DE700212C - Process for the production of compounds containing titanium oxide for ceramic purposes - Google Patents

Process for the production of compounds containing titanium oxide for ceramic purposes

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Publication number
DE700212C
DE700212C DE1936R0097539 DER0097539D DE700212C DE 700212 C DE700212 C DE 700212C DE 1936R0097539 DE1936R0097539 DE 1936R0097539 DE R0097539 D DER0097539 D DE R0097539D DE 700212 C DE700212 C DE 700212C
Authority
DE
Germany
Prior art keywords
production
ceramic
titanium oxide
compounds containing
purposes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1936R0097539
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rosenthal Isolatoren GmbH
Original Assignee
Rosenthal Isolatoren GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rosenthal Isolatoren GmbH filed Critical Rosenthal Isolatoren GmbH
Priority to DE1936R0097539 priority Critical patent/DE700212C/en
Application granted granted Critical
Publication of DE700212C publication Critical patent/DE700212C/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/49Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Description

Verfahren zur Herstellung titanoxydhaltiger Massen für keramische Zwecke Bei der Herstellung von keramischen elektrischen Isolierkörpern aus Titandioxyd wird das im Handel befindliche, fein gemahlene Titanweiß mit Zusätzen versehen, welche für die Erzielung eines elektrisch und keramisch hochwertigen Scherbens notwendig sind. Solche Zusätze können z. B. sein: Magnesiumoxyd, Calciumoxyd, Zirkonoxyd usw.Process for the production of titanium oxide-containing compounds for ceramic Purposes In the manufacture of ceramic electrical insulating bodies made of titanium dioxide the finely ground titanium white available on the market is provided with additives, which is necessary for the achievement of an electrically and ceramic high quality body are. Such additives can, for. B. be: magnesium oxide, calcium oxide, zirconium oxide etc.

Titanweiß hat aber infolge seiner Kornfeinheit eine große Brennschwindung von 2o bis 25%. Um diese zu verringern, ist bisher ein Teil dieses Titandioxyds bei Temperaturen von i2oo bis 140o° vorgebrannt und nochmals gemahlen worden; denn eine; gute Reaktion hängt sehr von der Kornfeinheit der Oxydkomponenten ab. Da der Feinmahlung im keramischen Betrieb aus wirtschaftlichen Gründen Grenzen gesetzt sind und eine Verwendung von Hydroxyden oder eine gemeinsame Ausfällung der Hydroxyde im Arbeitsprozeß einer keramischen Fabrik schwer durchführbar ist, so wird das Mischgut im keramischen Brand erst bei verhältnismäßig hohen Temperaturen reagieren.However, due to its fineness, titanium white has a large firing shrinkage from 2o to 25%. In order to reduce this, part of this has been titanium dioxide pre-fired at temperatures from 120 to 140o ° and ground again; because one; good reaction depends very much on the grain size of the oxide components. Since the Fine grinding in ceramic operations is limited for economic reasons are and a use of hydroxides or a coprecipitation of the hydroxides is difficult to carry out in the work process of a ceramic factory, so the mix only react in ceramic firing at relatively high temperatures.

Gemäß der Erfindung werden unter Vereinfachung des Arbeitsverfahrens die Aufbereitungskosten herabgesetzt sowie bessere Reaktionsbedingungen der Mischungen erzielt, wenn die Zusätze schon während des Herstellungsverfahrens des Titanweißes eingeführt werden und nicht erst bei der Aufbereitung des Versatzes in der keramischen Fabrik.According to the invention, while simplifying the working procedure the processing costs are reduced and the reaction conditions of the mixtures are improved achieved if the additives are used during the manufacturing process of the titanium white are introduced and not only during the preparation of the offset in the ceramic Factory.

Zu diesem Zweck wird eine Titansulfatlösung oder ausgefällte Metatitansäure mit dem oxydischen oder oxydbildenden Zuschlagstoff, z. B. mit Zirkonsulfat oder mit Zirkonoxyd, vermischt, um gemeinsam mit der Metatitansäure in den Calcinierofen zu gelangen. Dort wird das Gut bei einer Temperatur, die dem Zuschlagstoff angepaßt is@i entwässert. Die sonst für die Titanweißfarberr notwendige Feinstmahlung unterbleibt. Das Erzeugnis ist sehr gut durchgemischt und kann unmittelbar nach dem Verlassen des Calcinierofens keramisch aufbereitet und geformt werden. Der Zusatz von notwendigen Plastifizierungsmitteln, z. B. von rohem Ton, erfolgt nach dem Calcinieren.A titanium sulfate solution or precipitated metatitanic acid is used for this purpose with the oxidic or oxide-forming aggregate, e.g. B. with zirconium sulfate or with zirconium oxide, mixed together with the metatitanic acid in the calcining furnace to get. There the material is at a temperature that is adapted to the aggregate is @ i dehydrated. The fine grinding otherwise necessary for the titanium white color is omitted. The product is very well mixed and can be used immediately after leaving of the calcining furnace can be ceramically prepared and shaped. The addition of necessary Plasticizers, e.g. B. of raw clay, takes place after calcining.

Es ist bekannt, bei der Herstellung von Titanweiß für Farbzwecke sog. Kompositions-oder Mischpigmente mit anderen Oxyden, wie Zirkonoxyd, seltenen Erden, Zinkoxyd, Bariumsulfat oder Calciumsulfat, in der geschilderten Weise zu erzeugen. Diese Verbindungen dienen ausschließlich Anstrichzwecken und werden infolgedessen nach dem Verlassen des Calcinierofens sehr fein gemahlen.It is known in the production of titanium white for color purposes so-called. Composition or mixed pigments with other oxides, such as zirconium oxide, rare earths, Zinc oxide, barium sulfate or calcium sulfate, in the one described way to create. These compounds are and are used for painting purposes only as a result, it is very finely ground after leaving the calcining furnace.

Das hier beschriebene Verfahren unterscheidet sich in seiner Aufgabenstellung und Zielsetzung von der Farbenherstellung auf der Basis von Titanweiß, ferner auch durch den Verzicht auf Farbwirkung und durch die Verwendung des Drehofenproduktes ohne Feinstvermahlung.The procedure described here differs in terms of its task and the aim of producing paints on the basis of titanium white, as well by renouncing the color effect and by using the rotary kiln product without fine grinding.

Claims (1)

PATENTANSPRUCH: Die Anwendung von Titandioxyderaeugnissen, die aus Titandioxyd unter Zusatz anderer Oxyde, wie z. B. Magnesium- oder Zirkonoxyd oder deren Salze oder Hydrate, in der für Farbzwecke bekannten Weise hergestellt sind, unter Ausschaltung der Feinmahlung unmittelbar nach dem Calcinieren zur Herstellung von keramischen Massen für elektrische Isolierzwecke. PATENT CLAIM: The use of titanium dioxide products made from titanium dioxide with the addition of other oxides, such as B. magnesium or zirconium oxide or their salts or hydrates, are prepared in the manner known for color purposes, with elimination of fine grinding immediately after calcining for the production of ceramic masses for electrical insulation purposes.
DE1936R0097539 1936-10-09 1936-10-09 Process for the production of compounds containing titanium oxide for ceramic purposes Expired DE700212C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE1936R0097539 DE700212C (en) 1936-10-09 1936-10-09 Process for the production of compounds containing titanium oxide for ceramic purposes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1936R0097539 DE700212C (en) 1936-10-09 1936-10-09 Process for the production of compounds containing titanium oxide for ceramic purposes

Publications (1)

Publication Number Publication Date
DE700212C true DE700212C (en) 1940-12-16

Family

ID=7419795

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1936R0097539 Expired DE700212C (en) 1936-10-09 1936-10-09 Process for the production of compounds containing titanium oxide for ceramic purposes

Country Status (1)

Country Link
DE (1) DE700212C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE916157C (en) * 1943-05-19 1954-08-05 Nat Lead Co Method of making a dielectric ceramic body
DE916189C (en) * 1943-11-02 1954-08-05 Nat Lead Co Body of high dielectric constant
DE976673C (en) * 1944-10-27 1964-07-16 Steatit Magnesia Ag Process for the production of TiO and predominantly titanium-containing, densely sintered ceramic compounds for electrical insulating materials and capacitor dielectrics
DE1181609B (en) * 1958-05-05 1964-11-12 Renault Process for the production of ceramic parts for electrical purposes and thus obtained ceramic bodies with dielectric and semiconductor properties

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE916157C (en) * 1943-05-19 1954-08-05 Nat Lead Co Method of making a dielectric ceramic body
DE916189C (en) * 1943-11-02 1954-08-05 Nat Lead Co Body of high dielectric constant
DE976673C (en) * 1944-10-27 1964-07-16 Steatit Magnesia Ag Process for the production of TiO and predominantly titanium-containing, densely sintered ceramic compounds for electrical insulating materials and capacitor dielectrics
DE1181609B (en) * 1958-05-05 1964-11-12 Renault Process for the production of ceramic parts for electrical purposes and thus obtained ceramic bodies with dielectric and semiconductor properties

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