DE69430873T2 - METHOD FOR TREATING TEXTILE PRODUCTS AND TEXTILE PRODUCTS TREATED WITH IT - Google Patents

METHOD FOR TREATING TEXTILE PRODUCTS AND TEXTILE PRODUCTS TREATED WITH IT

Info

Publication number
DE69430873T2
DE69430873T2 DE69430873T DE69430873T DE69430873T2 DE 69430873 T2 DE69430873 T2 DE 69430873T2 DE 69430873 T DE69430873 T DE 69430873T DE 69430873 T DE69430873 T DE 69430873T DE 69430873 T2 DE69430873 T2 DE 69430873T2
Authority
DE
Germany
Prior art keywords
textile products
treated
treating
stage
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69430873T
Other languages
German (de)
Other versions
DE69430873D1 (en
Inventor
Yasuo Itami
Tetsuya Masutani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
Original Assignee
Daikin Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries Ltd filed Critical Daikin Industries Ltd
Application granted granted Critical
Publication of DE69430873D1 publication Critical patent/DE69430873D1/en
Publication of DE69430873T2 publication Critical patent/DE69430873T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/2035Aromatic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845Aromatic mono- or polycarboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D06M13/21Halogenated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/213Perfluoroalkyl carboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243Mono-, di-, or triglycerides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/425Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D06M13/428Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes containing fluorine atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/11Oleophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Abstract

A fiber is firstly treated with a carboxylic acid-metal complex obtained from a metal salt and a carboxylic acid in a first stage, and then treated with a usual fluorine-containing water- and oil-repellent in a second stage. According to the present invention, the water-repellency which is durable to washing and friction is imparted to a textile, and the touch, the feeling and the flexibility of the textile itself are not deteriorated.
DE69430873T 1993-12-28 1994-12-27 METHOD FOR TREATING TEXTILE PRODUCTS AND TEXTILE PRODUCTS TREATED WITH IT Expired - Fee Related DE69430873T2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP5353613A JPH07197377A (en) 1993-12-28 1993-12-28 Method for treating fiber product and fiber product treated thereby
PCT/JP1994/002223 WO1995018258A1 (en) 1993-12-28 1994-12-27 Method of treating textile products and textile products thus treated

Publications (2)

Publication Number Publication Date
DE69430873D1 DE69430873D1 (en) 2002-08-01
DE69430873T2 true DE69430873T2 (en) 2002-11-28

Family

ID=18432034

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69430873T Expired - Fee Related DE69430873T2 (en) 1993-12-28 1994-12-27 METHOD FOR TREATING TEXTILE PRODUCTS AND TEXTILE PRODUCTS TREATED WITH IT

Country Status (7)

Country Link
EP (2) EP1039018A1 (en)
JP (1) JPH07197377A (en)
CN (1) CN1096522C (en)
AT (1) ATE219804T1 (en)
DE (1) DE69430873T2 (en)
TW (1) TW327198B (en)
WO (1) WO1995018258A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7931944B2 (en) 2003-11-25 2011-04-26 Kimberly-Clark Worldwide, Inc. Method of treating substrates with ionic fluoropolymers
US7811949B2 (en) 2003-11-25 2010-10-12 Kimberly-Clark Worldwide, Inc. Method of treating nonwoven fabrics with non-ionic fluoropolymers
EP2302130A1 (en) * 2009-09-26 2011-03-30 Huntsman Textile Effects (Germany) GmbH Compound for making fibre materials oil and/or water resistant
FR2954454B1 (en) * 2009-12-23 2012-02-10 Vallourec Mannesmann Oil & Gas TRIPULATIVE TUBULAR THREADED COMPONENT AND METHOD FOR COATING SUCH COMPONENT
CN102797148A (en) * 2012-08-30 2012-11-28 源达日化(天津)有限公司 Moth repellent for textile products
CN111041834B (en) * 2019-12-10 2022-09-23 上海驰纺材料科技有限公司 Preparation method of multifunctional super-soft cotton-containing knitted fabric

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3061473A (en) * 1960-06-23 1962-10-30 Stevens & Co Inc J P Process of and composition for producing improved textile materials having oil and water repellent and antistatic properties
GB1296255A (en) * 1970-03-26 1972-11-15
NL7505229A (en) * 1974-05-07 1975-11-11 Hoechst Ag METHOD AND MEANS FOR THE DIRT-REPELLENT AND ANTISTATIC FINISHING OF FIBER MATERIAL.
JPS598568A (en) * 1982-07-07 1984-01-17 Nissan Motor Co Ltd Kicking plate
JPS63105175A (en) * 1986-10-23 1988-05-10 カネボウ株式会社 Antistatic and water repellent processing of synthetic fiber structure
JPH03193975A (en) * 1989-12-22 1991-08-23 Minnesota Mining & Mfg Co <3M> Water-repellant oil-repellant treating agent
JP2796385B2 (en) * 1989-12-22 1998-09-10 ミネソタ マイニング アンド マニユフアクチユアリング カンパニー Water and oil repellent treatment agent
JPH0598568A (en) * 1991-10-09 1993-04-20 Senka Kk Treatment of animal hair fiber
ES2185626T3 (en) * 1992-01-27 2003-05-01 Daikin Ind Ltd USE OF A TREATMENT AGENT FOR FIBER PRODUCTS, PROCESSING PROCESSING OF FIBER PRODUCTS TREATED ACCORDING TO THIS PROCEDURE.

Also Published As

Publication number Publication date
EP0737773A1 (en) 1996-10-16
JPH07197377A (en) 1995-08-01
WO1995018258A1 (en) 1995-07-06
EP0737773B1 (en) 2002-06-26
CN1139965A (en) 1997-01-08
DE69430873D1 (en) 2002-08-01
ATE219804T1 (en) 2002-07-15
EP0737773A4 (en) 1998-06-10
TW327198B (en) 1998-02-21
CN1096522C (en) 2002-12-18
EP1039018A1 (en) 2000-09-27

Similar Documents

Publication Publication Date Title
ATE202956T1 (en) METHOD FOR TREATING CARPET YARN AND CARPETS
DE59009925D1 (en) Process for the photochemical stabilization of dyed polyamide fiber materials.
DE69112889D1 (en) Leather treatment and process for treating leather.
ATE127144T1 (en) METHOD AND DEVICE FOR THE THERMOLYSIS OF INDUSTRIAL AND/OR HOUSEHOLD WASTE.
DE69430873D1 (en) METHOD FOR TREATING TEXTILE PRODUCTS AND TEXTILE PRODUCTS TREATED WITH IT
ATE89333T1 (en) PROCESS FOR NITROCARBURIZING STEEL COMPONENTS.
DE59004629D1 (en) Process for smooth or deep rolling of multi-stroke crankshafts and machine for carrying out the process.
DE69816873D1 (en) METHOD FOR FLAME RESISTANT TEXTILE MATERIALS
ATE80422T1 (en) PROCESSES FOR WASHING AND/OR RINSEING TEXTILE MATERIALS AND APPARATUS THEREFORE.
DE3855382T2 (en) WASHING OUT AMMONIA
DE69723402D1 (en) Method and device for washing textiles and the like
DE69020659D1 (en) Process for the treatment of skins and skins thus obtained.
DE60107671D1 (en) METHOD FOR TREATING TEXTILES WHICH HIGH-NETWORKED ACRYLIC POLYMERS CONTAIN BEFORE STAINING; METHOD FOR STAINING TEXTILES; TEXTILE PRODUCT TREATED BEFORE STAINING; AS WELL AS TEXTILE PRODUCT
DE602004031738D1 (en) PROCESS FOR PROVIDING A WASH-FREE WASHING FUNCTION
DE69520946T2 (en) Process for treating textile fabrics with foam
DE69520380D1 (en) Process for the wet surface treatment of continuous textile goods
ATE135342T1 (en) METHOD FOR PRODUCING DIACETYLRHEIN
DE69025503T2 (en) Process for the surface treatment of carbon fiber strands
DE69426025D1 (en) METHOD FOR TREATING TEXTILES
ATE279569T1 (en) METHOD FOR PRODUCING TEXTILE PRE- OR FINAL TEXTILE PRODUCTS WITH AT LEAST PARTIAL FLUORESCENCE RADIATION
DE69302758D1 (en) Process for the treatment of soil contaminated with hydrocarbons
DE59102285D1 (en) METHOD FOR DECONTAMINATING POLLUTED, LOOSE, PIECE OF GOODS.
ATE8065T1 (en) PROCESS FOR TREATMENT OF TEMPLATE GAZE WITH AT LEAST ONE WHITE TONER.
DE69007880D1 (en) Process for treating textiles.
DE69006109T2 (en) Composition for the non-felting treatment of wool and finishing process.

Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee