wird sodann getheilt. Die eine Portion wird mit Alkalien oder deren Carbonaten oder aber mit Aetzkalk behandelt, derart, dafs alles Kupfer oder aber nur ein Theil desselben in Form von reinem Kupferoxydul (Cu2O) oder kohlensaurem Kupferoxydul ausgefällt wird. . Sollte dieser Niederschlag noch Blei bezw. Arsen oder Antimon enthalten, so können diese Verunreinigungen leicht, z. B. durch Alkalilösungen, daraus entfernt werden. Das so fast chemisch rein gewonnene Kupferoxydul kann jetzt in beliebiger Weise weiter verarbeitet werden.The pure copper chloride solution obtained is then divided. The one portion but is treated with alkalis or their carbonates or caustic lime, in such a way, that all copper or only a portion of it in the form of pure cuprous oxide (Cu 2 O) or carbonate of cuprous oxide is precipitated. . Should this precipitation still lead respectively. Contain arsenic or antimony, these impurities can easily, e.g. B. by alkali solutions, are removed therefrom. The copper oxide obtained in this way almost chemically pure can now be further processed in any way.
Der Kupfergehalt der anderen Laugenportion wird in Kupferchlorid verwandelt. Dieses geschieht durch Einwirkung von Säuren unter dem Einflufs der atmosphärischen Luft oder von Sauerstoff, bezw. auch wohl durch Einwirkung von Chlor. Besonders vortheilhaft und billig ist die Verwendung von schwefliger Säure für diesen Zweck, welche sich dabei in der Lauge zu Schwefelsäure oxydirt, welch letztere durch Chlorcalcium unter Bildung von Salzsäure wieder ausgefällt wird.The copper content of the other lye portion is converted into copper chloride. This happens by the action of acids under the influence of atmospheric air or of oxygen, respectively. also probably through the action of chlorine. Particularly beneficial and cheap is the use of sulphurous acid for this purpose, which is found in the lye is oxidized to sulfuric acid, the latter by calcium chloride with the formation of Hydrochloric acid is precipitated again.
In Formeln ausgedrückt, stellt sich das ganze Verfahren dar wie folgt:Expressed in formulas, the whole procedure is as follows:
ι. 2 Cu Cl2 + 2 Cu S — 2 Cu2 Cl2 +2 S, 2 Cm2 Cl2 ι. 2 Cu Cl 2 + 2 Cu S - 2 Cu 2 Cl 2 + 2 S, 2 Cm 2 Cl 2
=: Cu2 O + Cm2 CZ2 =: Cu 2 O + Cm 2 CZ 2
+ Ca Cl2, Cu2 Cl2+SO2 + 2 0+H2 O= Cu2 Cl2O+ Ca Cl 2 , Cu 2 Cl 2 + SO 2 + 2 O + H 2 O = Cu 2 Cl 2 O
4. Cm2 Cl2 0 + H2 SO, +CaCl2 = 2 CmCl2 4. Cm 2 Cl 2 O + H 2 SO, + CaCl 2 = 2 Cm Cl 2
+ H2 0 +Ca S O4, + H 2 0 + Ca S O 4 ,
5. 2 Cm Cl2 + 2 Cm S = 2 Cu2 Cl2 + 2 S 5. 2 Cm Cl 2 + 2 Cm S = 2 Cu 2 Cl 2 + 2 S
U. S. W.U. S. W.
Aus Rückständen, welche metallisches Kupfer enthalten, kann letzteres nach diesem Verfahren ebenfalls in Form von Kupferoxydul bezw. kohlensaurem Kupferoxydul gewonnen werden.The latter can be extracted from residues containing metallic copper using this method also in the form of copper oxide respectively. carbonic acid copper oxide.
In dieser Weise kann in fortlaufendem Kreisprocefs aus rohen Erzen bezw. Hüttenproducten oder Kupferrückständen Kupferoxydul in beliebiger Menge und zu beliebigem Zwecke hergestellt und der Kupfergehalt der Extractionslauge constant erhalten werden.In this way, in continuous Kreisprocefs from raw ores BEZW. Metallurgical products or copper residues copper oxide produced in any quantity and for any purpose and the copper content of the extraction liquor can be kept constant.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE73179C true DE73179C (en) | 1900-01-01 |
Family
ID=346330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT73179D Expired DE73179C (en) | Representation of copper oxide |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE73179C (en) |
-
0
- DE DENDAT73179D patent/DE73179C/en not_active Expired
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