DE69417621D1 - Catalyst support and catalyst for alpha olefin polymerization; Process for their preparation and polymerization of alpha olefins in the presence of the catalyst - Google Patents

Catalyst support and catalyst for alpha olefin polymerization; Process for their preparation and polymerization of alpha olefins in the presence of the catalyst

Info

Publication number
DE69417621D1
DE69417621D1 DE69417621T DE69417621T DE69417621D1 DE 69417621 D1 DE69417621 D1 DE 69417621D1 DE 69417621 T DE69417621 T DE 69417621T DE 69417621 T DE69417621 T DE 69417621T DE 69417621 D1 DE69417621 D1 DE 69417621D1
Authority
DE
Germany
Prior art keywords
catalyst
alpha
polymerization
preparation
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69417621T
Other languages
German (de)
Other versions
DE69417621T2 (en
Inventor
Jean-Louis Costa
Vincent Laurent
Philippe Francois
Dirk Vercammen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Manufacturing Belgium NV
Solvay SA
Original Assignee
Solvay Polyolefins Europe Belgium SA
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Polyolefins Europe Belgium SA, Solvay SA filed Critical Solvay Polyolefins Europe Belgium SA
Application granted granted Critical
Publication of DE69417621D1 publication Critical patent/DE69417621D1/en
Publication of DE69417621T2 publication Critical patent/DE69417621T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/027—Polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

Catalyst support containing an alpha -olefin polymer in the form of particles of mean size from 5 to 350 mu m in which the pore volume produced by the pores of radius from 1000 to 75,000 ANGSTROM is at least 0.2 cm<3>/g. Catalyst usable for the polymerisation of alpha -olefins, including a compound containing at least one transition metal belonging to groups IIIb, IVb, Vb and VIb of the Periodic Table, bound into or onto this support.
DE69417621T 1993-05-25 1994-05-18 Catalyst support and catalyst for alpha olefin polymerization; Process for their preparation and polymerization of alpha olefins in the presence of the catalyst Expired - Fee Related DE69417621T2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE9300539A BE1007040A3 (en) 1993-05-25 1993-05-25 CATALYST SUPPORT AND ALPHA-OLEFIN POLYMERIZATION CATALYST; PROCESSES FOR THEIR PRODUCTION AND POLYMERIZATION OF ALPHA-OLEFINS IN THE PRESENCE OF THE CATALYST.

Publications (2)

Publication Number Publication Date
DE69417621D1 true DE69417621D1 (en) 1999-05-12
DE69417621T2 DE69417621T2 (en) 1999-10-21

Family

ID=3887068

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69417621T Expired - Fee Related DE69417621T2 (en) 1993-05-25 1994-05-18 Catalyst support and catalyst for alpha olefin polymerization; Process for their preparation and polymerization of alpha olefins in the presence of the catalyst

Country Status (25)

Country Link
US (4) US5556893A (en)
EP (1) EP0627447B1 (en)
JP (1) JPH06329715A (en)
KR (1) KR100314793B1 (en)
CN (1) CN1078892C (en)
AT (1) ATE178617T1 (en)
AU (1) AU681125B2 (en)
BE (1) BE1007040A3 (en)
BR (1) BR9402065A (en)
CA (1) CA2124176A1 (en)
CZ (1) CZ289915B6 (en)
DE (1) DE69417621T2 (en)
DK (1) DK0627447T3 (en)
ES (1) ES2132322T3 (en)
FI (1) FI112244B (en)
HK (1) HK1013658A1 (en)
HU (1) HU221058B1 (en)
NO (1) NO308168B1 (en)
PH (1) PH31214A (en)
RO (1) RO112875B1 (en)
RU (1) RU2131439C1 (en)
SG (1) SG54161A1 (en)
SK (1) SK281610B6 (en)
TW (1) TW294617B (en)
ZA (1) ZA943656B (en)

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BE1007040A3 (en) * 1993-05-25 1995-02-28 Solvay CATALYST SUPPORT AND ALPHA-OLEFIN POLYMERIZATION CATALYST; PROCESSES FOR THEIR PRODUCTION AND POLYMERIZATION OF ALPHA-OLEFINS IN THE PRESENCE OF THE CATALYST.
FR2717816B1 (en) 1994-03-23 1996-04-26 Atochem Elf Sa Catalytic component for the polymerization of olefins obtained by impregnating a prepolymer with a solution of a catalytic component. Prepolymer and polymer obtained from said catalytic component.
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
HUP0102282A3 (en) * 1998-05-18 2002-06-28 Phillips Petroleum Co Catalyst composition for polymerizing monomers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
BE1012364A3 (en) * 1998-12-22 2000-10-03 Solvay Method for preparing a catalyst composition for polymerization of alpha-olefins, catalyst composition obtained and method of using the polymerization catalyst composition
BE1012363A3 (en) * 1998-12-22 2000-10-03 Solvay Method for the preparation of a catalyst for polymerization of alpha-olefins, catalyst obtained and method of using polymerization catalyst as.
BE1012568A3 (en) 1999-03-24 2000-12-05 Solvay METHOD FOR CURING alpha-olefins.
ITMI991552A1 (en) * 1999-07-14 2001-01-14 Licio Zambon CATALYST COMPONENTS FOR OLEFINE POLYMERIZATION
US6403520B1 (en) 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
JP2004516365A (en) * 2000-12-22 2004-06-03 バセル ポリオレフィン イタリア エス．ピー．エー． Method for producing porous polymer and polymer obtained therefrom
EP1231224B1 (en) * 2001-02-07 2004-08-11 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins and method for preparing the same
JP2005510590A (en) * 2001-11-27 2005-04-21 バセル ポリオレフィン ジーエムビーエイチ Method of processing a polymer composition
WO2003046023A1 (en) * 2001-11-27 2003-06-05 Basell Poliolefine Italia S.P.A. Porous polymers of propylene
BR0116888A (en) * 2001-12-19 2004-06-22 Pirelli Method for manufacturing a vehicle wheel tire, semi-finished product of elastomeric material, and vehicle tubeless tire
US20040005445A1 (en) * 2002-07-02 2004-01-08 Ou Yang David T. Colored multi-layer films and decorative articles made therefrom
EP1380601B1 (en) * 2002-07-12 2005-05-25 Saudi Basic Industries Corporation Supported Ziegler - metallocene catalyst composition and process for olefin polymerization and olefin copolymerization with alpha olefins using novel catalyst systems
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP4972284B2 (en) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク Multiple catalyst systems for olefin polymerization and polymers produced therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US6933353B2 (en) * 2003-07-07 2005-08-23 Equistar Chemicals, Lp Olefin polymerization process
US20070276095A1 (en) * 2003-09-11 2007-11-29 Basell Polyolefine Gmbh Multistep Process for Preparing Heterophasic Propylene Copolymers
WO2013036211A1 (en) * 2011-09-05 2013-03-14 Ptt Global Chemical Public Company Limited High activity olefin polymerization catalyst comprising boron-containing silica support and the preparation thereof
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
CN114591455B (en) * 2020-12-03 2023-10-31 中国石油天然气股份有限公司 Catalyst, preparation method thereof and olefin polymerization catalyst system

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Also Published As

Publication number Publication date
ES2132322T3 (en) 1999-08-16
HUT69050A (en) 1995-08-28
EP0627447A1 (en) 1994-12-07
SG54161A1 (en) 2001-12-19
DE69417621T2 (en) 1999-10-21
NO308168B1 (en) 2000-08-07
CN1078892C (en) 2002-02-06
SK281610B6 (en) 2001-05-10
ZA943656B (en) 1995-01-26
EP0627447B1 (en) 1999-04-07
HU221058B1 (en) 2002-07-29
HK1013658A1 (en) 1999-09-03
PH31214A (en) 1998-05-05
FI112244B (en) 2003-11-14
RU2131439C1 (en) 1999-06-10
US5556893A (en) 1996-09-17
US6524986B2 (en) 2003-02-25
NO941923D0 (en) 1994-05-24
CN1100343A (en) 1995-03-22
TW294617B (en) 1997-01-01
CZ127094A3 (en) 1994-12-15
AU6322594A (en) 1994-12-01
ATE178617T1 (en) 1999-04-15
BR9402065A (en) 1994-12-20
FI942427A (en) 1994-11-26
JPH06329715A (en) 1994-11-29
CZ289915B6 (en) 2002-04-17
RO112875B1 (en) 1998-01-30
CA2124176A1 (en) 1994-11-26
BE1007040A3 (en) 1995-02-28
SK60594A3 (en) 1995-02-08
KR100314793B1 (en) 2002-06-22
AU681125B2 (en) 1997-08-21
NO941923L (en) 1994-11-28
US6221802B1 (en) 2001-04-24
HU9401573D0 (en) 1994-08-29
DK0627447T3 (en) 1999-10-25
FI942427A0 (en) 1994-05-25
US5756613A (en) 1998-05-26
US20010014727A1 (en) 2001-08-16

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