DE69716720D1 - Verfahren zur cyclotrimerisierung von alkinen in wässrigen lösungen - Google Patents

Verfahren zur cyclotrimerisierung von alkinen in wässrigen lösungen

Info

Publication number
DE69716720D1
DE69716720D1 DE69716720T DE69716720T DE69716720D1 DE 69716720 D1 DE69716720 D1 DE 69716720D1 DE 69716720 T DE69716720 T DE 69716720T DE 69716720 T DE69716720 T DE 69716720T DE 69716720 D1 DE69716720 D1 DE 69716720D1
Authority
DE
Germany
Prior art keywords
aqueous solutions
cyclotrimerizing
alkines
discloses
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69716720T
Other languages
English (en)
Other versions
DE69716720T2 (de
Inventor
Bruce Eaton
S Sigman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Invenux Inc
Original Assignee
Invenux Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Invenux Inc filed Critical Invenux Inc
Publication of DE69716720D1 publication Critical patent/DE69716720D1/de
Application granted granted Critical
Publication of DE69716720T2 publication Critical patent/DE69716720T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/44—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/73—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/328—Cycloadditions involving more than 2 components or moieties, e.g. intra-/intermolecualar [2+2+2] or [2+2+1], e.g. Pauson-Khand type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
DE69716720T 1996-03-20 1997-02-25 Verfahren zur cyclotrimerisierung von alkinen in wässrigen lösungen Expired - Lifetime DE69716720T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/619,228 US5659069A (en) 1996-03-20 1996-03-20 Method for the cyclotrimerization of alkynes in aqueous solutions
PCT/US1997/002820 WO1997034857A1 (en) 1996-03-20 1997-02-25 Method for the cyclotrimerization of alkynes in aqueous solutions

Publications (2)

Publication Number Publication Date
DE69716720D1 true DE69716720D1 (de) 2002-12-05
DE69716720T2 DE69716720T2 (de) 2003-06-12

Family

ID=24481004

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69716720T Expired - Lifetime DE69716720T2 (de) 1996-03-20 1997-02-25 Verfahren zur cyclotrimerisierung von alkinen in wässrigen lösungen

Country Status (11)

Country Link
US (3) US5659069A (de)
EP (1) EP0888268B1 (de)
JP (2) JP2000506888A (de)
AT (1) ATE226929T1 (de)
AU (1) AU715066B2 (de)
CA (1) CA2248352C (de)
DE (1) DE69716720T2 (de)
DK (1) DK0888268T3 (de)
ES (1) ES2185912T3 (de)
PT (1) PT888268E (de)
WO (1) WO1997034857A1 (de)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7179907B2 (en) * 2001-12-18 2007-02-20 Bruce Eaton Antibiotic compounds
DE60326640D1 (de) * 2002-08-05 2009-04-23 Cropsolution Inc Rekombinante biotincarboxylasedomänen zur identifizierung von acetyl-coa-carboxylase-inhibitoren
US8143465B2 (en) * 2005-05-02 2012-03-27 The Hong Kong University Of Science & Technology Soluble branched triaroylbenzene-based polymer and its synthetic method
WO2008151499A1 (en) * 2007-06-11 2008-12-18 The Hong Kong University Of Science And Technology Synthesis of acylarylenes and hyperbranched poly(acylarylene)s by metal-free cyclotrimerization of alkynes
FR2948373B1 (fr) 2009-07-23 2011-09-30 Centre Nat Rech Scient Complexes organometalliques actifs derives de selenoquinone, leurs procedes de synthese et utilisations
US9656229B2 (en) 2012-08-21 2017-05-23 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9205398B2 (en) 2012-08-21 2015-12-08 Uop Llc Production of butanediol from a methane conversion process
US8927769B2 (en) 2012-08-21 2015-01-06 Uop Llc Production of acrylic acid from a methane conversion process
US9689615B2 (en) 2012-08-21 2017-06-27 Uop Llc Steady state high temperature reactor
US8933275B2 (en) 2012-08-21 2015-01-13 Uop Llc Production of oxygenates from a methane conversion process
US9308513B2 (en) 2012-08-21 2016-04-12 Uop Llc Production of vinyl chloride from a methane conversion process
US9370757B2 (en) 2012-08-21 2016-06-21 Uop Llc Pyrolytic reactor
US9023255B2 (en) 2012-08-21 2015-05-05 Uop Llc Production of nitrogen compounds from a methane conversion process
US9327265B2 (en) * 2012-08-21 2016-05-03 Uop Llc Production of aromatics from a methane conversion process
US9434663B2 (en) 2012-08-21 2016-09-06 Uop Llc Glycols removal and methane conversion process using a supersonic flow reactor
US9707530B2 (en) 2012-08-21 2017-07-18 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US8937186B2 (en) 2012-08-21 2015-01-20 Uop Llc Acids removal and methane conversion process using a supersonic flow reactor
CN110041455B (zh) * 2019-05-21 2021-06-25 南京工业大学 一种炔烃聚合的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2613208A (en) * 1949-06-29 1952-10-07 Rohm & Haas Tertiary aminomethylbenzenes
US2542417A (en) * 1949-12-10 1951-02-20 Gen Aniline & Film Corp Hexamethyl benzene compounds
BE567744A (de) * 1957-05-16
DE1159951B (de) * 1961-10-21 1963-12-27 Basf Ag Verfahren zur katalytischen Trimerisierung von Acetylenverbindungen
DE2103678A1 (de) * 1971-01-27 1972-08-17 Dynamit Nobel Ag
DE3379465D1 (en) * 1982-11-06 1989-04-27 Denki Kagaku Kogyo Kk Substituted cyclopentadienyl cobalt complexes and synthesis of pyridine homologues by means of the complexes
DE3819487A1 (de) * 1988-06-08 1989-12-14 Basf Ag Uebergangsmetallkomplexe
DE4205115C1 (de) * 1992-02-20 1993-08-26 Huels Ag, 4370 Marl, De
US5194538A (en) * 1992-07-15 1993-03-16 Polysar Corporation Preparation of butyl rubber with bimodal molecular weight distribution

Also Published As

Publication number Publication date
AU2135197A (en) 1997-10-10
US6225500B1 (en) 2001-05-01
PT888268E (pt) 2003-03-31
EP0888268A4 (de) 1999-06-09
CA2248352A1 (en) 1997-09-25
DE69716720T2 (de) 2003-06-12
EP0888268B1 (de) 2002-10-30
CA2248352C (en) 2008-04-15
ES2185912T3 (es) 2003-05-01
JP2007277256A (ja) 2007-10-25
WO1997034857A1 (en) 1997-09-25
AU715066B2 (en) 2000-01-13
JP2000506888A (ja) 2000-06-06
US5760266A (en) 1998-06-02
US5659069A (en) 1997-08-19
DK0888268T3 (da) 2003-03-03
EP0888268A1 (de) 1999-01-07
ATE226929T1 (de) 2002-11-15

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